2020 MERCEDES-BENZ S-CLASS COUPE battery

#
Toactiv ate: press anybutt onontheSmar t‐
Ke y.
% When theve hicle isstar tedwit hth eSmar t‐
Ke yin themar kedspace ofthecent ercon ‐
sole, theSmar tKey functions areau tomati‐
cally activated (/ page14 1). Re
mo ving /ins ertin gthe eme rgency key #
Toremo ve:pr ess release knob 1.
Em erge ncy key2 ispush edout slightly. #
Pull outemer gency key2 untilit en gage sin
th eint ermediat eposition . #
Press release knob 1 again and fully
re mo veemer gency key2. #
Toinser t:press release knob 1. #
Insertemer gency key2 totheint ermediat e
position orfull yuntil iteng ages.
% Youcan usetheint ermediat eposition of
emer gency key2 toatt achth eSmar tKey to
a ke yring. Re
plac ingthe Smar tKey batt ery &
DANG ER Serious damag eto healt h
caused byswallo wing batteries
Batt eries cont aintoxic and corrosiv esub‐
st anc es.Swallo wing batteries ma ycause
ser ious damag eto healt h.
Ther eis arisk offata linj ury. #
Keep batt eries out ofthere ac hof chil‐
dr en. #
Ifbatt eries aresw allo wed,seek medical
att ent ion immediat ely. +
ENVIR
ONMEN TALNO TEEnvironme ntal
da ma gecau sed byimproper disposal of
batt eries Bat
teries con tain polluta nts. Itis
illeg alto dispose ofthem withth ehousehold
ru bbish. #
Dispose
ofbatt eries inan
en vironmen tally re sponsible manner.
Ta ke disc hargedbatt eries toaqu alif ied
spec ialistwo rkshop ortoacol lection
poin tfo rused batteries. Re
quirement s:
R Youre qu ire aCR 203 23V cell battery.
Mer cedes-Ben zre comme ndsthat youha ve the
batt eryre placed ataqu alif ied spec ialistwo rk‐
shop. Opening
andclosing 63

#
Toswitc hon: slide theswitc hto position
0048. #
Toswitc hof f:slide theswitc hto position
0047.
% Ifan acciden thas been detected, thetrunk
will unloc keve nif sep aratelock ing is
switc hedon. Un
loc king thetrunk from insid ewit hth e
emer gency release Re
quirement s:
R The 12Vve hicle batteryis conn ectedand
ch arge d. #
Press emer gency release button1 brief ly.
The trunk lidwill unloc kand open. Un
loc king thetrunk lidusing theemer gency
ke y #
Take theemer gency keyout oftheSmar tKey
( / pag e63). #
Press theto pof Mer cedes star 1. Open
ingand closing 75

#
Mak esur eth at mar kedspace 2isem pty. #
Remo veSmar tKey 1 from theke yring. #
Place Sma rtKe y1 inmar kedspace 2.
The vehicle willstar taf te ra shor ttime.
If yo ure mo veSmar tKey 1 from mar ked
space 2theengine continues running .Fo r
fur ther vehicle star ts howe ver,Smar tKey 1
mus tbe locat edinmar kedspace 2during
th eent ire jour ney. #
Have Smar tKey 1 checkedat aqu alif ied
spec ialistwo rkshop.
If th eve hicl edoes notst ar t: #
Lea veSmar tKey 1 inmar kedspace 2. #
Depr essthebr ak epedal andstar tth eve hi‐
cle using thest ar t/ stop butt on.
% Youcan also switchon thepo we rsupp lyor
th eignition withth est ar t/ stop butt on. St
arting theve hicl evia Remo teOnline serv‐
ices Cooling
orheating theve hicl eint erior before
co mmenci ngyour jour ney
% This function isno tav ailable inall coun tries.
If yo ust ar tth eve hicle viayour smar tphon e,the
pr ev iousl yselec tedair con dition ingadjus tment
is activ e.
En sur eth efo llo wing beforest ar tin gth eengine:
R The legalstipulation sin thear ea wher eyo ur
ve hicle ispar kedallo wengin est ar tin gvia
smar tphon e.
R Itis saf eto star tand runth eengine where
yo ur vehicle ispar ked.
R The fuel tank issu fficien tly filled.
R The star terbatt eryis suf ficie ntly charge d. %
Youcan also setth ete mp eratur ewit hyo ur
smar tphon e.Info rm atio non Mer cedesme
con nectand other services: https://
www .mercedes.me
This funct ionisno tav ailable forall model s.
Char ging thebat tery bef orecommencing
yo ur jour ney
% This function isno tav ailable inall coun tries.
If th eve hicle batteryis disc harged, youre cei vea
messa geon your smar tphon e.Youcan then
st ar tth eve hicle withth esmar tphon eto charge
th ebatt ery. The vehicle isaut omaticall y
switc hedoffaf te rte nminu tes.
Ensur eth efo llo wing beforest ar tin gth eengine:
R The legalstipulation sin thear ea wher eyo ur
ve hicle ispar kedallo wengin est ar tin gvia
smar tphon e.
R Itis saf eto star tand runth eengine where
yo ur vehicle ispar ked.
R The fuel tank issu fficien tly filled. 14
2
Driving and parking

We
arsaf etygl asses . Ke
ep childr enaway. Obser
vethis Opera tor's Manua l.
Obser vethefo llo wing ifyo udo notint endto use
th eve hicle overan extende dpe riod oftime:
R Activatest andb ymode .
R Alternat ivel y: con nectth ebatt eryto abat ‐
te ry charge rapp rove dby Mer cedes-Ben zor
consult aqu alif ied spec ialistwo rkshop to
discon nectth ebatt ery. No
teson star ting assistance andoncharg‐
ing the12 Vbatt ery Ve
hicl eswith alithium-ion battery
When chargin gth ebatt eryand during star tin g
assis tance, alwa ys use thejum p-start connec‐
tion pointintheengine compartmen t.
* NO
TEDama ging thebatt eryth ro ugh
ove rvolt age When
chargin gusin gabat tery charge rwit h‐
out amaximu mchargin gvo ltag e, thebatt ery
or theve hicle electr onics maybe damag ed. #
Onlyuse batterych arge rs wit hamax i‐
mum chargin gvo ltag eof 14.8 V. All
other vehicl es
When chargin gth ebatt eryand during star tin g
assis tance, alwa ys use thejum p-start connec‐
tion pointintheengine compartmen t. *
NO
TEDama ging thebatt eryth ro ugh
ove rvolt age When
chargin gusin gabat tery charge rwit h‐
out amaximu mchargin gvo ltag e, thebatt ery
or theve hicle electr onics maybe damag ed. #
Onlyuse batterych arge rs wit hamax i‐
mum chargin gvo ltag eof 14.8 V. &
WARNIN GRisk ofexplosion from hydro‐
ge nga signiting
A batt eryge ner ates hydrog en gasdur ing the
ch argin gpr oce ss.Ifth er eis ashor tcir cuit or
spar ksstar tto form ,th er eis adang erofthe
hy drog en gasigniting. #
Mak esur eth at thepositiv ete rm inal of
th econ nect edbatt erydoes notcome
int ocon tact with vehicle parts. #
Neverpla ceme talobje ctsor tools ona
batt ery. #
When connectin gand disconn ectingth e
batt ery, yo umus tobse rveth edescr i‐
bed order forth ebatt eryclam ps. 380
Breakdo wnassis tance

#
When giving star tin gassis tance, alwa ys
mak esur eth at youon lyconnect bat‐
te ry term inals withident icalpolar ity. #
Dur ing star tin gassis tance, youmus t
obse rveth edescr ibedorder forcon‐
necting anddisconnecting thejum per
cables. #
Donotcon nect ordiscon nectthebat‐
te ry cla mp swhile theengine isrunning . &
WARNIN GRisk ofexplosion during
ch argin gpr oce ssand star tin gassis tance
Dur ing thech argin gpr oce ssand star tin g
assis tance, thebatt eryma yre lease anexplo‐
siv ega smixtur e. #
Avoid fire ,open flames ,cr eat ing spar ks
and smoking. #
Mak esur eth at ther eis suf ficie ntventi‐
la tio ndu ring thech argin gpr oce ssand
dur ing star tin gassis tance. #
Donotle an ove ra batt ery. &
WARNIN GRisk ofexplosion from afro‐
zen battery
A disc hargedbatt eryma yfreeze attemp era‐
tur es slightl yabo veorbelo wfreezing point.
Dur ing star tin gassis tance orbatter ych arg‐
ing ,bat tery gasma ybe released. #
Alw aysth aw afroz en bat tery out firs t
bef orech argin git or per form ing star t‐
ing assis tance. If
th eindicat or/warning lampsintheins trument
clus terdo notlig ht up atlow temp eratur es,itis
ve ry likelyth at thedisc hargedbatt eryhas fro‐
zen .In this case youma yne ither jump-start the
ve hicle norcharge thebatt ery.
The service life of abatt eryth at has been
th awe dma ybe dramaticall yshor tened .The
st ar tin gch aract eristic sma ybe impair ed,espe ‐
ciall yat low temp eratur es.
It is recomme ndedthat youha ve ath aw ed bat‐
te ry checkedat aqu alif ied spec ialistwo rkshop. All
vehicl es
* NO
TEDama gecau sed bynum erou sor
ex tende datt em ptsto star tth eengine Nu
me rous orextende datt em ptsto star tth e
engine maydamag eth ecat alytic converter
due tonon-co mbusted fuel. #
Avoid numer ousand extende datt em pts
to star tth eengine. Obser
vethefo llo wing pointsdur ing star tin g
assis tance and when chargin gth ebatt ery:
R Onlyuse undamag edjum per cables/c harg‐
ing cables withasuf ficie ntcross -secti onand
insu late dte rm inal clam ps.
R Non-insulat edpar tsof thete rm inal clam ps
mus tno tcom eint ocon tact with other metal
par tswhile thejum per cable/c harging cable
is con nect edtothebatt ery/jum p-start con‐
nectio npoi nt.
R The jumper cable/c harging cable mustno t
com eint ocon tact with anypar tswhic hma y
mo vewhen theengine isrunning . Br
ea kdo wnassist anc e38
1

R
Alw aysmak esur eth at nei ther youno rth e
batt eryis elect rostatic allych arge d.
R Keep away from fire and open flames .
R Donotlean overth ebatt ery.
Obser vetheadditional follo wing pointswhen
ch argin gth ebatt ery:
R Onlyuse batterych arge rs tested and
appr ovedfo rMer cedes-Benz.
R Read thebatt erych arge r's oper ating instruc‐
tions beforech argin gth ebatt ery.
Obser vetheadditional follo wing pointsdur ing
st ar tin gassis tance:
R Startin gassis tance maybe perfor med using
onl ybatt eries withanominal voltag eof 12 V.
R The vehicles mustno tto uc h.
R Vehicl eswith aga soline engine: Jump-
st ar tth eve hicle onlywhen theengine and
ex haus tsy stem arecold. St
arting assistance andchargin gth e12 V
batt ery Re
quirement s:
R The vehicle issecur edwithth eelectr icpar k‐
ing brak e.
R The transmission isin position 005D.
R The ignition andallelectr icalconsumer sar e
switc hedoff.
R The hood isopen. #
Slide cover3 ofposi tiveclam p4 onthe
jum p-starting con nection point inthedir ec‐
tion ofthear row . #
Con nect posi tiveclam p4 onyour vehicle to
th epositiv epole ofthedonor batteryusing
th ejum per cable/c harging cable. Always
begin withpositiv eclam p4 onyour ow n
ve hicle firs t. 38
2
Brea kdo wnassist anc e

#
Dur ing star ting assistance :st ar tth e
engine ofthedonor vehicle andrunat idle
spe ed. #
Connect theneg ativepole ofthedonor bat‐
te ry and grou nd point 5 ofyour ow nve hicle
by usin gth ejum per cable/c harging cable.
Begin withth edonor batteryfirs t. #
During star ting assistance :st ar tth e
engine ofyour ow nve hicle. #
Dur ing thech argin gpr oc ess :st ar tth e
ch argin gpr oce ss. #
Dur ing star ting assistance :le tth eengines
ru nfo rse veralmin utes. #
Dur ing star ting assistance :bef oredis con‐
necting thejum per cable, switchon anelec‐
tr ical consumer inyour ow nve hicle, e.g.the
re ar wind owdefr osteror lighting.
When thest ar tin gassis tance/c harging proce ss
is com plet e: #
First,re mo vethejum per cable/c harging
cable from ground point 5and negative
pole ofthedonor battery, then from positiv e
clam p4 and positiv epole ofthedonor bat‐ te
ry.Begi nea ch tim ewi th thecon tacts on
yo ur ow nve hicle firs t. #
Afterre mo ving thejum per cable/c harging
cable, closecover3 ofposi tiveclam p4.
Fu rther information canbeobt ained ataqu ali‐
fi ed specialis two rkshop. Re
plac ingthe 12Vbatt ery #
Obs erve theno teson the12 Vbatt ery
(/ page37 8).
Me rcedes-B enzrecomme ndsthat youha ve the
12 Vbatt eryre placed ataqu alif ied spec ialist
wo rkshop, e.g.atan aut hor ized Mercedes-Benz
Cent er.
Obser vethefo llo wing notesif yo uwa ntto
re place thebatt eryyo urself :
R Alw aysre place afa ulty battery wit habatt ery
whic hmee tsthespecif icvehicle requ ire‐
men ts.
The vehicle iseq uipped withan AGMtech nol ‐
ogy batter y(A bso rbentGlas sMa t)or alith ‐
ium-io nbatt ery. Fu llve hicle functionality is onl
yguar anteed withan AGMbatt eryor lith‐
ium-ion battery. Fo rsaf etyre ason s,
Mer cedes-Ben zre comme ndsthat youon ly
use batteries whic hha ve been tested and
appr ovedfo ryo ur vehicle byMer cedes-Ben z.
R Carryove rde tach able parts,suc has vent
hos es,elbo wfitting orterm inal covers from
th ebatt erybeing replaced.
R Mak esur eth at theve nt hos eis alwa ys con‐
nect edtotheor iginal opening ontheside of
th ebatt ery.
Ins tallan yex istin gor supplied cellcaps.
Ot her wise, gases orbatt eryacid could
escape.
R Mak esur eth at detach able partsarere con‐
nect edinthesame way. To
w star ting ortowing away Pe
rm itted towing methods Mer
cede s-Ben zre comme ndstransp orting your
ve hicle inthecase ofabr eakdo wn,rath er than
to wing itaw ay. Br
ea kdo wnassista nce 38
3

Disp
laymes sages
Possible causes/conseq uencesand0050 0050
Solutions
Á Replace KeyBattery *T
heSmar tKey batt eryis disc harged. #
Replace thebatt ery(/ page63).
Á Key NotDetected (whit e
displa ymessag e) *T
heSmar tKey iscur rentl yund etect ed. #
Chang eth elocation oftheSmar tKey intheve hicle. #
Ifth eSmar tKey isstill no tre cogni zed,place itin themar kedspace forst ar tin gwit hth eSmar tKey
( / pag e14 1).
Á
Ke yNo tDete cted (red dis‐
pl ay messa ge) *T
heSmar tKey canno tbe detected and mayno long erbe intheve hicle.
The Smar tKey isno long erintheve hicle andyouswit choffth eengine:
R Youcan nolongerst ar tth eengine.
R Youcan notcen trally lockth eve hicle. #
Ensur eth at theSmar tKey isin theve hicle.
If th eSmar tKey detection functi onhasa mal functi ondueto ast ro ng radio signal source: #
Stop theve hicle immediat elyinaccor dance withth etraf fic condi tions. #
PlacetheSmar tKey inthemar kedspace forst ar tin gth eengine withth eSmar tKey (/ pag e14 1). 44
2
Dis play messa gesand warning/ indic ator lam ps