Page 1 of 44
ML 450 HYBRID
Supplemental Operating Instructions
164_ZA; 2; 2, en-US
d2ureepe,Version: 2.11.8.1 2009-05-12T15:08:04+02:00 - Seite 1
Page 2 of 44
Symbols
Trademarks
®
:
R ESP ®
is a registered trademark of Daimler.
The following symbols are found in this
Supplemental Operating Instructions: G
Warning!
Warning notices draw your attention to
hazards
that may endanger your health or life,
or the health or life of others.
! Highlights hazards that may result in
damage to your vehicle.
i Helpful hints or further information you
may find useful.
X This symbol points to instructions
for you to follow.
X A number of these symbols
appearing in succession indicates
a multiple-step procedure.
Y page This symbol tells you where to look
for further information on a topic.
YY This continuation symbol marks a
warning or procedure which is
continued on the next page.
Display Text in displays, such as the control
system, are printed in the type
shown here.
164_ZA; 2; 2, en-US
d2ureepe,
Version: 2.11.8.1 2009-05-12T15:08:04+02:00 - Seite 2
Page 3 of 44

Our company and staff congratulate you on
the purchase of your new Mercedes-Benz.
Your selection of our product is a
demonstration of your trust in our company
name.
Furthermore, it exemplifies your desire
to own an automobile that will be as easy as
possible to operate and provide years of
service.
Your Mercedes-Benz represents the efforts of
many skilled engineers and craftsmen. To
help assure your driving pleasure, and also
the safety of you and your passengers, we ask
you to make a small investment of time:
R Please read this manual carefully, then
return it to your vehicle where it will be
handy for your reference.
R Please follow the recommendations
contained in this manual. They are
designed to acquaint you with the
operation of your Mercedes-Benz.
R Please pay attention to the warnings and
cautions contained in this manual. They are
designed to help improve the safety of the
vehicle operator and occupants.
We extend our best wishes for many miles of
safe, pleasurable driving.
Mercedes-Benz USA, LLC
A Daimler Company
1645845583 É164584558
3BËÍ
164_ZA; 2; 2, en-US
d2ureepe,
Version: 2.11.8.1 2009-05-12T15:08:04+02:00 - Seite 1
Page 4 of 44
164_ZA; 2; 2, en-US
d2ureepe,
Version: 2.11.8.1 2009-05-12T15:08:04+02:00 - Seite 2
Page 5 of 44
Index
....................................................... 4Introduction ...........................................
7Safety and security
...............................8Controls in detail
................................. 11Operation .............................................
20Practical hints .....................................
24Technical data .....................................
36 Contents
3164_ZA; 2; 2, en-US
d2ureepe,
Version: 2.11.8.1 2009-05-12T15:08:04+02:00 - Seite 3
Page 6 of 44

A
ABS (Antilock Brake System) ............... 9
Warning lamp .............................
13, 29
Anticorrosion/antifreeze ....................39
Antilock Brake System see ABS
Automatic shift program ....................18
Automatic transmission Automatic shift program ..................18
Messages in the multifunction
display ............................................. 25
Program mode
indicator .................................... 13, 19
Program mode selector switch
(automatic shift program) ................18
Axle oils ................................................ 38B
BAS (Brake Assist System) ................... 9
Battery Charging .......................................... 32
Charging condition high-voltage
battery (COMAND) ........................... 14
Jump starting ................................... 33
Messages in the multifunction
display
............................................. 26
Safety notes ..................................... 32
see High-voltage battery
Brake Assist System
see BAS
Brakes
Warning
lamp .......................................... 13, 29
Brake system
see RBS C
Capacities and recommended
fuel/lubricants .................................... 38
Charging condition high-voltage
battery (COMAND) ...............................
14
COMAND
Charging condition high-voltage
battery ............................................. 14
Fuel consumption ............................ 15Generated electric power
................15
Overview .......................................... 13
Combustion engine
Malfunction ......................................
30
Starting ............................................ 16
Consumption statistics (COMAND) ...15
Control system Overview .......................................... 13
Coolant
Anticorrosion/antifreeze ................. 39
Capacities ........................................ 38
Cruise control ...................................... 10 D
Displays
Charging condition high-voltage
battery (COMAND) ........................... 14
Messages in the multifunction
display
............................................. 24
Driving and parking
Safety notes ..................................... 16
Driving off ............................................ 17
Driving safety systems ABS .................................................... 9
BAS .................................................... 9
RBS .................................................... 9
Driving systems
Cruise control .................................. 10
Driving tips .......................................... 17 E
Engine .............................................
16, 30
Malfunction indicator
lamp ................................................. 13
see Combustion engine
Engine oil
Adding ............................................. 22
Checking level ................................. 21
Enviromental protection ....................... 7
ESP ®
(Electronic Stability Program)
Warning lamp ............................. 13, 29 F
Fluids
Automatic transmission fluid ........... 38
Brake fluid ....................................... 384
Index 164_ZA; 2; 2, en-US
d2ureepe,
Version: 2.11.8.1 2009-05-12T15:08:04+02:00 - Seite 4
Page 7 of 44

Capacities ........................................
38
Engine coolant ................................. 38
Engine oil ......................................... 38
Power steering fluid ......................... 38
Washer and headlamp cleaning
system ............................................. 39
Front axle oil ........................................ 38
Fuel ....................................................... 20
Capacity, fuel tank ........................... 38
Fuel filler flap and cap ...................... 21
Premium unleaded gasoline .............38
Fuel filler flap ....................................... 21
Opening manually ............................ 31
Unlocking ......................................... 20
Fuel filler flap switch ..........................20
Fuels, coolants, lubricants etc.
Capacities ........................................ 38
Fuel tank
Capacity ........................................... 38
Fuel filler flap and cap ...................... 21 G
Gasoline see Fuel
H
High voltage see Safety notes
High-voltage battery ............................. 8
Charging condition (COMAND) ........ 14
Exhaustive discharge .......................32
Messages in the multifunction
display ............................................. 26
HYBRID system
Automatic switch-off .................... 8, 31
Overview .......................................... 12
READY indicator ......................... 13, 16 I
Indicator and warning lamp SRS .................................................. 31
Indicator lamp
see Lamps, indicator and warning
Instrument cluster .............................. 13
Lamps .............................................. 29
Introduction ......................................... 11 J
Jump starting ....................................... 33 L
Lamp see Lamps, indicator and warning
Lamps, indicator and warning ............ 29
ABS/ESP ®
................................. 13, 29
Brakes
(red) ........................................... 13, 29
Instrument cluster .....................13, 29
RBS ............................................ 13, 29 M
Message see Lamps, indicator and warning
Motor Octane Number
see MON
Multifunction display
Symbol messages ............................ 26
Text messages ................................. 25
Vehicle status messages ................. 24
Multifunction display messages
Automatic transmission ................... 25
Battery ....................................... 26, 28
Display malfunction .........................24
Gas cap ............................................ 27
Power steering ................................. 27 O
Oil level see Engine oil, Checking level
Operating safety .................................... 7 P
Parking ................................................. 18
Power gauge .................................. 13, 14
Power steering
Messages in the multifunction
display
............................................. 27
Program mode selector switch
Automatic shift program ..................18 Index
5 164_ZA; 2; 2, en-US
d2ureepe,
Version: 2.11.8.1 2009-05-12T15:08:04+02:00 - Seite 5
Page 8 of 44

R
RBS (Recuperative Brake
System) ............................................ 9, 11
Malfunction ................................
29, 30
Warning lamp ............................. 13, 29
READY indicator ............................ 13, 16
Rear axle oil ......................................... 38
Recuperation statistics (COMAND) ...15
Refueling .............................................. 20
Research Octane Number see RON
Rims ...................................................... 37
Risk of fire
see Safety notes S
Safety see Operating safety
Safety notes ........................................... 8
Silent-Start mode ................................ 16
SRS (Supplemental Restraint System)
Warning lamp ................................... 31
Starting
see Combustion engine
Submenu
Resetting values (COMAND) ............ 16T
Technical data Capacities fuels, coolants,
lubricants etc. .................................. 38
Coolant ............................................ 39
Engine oils ....................................... 39
Rims and tires .................................. 37
Vehicle specification ML 450
HYBRID ............................................ 36
Washer and headlamp cleaning
system ............................................. 39
Tires ...................................................... 37U
Unlocking
Fuel filler flap
................................... 20 V
Vehicle
Disuse .............................................. 32
Vehicle fire
see Safety notes
Vehicle modifications ........................... 7
Vehicle specification
ML 450 HYBRID ............................... 36 W
Warning labels ....................................... 8
Wheels, sizes ....................................... 37
Winter tires .......................................... 376
Index 164_ZA; 2; 2, en-US
d2ureepe,
Version: 2.11.8.1 2009-05-12T15:08:04+02:00 - Seite 6