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S-Class
Operator's Manual
Order no. 6515 2443 13 Part no. 222 584 44 00 Edition D 2014
É2225844400'ËÍ
2225844400
S-Class Operator's Manual
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Publication details
Internet
Further information about Mercedes-Benz
vehicles and about Daimler AG can be found
on the following websites:
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only) Editorial office
© Daimler AG: Not to be reprinted, translated
or otherwise reproduced, in whole or in part,
without written permission from Daimler AG. Vehicle manufacturer
Daimler AG
Mercedesstraße 137
70327 Stuttgart
Germany
Symbols
Registered trademarks:
R
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LLC.
In this Operator's Manual you will find the
following symbols: G
WARNING
Warning notes make you aware of dangers
which could pose a threat to your health or
life, or to the health and life of others. H
Environmental note
Environmental notes provide you with
information on environmentally aware actions
or disposal.
! Notes on material damage alert you to
dangers that could lead to damage to your
vehicle. i
Practical tips or further information that
could be helpful to you.
X This symbol indicates an
instruction that must be followed.
X Several of these symbols in
succession indicate an instruction
with several steps.
(Y page) This symbol tells you where you
can find more information about a
topic.
YY This symbol indicates a warning or
an instruction that is continued on
the next page.
Display
Display This font indicates a display in the
multifunction display/COMAND
display.
Parts of the software in the vehicle are
protected by copyright ©
2005
The FreeType Project
http://www.freetype.org. All rights
reserved.
As at 19.02.2013
Page 3 of 434

Welcome to the world of Mercedes-Benz
We urge you to read this Operator's Manual
carefully and familiarize yourself with the
vehicle before driving. For your own safety
and a longer vehicle life, follow the
instructions and warning notices in this
manual. Ignoring them could result in damage
to the vehicle or personal injury to you or
others.
Vehicle damage caused by failure to follow
instructions is not covered by the Mercedes-
Benz Limited Warranty.
The equipment or product designation of your
vehicle may vary depending on:
R model
R order
R country specification
R availability
Mercedes-Benz therefore reserves the right
to introduce changes in the following areas:
R design
R equipment
R technical features
The equipment in your vehicle may therefore
differ from that shown in the descriptions and
illustrations.
The following are integral components of the
vehicle:
R Operator's Manual
R Maintenance Booklet
R Equipment-dependent supplements
Keep these documents in the vehicle at all
times. If you sell the vehicle, always pass all
documents on to the new owner.
You can also use the S-Class Guide
smartphone app: Apple
®
iOS Android™
Please note that the Mercedes-Benz Guides
App may not yet be available in your country.
The technical documentation team at
Daimler AG wishes you safe and pleasant
motoring.
Mercedes-Benz USA, LLC
Mercedes-Benz Canada, Inc.
A Daimler Company
2225844400 É2225844400'ËÍ
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Page 5 of 434
Index
....................................................... 4Introduction
......................................... 22 At a glance
........................................... 31 Safety
................................................... 43 Opening and closing
...........................83 Seats, steering wheel and mirrors
..109 Lights and windshield wipers
..........137 Climate control
................................. 151 Driving and parking
..........................169 On-board computer and displays
....247 Stowage and features
......................315 Maintenance and care
......................347 Breakdown assistance
.....................363 Wheels and tires
............................... 383 Technical data
................................... 421 Contents
3
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1, 2, 3 ...
115 V socket ...................................... 329
12 V socket see Sockets
360° camera
Cleaning .........................................3 58
Function/notes ............................. 230
4ETS
see ETS/4ETS (Electronic
Traction System)
4MATIC (permanent four-wheel
drive) .................................................. 218A
ABS (Anti-lock Braking System) Display message ............................ 266
Function/notes ................................ 71
Important safety notes ....................71
Warning lamp ................................. 304
Accident
Automatic measures after an
accident ........................................... 57
Activating/deactivating cooling
with air dehumidification .................156
Activating/deactivating Night
View Assist Plus
With spotlight function ................... 238
Active Blind Spot Assist
Activating/deactivating (on-
board computer) ............................ 261
Display message ............................ 290
Function/informatio n.................... 240
Active Body Control (ABC)
Display message ............................ 288
Function/notes ............................. 214
Active Lane Keeping Assist
Activating/deactivating (on-
board computer) ............................ 262
Display message ............................ 289
Function/informatio n.................... 243
Active multicontour seat ..................125
Active Parking Assist Detecting parking spaces ..............222
Display message ............................ 290
Exiting a parking space ..................224
Function/notes ............................. 221Important safety notes
..................221
Parking .......................................... 223
ADAPTIVE BRAKE ................................. 78
Adaptive Brake Assist Function/notes ................................ 75
Adaptive Damping System (ADS) ..... 217
Adaptive Highbeam Assist Display message ............................ 283
Function/notes ............................. 141
Switching on/off ........................... 142
Adaptive Highbeam Assist PLUS
Display messages ..........................283
Function/notes ............................. 143
Switching on/off ........................... 144
Additional speedometer ...................263
Additives (engine oil) ........................426
Air bags Belt bags .......................................... 63
Cushion air bag s.............................. 51
Display message ............................ 279
Front air bag (driver, front
passenger) ....................................... 48
Important safety notes ....................46
Knee bag .......................................... 49
PASSENGER AIR BAG OFF
indicator lamp .................................. 51
Safety guidelines ............................. 45
Side impact air bag ..........................49
Window curtain air bag ....................50
Air-conditioning system
see Climate control
AIRMATIC
Display message ............................ 287
Function/notes ............................. 216
Air vents
Glove box ...................................... .167
Important safety notes ..................166
Rear ............................................... 167
Setting ........................................... 166
Setting the center air vents ...........166
Setting the side air vents ...............167
Alarm
ATA (Anti-Theft Alarm system) .........81
Switching off (ATA) ..........................81
Switching the function on/off
(ATA) ................................................ 81
Alarm system
see ATA (Anti-Theft Alarm system) 4
Index
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Anti-lock braking system
see ABS (Anti-lock Braking System)
Anti-Theft Alarm system
see ATA (Anti-Theft Alarm system)
Armrest
Stowage compartment ..................318
Ashtray ............................................... 326
Assistance display (on-board
computer) .......................................... 258
Assistance menu (on-board
computer) .......................................... 259
ASSYST PLUS Displaying a service message ........352
Hiding a service message ..............352
Notes ............................................. 352
Resetting the service interval
displa y........................................... 353
Service message ............................ 352
Special service requirements ......... 353
ATA (Anti-Theft Alarm system)
Activating/deactivating ...................81
Function .......................................... .81
Switching off the alarm ....................81
ATTENTION ASSIST
Activating/deactivating .................261
Display message ............................ 287
Function/notes ............................. 234
Authorized Mercedes-Benz Center
see Qualified specialist workshop
Authorized Workshop
see Qualified specialist workshop
AUTO lights
Display message ............................ 282
see Lights
Automatic engine start (ECO start/
stop function) .................................... 176
Automatic engine switch-off (ECO
start/stop function) ..........................175
Automatic headlamp mode ..............138
Automatic transmission Automatic drive program ...............183
Changing gea r............................... 182
DIRECT SELECT lever .....................179
Display message ............................ 297
Driving tips .................................... 182
Emergency running mode ..............187
Engaging drive position .................. 180 Engaging neutral
............................ 180
Engaging park position
automatically ................................. 179
Engaging reverse gear ...................179
Engaging the park position ............179
Kickdown ....................................... 182
Manual drive program ....................184
Manual drive program (AMG
vehicles) ........................................ 185
Overview ........................................ 179
Problem (malfunction) ...................187
Program selector button ................182
Pulling away ................................... 174
Starting the engine ........................174
Steering wheel paddle shifters ......183
Transmission position displa y........ 181
Transmission positions ..................181
Automatic transmission
emergency mode ............................... 187 B
BAS (Brake Assist System) .................71
BAS PLUS (Brake Assist System
PLUS) with Cross-Traffic Assist
Function/notes ................................ 72
BAS PLUS Q (Brake Assist System
PLUS) with Cross-Traffic Assist Important safety notes ....................72
Battery (SmartKey)
Checking .......................................... 87
Important safety notes ....................87
Replacing ......................................... 87
Battery (vehicle)
Charging ........................................ 371
Display message ............................ 285
Important safety notes ..................369
Jump starting ................................. 373
Belt
see Seat belts
Belt bag ................................................ 63
Belt force limiter Activation ......................................... 62
Function .......................................... .62
Blind Spot Assist
see Active Blind Spot Assist
Brake Assist
see BAS (Brake Assist System) Index
5
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Brake fluid
Display message ............................ 272
Notes ............................................. 426
Brake force distribution,
electronic
see EBD (electronic brake force
distribution)
Brake lamps
Display message ............................ 281
Brakes
ABS .................................................. 71
Adaptive Brake Assist ......................75
BAS .................................................. 71
BAS PLUS with Cross-Traffic Assist .72
Brake fluid (notes) .........................426
Display message ............................ 266
EBD .................................................. 78
High-performance brake system ....197
Hill start assist ............................... 175
HOLD function ............................... 212
Important safety notes ..................196
Maintenance .................................. 196
Parking brake ................................ 192
Riding tips ...................................... 196
Warning lamp ................................. 303
Breakdown
see Flat tire
see Towing away
Buttons on the steering wheel .........249 C
California Important notice for retail
customers and lessees ....................24
Calling up a malfunction
see Display messages
Camera
see 360° camera
Car
see Vehicle
Care
360° camera ................................. 358
Carpets .......................................... 361
Car wash ........................................ 354
Display ........................................... 359
Exhaust pipe .................................. 359
Exterior lights ................................ 357Gear or selector lever
....................360
Interior ........................................... 359
Matte finish ................................... 356
Night View Assist Plus ...................359
Notes ............................................. 353
Paint .............................................. 356
Plastic trim .................................... 360
Power washer ................................ 355
Rear view camera .......................... 358
Roof lining ...................................... 361
Seat belt ........................................ 361
Seat cover ..................................... 361
Sensors ......................................... 358
Steering wheel ............................... 360
Trim pieces .................................... 360
Washing by hand ........................... 355
Wheels ........................................... 356
Windows ........................................ 357
Wiper blades .................................. 357
Wooden trim .................................. 360
Car key
see SmartKey
Car wash (care) ................................. 354
CD player/CD changer (on-board
computer) .......................................... 256
Center console Overview .......................................... 37
Stowage space .............................. 317
Center console in the rear
compartment
Stowage compartment ..................319
Central locking
Locking/unlocking (SmartKey) ........85
Chauffeur mode
Display message ............................ 299
Fully reclined position ....................121
General notes ................................ 117
Installing the head restraint ...........119
Moving front-passenger seat into
the chauffeur position .................... 118
Moving the front-passenger seat
into the normal position ................. 120
Removing the head restraint .......... 119
Child-proof locks
Important safety notes ....................69
Rear doors ....................................... 696
Index