2008 MERCEDES-BENZ S-Class octane

16 IntroductionOperator’s ManualFor additional information refer to the
Mercedes-Benz Roadside Assistance Pro-
gram brochure (in the USA) or the Road-
side Assistance section of the Service &
Warranty Information booklet (in Canada)
in your vehicle literature portfolio.Change of address or ownership
If you change your address, be sure to
send in the “Change of Address Notice”
found in the Service and Warranty Informa-
tion Booklet, or simply call the
Mercedes-Benz Customer Assistance
Center (in the USA) at
1-800-FOR-MERCedes, or Customer
Service (in Canada) at 1-800-387-0100.
This will assist us in contacting you in a
timely manner should the need arise.
If you sell your Mercedes, please leave all
literature with the vehicle to make it avail-
able to the next operator.If you bought this vehicle used, be sure to
send in the “Notice of Purchase of Used
Car” found in the Service and Warranty In-
formation Booklet, or call the
Mercedes-Benz Customer Assistance Cen-
ter (in the USA) at 1-800-FOR-MERCedes,
or Customer Service (in Canada) at
1-800-387-0100.
Operating your vehicle outside the USA
or Canada
If you plan to operate your vehicle in for-
eign countries, please be aware that:

service facilities or replacement parts
may not be readily available,


unleaded gasoline for vehicles with cat-
alytic converters may not be available;
the use of leaded fuels will damage the
catalysts,


gasoline may have a considerably low-
er octane rating, and improper fuel can
cause engine damage.Certain Mercedes-Benz models are avail-
able for delivery in Europe under our Euro-
pean Delivery Program. For details, consult
an authorized Mercedes-Benz Center or
write to:
In the USA:
Mercedes-Benz USA, LLC
European Delivery Department
One Mercedes Drive
Montvale, NJ 07645-0350
In Canada:
Mercedes-Benz Canada, Inc.
European Delivery Department
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9

571 Operation
At the gas station

Take off the fuel filler cap and set it in
the direction of arrow 2 and place it
into holder 3 located on the inside of
the fuel filler flap.
To prevent fuel vapors from escaping
into open air, fully insert filler nozzle
unit.

Only fill your tank until the filler nozzle
unit cuts out – do not top off or over-
fill.

Replace the fuel cap by turning it clock-
wise until it audibly engages.

Close the fuel filler flap.
You should hear the latch close shut.Warning!
G
Overfilling of the fuel tank may create pres-
sure in the system which could cause a gas
discharge. This could cause the gas to spray
back out when removing the fuel pump noz-
zle, which could cause personal injury.i
Make sure to close the fuel filler flap before
locking your vehicle as the flap locking pin pre-
vents closing after you have locked the vehicle.
i
Only use premium unleaded gasoline with a
minimum Posted Octane Rating of 91 (average of
96 RON/86 MON). Please contact gas station
personnel in case labels on the pump cannot be
found.
For more information on gasoline see “Premium
unleaded gasoline” (
page 770), see “Fuel re-
quirements” (
page 770) and the Factory Ap-
proved Service Products pamphlet.
i
Leaving the engine running and the fuel cap
open can cause the yellow engine malfunction
indicator lamp ± to illuminate.
For more information, see the “Practical hints”
section (
page 632).

751 Technical data
Engine
Engine
Model
S 450 4MATIC (221.184)
1,2
1The quoted data apply only to the standard vehicle. Contact an authorized Mercedes-Benz Center for the corresponding data of all special bodies and special equip-
ment.2Canada only
S 550 (221.171)
1
Engine
273
273
Mode of operation
4-stroke engine, gasoline injection
4-stroke engine, gasoline injection
No. of cylinders
8
8
Bore
3.66 in (92.90 mm)
3.86 in (98.00 mm)
Stroke
3.39 in (86.00 mm)
3.56 in (90.50 mm)
Total piston displacement
284.6 cu in (4 663 cm
3)
333.3 cu in (5 461 cm
3)
Compression ratio
10.5:1
10.7:1
Output acc. to SAE J 1349
3
3Premium fuel required. Performance may vary with fuel octane rating.
335 hp/6 000 rpm
(250 kW/6 000 rpm)
382 hp/6 000 rpm
(285 kW/6 000 rpm)
Maximum torque
acc. to SAE J 1349
391 lb-ft/2 700 - 5 000 rpm
(460 Nm/2 700 - 5 000 rpm)
391 lb-ft/3 000 rpm
(530 Nm/3 000 rpm)
Maximum engine speed
6 500 rpm
6500 rpm
Firing order
1-5-4-2-6-3-7-8
1-5-4-2-6-3-7-8
Poly-V-belt
2 404 mm
2404 mm

752 Technical dataEngineModel
S 550 4MATIC (221.186)
1
S 600 (221.176)
1
1The quoted data apply only to the standard vehicle. Contact an authorized Mercedes-Benz Center for the corresponding data of all special bodies and special equip-
ment.Engine
273
275
Mode of operation
4-stroke engine, gasoline injection
4-stroke engine, gasoline injection
No. of cylinders
8
12
Bore
3.86 in (98.00 mm)
3.23 in (82.00 mm)
Stroke
3.56 in (90.50 mm)
3.43 in (87.00 mm)
Total piston displacement
333.3 cu in (5 461 cm
3)
336.4 cu in (5 513 cm
3)
Compression ratio
10.5:1
9:1
Output acc. to SAE J 1349
2
2Premium fuel required. Performance may vary with fuel octane rating.
382 hp/6 000 rpm
(285 kW/6 000 rpm)
510 hp/5 000 rpm
(380 kW/5 000 rpm)
Maximum torque
acc. to SAE J 1349
391lb-ft/2800-4800rpm
(530 Nm/2 800 - 4 800 rpm)
612 lb-ft/1 800 - 3 500 rpm
(830 Nm/1 800 - 3 500 rpm)
Maximum engine speed
6500 rpm
5 950 rpm
Firing order
1-5-4-2-6-3-7-8
1-12-5-8-3-10-6-7-2-11-4-9
Poly-V-belt
2404 mm
2 370 mm

753 Technical data
Engine
Model
S 63 AMG (221.077)
1
S 65 AMG (221.179)
1
1The quoted data apply only to the standard vehicle. Contact an authorized Mercedes-Benz Center for the corresponding data of all special bodies and special equip-
ment.Engine
156
275
Mode of operation
4-stroke engine, gasoline injection
4-stroke engine, gasoline injection
No. of cylinders
8
12
Bore
4.02 in (102.20 mm)
3.25 in (82.60 mm)
Stroke
3.72 in (94.60 mm)
3.66 in (93.00 mm)
Total piston displacement
378.8 cu in (6 208 cm
3)
364.9 cu in (5 980 cm
3)
Compression ratio
11.3:1
9:1
Output acc. to SAE J 1349
2
2Premium fuel required. Performance may vary with fuel octane rating.
518 hp/6 800 rpm
(386 kW/6 800 rpm)
603 hp/4 800 - 5 100 rpm
(450 kW/4 800 - 5 100 rpm)
Maximum torque
acc. to SAE J 1349
465 lb-ft/5 200 rpm
(630 Nm/5 200 rpm)
738 lb-ft/2 000 - 4 000 rpm
(1 000 Nm/2 000 - 4 000 rpm)
Maximum engine speed
7 200 rpm
5950 rpm
Firing order
1-5-4-2-6-3-7-8
1-12-5-8-3-10-6-7-2-11-4-9
Poly-V-belt
2360 mm
2370 mm

767 Technical data
Fuels, coolants, lubricants, etc.
Model
Capacity
Fuels, coolants, lubricants, etc.
Cooling
system
Vehicles without rear passen-
ger compartment climate
control*
S 450 4MATIC
1
S 550
S 550 4MATIC
1Canada only
12.15 US qt. (11.5 l)
MB 325.0 Anticorrosion/Antifreeze
Vehicles with rear passenger
compartment climate control*
S 450 4MATIC
1
S 550
S 550 4MATIC
13.84 US qt. (13.1 l)
S 600
14.69 US qt. (13.9 l)
S63 AMG
11.83 US qt. (11.2 l)
S65 AMG
14.69 US qt. (13.9 l)
Low temperature cooling system
S 600
2.75 US qt. (2.6 l)
MB 325.0 Anticorrosion/Antifreeze
S65 AMG
3.28 US qt. (3.1 l)
Fuel tank
All models
23.78 US gal (90.0 l)
Premium unleaded gasoline:
Minimum Posted Octane 91
(Avg.of96RON/86MON)
including a reserve of
S 450 4MATIC
1
S 550
S 550 4MATIC
S 600
2.9 US gal (11.0 l)
S63 AMG
3.7 US gal (14.0 l)
S65 AMG
3.7 US gal (14.0 l)

770 Technical dataFuels, coolants, lubricants, etc.Premium unleaded gasoline
Fuel requirements
Only use premium unleaded fuel:

The octane number (posted at the
pump) must be 91 min. It is an average
of both the Research Octane Number
(RON) and the Motor Octane Number
(MON): (RON+MON)/2. This is also
known as the ANTI-KNOCK INDEX.
Unleaded gasoline containing oxygenates
such as ethanol, IPA, IBA and TBA can be
used provided the ratio of any one of these
oxygenates to gasoline does not exceed
10%; MTBE must not exceed 15%.
The ratio of methanol to gasoline must not
exceed 3% plus additional co-solvents.
Using mixtures of ethanol and methanol is
not allowed. Gasohol, which contains
10% ethanol and 90% unleaded gasoline,
can be used.
These blends must also meet all other fuel
requirements, such as resistance to spark
knock, boiling range, vapor pressure, etc.
Warning!
G
Gasoline is highly flammable and poisonous.
It burns violently and can cause serious per-
sonal injury.
Never allow sparks, flame or smoking mate-
rials near gasoline!
Turn off the engine before refueling.
Whenever you are around gasoline, avoid in-
haling fumes and skin or clothing contact,
extinguish all smoking materials.
Direct skin contact with fuels and the inha-
lation of fuel vapors are damaging to your
health.
!
To maintain the engine’s durability and per-
formance, premium unleaded gasoline must be
used. If premium unleaded gasoline is not avail-
able and low octane fuel is used, follow these
precautions:


Have the fuel tank only partially filled with
unleaded regular gasoline and fill up with
premium unleaded gasoline as soon as
possible.


Avoid full throttle driving and abrupt acceler-
ation.


Do not exceed an engine speed of 3 000 rpm
if the vehicle is loaded with a light load such
as two persons and no luggage.


Do not exceed
2/3 of maximum accelerator
pedal position if the vehicle is fully loaded or
operating in mountainous terrain.

782 IndexExterior lighting
Delayed switch-off (COMAND) 264
Locator lighting (COMAND) 265
Exterior rear view mirrors
Adjusting 388
Auto-dimming on the
driver’s side 390
Fold in automatically when locking
(COMAND) 266
Lower mirror when reversing
(COMAND) 266
Power folding 389F
Favorite button 263
First aid kit 705
Flat tire 723
Jacking up the vehicle 724
Lowering the vehicle 727
Mounting the spare wheel 723
Preparing the vehicle 723
Floormats* 538
Fluids
Automatic transmission fluid 765
Brake fluid 766, 769
Capacities 764
Engine coolant 579, 767, 771
Engine oil 578, 765, 769
Power steering fluid 766
Windshield washer system and head-
lamp cleaning system 768, 774
Fog lamps
Messages in display 690
Replacing bulbs 715
Four wheel electronic traction system with
ESP
® see 4MATIC
4MATIC 76
Front air bags 46Front lamps
Replacing bulbs 715, 717
Front lamps see headlamps
Front passenger front air bag 46
Messages in display 649
Front passenger front air bag off
indicator lamp 51, 640
Fuel 571, 767, 770
Additives 771
Capacity, Fuel tank 767
Filling the tank 570
Fuel filler flap and cap 570
Fuel reserve warning lamp 29
Gauge 29
Premium unleaded gasoline 571,
767, 770
Requirements, Octane rating 770
Fuel cap
Message in display 683
Fuel consumption statistics
Since last reset 291
Since start 291
Fuel filler flap 570
Locking/Unlocking 570