Inserting
........................................ 225
Inserting/loading (Rear Seat
Entertainment System) ..................255
Notes on discs ............................... 234
Removing/ejecting (Rear Seat
Entertainment System) ..................256
Selecting amedia type .................. 228
Selecting atrack ............................ 229
Sound settings (balance, bass,
fader, treble ).................................. 139
DVD audio
Operating (on-board computer) .....381
DVD video
Operating (on-board computer) .....381 E
EASY-ENTRY feature Activating (COMAND) ....................266
Function/notes ............................. 115
EASY-EXIT feature
Activating (COMAND) ....................266
Crash-responsive ........................... 115
Function/notes ............................. 115
EBD (electronic brake force
distribution)
Display message ............................ 395
Function/notes ................................ 76
ECO function ...................................... 265
ECO start/stop function Deactivating/activating .................311
General information .......................310
Electrical fuses
see Fuses
Electronic brake force distribution
see EBD (electronic brake force
distribution)
Electronic Stability Program
see ESP ®
(Electroni cStability Program)
Electronic Traction System
see ETS/4ETS (Electronic
Tractio nSystem)
Emergency release
Driver' sdoor .................................... 90
Trunk ......................................... 94, 95
Vehicle ............................................. 90
Emergency spare wheel
Storage location ............................ 478Emergency Tensioning Devices
Function .......................................... .65
Safety guideline s............................. 49
Emissions control
Service and warranty information ....28
Engine
Check Engine warning lamp ........... 434
Display message ............................ 408
ECO start/stop function ................310
Engine number ............................... 530
Irregularr unning............................ 313
Jump-starting ................................. 488
Starting problems ..........................313
Starting the engine with the
SmartKey ....................................... 309
Starting with KEYLESS-GO .............309
Switching off .................................. 327
Tow-starting (vehicle) ..................... 492
Engine electronics
Problem (malfunction) ...................313
Engine emergency stop ....................495
Engine oil Adding ........................................... 466
Additives ........................................ 535
Checking the oil level ..................... 463
Checking the oil level using the
dipstick .......................................... 464
Checking the oil level using the
on-board computer ........................464
Display message ............................ 410
Filling capacity ............................... 535
Notes about oil grades ................... 534
Notes on oil level/consumption ....463
Temperature (on-board computer) .381
Viscosity ........................................ 535
Entering the frequency .....................217
Entry Deleting ......................................... 135
Saving ............................................ 137
ESP ®
(Electronic Stability
Program) Deactivating/activating .................386
Deactivating/activating (notes) .......76
Display message ............................ 391
ETS/4ETS ........................................ 76
Function/notes ................................ 75 Index
11
Temperature
Coolant .......................................... 374
Coolant (on-board computer) ......... 381
Engine oil (on-board computer) ...... 381
Outside temperature ..................... .375
Setting (climate control) ................298
Setting (COMAND) .........................270
Theft deterrent systems
ATA (Anti-Theft Alarm system) .........79
Immobilize r...................................... 79
Tilt/sliding sunroof
see Sliding sunroof
Time
Setting ........................................... 148
Setting summer/standard time .....148
Setting the forma t......................... 148
Setting the time ............................. 148
Setting the time/date forma t........ 148
Setting the time zone ..................... 148
Timing (RACETIMER) .........................382
Tiredness assistant see ATTENTION ASSIST
Tire pressure
Calling up (on-board computer) .....505
Checking manually ........................505
Display message ............................ 419
Maximum ....................................... 504
Notes ............................................. 503
Recommended ............................... 501
Tire pressure monitoring system
Function/notes ............................. 505
Restarting ...................................... 507
Warning lamp ................................. 436
Tires
Aspect ratio (definition) .................520
Average weight of the vehicle
occupants (definition) ....................518
Bar (definition) ............................... 518
Characteristics .............................. 518
Checking ........................................ 499
Definition of terms .........................518
Direction of rotatio n...................... 521
Display message ............................ 419
Distributio nofthe vehicle
occupants (definition) ....................520
DOT, Tire Identification Number
(TIN) .............................................. .517 DOT (Department of
Transportation) (definition)
............518
GAWR (Gross Axle Weight Rating)
(definition) ..................................... 519
GVW (Gross Vehicle Weight)
(definition) ..................................... 519
GVWR (Gross Vehicle Weight
Rating) (definition) .........................519
Important safety notes ..................498
Increased vehicle weight due to
optional equipment (definition) ......518
Kilopascal (kPa) (definition) ...........519
Labeling (overview )........................ 514
Load bearing index (definition) ......520
Load index ..................................... 517
Load index (definition) ...................519
M+S tires ....................................... 500
Maximum loaded vehicle weight
(definition) ..................................... 519
Maximum load on a tire
(definition) ..................................... 519
Maximum permissible tire
pressure (definition) ....................... 519
Maximum tire loa d......................... 512
Maximum tire load (definition) .......519
Optional equipment weight
(definition) ..................................... 520
PSI (pounds per square inch)
(definition) ..................................... 519
Replacing ....................................... 521
Service life ..................................... 499
Sidewall (definition) .......................520
Speed rating (definition) ................519
Storing ........................................... 521
Structure and characteristics
(definition) ..................................... 518
Temperature .................................. 514
TIN (Tire Identification Number)
(definition) ..................................... 520
Tire bea d(definition) ...................... 520
Tire pressure (definition) ................520
Tire pressures (recommended )...... 518
Tire size (data) ............................... 521
Tire size designation, load-bearing
capacity, speed rating .................... 515
Tire tread ....................................... 499
Tire tread (definition) .....................520
Total load limit (definition) .............520 24
Index
R
lubricants (e.g .engine oil, transmission oil)
R coolant
R brake fluid
R windshield washe rfluid
R climate control system refrigerant
Components and service products must be
matched .You should therefor eonly use
products tha thave been tested and approved
by Mercedes-Benz.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.co m.
You can recognize service products approved
by Mercedes-Ben zby the following
inscription on the containers:
R MB approval (e.g. MB approval 229.51)
R MB Approval (e.g. MB Approval 229.51)
Other designations or recommendations
indicate a level of quality or a specification in
accordance with an MB Sheet number (e.g.
MB 229.5). The yhave no tnecessarily been
approved by Mercedes-Benz. Fuel
Important safety notes G
WARNING
Gasoline and diesel fuels are highly flammable
and poisonous. They burn violently and can
cause serious injury.
Never allow sparks, flames or smoking
materials near gasoline or diesel fuel!
Turn off the engine before refueling.
Whenever you are around gasoline or diesel
fuel, avoid inhaling fumes and any skin or
clothing contact. Extinguish all smoking
materials.
Direct skin contact with fuels and the
inhalation of fuel vapors are damaging your
health. Tank capacity Total capacity
S 550
30
S 550 4MATIC 30
S 350 BlueTEC 4MATIC 21.9 US gal
(83.0 l) S 600
AMG vehicles
23.8 US gal
(90.0 l) Of which reserve
Approx.
2.9 US gal (11.0 l) Of which reserve fuel in
AMG vehicles
Approx.
3.7 US gal (14.0 l) Gasoline
Fuel grade
!
Do not use diesel to refuel vehicles with a
gasoline engine. Even small amounts of the
wrong fuel result in damage to the fuel
system and engine.
! You should only refuel with unleaded
premium-grade gasoline as this avoids
damaging the catalytic converter.
If engine running problems are apparent,
have the cause checked immediately and
repaired. Excess unburned fuel can
otherwise enter the catalytic converter,
leading to overheating and possibly
causing a fire.
! To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline may be used.
If there is no premium-grade unleaded
gasoline available and regular unleaded
gasoline must be used, please observe the
following precautions:
R only fill the fuel tank to half full with
regular unleaded gasoline and fill the rest
30 BlueEFFICIENCY Service products and filling capacities
531Technical data Z
Ammonia vapors have a pungent odor and are
particularly irritating to:
R skin
R mucous membranes
R eyes
You may experience a burning sensation in
your eyes, nose and throat, as well as
coughing and watering of the eyes.
Do not inhale any ammonia vapors that may
be released .Fill the DE Ftank only in well-
ventilated areas.
Low outside temperatures DEF freezes at a temperature of
approximately 12
‡(-11 †). The vehicl eis
equipped with a DEFp reheating system when
it leaves the factory. Winter operation is
therefore also guaranteed at temperatures
below 12 ‡ (-11 †).
Additives !
Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity !
Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC exhaust gas
aftertreatment system
Assuring the purity of DEF is particularly
important with respect to avoiding
malfunctions in the BlueTEC exhaust gas
aftertreatment system. If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
Total capacity of the DEF tank Model Total capacity
S 350 BlueTEC 4MATIC
6.6 US gal
(25.0 l) Engine oil
Points to note !
Never use engine oil or an oil filter of a
specificatio nothe rthan is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
intervals than those prescribed. You could
otherwise cause engine damage or damage
to the exhaust gas aftertreatment.
Follow the instructions in the service
interval display regarding the oil change.
Otherwise, you may damage the engine and
the exhaust gas aftertreatment.
The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz
Center. Or visit the website
http://bevo.mercedes-benz.com.
The table shows which engine oils have been
approved for your vehicle. 534
Service products and fillingc
apacitiesTechnical data
Model Engine
model MB
Approval
S 550
31
S 550 4MATIC 31 278 229.5
S 600
275
S 63 AMG
32 157
S 65 AMG
32 275
S 350 BlueTEC
4MATIC
642 228.51,
229.31,
229.51
i
MB approval is indicated on the oil
containers.
Filling capacities The following values refer to an oil change
including the oil filter. Model Capacity
S 550
33
S 550 4MATIC 33 9.0 US qt (8.5 l)
S 63 AMG
10.0 US qt (9.5 l)
34 S 600
S 65 AMG
9.5 US qt (9.0 l)
S 350 BlueTEC
4MATIC
8.5 US qt (8.0 l)
Additives
!
Do not use any additives in the engine oil.
This could damage the engine. Engine oil viscosity Viscosity describes the flow characteristics
of a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE (viscosity)
classification suitable for the prevailing
outside temperatures. The table shows you
which SAE classifications are to be used. The
low-temperature characteristics of engine
oils can deteriorate significantly, e.g. as a
result of aging, soot and fuel deposits. It is
therefore strongly recommended that you
carry out regular oil changes using an
approved engine oil with the appropriate SAE
classification.
Brake fluid
G
WARNING
Over a period of time, the brake fluid absorbs
moisture from the air; this lowers its boiling
point.
If the boiling point of the brake fluid is too low,
vapor pockets may form in the brake system
when the brakes are applied hard (e.g. when
driving downhill). This would impair braking
efficiency.
You should have the brake fluid renewed at
regular intervals. The brake fluid change
31 BlueEFFICIENCY
32 Only SAE 0W-40/SAE 5W-40 engine oils may be used.
33 BlueEFFICIENCY
34 Including external oil cooler. Service products and filling capacities
535Technical data
Z
intervals can be found in the Maintenance
Booklet.
Only use brake fluid approved by Mercedes-
Benz. Informatio nabout approved brake fluid
can be obtained at any qualified specialist
workshop or on the Internet at
http://bevo.mercedes-benz.com. Coolant
Important safety notes G
WARNING
Antifreeze is highly flammable. Fire, open
flames and smoking are prohibited when
handling antifreeze.
If antifreeze comes into contact with hot
engine parts, it may ignite and you could burn
yourself. Do not spill any antifreeze on hot
engine parts.
! Only add coolant that has been premixed
with the desired antifreeze protection. You
could otherwise damage the engine.
Further information on coolants can be
found in the Mercedes-Benz Specifications
for Service Products, MB Specifications for
Service Products 310.1, e.g. on the
Internet at
http://bevo.mercedes-benz.com. Or
contact a qualified specialist workshop.
! Always use a suitable coolant mixture,
even in countries where high temperatures
prevail.
Otherwise, the engine coolin gsystem is not
sufficiently protected from corrosion and
overheating.
The coolan tis a mixture of water and
antifreeze/corrosion inhibitor. It performs
the following tasks:
R corrosion protection
R antifreeze protection
R raising the boiling point If the coolant has antifreeze protection down
to -35 ‡ (-37 †), the boiling point of the
coolant under operating conditions is
approximately 266 ‡ (130 †).
The antifreeze/corrosion inhibitor
concentration in the engine cooling system
should:
R
be at least 50 %. This will protect the engine
cooling system against freezing down to
approximately -35 ‡ (-37 †).
R not exceed 55% (antifreeze protection
down to -49 ‡ [-45 †]). Otherwise, heat
will not be dissipated as effectively.
If the vehicle has lost coolant, add equal
amounts of water and antifreeze/corrosion
inhibitor. Mercedes-Benz recommends an
antifreeze/corrosion inhibitor concentrate in
accordance with MB Specifications for
Service Products 310.1.
The coolant is checked with every
maintenance interval at a qualified specialist
workshop.
i When the vehicle is first delivered, it is
filled with a coolant mixture that ensures
adequate antifreeze and corrosion
protection.
Capacity Model Capacity
S 550
35
S 550 4MATIC 35 Approx. 14.5 US qt
(13.7 l) S 600
Approx. 15.3 US qt
(14.5 l) S 63 AMG
Approx. 12.2 US qt
(11.5 l) S 65 AMG
Approx. 14.7 US qt
(13.9 l) S 350 BlueTEC
4MATIC
Approx. 12.0 US qt
(11.4 l) 35
BlueEFFICIENCY 536
Service products and filling capacitiesTechnical data