2013 MERCEDES-BENZ S-Class air condition

Switching the rear-compartment
climate control on/off using the rear
control panel X
Turn the SmartKey to position 2in the
ignition lock.
X To switch on: press rocker switch
001F(Y page 295) up or down and select
AUTO .
or
X Press rocker switch 001F(Ypage 295) up or
down and select MAN .
X To switch off: press rocker switch
001F(Y page 295) up or down and select
OFF .
Activating/deactivating cooling with
air dehumidification
Important information The cooling with air dehumidification function
is only available when the engine is running.
The air inside the vehicle is cooled and
dehumidified according to the temperature
selected. G
WARNING
If you switch off the cooling function, the
vehicle will not be cooled when weather
conditions are warm. The windows can fog up
more quickly. Window fogging may impair
visibility and endanger you and others.
Condensation may drip from the underside of
the vehicle when it is in cooling mode. This is
normal and not a sign that there is a
malfunction.
You can activate or deactivate the cooling
with air dehumidification function via
COMAND (Y page 271).
i The cooling with air dehumidification
function uses refrigerant R134a. This
coolant does not contain
chlorofluorocarbons, and therefore does
not damage the ozone layer. Problems with the cooling with air
dehumidification function If you can no longer switch on the cooling with
air dehumidification function via COMAND,
the cooling with air dehumidification function
is switched off due to a malfunction.
X
Consult a qualified specialist workshop. Setting climate control to automatic
G
WARNING
If you switch off the cooling function, the
vehicle will not be cooled when weather
conditions are warm. The windows can fog up
more quickly. Window fogging may impair
visibility and endanger you and others.
In automatic mode, the set temperature is
maintained automatically at a constant level.
The system automatically regulates the
temperature of the dispensed air, the airflow
and the air distribution.
Automatic mode will achieve optimal
operation if cooling with air dehumidification
is also activated. If desired, cooling with air
dehumidification can be deactivated.
Controlling the front climate control
using the front control panel X
Turn the SmartKey to position 2in the
ignition lock.
X Set the desired temperature.
X To switch on: press the0004rocker
switch up or down.
The indicator lamp in the 0004rocker
switch lights up. Operating the climate control systems
297Climate control Z

Windows fogged up on the outside
X
Switch on the windshield wipers.
X Activate automatic climate control.
i You should only select this setting until
the windshield is clea ragain. Rear window defroster
Activating/deactivating G
WARNING
Any accumulation of snow and ice should be
removed from the rear window before driving.
Visibility could otherwise be impaired,
endangering you and others.
The rear window defroster has a high current
draw. You should therefore switch it off as
soon as the window is clear. Otherwise, the
rear window defroster switches off
automatically after several minutes.
If the battery voltage is too low, the rear
window defroster may switch off.
X Turn the SmartKey to position 2in the
ignition lock.
X Press the 000Brocker switch up or down.
The indicator lamp in the 000Brocker
switch lights up or goes out.
Problems with the rear window
defroster The rear window defroster has deactivated
prematurely or cannot be activated.
X
Switch off any consumers that are not
required, e.g. reading lamps or interior
lighting.
When the battery is sufficiently charged,
the rear window defroster is activated
again automatically. Activating/deactivating air-
recirculation mode
You can deactivate the flow of fresh air if
unpleasant odors are entering the vehicle
from outside. The air already inside the
vehicle will then be recirculated. G
WARNING
Fogged windows impair visibility,
endangering you and others. If the windows
begin to fog on the inside, switching off the
air recirculation mode immediately should
clear interior window fogging. If interior
window fogging persists, make sure the air
conditioning is activated, or press the 0008
button.
X Turn the SmartKey to position 2in the
ignition lock.
X To activate: press the0010rocker switch
up or down.
The indicator lamp in the 0010rocker
switch lights up.
i Air-recirculation mode is activated
automatically at high outside
temperatures. The indicator lamp in the
0010 rocker switch is not lit when
automatic air-recirculation mode is
activated.
Outside air is added after about
30 minutes.
X To deactivate: press the0010rocker
switch up or down.
The indicator lamp in the 0010rocker
switch goes out. Operating the climate control systems
301Climate control Z

0025
Cente rvent thumbwheel, left
0023 Center air vent, left
X To open/close: turn thumbwheels 0026
and 0025up or down. Setting the side air vents
X
To open/close: turn thumbwheel 0026up or
down.
i Side window defroster vent 0002is never
completely shut, even if side air vent 0003is
shut. Setting the glove box air vent
When automatic climate control is activated,
the glove box can be ventilated, for instance
to cool its contents. The level of airflow
depends on the airflow and air distribution
settings.
! Close the air vent when heating the
vehicle.
At high outside temperatures, open the air
vent and activate the "cooling with air
dehumidification" function .Otherwise,
temperature-sensitive items stored in the
glove bo xcould be damaged. X
To open: turn thumbwheel 0002counter-
clockwise from position 0007to position 0006.
X To close: turn thumbwheel 0002clockwise
from position 0006to position 0007. Setting the rear-compartment air
vents
Setting the center vents in the rear
compartment 0002
Rear-compartment air vent, left
0003 Rear-compartment air vent, right
0026 Rear-compartment air vent thumbwheel,
right
0025 Rear control panel for automatic climate
control
0023 Rear-compartment air vent thumbwheel,
left
X To open/close: turn thumbwheel 0026or
0023 to the right or left.
i In vehicles without rear-compartmen tair-
conditioning system: close the rear- Setting the air vents
303Climate control Z

G
WARNING
If the engine is switched off and the ECO
symbol is show ningreen in the multifunction
display, the engine has been switched off
automatically. All of the vehicle's systems
remain active. If you open the door, unfasten
your seat belt or remove your foot from the
brake pedal, the engine will automatically
start. The vehicle may begi nmoving. You
could suffer serious or even fatal injury or
cause an accident resulting in injury or death.
Never leave the vehicle while the ECO symbol
in the multifunction display is shown in green
or yellow .Always secure the vehicle against
rolling away before leaving it.
! Always switch the ignition off and take the
key with you when leaving the vehicle.
Automatic engine switch-off The ECO start/stop function switches the
engine off automatically if the vehicle is
braked to a standstill and the brake remains
depressed with the transmission in position
D or N.
i You can still activate the HOLD function
when the vehicle is stationary, even if the
engine has been switched off
automatically. It is then not necessary to
continue applying the brakes during the
automatic stop phase. When you depress
the accelerator pedal, the engine starts
automatically and the braking effect of the
HOL Dfunction is deactivated. Depress the
accelerato rpedal carefully, as the engine
must be started first.
The engine is only switched off if:
R the outside temperature is within the range
which is suitable for the system.
R the engine is at normal operating
temperature.
R the set temperature for the vehicle interior
has been reached.
R the battery is sufficiently charged. R
the system detects that the windshield is
not fogged up when the air-conditioning
system is switched on.
R the hood is closed.
R no engine-relevant diagnostics are active.
R the driver's door is closed and the seat belt
is fastened.
Automatic engine start The engine is started automatically if you:
R
release the brake pedal when HOLD is not
activated and the transmission is in
position Dor N
R shift the transmission to position R
R depress the accelerator pedal
R switch off the ECO start/stop function or
switch to drive program Sor M
R unfasten your seat belt or open the driver's
door
The engine is also started automatically if:
R the vehicle starts to roll.
R the brake system requires this.
R the system detects moisture on the
windshield when the air-conditioning
system is switched on.
R the temperature in the vehicle interior
deviates from the set range.
R the charge level of the battery is too low.
Deactivating/activating the ECO start/
stop function General notes
You can deactivate and activate the ECO
start/stop function using COMAND
(Y
page 265).
i You can also use the programmable
button (Y page 124) to activate and
deactivate the ECO start/stop function if
you have assigned this function to the
button. Driving
311Driving and parking Z

Steering and braking requires significantly
more effort and you could lose control of the
vehicle and cause an accident as a result.
Do not turn off the engine while the vehicle is
in motion.
Exhaust check G
WARNING
Inhalation of exhaus tgas is hazardous to your
health. All exhaust gas contains carbon
monoxide (CO), and inhaling it can cause
unconsciousness and possible death.
Do no trun the engin einconfined areas (such
as a garage) which are not properly ventilated.
If you think that exhaust gas fumes are
entering the vehicle while driving, have the
cause determined and corrected
immediately. If you must drive under these
conditions, drive only with at least one
window fully open at all times.
Certain engine systems are designed to keep
the level of poisonous components in exhaust
fumes within legal limits.
These systems only work at peak efficiency if
they are serviced exactly in accordance with
the manufacturer's specifications. For this
reason, all work on the engine should only be
carried out by qualified and authorized
Mercedes-Benz technicians.
The engine settings must not be changed
under any circumstances. Furthermore, all
specific service work must be carried out at
regular intervals and in accordance with the
Mercedes-Benz service requirements. Details
can be found in the Maintenance Booklet. Braking
Important safety notes G
WARNING
On slippery road surfaces, never downshift in
order to obtain braking action. This could
result in drive wheel slip and reduced vehicle control. Your vehicle's ABS will not prevent
this type of loss of control.
G
WARNING
Make sure that you do not endanger other
road users when you apply the brakes.
Downhill gradients !
On long and steep gradients, you must
reduce the load on the brakes by shifting
early to a lower gear. This allows you to take
advantage of the engine braking effect and
helps avoid overheating and excessive
wear of the brakes.
When you take advantage of the engine
braking effect, a drive wheel may not turn
for some time, e.g. on a slippery road
surface. This could cause damage to the
drive train. This type of damage is not
covered by the Mercedes-Benz warranty.
Heavy and light loads G
WARNING
Depressing the brake pedal constantly results
in excessive and premature wear to the brake
pads.
It may also cause the brakes to overheat,
seriously impairing their effectiveness. It may
then not be possible to stop the vehicle in
sufficient time to avoid an accident.
If the brakes have been subjected to a heavy
load, do not stop the vehicle immediately, but
drive on for a short while. This allows the
airflow to cool the brakes more quickly.
Wet roads G
WARNING
After driving in heavy rain for some time
without applying the brakes or through water
deep enough to wet brake components, the
first braking action may be somewhat
reduced. You have to depress the brake pedal Driving tips
331Driving and parking
Z

more firmly. Maintain a safe distance from
vehicles in front.
After driving on a wet road or having the
vehicle washed, brake firmly while paying
attention to the traffic conditions. This will
warm up the brake discs, thereby drying them
more quickly and protecting them against
corrosion.
Limited braking performance on salt-
treated roads G
WARNING
The layer of saltont he brake discs and the
brake pads/linings may cause a delay in the
braking effect, resulting in a significantly
longer braking distance, which could lead to
an accident.
To avoid this danger, you should:
R occasionally brake carefully, without
putting other road users at risk, when you
are driving on salted roads. This helps to
remove any salt that may have started to
build up on the brake discs and the brake
pads/linings.
R maintain a greater distance to the vehicle
ahead and drive with particular care.
R carefully apply the brakes at the end of a
trip and immediately after commencing a
new trip, so that salt residues are removed
from the brake discs.
Servicing the brakes !
If the red brake warning lamp lights up in
the instrumentc luster and you hear a
warning tone while the engine is running,
the brake fluid level may be too low.
Observe additional warning messages in
the multifunction display.
The brake fluid level may be too low due to
brake pad wear or leaking brake lines.
Have the brake system checked
immediately. This work should be carried
out at a qualified specialist workshop. All checks and maintenance work on the
brake system must be carried out at a
qualified specialist workshop. Consult a
qualified specialist workshop to arrange this.
Have brake pads installed and brake fluid
replaced at a qualified specialist workshop. G
WARNING
If brake pads or brake fluid other than those
recommended are used, the braking
properties of the vehicle can be degraded to
an extent that safe braking is substantially
impaired. This could result in an accident.
! Vehicles with 4MATIC: function or
performance tests may only be carried out
on a 2-axle dynamometer. If you are
planning to have the vehicle tested on such
a dynamometer, contact an authorized
Mercedes-Benz Center to obtain further
information first. Otherwise, you could
damage the drive train or the brake system.
! Vehicles with 4MATIC: as the ESP®
system operates automatically, the engine
and the ignition must be switched off
(SmartKey in position 0or 1in the ignition
lock or Start/Stop button in position 0or
1) when the electric parking brake is being
tested on a brake dynamometer.
Braking maneuvers triggere dautomatically
by ESP ®
may seriously damage the brake
system.
! Vehicles with 4MATIC: as the ESP®
system operates automatically, the engine
and the ignition system must be switched
off (SmartKey in position 0or 1in the
ignition lock or Start/Stop button in
position 0or 1) when:
R testing the electric parking brake on a
brake dynamometer.
R you intend to have the vehicle towed with
one of the axles raised.
Braking maneuvers triggered automatically
by ESP ®
may seriously damage the brake
system. 332
Driving tipsDriving and pa
rking

If the brake system has only been subject to
moderate loads, you should test the
functionality of yourb rakes at regular
intervals. To do so, press firmly on the brake
pedal when driving at a high speed. This
improves the grip of the brake pads. G
WARNING
Make sure that you do not endange rother
road users when you apply the brakes.
You can find a description of Brake Assist
(BAS) on ( Ypage 74) or of BAS PLUS on
(Y page 74).
High-performance brake system for
AM Gvehicles The high-performance brake system is
installed only on the S63AMG and S65AMG. G
WARNING
New vehicle brake pads and discs, and
replacement brake pads and discs may take
several hundred miles of driving until they
provide optimum braking efficiency. Until that
time, you may need to use increased brake
pedal pressure while braking. Please be aware
of this and adjust your driving and braking
accordingly during this break-in period.
Excessive high-demand braking will cause
correspondingly high brake wear. Please be
attentive to the brake warning lamp in the
instrument cluster and brake condition
messages in the multifunction display.
Especially for high performance driving, it is
important to maintain and have the brake
system checked regularly.
The high-performance brake system is
designed for heavy loads. This may lead to
noise when braking. This will depend on:
R speed
R braking force
R environmental conditions, such as
temperature and humidity
The wear of individual components of the
brake system, such as the brake pads/linings or brake discs, depends on the individual
driving style and operating conditions.
For this reason, it is impossible to state a
mileage that will be valid under all
circumstances. An aggressive driving style
will lead to high wear. You can obtain further
information about this from your authorized
Mercedes-Ben
zCenter. Driving on wet roads
Hydroplaning If water has accumulated to a certain depth
on the road surface, there is a danger of
hydroplaning occurring, even if:
R
you drive at low speeds.
R the tires have adequate tread depth.
For this reason, in the event of heavy rain or
in conditions in which hydroplaning can
occur, you must drive in the following
manner:
R lower your speed.
R avoid ruts.
R brake carefully.
Driving on flooded roads !
Do not drive through flooded areas.
Check the depth of any water before driving
through it. Drive slowly through standing
water. Otherwise, water may enter the
vehicle interior or the engine compartment.
This can damage the electronic
components in the engin eorthe automatic
transmission. Water can also be drawn in
by the engine's air suction nozzles and this
can cause engine damage. Winter driving
Important safety notes G
WARNING
If the vehicle becomes trapped in snow,
ensure that snow is kept away from the Driving tips
333Driving and parking
Z

exhaust pipe and from around the vehicle as
long as the engine is running. Otherwise,
poisonous carbon monoxide (CO) may enter
the vehicle, resulting in loss of consciousness
and even death.
To assure sufficien
tfresh air ventilation, open
a window slightly on the side of the vehicle
not facing the wind.
Have yourv ehicle winterproofed at a qualified
specialist workshop at the onset of winter.
Observe the notes in the "Winter operation"
section (Y page 500).
Driving with summer tires Observe the notes in the "Winter operation"
section (Y page 500).
Slippery road surfaces G
WARNING
The outside temperature indicator is not
designed to serve as an ice-warning device
and is therefore unsuitable for that purpose.
Indicated temperatures just above the
freezing point do not guarantee that the road
surface is free of ice. The road may still be icy,
especially in wooded areas or on bridges. G
WARNING
On slippery road surfaces, never downshift in
order to obtain braking action .This could
result in drive wheel slip and reduced vehicle
control. Your vehicle's ABS will not prevent
this type of loss of control.
Drive particularly carefully on slippery road
surfaces. Avoid sudden acceleration, steering
and braking maneuvers. Do not use the cruise
control or DISTRONIC PLUS.
If the vehicle threatens to skid or cannot be
stopped when moving at low speed:
X Shift the transmission to position N.
i For more information on driving with
snow chains, see (Y page 501). G
WARNING
Make sure that you do not endanger other
road users when you apply the brakes. Driving systems
Cruise control
Important safety notes Cruise control maintains a constant road
speed for you. It brakes automatically in order
to avoid exceeding the set speed. On long and
steep downhill gradients, especially if the
vehicle is laden, you must select shift range
1, 2or 3in good time. By doing so, you will
make use of the braking effect of the engine,
which relieves the load on the brake system
and prevents the brakes from overheating
and wearing too quickly.
Use cruise control only if road and traffic
conditions make it appropriate to maintain a
steady speed for a prolonged period. You can
store any road speed above 20 mph
(30 km/h). G
WARNING
The cruise control is a convenience system
designed to assist the driver during vehicle
operation. The driver is and must always
remain responsible for the vehicle's speed
and for safe brake operation.
Only use the cruise control if the road, traffic,
and weather conditions make it advisable to
travel at a constant speed.
R The use of the cruise control can be
dangerous on winding roads or in heavy
traffic because conditions do not allow safe
driving at a constant speed.
R The use of the cruise control can be
dangerous on slippery roads. Rapid
changes in tire traction can result in wheel
spin and loss of control.
R Deactivate the cruise control when driving
in fog. 334
Driving systemsDriving and parking