2022 MERCEDES-BENZ S-CLASS SALOON LONG Owners Manual

Frequency band Maximum transmis-
sion output
70!

Vehicle
identiNcation plat e, VIN and engine num-
ber overview
Vehicle identiNcation plate Vehicle
identiNcation plat
e (example: Kuwait)
1 Vehicle manufacturer
2 Place of manufacture
3 Manufacturing date
4 Paint code
5 VIN (vehicle identiNcation number) Vehicle
identiNcation plat e (example: all other
countries)
1 Vehicle manufacturer
2 EU general operating permit number (only for
cer

tain countries)
3 VIN (vehicle identiNcation number)
4 Maximum permissible gross vehicle weight
(k
g) Technical data
487

5
Maximum permissible gross weight of vehicle
combination (k g) (for certain countries only,
optional)
6 Maximum permissible front axle load (kg)
7 Maximum permissible rear axle load (kg)
8 Paint code
% The data shown in the illustration is example
dat
a.
VIN at the lower edge of the windscreen 1
VIN (vehicle identiNcation number)
The VIN at the lower edge of the windscreen is
onl
y available in some countries. VIN in the engine compartment
1
VIN (vehicle identiNcation number)
Engine number
The engine number is s
tamped into the crank-
case.
% Further information can be obtained at a
q

ualiNed specialist workshop. Operating Ouids
Notes on operating
Ouids &
WARNING Risk of injur
y from operating
Ouids harmful to your health
Operating Ouids ma
y be poisonous and harm-
ful to your health. 
Observe the text on the original contain-
er
s when using, storing or disposing of
operating Ouids. 
Always store operating Ouids sealed in
t
heir original containers. 
Always keep children away from operat-
ing Ouids. +
ENVIRONMENTAL NOTE
P
ollution of the
environment due to irresponsible disposal
of operating Ouids Incorrect disposal of operating
Ouids can
cause consider
able damage to the environ-
ment. 488
Technical data


Dispose of operating Ouids in an en viron-
mentally responsible manner. Operating Ouids
include t
he following:
= fuels
= DeNOx agent AdBlue n
for exhaust gas aser-
treatment
= lubricants
= coolant
= Brake Ouid
= windscreen washer Ouid
= climate control system refrigerant
Only use products approved by Mercedes-Benz.
Damage caused by the use of products that have
not been approved is not covered by the
Mercedes-Benz warranty or goodwill gestures.
The operating Ouids approved by Mercedes-Benz
can be identiNed by the following inscriptions on
the container:
= MB-Freigabe (e.g. MB-Freigabe 229.51)
= MB-Approval (e.g. MB-Approval 229.51) Further information on approved operating
Ouids
= in t

he Mercedes-Benz SpeciNcations for Oper-
ating Fluids by entering the designation
- at https://bevo.mercedes-benz.com
- in the Mercedes-Benz BeVo App
= At a qualiNed specialist workshop &
WARNING Risk of Nr
e or explosion from
fuel
Fuels are highly Oammable. 
Fire, naked Oames, smoking and cr
eating
sparks must be avoided. 
Before and during refuelling, switch oM
t

he vehicle and, if Ntted, the stationary
heater. &
WARNING Risk of injur
y from fuels
Fuels are poisonous and hazardous to your
healt
h. 
Do not swallow fuel or let it come into
cont

act with skin, eyes or clothing. 
Do not inhale fuel vapour. 
Keep children away from fuel. 
Keep doors and windows closed during
t

he refuelling process.
If you or other people come into contact with
fuel, obser
ve the following: 
Immediately rinse fuel oM y
our skin with
soap and water. 
If fuel comes into contact with your eyes,
immediat
ely rinse them thoroughly with
clean water. Seek medical attention
immediately. 
If you swallow fuel, seek medical atten-
tion immediat

ely. Do not induce vomit-
ing. 
Change immediately out of clothing that
has come int
o contact with fuel. Flexible-fuel vehicles can be refuelled with the fol-
lo

wing fuel types:
= unleaded petrol
= E85 fuel Technical data
489

=
a mixtur e of E85 fuel and unleaded petrol
Flexible-fuel vehicles can be identiNed by the
Ethanol up to E85 sticker on the inside of the fuel
Nller Oap.
Depending on the country, the fuels you can use
in your vehicle may diMer from the information in
the Owner's Manual. The fuels that have been
approved for your vehicle can be found on the
instruction label on the inside of the fuel Nller Oap.Fuel
Information on fuel quality for vehicles with a pet-
r
ol engine
Observe the notes on operating Ouids
(  page 488).
* NOTE Damag
e caused by the wrong fuel Even small amounts of the wrong fuel could
r

esult in damage to the fuel system, the
engine and the emission control system. 
Only refuel using unleaded, sulphur-free
spar
k-ignition engine fuel that conforms to European EN 228, or an equivalent
speciNcation.
Fuel of this speciNcation ma
y contain up to
10% ethanol by volume. Your vehicle is suita-
ble for use with E10 fuel. 
See the information label in fuel Nller Oap
f
or other compatible fuels .
Never refuel with one of the following fuels: = Diesel
= R

egular petrol with an octane number
lower than 91 RON
= Petrol with more than 3% methanol by vol-
ume, e.g. M15, M30
= Petrol with additives containing metal
If you have accidentally refuelled with the
wrong fuel: 
Do not switch on the vehicle. 
Consult a q
ualiNed specialist workshop. According to European standard EN 16942, you
can Nnd t

he compatibility indications at the fol-
lowing locations:
= On the vehicle on the information label in the
fuel Nller Oap
= On the fuel dispenser or pump nozzle suitable
for your vehicle throughout Europe 1
For petrol with a maximum of 5% ethanol by
v
olume
2 For petrol with a maximum of 10% ethanol by
v
olume
If the available fuel is not suPcientl
y low in sul-
phur, it may produce unpleasant odours. 490
Technical data

Recommended fuel: t
he recommended octane
number for your vehicle can be found on the infor-
mation label on the fuel Nller Oap ( page 233).
% Vehicles with petrol engine M256: when using
95 R
ON, there may be slight limitations in per-
formance that have no further consequences.
All models: if y
ou wish to achieve maximum
engine output, refuel using only super unleaded
petrol with an octane number of at least 98 RON.
Alternatively, you can also refuel using premium-
grade petrol with an octane number of at least
95 RON.
All models: as a temporary measure, if the recom-
mended fuel is not available, you may also use
regular unleaded petrol with an octane number of
at least 91 RON. This may reduce engine output
and increase fuel consumption.
Never refuel using petrol with a lower RON.
Further information on fuel can be obtained at a
Nlling station or a qualiNed specialist workshop. Information on additives in petrol (vehicles with
pe

trol engine)
Observe the notes on operating Ouids
(  page 488).
* NOTE Damag
e from use of unsuitable
additives Even small amounts of the wrong additive may
lead t
o malfunctions occurring. 
Only add cleaning additives recommen-
ded b

y Mercedes-Benz to the fuel. Mercedes-Benz recommends that you use brand-
name fuels wit

h additives.
In some countries, the fuel available may not have
suPcient additives. Deposits could build up in the
fuel injection system as a result. In this case, in
consultation with a Mercedes-Benz service
centre, mix the fuel with the cleaning additive rec-
ommended by Mercedes-Benz. Observe the notes
and mixing ratios indicated on the tank. Information on fuel quality for vehicles with a die-
sel engine
Gener

al notes
Observe the notes on operating Ouids
(  page 488). &
WARNING Risk of Nr
e from fuel mixture
If you mix diesel fuel with petrol, the Oash
point of t
he fuel mixture is lower than that of
pure diesel fuel. 
Never refuel using petrol in diesel
engines. 
Never mix petrol with diesel fuel. *
NOTE Damag
e caused by the wrong fuel Even small amounts of the wrong fuel could
r

esult in damage to the fuel system, the
engine and the emission control system.
Vehicles with a diesel particulate Nlter Technical data
491


Only refuel using sulphur-free diesel fuel
t
hat conforms to European standard
EN 590, or an equivalent speciNcation.
In countries without sulphur-free diesel
fuel, refuel using only low-sulphur diesel
fuel with a sulphur content less than
50 ppm.
Vehicle without diesel particulate Nlt
er
Only refuel using diesel fuel with a sul-
phur cont

ent less than 500 ppm.
Never refuel with one of the following fuels: = P

etrol
= Marine diesel
= Heating oil
= Pure fatty acid methyl ester or vegetable
oil
= ParaPn or kerosene
If you have accidentally refuelled with the
wrong fuel: 
Do not switch on the vehicle. 
Consult a q
ualiNed specialist workshop. The following compatibility indications for fuel
appl

y to your vehicle: 1
For diesel fuel with a maximum of 7% fatty
acid me
thyl ester by volume (bio-diesel)
2 For diesel fuel with a maximum of 10% fatty
acid me
thyl ester by volume (bio-diesel)
According to European standard EN 16942 you
can Nnd t

he compatibility indications at the fol-
lowing locations:
= On the vehicle on the information label on the
fuel Nller Oap ( page 233) =
On t
he fuel dispenser or pump nozzle suitable
for your vehicle throughout Europe
Information on low outside temperatures
Refuel your vehicle with as much winter diesel fuel
as possible at the beginning of winter.
Before changing over to winter diesel fuel, the fuel
tank should be empty, if possible. When Nrst refu-
elling with winter diesel fuel, keep the fuel level
low, e.g. to reserve level. The fuel tank can be Nl-
led as usual when next refuelling.
Further information on fuel can be obtained at a
Nlling station or a qualiNed specialist workshop.
Tank content and fuel reserve
The total capacity of the fuel tank may vary,
depending on the vehicle equipment.
Not for plug-in hybrid: 492
Technical data

Total fuel tank capacity
Model
S 580 4MATIC
76.0 litres
All other models 65.0 litres
or
76.0 litr
es Fuel tank reserve
Model
All models
8.0 litresPlug-in hybrid:
T

otal fuel tank capacity Model
S 580 e
S 580 e 4MA

TIC 67.0 litres Fuel tank reserve
Model
S 580 e
S 580 e 4MA

TIC 8.0 litres AdBlue
n
(v
ehicles with a diesel engine only) Notes on AdBlue
n
Obser
ve the notes on operating Ouids
(  page 488).
AdBlue n
is a water-soluble Ouid for the NOx
exhaust gas asertreatment of diesel engines.
It may be improper or punishable in some coun-
tries to operate a vehicle that uses no AdBlue n
or
one that does not comply with the speciNcations
of this Owner's Manual. *
NOTE Malfunctions due t
o the dilution of
AdBlue n
or the use of additive-enhanced
AdBlue n The function of the NOx exhaust gas
aser
-
treatment can be impaired by the use of
unsuitable denoxiNcation agents. 
Only use AdBlue n
in accor
dance with
ISO 22241. 
Do not dilute AdBlue n
wit
h water. 
Do not use additive-enhanced AdBlue n
. *
NOTE Damag
e and malfunctions due to
impurities in AdBlue n Consequences of impurities in AdBlue
n
:
= incr

eased emission values
= damage to the catalytic converter
= NOx exhaust gas asertreatment malfunc-
tions 
Avoid impurities in AdBlue n
. Technical data
493