2016 MERCEDES-BENZ S CLASS Owners Manual

Useful information
i This Operator's Manual describes all models
and all standard and optional equipment of
your vehicle available at the time of publica-
tion of the Operator's Manual. Country-spe-
cific differences are possible. Please note
that your vehicle may not be equipped with all
features described. This also applies to
safety-related systems and functions.
i Read the information on qualified specialist
workshops ( Y
page 28).
Where will I find...?
Vehicle tool kit
General notes The towing eye is located in the stowage well
under the trunk floor.
Some tools for changing a wheel are specific to
the vehicle. For more information on which tire
changing tools are required and approved to
perform a wheel change on your vehicle, consult
a qualified specialist workshop.
Tools required for changing a wheel may
include, for example: R
Jack R
Wheel chock R
Lug wrench R
Ratchet wrench R
Alignment bolt
Vehicles with a TIREFIT kit
C
Tire sealant filler bottle
D
Tire inflation compressor

winter tires. A TIREFIT kit may be obtained from
a qualified specialist workshop.
Information on changing and mounting wheels
( Y
page 405). X
Stop the vehicle on solid, non-slippery and
level ground, as far away as possible from
traffic. X
Switch on the hazard warning lamps. X
Secure the vehicle against rolling away
( Y
page 189).X
If possible, bring the front wheels into the
straight-ahead position. X
Switch off the engine. X
Open the driver's door.
The on-board electronics now have status 0 .
This is the same as the SmartKey having been
removed. X
Remove the Start/Stop button from the igni-
tion lock ( Y
page 162).
or, if the SmartKey is inserted in the ignition
lock: X
Remove the SmartKey from the ignition lock. X
Make sure that the engine cannot be started
via your smartphone ( Y
page 164).X
Make sure that the passengers are not endan-
gered as they do so. Make sure that no one is
near the danger area while a wheel is being
changed. Anyone who is not directly assisting
in the wheel change should, for example,
stand behind the barrier. X
Get out of the vehicle. Pay attention to traffic
conditions when doing so. X
Close the driver's door.
MOExtended tires (tires with run-flat
properties)
General notes With MOExtended tires (tires with run flat char-
acteristics), you can continue to drive your vehi-
cle even if there is a total loss of pressure in one
or more tires. The affected tire must not show
any clearly visible damage.
You can recognize MOExtended tires by the
MOExtended marking which appears on the
sidewall of the tire. You will find this marking
next to the tire size designation, the load-bear-
ing capacity and the speed index ( Y
page 400). MOExtended tires may only be used in conjunc-
tion with an active tire pressure loss warning
system or with an active tire pressure monitor.
If a pressure loss warning message appears
in the multifunction display: R
observe the instructions in the display mes-
sages ( Y
page 306). R
check the tire for damage. R
if driving on, observe the following notes.
The driving distance possible in run-flat mode is
approximately 50 miles (80 km) when the vehi-
cle is partially laden. When the vehicle is fully
laden it is approximately 19 miles (30 km).
In addition to the vehicle load, the driving dis-
tance possible depends upon: R
vehicle speed R
road condition R
outside temperature
The driving distance possible in run-flat mode
may be reduced by extreme driving conditions
or maneuvers, or it can be increased through a
moderate style of driving.
The driving distance possible in run-flat mode is
counted from the moment the tire pressure loss
warn ing appears in t h
e multifunction display.
You must not exceed a maximum speed of
50 mph (80 km/h).
When replacing one or all tires, please observe
the following specifications for your vehicle's
tires: R
size R
the type and R
the "MOExtended" mark
If a tire has gone flat and cannot be replaced
with a MOExtended tire, a standard tire may be
used as a temporary measure. Make sure that
you use the proper size and type (summer or
winter tire).
Vehicles equipped with MOExtended tires are
not equipped with a TIREFIT kit at the factory. It
is therefore recommended that you additionally
equip your vehicle with a TIREFIT kit if you mount
tires that do not feature run-flat properties, e.g.
winter tires. A TIREFIT kit may be obtained from
a qualified specialist workshop.368
Flat tire
Breakdown assistance

Important safety notes
G WARNIN G
When driving in emergenc y mode, th e driving
characteristics deteriorate, e.g. when corner-
ing , accelerating quickly and when braking .
Ther e is a ris k of an accident.
Do no t exceed th e state d maximum speed.
Avoid abrup t steering and driving maneuvers,
and driving ove r obstacles (curbs, potholes,
off-road). This applie s in particular to a laden
vehicle.
Stop driving in emergenc y mod e if:R
you hear bangin g noises .R
th e vehicl e start s to shake.R
you see smoke and smell rubber. R
ES P ®
is intervening constantly.R
there are tears in th e sidewalls of th e tire.
Afte r driving in emergenc y mode, have th e
whee l rim s checke d at a qualified specialist
workshop wit h regard to their further use. The
defective tire must be replace d in every case.
TIREFIT kit
Important safety notes TIREFI T is a tire sealant.
You can use TIREFI T to seal punctures of up to
0.16 in (4 mm), particularl y those in th e tire
tread. You can use TIREFI T at outside tempera-
tures down to

compressor from the stowage well under-
neath the trunk floor ( Y
page 367).X
Affix part C of the TIREFIT sticker to the
instrument cluster within the driver's field of
vision. X
Affix part D of the TIREFIT sticker near the
valve on the wheel with the defective tire.
X
Pull connector

Tire pressure reached
G WARNING
A tire temporarily sealed with tire sealant
impairs the driving characteristics and is not
suitable for higher speeds. There is a risk of
accident.
You should therefore adapt your driving style
accordingly and drive carefully. Do not exceed
the specified maximum speed with a tire that
has been repaired using tire sealant.
The maximum permissible speed for a tire
sealed with tire sealant is 50 mph (80 km/h).
The upper part of the TIREFIT sticker must be
affixed to the instrument cluster in the driver's
field of vision.
! Residue from the tire sealant may come out
of the filler hose after use. This could cause
stains.
Therefore, place the filler hose in the plastic
bag which contained the TIREFIT kit.
H Environmental note
Have the used tire sealant bottle disposed of
professionally, e.g. at a qualified specialist
workshop.
If a tire pressure of 180 kPa (1.8 bar/26 psi) has
been attained after five minutes: X
Switch off the tire inflation compressor. X
Unscrew the filler hose from the valve of the
faulty tire. X
Stow the tire sealant bottle and the tire infla-
tion compressor. X
Pull away immediately .X
Stop after driving for approximately ten
minutes and check the tire pressure with the
tire inflation compressor.
The tire pressure must now be at least
130 kPa (1.3 bar/19 psi).
G WARNING
If the required tire pressure is not reached
after driving for a short period, the tire is too
badly damaged. The tire sealant cannot repair
the tire in this instance. Damaged tires and a
tire pressure that is too low can significantly impair the vehicle's braking and driving char-
acteristics. There is a risk of accident.
Do not continue driving. Contact a qualified
specialist workshop.
i In cases such as the one mentioned above,
contact an authorized Mercedes-Benz Cen-
ter. Or call 1-800-FOR-MERCedes (i n the
USA) or 1-800-387-0100 (in Canada). X
Correct the tire pressure if it is still at least
130 kPa (1.3 bar/19 psi). See the Tire and
Loading Information placard on the driver's
side B-pillar or the tire pressure table in the
fuel filler flap for values. X
To increase the tire pressure: switch on the
tire inflation compressor.
X
To reduce the tire pressure: depress pres-
sure release button m next to pressure gauge
n . X
When the tire pressure is correct, unscrew the
filler hose from the valve of the sealed tire. X
Screw the valve cap onto the tire valve of the
sealed tire. X
Pull the tire sealant bottle out of the tire infla-
tion compressor.
The filler hose remains attached to the tire
sealant bottle. X
Drive to the nearest qualified specialist work-
shop and have the tire changed there. X
Have the tire sealant bottle replaced as soon
as possible at a qualified specialist workshop. X
Have the tire sealant bottle replaced every
four years at a qualified specialist workshop. Flat tire 371
Breakdo wn assis tance Z

Battery (vehicle)
12 V battery – important safety notes PLUG-IN HYBRID vehicles are equipped with a
12 V battery and a high-voltage battery. The fol-
lowing notes refer to the 12 V battery. Notes on
the high-voltage battery can be obtained in the
"High-voltage battery – important safety notes"
section ( Y
page 374).
Special tools and expert knowledge are required
when working on the battery, e.g. removal and
installation. You should therefore have all work
involving the battery carried out at a qualified
specialist workshop.
G WARNING
Work carried out incorrectly on the battery
can lead, for example, to a short circuit and
thus damage the vehicle electronics. This can
lead to function restrictions applying to
safety-relevant systems, e.g the lighting sys-
tem, the ABS (anti-lock braking system) or the
ESP ®
(Electronic Stability Program). The oper-
ating safety of your vehicle may be restricted.
You could lose control of the vehicle, for
example: R
when braking R
in the event of abrupt steering maneuvers
and/or when the vehicle's speed is not
adapted to the road conditions
There is a risk of an accident.
In the event of a short circuit or a similar inci-
dent, contact a qualified specialist workshop
immediately. Do not drive any further. You
should have all work involving the battery car-
ried out at a qualified specialist workshop.
For further information about ABS and ESP ®
,
see ( Y
page 68) and ( Y
page 73).
All vehicles except Mercedes-AMG vehicles:
G WARNING
Electrostatic build-up can lead to the creation
of sparks, which could ignite the highly explo-
sive gases of a battery. There is a risk of an
explosion. Before handling the battery, touch the vehicle
body to remove any existing electrostatic
build-up.
The highly flammable gas mixture forms when
charging the battery as well as when jump-start-
ing.
Always make sure that neither you nor the bat-
tery is electrostatically charged. A build-up of
electrostatic charge can be caused, for exam-
ple: R
by wearing clothing made from synthetic
fibers R
due to friction between clothing and seats R
if you push or pull the battery across the car-
pet or other synthetic materials R
if you wipe the battery with a cloth
G WARNING
During the charging process, a battery produ-
ces hydrogen gas. If a short circuit occurs or
sparks are created, the hydrogen gas can
ignite. There is a risk of an explosion. R
Make sure that the positive terminal of a
connected battery does not come into con-
tact with vehicle parts. R
Never place metal objects or tools on a bat-
tery. R
It is important that you observe the descri-
bed order of the battery terminals when
connecting and disconnecting a battery. R
When jump-starting, make sure that the
battery poles with identical polarity are
connected. R
It is particularly important to observe the
described order when connecting and dis-
connecting the jumper cables. R
Never connect or disconnect the battery
terminals while the engine is running.
G WARNING
Battery acid is caustic. There is a risk of injury.
Avoid contact with skin, eyes or clothing. Do
not inhale any battery gases. Do not lean over
the battery. Keep children away from batter-
ies. Wash away battery acid immediately with372
Battery (vehicle)
Breakdo wn assis tance

plenty of clean water and seek medical atten-
tion.
All vehicles:
H Environmental note
Batteries contain dangerous
substances. It is against the
law to dispose of them with
the household rubbish. They
must be collected separately
and recycled to protect the
environment.
Dispose of batteries in an
environmentally friendly
manner. Take discharged
batteries to a qualified spe-
cialist workshop or a special
collection point for used bat-
teries.
! Have the battery checked regularly at a
qualified specialist workshop.
Observe the service intervals in the Mainte-
nance Booklet or contact a qualified specialist
workshop for more information.
! Always have work on batteries carried out at
a qualified specialist workshop. Should it, in
exceptional circumstances, be absolutely
necessary to disconnect the 12-volt battery
yourself, observe the following: R
secure the vehicle to prevent it from rolling
away. R
switch off the ignition. R
always disconnect the negative terminal
clamp first, followed by the positive termi-
nal clamp.
After the battery has been disconnected, the
transmission is locked in position P .
After the work has been done, install the bat-
tery and replace the cover of the positive ter-
minal clamp firmly.
Comply with safety precautions and take pro-
tective measures when handling batteries. Risk of explosion.
Fire, open flames and smoking are
prohibited when handling the bat-
tery. Avoid creating sparks.
Electrolyte or battery acid is corro-
sive. Avoid contact with skin, eyes or
clothing.
Wear suitable protective clothing,
especially gloves, apron and face-
guard.
Immediately rinse electrolyte or acid
splashes off with clean water. Con-
tact a physician if necessary.
Wear eye protection.
Keep children away.
Observe this Operator's Manual.
For safety reasons, Mercedes-Benz recom-
mends that you only use batteries which have
been tested and approved for your vehicle by
Mercedes-Benz. These batteries provide
increased impact protection to prevent vehicle
occupants from suffering acid burns should the
battery be damaged in the event of an accident.
In order for the battery to achieve the maximum
possible service life, it must always be suffi-
ciently charged.
Like other batteries, the vehicle battery may
discharge over time if you do not use the vehicle.
In this case, have the battery disconnected at a
qualified specialist workshop. You can also
charge the battery with a charger recommended
by Mercedes-Benz. Contact a qualified special-
ist workshop for further information.
Have the battery condition of charge checked
more frequently if you use the vehicle mainly for
short trips or if you leave it standing idle for a
lengthy period. Consult a qualified specialist
workshop if you wish to leave your vehicle
parked for a long period of time.Battery (vehicle) 373
Breakdown assistance Z

Remove th e SmartKey if you park th e vehicl e
and do no t require any electrical consumers.
The vehicl e will then use ver y littl e energy, thus
conserving battery power .
PLUG-IN HYBRID vehicles: if th e battery
charge is sufficient, th e high-voltage battery can
also suppl y th e 12 V battery. This only happens
if th e condition of charge of th e 12 V battery
require s this, e.g. after usin g electrical consum-
ers for an extended period wit h th e engin e
switched off . As th e on-board voltag e is contin-
uously monitore d this can also be performed
when th e engin e is switched off . The condition of
charge of th e 12 V battery and th e on-board
voltag e are thereby kept stable for a longer
period.
High-voltage battery – important
safety notes Only PLUG-I N HYBRID vehicles are equipped
wit h a high-voltage battery.
G DANGER
The vehicle's high-voltage electrical system is
under high voltage. If you modify component s
in th e vehicle's high-voltage electrical system
or touch damaged components, you may be
electrocuted. The component s in th e vehi-
cle's high-voltage electrical system may be
damaged in an accident, althoug h th e damag e
is no t visible. There is a ris k of fatal injury.
Followin g an accident, do no t touch any high -
voltag e component s and never modify th e
vehicle's high-voltage electrical system. Hav e
th e vehicl e towed away after an acciden t and
th e vehicle's high-voltage electrical system
checke d by a qualified specialist workshop.
G WARNIN G
In th e event of a vehicl e fire, th e internal pres-
sur e of th e high-voltage battery can exceed a
critical value . In this cas e flammabl e gas
escapes throug h a ventilation valv e on th e
underbody. The gas can ignite. There is a ris k
of injury.
Leav e th e danger zone immediately. Secur e
th e danger area at a suitable distance, whils t
observing legal requirements . G WARNIN G
If th e housing of th e high-voltage battery has
been damaged, electrolyt e and gase s may
leak out . These are poisonous and caustic.
There is a ris k of injury.
Avoid contact wit h skin, eyes or clothing .
Immediately rinse electrolyt e splashes off
wit h water and seek medical attention
straight away.
! Exhaustive discharge caused by th e vehicl e
standing idle for lengthy periods can damag e
th e high-voltage battery. If th e vehicl e is idle
for lengthy periods leav e th e high-voltage bat -
tery connecte d to a charging station .
Consult an authorize d Mercedes-Benz Cente r if
you wish to leav e your vehicl e parked for a lon g
period of time.
Charging the 12 V battery Mercedes-AM G vehicles:
! Only use battery chargers wit h a maximum
charging voltag e of 14.4 V.
All other vehicles:
G WARNIN G
During charging and jump-starting , explosive
gase s can escape from th e battery. There is a
ris k of an explosion .
Particularly avoi d fire, open flames, creating
sparks and smoking. Ensur e there is sufficien t
ventilation while charging and jump-starting .
Do no t lean ove r a battery.
G WARNIN G
Battery acid is caustic. There is a ris k of injury.
Avoid contact wit h skin, eyes or clothing . Do
no t inhale any battery gases. Do no t lean ove r
th e battery. Kee p children away from batter-
ies. Wash away battery acid immediately wit h
plenty of clean water and seek medical atten -
tion .
G WARNIN G
A discharged battery can freez e at tempera-
tures belo w freezing point. When jump-start -374
Battery (vehicle)
Breakdown assistance