2013 MERCEDES-BENZ S-CLASS SEDAN service

!
Do not refuel with low-grade fuel and do
not use fuel additives that are not tested
and approved for Mercedes-Benz vehicles.
Damage to or malfunctions of the fuel
system may otherwise occur. DEF
Important safety notes i
For BlueTEC vehicles only.
DEF
is a non-flammable, non-toxic, colorless,
odorless and water-soluble fluid.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF
residues crystallize after time and
contaminate the affected surfaces.
High outside temperatures If DEF heats up to over 122 ‡ (50 †) for
extended periods, e.g. as a result of direct
sunlight on the DEF reservoir, DEF can
decompose. Ammonia vapors develop as a
result.
G
WARNING
When opening the filler cap of the DEF tank
ammonia gas vapors may escape. Refill DEF
in a well ventilated area only. Ammonia gas
vapors have a pungent odor and are
particularly irritating for your skin, mucous
membranes,

and eyes. Inhaling ammonia gas
vapors will cause burning eyes, nose, and
throat, as well as coughing and watering eyes.
Low outside temperatures DEF freezes at a temperature of
approximately 12 ‡ (–11 †). The vehicle is
equipped

with a DEF preheating system when
it leaves the factory. Winter operation is
therefore also guaranteed at temperatures
below 12 ‡ (–11 †). Additives !
Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity Assuring the purity of DEF is particularly
important with respect to avoiding
malfunctions in the exhaust gas
aftertreatment system.
If DEF is pumped out of the DEF tank, e.g.
during

repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
! Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC exhaust gas
aftertreatment system Engine oil
Please bear the following in mind The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For

a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz Center
or go to the Internet site
http://www.mbusa.com (USA only).
! Never use engine oil or an oil filter of a
specification other than is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement Service products and capacities
527Technical data Z

intervals than those prescribed. You could
otherwise
cause engine damage or damage
to the exhaust gas aftertreatment.
Follow the instructions in the service
interval display regarding the oil change.
Otherwise, you may damage the engine and
the exhaust gas aftertreatment.
The table shows which engine oils have been
approved for your vehicle. Model Engine
model MB
Approval
S 550
36
S 550 4MATIC 36 278 229.5
S 600
275
S 63 AMG
157
229.5
37 S 65 AMG
275
S 350 BlueTEC
4MATIC
642 228.51,
229.31,
229.51
i
MB approval is indicated on the oil
containers.
Additives !
Do
not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity Viscosity describes the flow characteristics
of

a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE (viscosity)
classification suitable for the prevailing
outside temperatures. The following table
shows the correct SAE classification to be
used. The low-temperature characteristics of
engine oils can deteriorate significantly, e.g.
as a result of aging, soot and fuel deposits. It is therefore strongly recommended that you
carry out regular oil changes using an
approved

engine oil with the appropriate SAE
classification. Refrigerant of the air-conditioning
system
The air-conditioning system is filled with
R134a refrigerant and a special PAG
lubricant.
! Never use refrigerant R 12 (CFC) or
mineral lubricants. Otherwise, you could
damage the air-conditioning system. Brake fluid
G
WARNING
Over a period of time, the brake fluid absorbs
moisture from the air; this lowers its boiling
point.
If

the boiling point of the brake fluid is too low,
vapor pockets may form in the brake system
when the brakes are applied hard (e.g. when
driving downhill). This would impair braking
efficiency.
You should have the brake fluid renewed at
regular intervals. The brake fluid change
intervals can be found in the Service Booklet.
Only use brake fluid approved by Mercedes-
Benz. Information about approved brake
36 BlueEFFICIENCY
37 Restriction: only SAE 0W-40

or SAE 5W-40 engine oils may be used.528
Service products and capacities
Technical data

fluids can be obtained from any authorized
Mercedes-Benz Center or on the Internet at
http://bevo.mercedes-benz.com
.Coolant
Important safety notes The coolant is a mixture of water and
antifreeze/corrosion inhibitor. It performs
the following tasks:
R
corrosion protection
R antifreeze protection
R raising the boiling point
The engine cooling system is filled at the
factory with coolant that contains an
antifreeze/corrosion inhibitor that ensures
protection down to approximately -35 ‡
(-37 †).
! Only

add coolant that has been premixed
with the desired antifreeze protection.
Otherwise, the engine could be damaged.
Further information on coolants and on
filling can be found in the Mercedes-Benz
Specifications for Service Products, MB
Approval 310.1, e.g. on the Internet at
http://bevo.mercedes-benz.com. You can
also consult an authorized Mercedes-Benz
Center.
! Always use a suitable coolant mixture,
even in countries where high temperatures
prevail.
Otherwise, the engine cooling system is not
sufficiently protected from corrosion and
overheating.
If the coolant has antifreeze protection down
to -35 ‡ (-37 †), the boiling point of the
coolant under operating conditions is
approximately 266 ‡ (130 †).
Your vehicle has a range of aluminum
components. Aluminum components in the
engine make it necessary to use antifreeze/
corrosion inhibitor coolant that has been
specifically formulated to protect the
aluminum parts. Using other antifreeze/ corrosion inhibitors without these
characteristics affects the service life.
The

coolant must be used throughout the year
in order to maintain the necessary corrosion
protection and to provide protection from
overheating. In the Service Booklet, you can
find information on the intervals for renewal.
The renewal interval is determined by the
coolant type and the engine cooling system
design. The renewal interval in the Service
Booklet is only valid if the coolant is renewed
or filled up with Mercedes-Benz approved
products. Therefore, only use MB 325.0 or
326.0 anticorrosion/antifreeze or another
Mercedes-Benz approved product of the
same specification.
Information on other products with the same
specifications that are approved by
Mercedes-Benz can be obtained at an
authorized Mercedes-Benz Center or on the
Internet at http://bevo.mercedes-benz.com.
The coolant is checked at every maintenance
interval at an authorized Mercedes-Benz
Center.
The antifreeze/corrosion inhibitor
concentration in the engine cooling system
should:
R be at least 50%. This will protect the engine
cooling system against freezing down to
approximately -35 ‡ (-37 † ).
R not exceed 55% (antifreeze protection to
-49 ‡ [-45 † ]); otherwise, heat will not
dissipate as effectively.
If the coolant level is too low, MB 325.0 or
326.0 anticorrosion/antifreeze should be
added. Have the engine cooling system
checked for possible leaks. Windshield/headlamp cleaning
system
G
WARNING
Washer solvent/antifreeze is highly
flammable. Do not spill washer solvent/
antifreeze

on hot engine parts, because it may Service products and capacities
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Technical data
Z