2014 MERCEDES-BENZ S-Class refrigerant

Children
In the vehicle ................................... 63
Restraint systems ............................ 63
Special seat belt retractor ...............66
Child seat
LATCH-type (ISOFIX) child seat
anchors ............................................ 67
Top Tether ....................................... 68
Cigarette lighter ................................ 326
Cleaning Mirror turn signal ........................... 357
Climate control
Automatic climate control .............153
Controlling automatically ...............157
Cooling with air dehumidification ..156
Defrosting the windows .................162
Defrosting the windshield ..............161
ECO start/stop function ................155
Important safety notes ..................152
Indicator lamp ................................ 157
Ionization ....................................... 166
Notes on using automatic climate
control ........................................... 155
Overview of systems ......................152
Perfume atomizer .......................... 164
Problems with cooling with air
dehumidification ............................ 157
Problem with the rear window
defroster ........................................ 163
Rear control panel .........................153
Refrigerant ..................................... 428
Refrigerant filling capacity .............428
Setting the air distribution .............160
Setting the airflow .........................160
Setting the air vents ......................166
Setting the climate mode .............. .159
Setting the temperature ................159
Switching air-recirculation mode
on/off ............................................ 163
Switching on/off ........................... 155
Switching residual heat on/off ......163
Switching the rear window
defroster on/off ............................ 162
Switching the synchronization
function on and off ........................161
Cockpit
Overview .......................................... 32COLLISION PREVENTION ASSIST
Activating/deactivating the
distance warning function .............. 261
Display message ............................ 273
Operation/notes .............................. 73
COMAND display
Cleaning ......................................... 359
Combination switch ..........................140
Consumption statistics (on-board
computer) .......................................... 251
Convenience closing feature ............100
Convenience opening feature ..........100
Coolant (engine) Checking the level .........................351
Display message ............................ 283
Filling capacity ............................... 427
Important safety notes ..................426
Temperature gauge ........................ 259
Warning lamp ................................. 309
Coolbox .............................................. 331
Cooling see Climate control
Copyright ............................................. 29
Cornering light function Display message ............................ 280
Function/notes ............................. 141
Crash-responsive emergency
lighting ............................................... 145
Crosswind, driving assistance
(vehicles without MAGIC BODY
CONTROL) ............................................ 77
Crosswind driving assistance
(vehicles with Magic Body
Control) .............................................. 214
Crosswind driving assistance
(vehicles without MAGIC BODY
CONTROL) ............................................ 77
Cruise control Cruise control lever .......................200
Deactivating ................................... 201
Display message ............................ 294
Driving system ............................... 199
Function/notes ............................. 199
Important safety notes ..................199
Setting a speed .............................. 201
Storing and maintaining current
speed ............................................ .200 Index
7

Parking lamps
Switching on/off ........................... 139
PARKTRONIC
Deactivating/activating .................220
Driving system ............................... 218
Function/notes ............................. 218
Important safety notes ..................218
Problem (malfunction) ...................221
Range of the sensors .....................219
Warning displa y............................. 220
PASSENGER AIR BAG OFF
Problem (malfunction) .....................55
Problems (malfunction) .................. 279
PASSENGER AIR BAG OFF indicator
lamp ...................................................... 51
Perfume atomizer Operating ...................................... .164
Perfume via l................................... 164
Problem (malfunction) ...................166
Plastic trim (cleaning instructions) .360
Power locks ......................................... 92
Power washers .................................. 355
Power windows see Side windows
PRE-SAFE ®
(anticipatory occupant
protection) Display message ............................ 272
Operation ........................................ .56
PRE-SAFE ®
Brake
Activating/deactivating .................260
Display message ............................ 273
Function/notes ................................ 78
Important safety notes ....................78
Warning lamp ................................. 311
PRE-SAFE ®
PLUS (anticipatory
occupant protection PLUS) Operation ........................................ .56
Program selector button ..................182
Protection of the environment General notes .................................. 22
Pulling away
Automatic transmission .................174
Hill start assist ............................... 175Q
Qualified specialist workshop ...........27 R
Radio Selecting a station .........................254
Radio-wave reception/
transmission in the vehicle
Declaration of conformity ................26
Reading lamp ..................................... 144
Rear compartment Activating/deactivating climate
control ........................................... 155
Setting the air distribution .............160
Setting the airflow .........................160
Setting the air vents ......................167
Setting the temperature ................159
Stowage compartment ..................318
Rear lamps
see Lights
Rear seats
Adjusting ....................................... 113
Adjusting a rear reclining seat .......113
Overview .......................................... 41
Setting the reclined position ..........113
Rear view camera
Cleaning instructions .....................358
Function/notes ............................. 226
Switching on/off ........................... 227
Rear-view mirror
Anti-glare (manual) ........................130
Dipping (automatic) .......................132
Rear window blind ............................325
Rear window defroster Problem (malfunction) ...................163
Switching on/off ........................... 162
Refrigerant (air-conditioning
system)
Important safety notes ..................428
Refueling
Fuel gauge ....................................... 33
Important safety notes ..................187
Notes for AMG vehicles .................425
Refueling proces s.......................... 188
see Fuel
Remote control
Garage door opene r....................... 341
Programming (garage door opener) 342
Replacing bulbs
General notes ................................ 146 Index
15

Important safety notes
..................423
Refrigerant (air-conditioning
system) .......................................... 428
Washer fluid .................................. .427
Settings
Factory (on-board computer) .........263
On-board computer .......................259
SETUP (on-board computer) .............264
Side impact air bag .............................49
Side marker lamp (display
message) ............................................ 282
Side windows Cleaning ......................................... 357
Convenience closing feature .......... 100
Convenience opening feature ........100
Important safety information ...........99
Opening/closing .............................. 99
Problem (malfunction) ...................102
Resetting ....................................... 101
Sliding sunroof
see Panorama roof with power
tilt/sliding panel
SmartKey
Changing the battery .......................87
Changing the programming .............86
Checking the battery .......................87
Convenience closing feature .......... 101
Convenience opening feature ........100
Display message ............................ 300
Door central locking/unlocking .......85
Important safety notes ....................84
Loss ................................................. 89
Mechanical key ................................ 86
Overview .......................................... 84
Positions (ignition lock) .................171
Problem (malfunction) .....................89
Starting the engine ........................174
Snow chains ...................................... 387
Sockets Center console .............................. 328
General notes ................................ 328
Rear compartment .........................328
Trunk ............................................. 329
Specialist workshop ............................ 27
Special seat belt retractor .................. 66
Speed, controlling see Cruise control Speedometer
Activating/deactivating the
additional speedometer .................263
Digital ............................................ 252
In the Instrument cluster .................33
Selecting the unit of measurement 262
see Instrument cluster
SRS (Supplemental Restraint
System)
Display message ............................ 276
Introduction ..................................... 45
Warning lamp ................................. 307
Warning lamp (function) ................... 45
Standing lamps
Display message ............................ 282
Switching on/off ........................... 139
Start/Stop button
Starting the engine ........................174
Start/stop function
see ECO start/stop function
Starting (engine) ................................ 173
STEER CONTROL .................................. 80
Steering Warning lamps ............................... 313
Steering (display message) ..............299
Steering Assist (DISTRONIC PLUS) Display message ............................ 293
Steering wheel
Adjusting (electrically) ...................127
Button overview ............................... 35
Buttons (on-board computer) ......... 249
Cleaning ......................................... 360
EASY ENTRY/EXIT feature .............129
Important safety notes ..................127
Paddle shifters ............................... 183
Steering wheel heating ..................128
Storing settings (memory function) 133
Steering wheel heating
Problem (malfunction) ...................129
Switching on/off ........................... 128
Steering wheel paddle shifters ........183
Stowage areas ................................... 316
Stowage compartments Armrest (under) ............................. 318
Center console .............................. 317
Center console in rear
compartment ................................. 319 Index
17

VIN
X
Open the front right-hand door.
X Fold cover 0043down and remove it.
You will see the VIN.
The VIN can also be found in the following
locations:
R on the lower edge of the windshield
(Y page 423)
R on the vehicle identification plate
(Y page 422) Engine number
0043
Engine number (stamped into the
crankcase)
0044 VIN (on the lower edge of the windshield)
0087 Emission control information plate,
including the certification of both federal
and Californian emissions standards Service products and filling
capacities
Important safety notes
G
WARNING
Comply with all valid regulations with respect
to handling, storing and disposing of service
fluids. Otherwise, you could endanger
persons or the environment.
Keep service fluids out of the reach of
children.
For health reasons, you should prevent
service fluids from coming into direct contact
with your skin or clothing.
If a service fluid is swallowed, contact a
physician immediately. H
Environmental note
Dispose of service products in an
environmentally responsible manner.
Service products include the following:
R Fuels
R Lubricants (e.g. engine oil, transmission oil)
R Coolant
R Brake fluid
R Windshield washer fluid
R Climate control system refrigerant
Components and service products must be
matched. You should therefore only use
products that have been tested and approved
by Mercedes-Benz.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
You can recognize service products approved
by Mercedes-Benz by the following
inscription on the containers:
R MB-Freigabe (e.g. MB-Freigabe 229.51)
R MB Approval (e.g. MB Approval 229.51)
Other designations or recommendations
indicate a level of quality or a specification in
accordance with an MB Sheet number (e.g. Service products and filling capacities
423Technical data Z

spray nozzles may otherwise become
blocked.
At temperatures above freezing:
X Fill the washer fluid reservoir with a mixture
of water and windshield washer fluid, e.g.
MB SummerFit.
Add 1 part MB SummerFit to 100 parts water.
At temperatures below freezing:
X Fill the washer fluid reservoir with a mixture
of water and washer fluid, e.g. MB
WinterFit.
Adapt the mixing ratio to the outside
temperature.
R Down to 14 ‡ (00F810 †): mix 1 part MB
WinterFit to 2 parts water.
R Down to 00F84 ‡ (00F820 †): mix 1 part MB
WinterFit to 1 part water.
R Down to 00F820.2 ‡ (00F829 †): mix 2 parts MB
WinterFit to 1 part water.
i Add windshield washer fluid, e.g. MB
SummerFit or MB WinterFit, to the washer
fluid all year round. Climate control system refrigerant
Important safety notes The climate control system of your vehicle is
filled with refrigerant R-134a.
The instruction label regarding the refrigerant
type used can be found on the radiator cross
member.
! Only the refrigerant R-134a and the PAG
oil approved by Mercedes-Benz may be
used. The approved PAG oil may not be
mixed with any other PAG oil that is not
approved for R-134a refrigerant.
Otherwise, the climate control system may
be damaged.
Service work, such as topping-up refrigerant
or replacing components, may only be carried
out by a qualified specialist workshop. All applicable regulations must be adhered to,
SAE standard J639 included.
Always have work on the climate control
system carried out at a qualified specialist
workshop.
Refrigerant instruction label
Example: refrigerant instruction label
0043
Warning symbol
0044 Refrigerant filling capacity
0087 Applicable SAE standards
0085 PAG oil part number
0083 Type of refrigerant
Warning symbols 0043indicate:
R possible dangers
R having service work carried out at a
qualified specialist workshop
Filling capacities Vehicles without rear-
compartment air
conditioning system Capacity
Refrigerant
23.3 ± 0.4 oz
(660 ± 10 g) PAG oil
3.9 oz
(110 g) 428
Service products and filling capacitiesTechnical data

Vehicles with rear-
compartment air
conditioning system Capacity
Refrigerant
27.1 ± 0.4 oz
(770 ± 10 g) PAG oil
4.2 oz
(120 g) Vehicle data
General notes
Please note that for the specified vehicle
data:
R the heights specified may vary as a result
of:
-tires
- load
- condition of the suspension
- optional equipment
R optional equipment reduces the maximum
payload. Dimensions and weights
Model 0043 0043
Opening height S 63 AMG 4MATIC
70.8 in - 72.2 in
(1799 mm -1834 mm) All other models
71.0 in (1803 mm) Short wheelbase models
All models
Vehicle length
201.4 in (5116 mm)
Vehicle width
including exterior
mirrors
83.9 in (2130 mm)
Vehicle height
58.9 in (1496 mm)
Wheelbase
119.5 in (3035 mm)
Turning radius
39.0 ft (11.90
m) Maxi
mum roof load 220 lb (100 kg)
Maximum trunk
load
220 lb (100 kg)
Long wheelbase models
S 63 AMG 4MATIC
Vehicle length
208.1 in (5287 mm)
Vehicle width
including exterior
mirrors
83.9 in (2130 mm)
Vehicle height
58.8 in - 60.1 in
(1491 mm -1526 mm) Wheelbase
124.6 in (3165 mm)
Turning radius
40.5 ft (12.34
m) Maxi
mum roof load 220 lb (100 kg)
Maximum trunk
load
220 lb (100 kg)
All other models
Vehicle length
206.5 in (5246 mm)
Vehicle width
including exterior
mirrors
83.9 in (2130 mm)
Vehicle height
58.8 in (1494 mm) Vehicle data
429Technical data Z