2013 MERCEDES-BENZ S-Class engine

pump nozzle, which could cause personal
injury. G
WARNING
Hybrid vehicles: be sure to read the "HYBRID"
supplement .Otherwise, you could fail to
recognize dangers. G
WARNING
Do not fill diesel tanks with gasoline .Do not
mix diesel fuel with gasoline. Otherwise the
fuel system and engine could be damaged. In
addition, the vehicle could catch fire.
! Do not use gasoline to refuel vehicles with
a diesel engine. Do not use diesel to refuel
vehicles with a gasoline engine. Even a
small quantity of the wrong fuel will
damage the fuel system and engine.
! Do not switch on the ignition if you
accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel lines.
Notify a qualified specialist workshop and
have the fuel tank and fuel lines drained
completely.
! Overfilling the fuel tank could damage the
fuel system.
! Take care not to spill any fuel on painted
surfaces. You could otherwise damage the
paintwork.
! Use a filter when refueling from a fuel can.
Otherwise, the fuel lines and/or injection
system could be blocked by particles from
the fuel can.
Further information on fuel and on fuel grades
can be found in the "Fuel" section
(Y page 531). Refueling
Fuel filler flap 0002
To open the fuel filler flap
0003 To insert the fuel filler cap
0026 Tire pressure table
0025 Fuel type
The fuel filler flap is unlocked or locked
automatically when you open or close the
vehicle with the SmartKey or with KEYLESS-
GO.
The position of the fuel filler cap 000Fis
displayed in the instrument cluster. The arrow
next to the filling pump indicates the side of
the vehicle.
Opening X
Switch off the engine.
X Remove the SmartKey from the ignition
lock.
X KEYLESS-GO: open the driver’s door.
This corresponds to SmartKey position 0:
"SmartKey removed".
The driver’s door can be closed again.
X Press the fuel filler flap in the direction of
arrow 0002.
The fuel filler flap opens slightly.
X Open the fuel filler flap fully.
X Turn the fuel filler flap counter-clockwise
and remove it.
X Insert the fuel filler cap into the holder
bracket on the inside of filler flap 0003.322
RefuelingDriving and parking

X
Completely insert the fille rneck of the fuel
pump nozzle into the tank and refuel.
X Only fill the tank until the pump nozzle
switches off.
i Do not add any more fuel after the pump
stops filling for the first time. Otherwise,
fuel may leak out.
Closing X
Replace the cap on the filler necka nd turn
clockwise until it engages audibly.
X Close the fuel fille rflap.
i If you drive with the fuel filler cap open,
the reserve fuel warning lamp flashes .In
addition, the 000ECheck Engine warning
lamp may light up. Amessage appears in
the multifunction display (Y page 411).
For further information on warning and
indicator lamps in the instrument cluster,
see (Y page 434).
i Close the fuel filler flap before locking the
vehicle. Otherwise, the locking pin of the
central locking prevents the fuel filler flap
from closing. Refueling
323Driving and parking Z

Problems with fuel and the fuel tank
Problem Possible causes/consequences and
0004 Solutions
Fuel is leaking from the
vehicle.
G
Risk of explosion or fire
The fuel line or the fuel tank is faulty.
X Turn the SmartKey to position 0in the ignition lock and remove
it immediately (Y page 307).
X Do not restart the engine under any circumstances.
X Consult a qualified specialist workshop. The engine does not
start. The fuel tank of a vehicle with a diesel engine has been run
completely dry.
X
Refuel the vehicle with at least 5.3 US qt (5 liters) of diesel.
X Turn the ignition on for about 10 seconds(Y page 307).
X Start the engine continuously for up to 10 seconds until it runs
smoothly.
or
X Start the engine via the touch-start function. To do this, turn the
SmartKey to position 3(Ypage 307) in the ignition lock and then
release it immediately.
If the engine does not start:
X Turn the ignition on again for approximately
10 seconds(Y page 307).
X Start the engine again continuously for up to 10 seconds until
it runs smoothly.
or
X Start the engine again via the touch-start function.
If the engine does not start after three attempts:
X Consult a qualified specialist workshop. The fuel filler flap
cannot be opened. The fuel filler flap is not unlocked.
or
The SmartKey battery is discharged.
X
Unlock the vehicle (Y page 82).
or
X Unlock the vehicle using the mechanical key (Y page 84).The fuel filler flap is unlocked, but the opening mechanism is
jammed.
X
Consult a qualified specialist workshop. 324
RefuelingDriving and parking

DEF (BlueTEC vehicles only)
Important notes on use To function properly, BlueTEC exhaus
tgas
aftertreatment must be operated with the
reducing agen tDEF. Adding DEF is one of the
tasks performed during maintenance. Under
normal operating conditions, a tank of DEF
lasts until the next service due date.
When the DEF level is too low, the CheckAdditive See Operator's Manual
message is shown in the multifunction
display.
When the DEF supply sinks to a minimum
level, the Remaining Starts: 16 message
is shown in the multifunctio ndisplay.
When the Remaining Starts: 16 message
is shown in the multifunction display, you can
start the engine 16 more times. If DEF is not
added, it will the nnot be possible to restart
the engine. Fill the DEFt ank with about1gal
(3.8l) of DEF or have the DEF tank refilled at
a qualified specialist workshop.
Use the special DE Frefill bottle when filling
between maintenance intervals. Contact an
authorized Mercedes-BenzC enter with any
questions or, if necessary, contact Roadside
Assistance (Y page 29).
If the outside temperature is lower than 12 ‡
(002711 †), damage may occur when adding
DEF. If DEF is frozen and there is an active
warning indicator, adding may not be
possible. Park the vehicle in a warmer place,
e.g. in a garage, until DEFh as become fluid
again .Itwill the nbe possible to add DEF
again. Alternatively, have the DEFt ank refilled
at a qualified specialist workshop.
Further informatio nabout BlueTEC exhaust
gas aftertreatment and DEFi s available at any
authorized Mercedes-Benz Center. Adding DEF G
WARNING
Make sure
R DEF does not come into contact with skin,
eyes, or clothing
R to keep DEF out of the reach of children
If you and/or others have come into contact
with DEF:
R If DEF has gotten into contact with eyes,
flush with plenty of water immediately and
seek medical help.
R Cleana ffected skin immediately with plenty
of water.
R If DEF was swallowed, rinse mouth
immediately with plenty of water and drink
plenty of water. Consult a physician. G
WARNING
If you open the DEF tank cap, small amounts
of ammonia vapo rmay be released. This
depends in particular upon the age of the DEF.
Ammonia vapors have a pungent odor and are
particularly irritating to:
R skin
R mucous membranes
R eyes
You may experience a burning sensation in
your eyes, nose and throat, as well as
coughing and watering of the eyes.
Do not inhale any ammonia vapors that may
be released. Fill the DE Ftank only in well-
ventilated areas.
! Only use DEF in accordance with
ISO 22241. Do not mix any additives with
DEF, and do no tdilute DE Fwith water .This
may destroy the BlueTEC exhaust gas
aftertreatment system.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF Refueling
325Driving and parking Z

residues crystallize after time and
contaminate the affected surfaces.
! DEF is not a fuel additive and must not be
added to the fuel tank. If DEF is added to
the fuel tank, this can lead to engine
damage.
! Only screw on the DEF refill bottle hand-
tight. It could otherwise be damaged.
The filler neck for DEF is located under the
"Minispare" emergency spare wheel in the
trunk floor.
X Switch off the ignition.
X Open the trunk.
X Lift the trunk floor up ( Ypage 442). X
Turn the "Minispare" emergency spare
wheel fastening in the direction of the
arrow and remove it.
X Remove the "Minispare" emergency spare
wheel. X
Turn DEF cap 0002counter-clockwise and
remove it. X
Turn DEF filler cap 0003counter-clockwise
and open it.
Filler cap 0003is secured with a plastic strap. X
Unscrew the covering cap from DEF refill
bottle 0026.
X Place DEF refill bottle 0026on the filler neck
as show nand screw on clockwise hand-
tight.
X Press DEF refill bottle 0026down.
The DEF tank is filled. This may take up to
one minute.
i To add between service intervals, fill the
DEF tank with approximately 1gal (3. 8l) of
DEF. 1 gal (3.8 l) of DEF is equivalent to
approximately 2DEF refill bottles. Then
have the DEF supply checked at a qualified
specialis tworkshop and completely refilled
if necessary.
X Release DEFr efill bottle0026.
Refilling stops when the DEFr efill bottle is
no longer pressed down. The DEFr efill
bottle can be removed when it has been
only partially emptied. 326
RefuelingDriving and parking

X
Turn DEFr efill bottle 0026counter-clockwise
and remove it.
X Place DEFf iller cap0003on the filler nec kand
turn it clockwise. X
Insert DEF cap 0002as shown and tur nit
clockwise as far as it will go.
X Place the "Minispare" emergency spare
wheel in the emergency spare wheel well
above the DEF tank.
X Inser tthe "Minispare" emergency spare
wheel fastening and tighten clockwise.
X Fold the trunk floor down.
X Close the trunk lid.
X Drive faster than 10 mph (16 km/h).
The Check Additive See Operator's Manual message goes out after
approximately one minute.
i If the Check Additive See Operator's Manual message remains
shown in the multifunction display, add an
additional bottle of DEF.
Further information on DEF (Y page 533).Parking
Important safety notes
G
WARNING
Do not park this vehicle in areas where
combustible materials can come into contact
with the hot exhaust system. Combustible
materials, such as grass, hay or leaves could
be ignited by the hot exhaust system and cause a vehicle fire. Do not park the vehicle
on dry grassland or harvested grain fields.
Unintended vehicle movement can cause
serious personal injury or damage to the
vehicle or the vehicle drivetrain. To reduce
such risks, always do the following before
turning off the engine and leaving the vehicle:
R
keep your right foot on the brake pedal.
R engage the electric parking brake.
R shift the automatic transmission into park
position P.
R slowly release the brake pedal.
R when parked on an incline, always turn the
front wheels towards the road curb.
R turn the SmartKey in the ignition lock to
position 0and remove the SmartKey from
the ignition lock, or press the KEYLESS-GO
Start/Stop button.
R take the SmartKey with you and lock the
vehicle when leaving. Switching off the engine
Important safety notes G
WARNING
Do not turn off the engine before the vehicle
has come to a complete stop. With the engine
not running, there is no power assistance for
the brake and steering systems. In this case,
it is important to keep in mind that a
considerably higher degree of effort is
necessary to brake and steer the vehicle. G
WARNING
Keep in mind that turning off the engine alone
only will shift the automatic transmission into
neutral position Nautomatically.
Always shift the automatic transmission into
park position Pbefore turning off the engine.
Otherwise the vehicle could roll away which
could result in an accident and/or serious
personal injury. Parking
327Driving and parking Z

i
If you cannot turn off the engine as
described here, see "Engine emergency
stop" (Y page 495).
Vehicles with automatic transmission X
Apply the electric parking brake.
X Shift the transmission to position P.
Using the SmartKey
X Turn the SmartKey to position 0in the
ignition lock and remove it.
The immobilizer is activated.
i If you turn off the engine with the
SmartKey and then remove it from the
ignition lock or open a front door, the
automatic transmission shifts to P
automatically.
Using KEYLESS-GO
X Press the Start/Stop button (Y page 307).
The engine stops and all the indicator
lamps in the instrument cluster go out.
i When the driver's door is closed, this
corresponds to SmartKey position 1.When
the driver's door is open, it corresponds to
SmartKey position 0or "SmartKey
removed".
i If you use the Start/Stop button to switch
off the engine, the automatic transmission
shifts to Nautomatically .Ifyou then open
the driver's or front-passenger door, the
automatic transmission shifts to P.
i In an emergency, the engine can be
turned off while the vehicle is in motion by
pressing and holding the Start/Stop button
for 3seconds. This function operates
independently from the ECO start/stop
automatic engine switch-off function. Electric parking brake
General notes G
WARNING
When leaving the vehicle, always remove the
SmartKey from the starter switch ,take it with
you, and loc kthe vehicle. Do not leave
children unattended in the vehicle, or with
access to an unlocked vehicle. Children could
release the parking brake and/or shift the
automatic transmission out of park position
P, either of which could result in an accident
and/or serious personal injury. Applying/releasing manually
X
To engage: push handle 0002.
When the electric parking brake is
engaged, the 0005(USA only) or 000A
(Canada only) red indicator lamp lights up
in the instrument cluster.
i The electric parking brake can also be
applied when the SmartKey is removed.
X To release: switch on the ignition.
X Pull handle 0002.
The red 0005(USA only) or 000A(Canada
only) indicator lamp in the instrument
cluster goes out.
i The electric parking brake can only be
released:
R if the SmartKey is in position 1in the
ignition lock or
R if the ignition was switched on using the
Start/Stop button. 328
ParkingDriving and parking

Engaging the electric parking brake
automatically If the HOLD function or DISTRONIC PLUS
brake the vehicle until it is stationary, the
electric parking brake is automatically
applied .Additionally, at least one of the
following conditions must be fulfilled:
R the engine is switched off.
R the driver's door is open and the seat belt
is not fastened.
R the hood is released.
R the trun klid is opened while the automatic
transmission is in position R.
R the vehicle is stationary for a lengthy
period.
The red 0005(USA only) or 000A(Canada
only) indicator lamp in the instrumen tcluster
lights up.
i In addition to the electric parking brake,
P may also be engaged automatically.
Releasing the electric parking brake
automatically The electric parking brake is released
automatically when the following conditions
are simultaneously fulfilled:
R the engine is running.
R the automatic transmission is in position
D or R.
R the hood is closed.
R your seat belt is fastened.
R you accelerate.
If the automatic transmission is in position
R, the trunk lid must be closed. If your seat belt is not fastened, the following
conditions must be fulfilled to automatically
release the electric parking brake:
R
the driver's door is closed.
R you have shifted out of Por you have
previously driven faster than 3 km/h.
R you have shifted out of Por you have
previously drive nfaster than 2mph
(3 km/h).
Emergency braking The vehicle can also be braked during an
emergency by using the electric parking
brake.
X
While driving, push handle 0002of the electric
parking brake (Y page 328).
i The vehicle is braked as long as you keep
the handle of the electric parking brake
pressed. The longer the electric parking
brake handle is depressed, the greater the
braking force.
During braking:
R a warning tone sounds.
R the Please Release Parking Brake message appears
R the red 0005(USA only) or 000A(Canada
only) indicator lamp in the instrument
cluster appears.
When the vehicle has been braked to a
standstill, the electric parking brake is
engaged. Parking the vehicle for
along period
If you leave the vehicle parked for longer than
four weeks, the battery may be damaged by
exhaustive discharging.
X Connecting a trickle charger.
i You can obtain information about trickle
chargers from a qualified specialist
workshop. Parking
329Driving and parking Z