Page 1 of 542
S-Class
Operator's Manual
Order no. 6515 2380 13 Part no. 221 584 02 96 Edition A 2013É2215840296ÆËÍ
2215840296S-Class Operator's Manual
Page 2 of 542

Publication details
Internet
Further information about Mercedes-Benz
vehicles and about Daimler AG can be found
on the following websites:
http://www.mbusa.com (USA only)
http://www.mercedes-benz.ca (Canada
only) Editorial office
Not to be reprinted, translated or otherwise
reproduced, in whole or in part, without the
written permission of Daimler AG.
Symbols
Registered trademarks:
R
Bluetooth ®
is a registered trademark of
Bluetooth SIG Inc.
R DTS is a registered trademark of DTS, Inc.
R Dolby and MLP are registered trademarks
of DOLBY Laboratories.
R BabySmart™, ESP ®
and PRE-SAFE ®
are
registered trademarks of Daimler AG.
R HomeLink ®
is a registered trademark of
Prince.
R iPod ®
and iTunes ®
are registered
trademarks of Apple Inc.
R Logic7 ®
is a registered trademark of
Harman International Industries.
R Microsoft ®
and Windows media ®
are
registered trademarks of Microsoft
Corporation.
R SIRIUS is a registered trademark of Sirius
XM radio Inc.
R HD Radio is a registered trademark of
iBiquity Digital Corporation.
R Gracenote ®
is a registered trademark of
Gracenote, Inc.
R ZAGATSurvey ®
and related brands are
registered trademarks of ZagatSurvey,
LLC.
In this Operator's Manual, you will find the
following symbols: G
WARNING
Warning notes draw your attention to hazards
that endanger your health or life, or the health
or life of others. H
Environmental note
Environmental notes provide you with
information on environmentally aware actions
or disposal.
! Notes on material damage alert you to
dangers that could lead to damage to your
vehicle. i
Practical tips or further information that
could be helpful to you.
X This symbol indicates an
instruction that must be followed.
X Several of these symbols in
succession indicate an instruction
with several steps.
(Y page) This symbol tells you where you
can find more information about a
topic.
YY This symbol indicates a warning or
an instruction that is continued on
the next page.
Display
Display This font indicates a display in the
multifunction display/COMAND
display.
Parts of the software in the vehicle are
protected by copyright ©
2005
The FreeType Project
http://www.freetype.org. All rights
reserved.
As at 14.11.2011
Page 3 of 542

Welcome to the world of Mercedes-Benz
Before you drive off, please familiarize
yourself with yourv ehicle and read this
manual, especially the safety and warning
notes. This will help you to obtain the
maximum pleasure from your vehicle and
avoid endangering yourself and others.
The equipment or model designation of your
vehicle may differ according to:
R model
R order
R country variant
R availability
Mercedes-Benz is constantly updating its
vehicles to the state of the art.
Mercedes-Benz therefore reserves the right
to introduce changes in the following areas:
R design
R equipment
R technical features
The equipment in your vehicle may therefore
differ from that shown in the descriptions and
illustrations.
The following are integral components of the
vehicle:
R Operator's Manual
R Maintenance Booklet
R Equipment-dependent supplements
Keep these documents in the vehicle at all
times. If you sell the vehicle, always pass the
documents on to the new owner.
The technical documentation team at
Daimler AG wishes you safe and pleasant
motoring.
Mercedes-Benz USA, LLC
Mercedes-Benz Canada, Inc.
AD aimler Company
2215840296É2215840296ÆËÍ
Page 4 of 542
Page 5 of 542
Index
....................................................... 4Introduction
......................................... 28 At
ag lance ........................................... 35 Safety
................................................... 47 Opening/closing
................................. 81 Seats, steering wheel and mirrors
..105 COMAND
............................................ 119 Lights and windshield wipers
..........279 Climate control
................................. 293 Driving and parking
..........................305 On-board computer and displays
....373 Stowage and features
......................437 Maintenance and care
......................461 Breakdown assistance
.....................477 Wheels and tires
............................... 497 Technical data
................................... 527 Contents
3
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1, 2, 3 ...
115 Vsocket ...................................... 448
12 Vsocket
see Sockets
4ETS
see ETS/4ETS (Electronic
Tractio nSystem)
4MATIC (permanent four-wheel
drive) .................................................. 350
4MATIC off-road system ...................350 A
ABC see Active Body Control (ABC)
ABS (Anti-lock Braking System)
Display message ............................ 391
Function/notes ................................ 73
Important safety notes ....................73
Warning lamp ................................. 428
Activating/deactivating cooling
with air dehumidification .................297
Active Blin dSpot Assist
Activating/deactivating (on-
board computer) ............................ 387
Display message ............................ 416
Function/informatio n.................... 367
Active Body Control (ABC)
Display message ............................ 414
Function/notes ............................. 348
Active Driving Assistance package .366
Active Lane Keeping Assist Activating/deactivating (on-
board computer) ............................ 387
Display message ............................ 415
Function/informatio n.................... 369
Active multicontour seat ..........112, 276
Active service syste mPLUS
see ASSYS TPLUS service interval
display
ADAPTIVE BRAKE .................................77
Adaptive Damping System (ADS) .....3 48
Adaptive Highbeam Assist Display message ............................ 408
Function/notes ............................. 284
Switching on/off (on-board
computer) ...................................... 388Additional speedometer
...................388
Additives (engine oil) ........................535
Address Entering (example )......................... 157
see Addres sbook
Address book
Calling up ....................................... 209
Connecting acall........................... 212
Creating an entry ........................... 210
Deleting an entry ........................... 211
Entering characters .......................136
Entry as ahome address ...............182
Importing contacts ........................208
Introduction ................................... 207
Starting route guidance .................212
Voice tag ....................................... 213
Airb ags
Display message ............................ 403
Front air bag (driver, front
passenger )....................................... 52
Important safety notes ....................50
PASSENGER AIR BAG OFF
indicator lamp .................................. 54
Safety guidelines ............................. 49
Side impact airb ag.......................... 52
Windo wcurtain air bag .................... 53
Air-conditioning system
see Climate control
Aird istribution
Settin g........................................... 299
Setting (COMAND) .........................270
Airf ilter (display message) ..............411
Airflow Setting ........................................... 299
Setting (COMAND) .........................271
AIRMATIC
Display message ............................ 413
Function/notes ............................. 347
Air pressure
see Tire pressure
Airv ents
Glove box ....................................... 303
Important safet ynotes .................. 302
Rea r............................................... 303
Setting ........................................... 302
Setting the center air vents ...........302
Setting the side air vents ...............303 4
Index
Page 7 of 542

Alarm system
see ATA (Anti-Theft Alarm system)
Alertness Assistant
see ATTENTION ASSIST
Alternative route ............................... 175
Ambient light setting (COMAND) .....268
AMG menu (on-board computer) .....381
Anticipatory occupant protection
see PRE-SAFE ®
(anticipatory
occupant protection)
Anti-loc kBraking System
see ABS (Anti-lock Braking System)
Anti-Theft Alarm system
see ATA (Anti-Theft Alarm system)
Ashtray ............................................... 446
Assistance menu (on-board
computer) .......................................... 385
ATA (Anti-Theft Alarm system) Activating/deactivating ...................79
Function .......................................... .79
Switching off the alarm ....................79
ATTENTIO NASSIST
Activating/deactivating .................386
Display message ............................ 412
Function/notes ............................. 359
Audio
Radio mode ................................... 215
Audio database
see MUSIC REGISTER
Audio DVD
Mode ,switchin gto........................ 226
Pause function ............................... 227
Playback options ........................... 232
Safety notes .................................. 225
Setting the audio forma t................ 232
Stop function ................................. 228
Audio format, setting
Audi oDVD ..................................... 232
Rear Seat Entertainment System ...262
Video DVD ..................................... 249
Audio menu (on-board computer) ....380
Authorized Mercedes-Benz Center see Qualified specialist workshop
Authorized workshop
see Qualified specialist workshop AUTO lights
Display message ............................ 408
see Lights
Automatic engine start (ECO start/
stop function) .................................... 311
Automatic engine switch-off (ECO
start/stop function) ..........................311
Automatic headlamp mode ..............281
Automatic transmission Automatic drive program ...............318
Changing gea r............................... 317
DIRECT SELECT leve r..................... 314
Display message ............................ 422
Drive position (ECO start/stop
function) ........................................ 315
Driving tips .................................... 317
Emergency running mode ..............321
Engaging drive position .................. 316
Engaging neutra l............................ 315
Engaging revers egear ................... 314
Engaging the par kposition ............ 314
Kickdow n....................................... 317
Manual drive program ....................319
Neutral (ECO start/stop function) .315
Problem (malfunction) ...................321
Progra mselector button ................317
Pulling away ................................... 309
Shift range s................................... 318
Starting the engine ........................309
Steering wheel paddle shifters ......318
Transmission position displa y........ 316
Transmissio npositions .................. 316
Automatic transmission
emergency mode ............................... 321
Autostore ........................................... 217
see Station memory (radio)
AUX (audio)
Notes/socket ................................ 243
Switching to ................................... 244
AUX (video)
Setting the picture .........................244
Setting the volume and sound .......250
Showing/hiding the menu .............250
Switching to ................................... 250 Index
5
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B
Back button ....................................... 123
Back support see Lumbar support
Bag hook ............................................ 441
Balance, adjusting .............................139
Bang &Olufsen sound system .........141
BAS (Brake Assist System) .................74
Basic carriers see Separate operating instructions
Basic settings
see Settings
BAS PLUS (Brake Assist System
PLUS) .................................................... 74
Bass, setting ...................................... 139
Battery (SmartKey) Checking .......................................... 85
Important safety notes ....................85
Replacing ......................................... 85
Battery (vehicle)
Charging ........................................ 486
Display message ............................ 410
Important safety notes ..................484
Jump starting ................................. 488
Belt
see Seat belts
Bird's-eye view (navigation) .............188
Blind see Roller sunblind
Blin dSpot Assist
Activating/deactivating .................387
Display message ............................ 416
Notes/function .............................. 363
see Active Blind Spot Assist
BlueTEC
Adding DEF .................................... 325
BlueTEC (DEF) .................................... 533
Bluetooth ®
Activating/deactivating .................151
Authorizing a device (registering) ..152
Conditions (general )...................... 151
Conditions (telephone ).................. 199
Connecting another mobile phone .201
Connecting devices .......................151
De-authorizing (de-registering) a
device ............................................ 153
External authorization (general) .....153 External authorization (telephone)
.201
General information .......................151
Introduction ................................... 197
Receiving vCards ........................... 208
Searching for devices ....................152
Settings ......................................... 151
Telephone basic menu ...................202
Telephony ...................................... 199
Telephony notes ............................ 197
Bluetooth ®
interface
Telephony ...................................... 197
Brake Assist System
see BAS (Brake Assist System)
Brake fluid
Display message ............................ 399
Notes ............................................. 535
Brake fluid level ................................ 468
Brake lamps Display message ............................ 406
Brakes
ABS .................................................. 73
BAS .................................................. 74
BAS PLUS ........................................ 74
Brake fluid (notes) .........................535
Display message ............................ 391
Driving tips .................................... 331
High-performance brake system ....333
Important safety notes ..................331
Maintenance .................................. 332
Parking brake ................................ 328
Warning lamp ................................. 427
Breakdown
see Flat tire
see Towing away
Brightness, setting (TV, video) .........244
Bulbs see Changing bulbs C
California Important notice for retail
customers and lessees ....................29
Call
Accepting/ending/rejecting .......... 203
see Telephone
Calling up a malfunction
see Display messages 6
Index