R
It is important that you observe the descri-
bed order of the battery terminals when
connecting and disconnecting a battery.
R When jump-starting, make sure that the
battery poles with identical polarity are
connected.
R It is particularly important to observe the
described order when connecting and dis-
connecting the jump leads.
R Never connect or disconnect the battery
terminals while the engine is running. G
WARNING
Battery acid is caustic. There is a risk of injury. Avoid contact with the skin, eyes or clothing.
Do not breathe in any battery gases. Do not
lean over the battery. Keep the batteries out
of the reach of children. Immediately rinse off
battery acid thoroughly with plenty of clean
water and seek medical attention at once. H
Environmental note Batteries contain pollutants.
It is illegal to dispose of them with the household rubbish.
They must be collected sep-
arately and disposed of in anenvironmentally responsible
recycling system. Dispose of batteries in an
environmentally responsible
manner. Take discharged
batteries to a qualified spe-
cialist workshop or to a col-
lection point for used batter-
ies.
! Have the battery checked regularly at a
qualified specialist workshop.
Observe the service intervals in the Service
Booklet or contact a qualified specialist work- shop for more information. !
Always have work on the batteries carried
out at a qualified specialist workshop. Should
it, in exceptional circumstances, be abso-
lutely necessary to disconnect the 12-volt
battery yourself, please observe the follow-
ing:
R secure the vehicle to prevent it from rolling
away.
R switch the ignition off.
R first, disconnect the negative terminal, fol-
lowed by the positive terminal.
The transmission is locked in position Pafter
disconnecting the battery.
After the work has been completed, firmly
reinstall the battery and the cover of the pos- itive terminal.
Comply with safety precautions and take pro-
tective measures when handling batteries. Risk of explosion
Fire, naked flames and smoking are
prohibited when handling the bat-
tery. Avoid creating sparks. Battery acid is caustic. Avoid contact
with the skin, eyes or clothing.
Wear suitable protective clothing; in
particular, gloves, an apron and a
face mask.
Immediately rinse acid splashes off
with clean water. Consult a doctor if necessary. Wear eye protection.
Keep children at a safe distance.
Observe this Owner's Manual.
For safety reasons, Mercedes-Benz recom-
mends that you use only batteries that have
been tested and approved for your vehicle by
Mercedes-Benz. These batteries provide
increased impact protection to prevent vehicle 352
Battery (vehicle)Breakdown assistance
R
paraffin
R kerosene
Do not mix such fuels with diesel fuel and do
not use any special additives. Otherwise,
engine damage may occur.
! Vehicles with diesel particle filters:
in
countries outside the EU, only use low sulphur
Euro diesel with a sulphur content of under
50 ppm. Otherwise, the emission control sys- tem could be damaged.
! Vehicles without a diesel particle filter:
in countries where only diesel fuel with a high
sulphur content is available, you will need to
carry out your vehicle's oil change at shorter
intervals. More information about the interval for oil change can be obtained from any quali-
fied specialist workshop.
Usually you will find information about the fuel
grade on the pump. If you cannot find the label
on the petrol pump, ask the filling station staff.
Information on refuelling (Y page 164).
Low outside temperatures In winter months, diesel fuel with an improved
cold flow quality is available. In Europe, the
EN 590 standard defines various climate-
dependent temperature categories. Malfunc-
tions can be avoided by refuelling with diesel
fuel that corresponds to the climatic specifica-
tions outlined in EN 590. At unusually low out-
side temperatures, it is possible that the flow
characteristics of the diesel fuel could be insuf- ficient. Accordingly, diesel fuel from warmer
areas may not be suitable for operation in colder climatic conditions.
i Further information on country-specific fuel
properties and fuel types with low-tempera-
ture resistance can be obtained from oil com-
panies, e.g. at filling stations. AdBlue
®
Important safety notes Comply with the important safety notes for ser-
vice products when handling AdBlue ®
(Y page 381). AdBlue
®
is a water-soluble fluid for the exhaust
gas aftertreatment of diesel engines. It is:
R non-toxic
R colourless and odourless
R non-flammable
If you open the AdBlue ®
tank, small amounts of
ammonia vapour may be released.
Ammonia vapours have a pungent odour and are
particularly irritating to the skin, mucous mem-
branes and eyes. You may experience a burning sensation in your eyes, nose and throat. You
may also experience coughing and watery eyes.
Do not inhale any ammonia vapours that may be
released. Fill the AdBlue ®
tank only in well-ven-
tilated areas.
Low outside temperatures AdBlue
®
freezes at a temperature of approx-
imately -11 †. The vehicle is delivered from the
factory equipped with an AdBlue ®
preheating
system. Winter operation can thus be guaran-
teed even at temperatures below -11 †.
Additives !
Only use AdBlue ®
in accordance with ISO
22241. Do not use additives with AdBlue ®
and do not dilute AdBlue ®
with water. This
may destroy the BlueTEC exhaust gas after-
treatment system.
Purity !
Impurities in AdBlue ®
(e.g. due to other ser-
vice products, cleaning agents or dust) lead
to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC ®
exhaust gas
aftertreatment system
The purity of AdBlue ®
is particularly important
with regard to avoiding malfunctions in the Blue- TEC exhaust gas aftertreatment system.
If AdBlue ®
is pumped out of the AdBlue ®
tank,
e.g. during repair work, do not use this fluid to
refill the tank. The purity of the fluid can no lon-
ger be guaranteed. 384
Service products and capacitiesTechnical data
Filling capacities
Model Total capacity
GLS 350 d 4MATIC
38.7 l
Engine oil
General notes When handling engine oil, observe the important
safety notes on service products (Y page 381).
The quality of the engine oil is decisive for the
function and service life of an engine. Mercedes-
Benz continually approves engine oils based on complex experiments according to the latest
technological standards.
Therefore, only Mercedes-Benz-approved
engine oils may be used in Mercedes-Benz
engines.
Further information on tested and approved
engine oils can be obtained from any Mercedes-
Benz Service Centre. Mercedes-Benz recom-
mends that you have the oil change carried out
at a qualified specialist workshop. Mercedes-
Benz approval is indicated on the oil container
by the inscription "MB-Freigabe" or "MB-
Approval" and the corresponding designation,
e.g. MB-Freigabe or MB-Approval 229.51.
You can call up an overview of approved engine oils on the Internet at
http://bevo.mercedes-benz.co mby entering
the designation, e.g. 229.5.
The table shows which engine oils have been
approved for your vehicle.
You can find the correct values for your model
with the help of the VIN on the vehicle identifi-
cation plate (Y page 380). Petrol engines:
in certain countries, different
engine oils can be used, provided that the main-
tenance intervals are reduced. For more infor-
mation, please contact a qualified specialist
workshop. Petrol engines MB-Freigabe or
MB-Approval All models
229.5
Diesel engines with a
diesel particulate filter MB-Freigabe or
MB-Approval GLS 350 d 4MATIC
228.51, 229.31,
229.51, 229.52 Mercedes
‑AMG vehicles: use only SAE 0W-40
or SAE 5W-4 0engine oils.
i If the engine oils listed in the table are not
available, you may add the following engine
oils until the next oil change:
R Petrol engines: MB-Freigabe or MB-
Approval 229.3 or ACEA A3/B3
R Diesel engines: MB-Freigabe or MB-
Approval 229.3, 229.5 or ACEA C3
It may be used only once and the topping-up
quantity must not exceed 1.0 l.
Filling ca pacities The following values refer to an oil change,
including the oil filter.
Model Replacement
amount GLS 350 d 4MATIC
8.0 l
GLS 500 4MATIC
Mercedes-AMG
vehicles
8.5 l
All other models
7.0 l
Additives
!
Do not use any additives with the engine oil.
This could damage the engine. Service products and capacities
385Technical data Z
Brake fluid
G
WARNING
The brake fluid continuously absorbs mois-
ture from the air. This results in the boiling
point of the brake fluid lowering. If the boiling
point of the brake fluid is too low, vapour
pockets may form when the brakes are sub-
jected to a heavy load. This would impair brak- ing efficiency. There is a risk of an accident.
Have the brake fluid renewed at the prescri-
bed intervals.
Comply with the important safety notes for ser- vice products when handling brake fluid
(Y page 381).
The brake fluid change intervals can be found in the Service Booklet.
Only use brake fluid approved by Mercedes-
Benz according to MB-Freigabe or MB-Approval
331.0.
Information about approved brake fluid can be
obtained at any qualified specialist workshop or
on the Internet at
http://bevo.mercedes-benz.com.
i Have the brake fluid regularly replaced at a
qualified specialist workshop in accordance
with the replacement intervals and the
replacement confirmed in the Service Book-
let. Coolant
Important safety notes G
WARNING
If antifreeze comes into contact with hot com- ponents in the engine compartment, it may
ignite. There is a risk of fire and injury.
Let the engine cool down before you top up
the antifreeze. Make sure that antifreeze is
not spilled next to the filler neck. Thoroughly
clean the antifreeze from components before
starting the engine.
! Only add coolant that has been premixed
with the desired antifreeze protection. You
could otherwise damage the engine. Further information on coolants can be found
in the Mercedes-Benz Specifications for Ser-
vice Products, MB Specifications for Service
Products 310.1, e.g. on the Internet at
http://bevo.mercedes-benz.com. Or contact
a qualified specialist workshop.
! Always use a suitable coolant mixture, even
in countries where high temperatures prevail.
Otherwise, the engine cooling system is not
sufficiently protected from corrosion and
overheating.
i Have the coolant regularly replaced at a
qualified specialist workshop and the replace-
ment confirmed in the Service Booklet.
Observe the important safety notes for service
products when handling coolant (Y page 381).
The coolant is a mixture of water and anti-
freeze/anti-corrosion additive. It is responsible
for the following:
R corrosion protection
R antifreeze protection
R raising the boiling point
If antifreeze/corrosion inhibitor is present in the
correct concentration, the boiling point of the
coolant during operation will be approximately
130 †.
The antifreeze/anti-corrosion additive concen-
tration in the engine cooling system should:
R be at least 50%. This will protect the engine
cooling system against freezing down to
approximately -37 †.
R not exceed 55% (antifreeze protection down
to -45 †). Heat will otherwise not be dissipa- ted as effectively.
Mercedes-Benz recommends an antifreeze/
anti-corrosion additive concentrate in accord-
ance with MB Specifications for Service Prod-
ucts 310.1.
i When the vehicle is first delivered, it is filled
with a coolant mixture that ensures adequate
antifreeze and corrosion protection.
i The coolant is checked at every mainte-
nance interval at a qualified specialist work-
shop. 386
Service products and capacitiesTechnical data