2012 MERCEDES-BENZ S-CLASS SEDAN oil additives

1, 2, 3 ...
115 V socket ...................................... 444
12 V socket see Sockets
4ETS
see ETS/4ETS (Electronic
Traction System)
4MATIC (permanent four-wheel
drive) .................................................. 350
4MATIC off-road system ................... 350
A
ABC see Active Body Control (ABC)
ABS (Anti-lock Braking System)
Display message ............................ 391
Function/notes ................................ 73
Important safety notes ....................73
Warning lamp ................................. 425
Activating/deactivating cooling
with air dehumidification ................. 297
Active Blind Spot Assist Activating/deactivating (on-
board computer) ............................ 387
Function/information ....................367
Active Body Control (ABC)
Display message ............................ 412
Function/notes ............................. 348
Active Driving Assistance package . 366
Active Lane Keeping Assist Activating/deactivating (on-
board computer) ............................ 387
Display message ............................ 413
Function/information ....................369
Active multicontour seat .......... 112, 276
Active service system PLUS see ASSYST PLUS service interval
display
ADAPTIVE BRAKE ................................. 77
Adaptive Damping System (ADS) ..... 348
Adaptive Highbeam Assist Display message ............................ 406
Function/notes ............................. 284
Switching on/off (on-board
computer) ...................................... 388
Additional speedometer ................... 388
Additives (engine oil) ........................ 529
Address Entering (example) .........................157
see Address book
Address book
Calling up ....................................... 209
Connecting a call ........................... 212
Creating an entry ........................... 210
Deleting an entry ........................... 211
Entering characters .......................136
Entry as a home address ...............182
Importing contacts ........................208
Introduction ................................... 207
Starting route guidance .................212
Voice tag ....................................... 213
Air bags
Display message ............................ 401
Front air bag (driver, front
passenger) ....................................... 52
Important safety notes ....................50
PASSENGER AIR BAG OFF
indicator lamp .................................. 54
Safety guidelines ............................. 49
Side impact air bag ..........................52
Window curtain air bag ....................53
Air-conditioning system
see Climate control
Air distribution
Setting ........................................... 299
Setting (COMAND) .........................270
Air filter (display message) .............. 409
Airflow Setting ........................................... 299
Setting (COMAND) .........................271
AIRMATIC
Display message ............................ 411
Function/notes ............................. 347
Air pressure
see Tire pressure
Air vents
Glove box ....................................... 303
Important safety notes ..................302
Rear ............................................... 303
Setting ........................................... 302
Setting the center air vents ...........302
Setting the side air vents ...............303
Alarm system
see ATA (Anti-Theft Alarm system) 4Index

Inserting/loading (Rear Seat
Entertainment System) ..................255
Notes on discs ............................... 234
Removing/ejecting (Rear Seat
Entertainment System) ..................256
Selecting a media type ..................228
Selecting a track ............................ 229
Sound settings (balance, bass,
fader, treble) .................................. 139
DVD audio
Operating (on-board computer) .....381
DVD video
Operating (on-board computer) .....381
E
EASY-ENTRY feature Activating (COMAND) ....................266
Function/notes ............................. 115
EASY-EXIT feature
Activating (COMAND) ....................266
Crash-responsive ........................... 115
Function/notes ............................. 115
EBD (electronic brake force
distribution) Display message ............................ 394
Function/notes ................................ 77
ECO function ...................................... 265
ECO start/stop function Deactivating/activating .................311
General information .......................310
Electrical fuses
see Fuses
Electronic brake force distribution
see EBD (electronic brake force
distribution)
Electronic Stability Program
see ESP ®
(Electronic Stability Program)
Electronic Traction System
see ETS/4ETS (Electronic
Traction System)
Emergency release
Driver's door .................................... 90
Trunk ......................................... 94, 95
Vehicle ............................................. 90
Emergency spare wheel
Storage location ............................ 474
Emergency Tensioning Devices
Function ........................................... 65
Safety guidelines ............................. 49
Emissions control
Service and warranty information ....28
Engine
Check Engine warning lamp ........... 429
Display message ............................ 406
ECO start/stop function ................310
Engine number ............................... 524
Irregular running ............................ 313
Jump-starting ................................. 483
Starting problems ..........................313
Starting the engine with the key ....309
Starting with KEYLESS-GO .............309
Switching off .................................. 327
Tow-starting (vehicle) ..................... 487
Engine electronics
Problem (malfunction) ...................313
Engine emergency stop .................... 490
Engine oil Adding ........................................... 462
Additives ........................................ 529
Checking the oil level ..................... 459
Checking the oil level using the
dipstick .......................................... 460
Checking the oil level using the
on-board computer ........................460
Display message ............................ 408
Filling capacity ............................... 529
Notes about oil grades ................... 528
Notes on oil level/consumption ....459
Temperature (on-board computer) . 381
Viscosity ........................................ 529
Entering the frequency ..................... 217
Entry Deleting ......................................... 135
Saving ............................................ 137
ESP ®
(Electronic Stability
Program) Deactivating/activating .................386
Deactivating/activating (notes) .......76
Display message ............................ 391
ETS/4ETS ........................................ 76
Function/notes ................................ 75
Important safety information ...........75
Warning lamp ................................. 426Index11

Important safety notes ..................107
Multicontour seat .......................... 112
Seat heating problem ....................113
Seat ventilation problem ................114
Selecting (COMAND) .....................274
Storing settings (memory
function) ........................................ 118
Switching seat heating on/off .......113
Switching seat ventilation on/off ..113
Selecting stations (radio)
Using station presets .....................216
Using station search ......................216
Sending DTMF tones ......................... 207
Sensors (cleaning instructions) ....... 470
Service Center see Qualified specialist workshop
Service interval display
Displaying service messages .........465
Hiding service messages ...............465
Notes ............................................. 465
Service messages ..........................465
Service menu (on-board computer) . 387
Service products Brake fluid ..................................... 529
Coolant (engine) ............................ 530
DEF special additives .....................527
Engine oil ....................................... 528
Fuel ................................................ 525
Important safety notes ..................524
Washer fluid ................................... 531
Setting a station (radio)
Via manual frequency entry ...........217
Settings
Display ........................................... 147
Menu overview .............................. 125
On-board computer .......................387
Picture (COMAND) .........................244
Picture (Rear Seat Entertainment
System) ......................................... 253
Sound settings ............................... 139
System settings ............................. 147
Setting the language
COMAND ....................................... 153
Rear Seat Entertainment System ...262
Setting the night design ................... 147
Setting the text reader speed .......... 149
Setting the vehicle level ................... 349Setting the volume
Telephone calls .............................. 138
Video AUX ..................................... 250
Side impact air bag ............................. 52
Side marker lamp (display
message) ............................................ 405
Side windows Convenience closing feature ............97
Convenience opening feature ..........96
Important safety information ...........95
Opening/closing .............................. 96
Problem (malfunction) .....................98
Resetting ......................................... 98
Sliding sunroof
Important safety notes ....................98
Opening/closing .............................. 99
Problem (malfunction) ...................103
Resetting ....................................... 100
see Panorama roof with power
tilt/sliding panel
SmartKey
Changing the battery .......................85
Changing the programming .............84
Checking the battery .......................85
Convenience closing feature ............97
Convenience opening feature ..........96
Display message ............................ 421
Door central locking/unlocking .......82
Important safety notes ....................82
Loss ................................................. 87
Mechanical key ................................ 84
Positions (ignition lock) .................307
Problem (malfunction) .....................87
Starting the engine ........................309
SMS message
see Text message
Snow chains ...................................... 495
Socket Glove box ....................................... 444
Sockets
Points to observe before use .........443
Rear compartment .........................444
Trunk ............................................. 444
Sound menu ....................................... 139
Sounds see Sound settings Index21

HEnvironmental note
When adding oil, take care not to spill any. If
oil enters the soil or waterways, it is harmful
to the environment.
! Only use engine oils and oil filters that
have been approved for vehicles with a
service system. You can obtain a list of the
engine oils and oil filters tested and
approved in accordance with the
Mercedes-Benz Specifications for Service
Products at any Mercedes-Benz Service
center.
Damage to the engine or exhaust system is
caused by the following:
R using engine oils and oil filters that have
not been specifically approved for the
service system
R replacing engine oil and oil filters after
the interval for replacement specified by
the service system has been exceeded
R using engine oil additives.
! Do not add too much oil. adding too much
engine oil can result in damage to the
engine or to the catalytic converter. Have
excess engine oil siphoned off.
Example: engine oil cap
XTurn cap : counterclockwise and remove
it.XAdd engine oil.
Vehicles with oil level measurement
function in the on-board computer: observe
the information in the on-board computer
when doing so. Vehicles with oil dipstick: if
the oil level is at or below the MIN mark onthe oil dipstick, add 0.55 to 1.1 US qt (0.5
to 1.0 l) engine oil.XReplace cap : on the filler neck and turn
clockwise.
Ensure that the cap locks into place
securely.XCheck the oil level again with the oil
dipstick ( Y page 460) or the on-board
computer ( Y page 460).
Further information on engine oil
( Y page 528).
Checking and adding other service
products
Checking the coolant level
GWARNING
In order to avoid any potentially serious burns:
R use extreme caution when opening the
hood if there are any signs of steam or
coolant leaking from the cooling system, or
if the coolant temperature display indicates
that the coolant is overheated.
R do not remove the pressure cap on the
coolant reservoir if the coolant temperature
is above 158 ‡ (70 †). Allow the engine to
cool down before removing the cap. The
coolant reservoir contains hot fluid and is
under pressure.
R using a rag, slowly turn the cap
approximately 1
/ 2 turn to relieve excess
pressure. If opened immediately, scalding
hot fluid and steam will be blown out under
pressure.
R do not spill antifreeze on hot engine parts.
Antifreeze contains ethylene glycol which
may burn if it comes into contact with hot
engine parts.
Engine compartment463Maintenance and careZ

iThe data shown on the identification plate
is example data. This data is different for
every vehicle and can deviate from the data
shown here. You can find the data
applicable to your vehicle on the vehicle's
identification plate.
Vehicle identification number (VIN)
The vehicle identification number (VIN) can
be found in the following locations:
R on the vehicle identification plate
( Y page 523)
R at the lower edge of the windshield
( Y page 524)
In addition to being stamped on the vehicle
identification plate, the vehicle identification
number (VIN) is also stamped onto the vehicle
body. It is under the trim behind the rear seat
armrest.
XFold down the rear seat armrest.XOpen the trim.
You will see vehicle identification number
(VIN) :.Engine number:Emission control information plate,
including the certification of both federal
and Californian emissions standards;Engine number (stamped into the
crankcase)=VIN (on the lower edge of the windshield)
Service products and filling
capacities
Important safety notes
GWARNING
Comply with all valid regulations with respect
to handling, storing and disposing of service
fluids. Otherwise, you could endanger
persons or the environment.
Keep service fluids out of the reach of
children.
For health reasons, you should prevent
service fluids from coming into direct contact
with your skin or clothing.
If a service fluid is swallowed, contact a
physician immediately.
Service products include the following:
R fuels (e.g. gasoline, diesel)
R additives for exhaust gas aftertreatment,
e.g. DEF
R lubricants (e.g. engine oil, transmission oil)
R coolant
R brake fluid
524Service products and filling capacitiesTechnical data

with premium-grade unleaded gasoline
as soon as possible.
R do not drive at the maximum speed.
R avoid sudden acceleration.
R if the vehicle is carrying a light load, e.g.
two passengers without luggage, do not
allow the engine to rev above 3000 rpm.
R if the vehicle is fully loaded or is being
operated in mountainous terrain, do not
depress the accelerator pedal further
than Ô of the pedal travel.
Only refuel with premium-grade unleaded
gasoline with a minimum octane number of
91.
Reformulated Gasoline (RFG) and/or
unleaded gasoline with additives can be used.
However, the concentration of additives in
the fuel must be less than 10%, e.g.
R Ethanol
R TAME
R ETBE
R IPA
R TBA
For MTBE, the concentration should not
exceed 15%.
The concentration of methanol in gasoline
including other additives must not exceed
3%.
Using mixtures of methanol and ethanol is not
permitted. Gasohol, a mixture of 10% ethanol
and 90% unleaded gasoline, can be used.
All of these mix fuels must fulfill the fuel
requirements, e.g.:
R knock resistance
R boiling point
R vapor pressure
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult an
authorized Mercedes-Benz Center or visit
http://www.mbusa.com (USA only).Information on refueling ( Y page 321).
Additives
! Do not refuel with low-grade fuel and do
not use fuel additives that are not tested
and approved for Mercedes-Benz vehicles.
Damage to or malfunctions of the fuel
system may otherwise occur.
One of the main problems of poor fuel quality
is the forming of deposits that are created
during the gasoline combustion process.
Mercedes-Benz recommends that you use
branded fuels that have additives.
If you use fuels without these additives over
a longer period of time, carbon deposits may
build up. These deposits form at the inlet
valves and in the combustion chamber in
particular.
This could lead to engine problems, e.g.:
R longer engine warm-up phase
R uneven idle
R engine noise
R misfiring
R loss of power
Carbon deposits may form if the availability
of gasoline with relevant additives is
insufficient (in certain regions). In this case,
Mercedes-Benz recommends additives
approved for use in Mercedes-Benz vehicles;
see http://bevo.mercedes-benz.com.
For a list of approved products, consult an
authorized Mercedes-Benz Center. Comply
with the instructions for use on the product
label.
Do not mix other fuel additives with fuel. This
causes unnecessary costs and could damage
the engine.
Diesel
Fuel grade
GWARNING
Do not use gasoline to refuel vehicles with a
diesel engine. Never mix diesel with gasoline.
This causes damage to the fuel system and
526Service products and filling capacitiesTechnical data

Ammonia vapors have a pungent odor and are
particularly irritating to:
R skin
R mucous membranes
R eyes
You may experience a burning sensation in
your eyes, nose and throat, as well as
coughing and watering of the eyes.
Do not inhale any ammonia vapors that may
be released. Fill the DEF tank only in well-
ventilated areas.
Low outside temperatures
DEF freezes at a temperature of
approximately 12 ‡ (-11 †). The vehicle is
equipped with a DEF preheating system when
it leaves the factory. Winter operation is
therefore also guaranteed at temperatures
below 12 ‡ (-11 †).
Additives
! Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity
! Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC exhaust gas
aftertreatment system
Assuring the purity of DEF is particularly
important with respect to avoiding
malfunctions in the BlueTEC exhaust gas
aftertreatment system.
If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
Total capacity of the DEF tankModelTotal capacityS 350 BlueTEC 4MATIC6.6 US gal (25.0 l)
Engine oil
Please bear the following in mind
! Never use engine oil or an oil filter of a
specification other than is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
intervals than those prescribed. You could
otherwise cause engine damage or damage
to the exhaust gas aftertreatment.
Follow the instructions in the service
interval display regarding the oil change.
Otherwise, you may damage the engine and
the exhaust gas aftertreatment.
The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz
Center. Or go to
http://bevo.mercedes-benz.com (USA only).
The table shows which engine oils have been
approved for your vehicle.
528Service products and filling capacitiesTechnical data

ModelEngine
modelMB
ApprovalS 550 32
S 550 4MATIC 32278229.5S 600275S 63 AMG33157S 65 AMG33275S 350 BlueTEC
4MATIC642228.51,
229.31,
229.51
i MB approval is indicated on the oil
containers.
Capacities
The following values refer to an oil change
including the oil filter.
ModelCapacityS 350 BlueTEC
4MATIC8.5 US qt (8.0 l)S 550 34
S 550 4MATIC 34
S 63 AMG9.0 US qt (8.5 l)S 600
S 65 AMG9.5 US qt (9.0 l)
Additives
! Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity
Viscosity describes the flow characteristics
of a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE (viscosity)
classification suitable for the prevailing
outside temperatures. The table shows you
which SAE classifications are to be used. The
low-temperature characteristics of engine
oils can deteriorate significantly, e.g. as a
result of aging, soot and fuel deposits. It is
therefore strongly recommended that you
carry out regular oil changes using an
approved engine oil with the appropriate SAE
classification.
Brake fluid
GWARNING
Over a period of time, the brake fluid absorbs
moisture from the air; this lowers its boiling
point.
If the boiling point of the brake fluid is too low,
vapor pockets may form in the brake system
when the brakes are applied hard (e.g. when
driving downhill). This would impair braking
efficiency.
You should have the brake fluid renewed at
regular intervals. The brake fluid change
32 BlueEFFICIENCY.
33 Only SAE 0W-40/SAE 5W-40 engine oils may be used.
34 BlueEFFICIENCY.Service products and filling capacities529Technical dataZ