2016 MERCEDES-BENZ S-Class SEDAN Sit

Publication details
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Further information about Mercedes-Benz vehi-
cles and about Daimler AG can be found on the
following websites:
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Editorial office
©Daimler AG: not to be reprinted, translated or
otherwise reproduced, in whole or in part, with- out written permission from Daimler AG.
Vehicle manufacturer
Daimler AG
Mercedesstraße 137
70327 Stuttgart
Germany
Symbols
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In this Operator's Manual you will find the fol-
lowing symbols:
GWARNING
Warning notes make you aware of dangers
which could pose a threat to your health or
life, or to the health and life of others.
HEnvironmental note
Environmental notes provide you with infor-
mation on environmentally aware actions or
disposal.
!Notes on material damage alert you to dan-
gers that could lead to damage to your vehi-
cle.
iPractical tips or further information that
could be helpful to you.
X This symbol indicates an instruction
that must be followed.
X Several of these symbols in succession
indicate an instruction with several
steps. (Y
page)
This symbol tells you where you can find
more information about a topic.
YY This symbol indicates a warning or an
instruction that is continued on the next
page.
Dis‐
playThis text indicates a message on the
multifunction display/multimedia dis-
play.
As at 26.03.2015

Anti-Theft Alarm systemsee ATA (Anti-Theft Alarm system)
Arm rest
St owage compartment .................. 327
Asht ray.............................................. .334
Assistance display (on-board com-
puter) ..................................................2 68
Assistance menu (on-board com-
puter) ..................................................2 69
ASSYST PLUS
Displaying a service message ........3 58
Hiding a service message .............. 358
Resetting the service interval dis-
play ................................................ 358
Service message ............................ 357
Special service requirements ......... 358
ATA (Anti-Theft Alarm system)
Activating/deactivating ................... 78
Function ...........................................7 8
Switching off the alarm .................... 78
ATTENTION ASSIST
Activating/deactivating ................. 271
Display message ............................ 299
Function/notes ............................. 228
Authorized Mercedes-Benz Center
see Qualified specialist workshop
Authorized workshop
see Qualified specialist workshop
AUTO lights
Display message ............................ 293
see Lights
Automatic car wash (care) ............... 359
Automatic engine start (ECO start/
stop function) .................................... 167
Automatic engine switch-off (ECO
start/stop function) .......................... 166
Automatic headlamp mode .............. 130
Automatic transmission
Accelerator pedal position ............. 173
Automatic drive program ............... 174
Changing gear ............................... 173
DIRECT SELECT lever ..................... 170
Display message ............................ 308
Driving tips .................................... 173
Emergency running mode .............. 177
Engaging drive pos itio
n .................. 171
Engaging neutral ............................ 171 Engaging park position automati-
cally ............................................... 170
Engaging reverse gear ................... 171
Engaging the park position ............ 170
Kickdown ....................................... 173
Manual drive program .................... 174
Manual drive program (Mercedes-
AMG vehicles) ................................ 175
Oil temperature (on-board com-
puter, Mercedes-AMG vehicles) ..... 275
Overview ........................................ 170
Problem (malfunction) ................... 177
Program selector button ................ 173
Pulling away ................................... 165
Starting the engine ........................ 164
Steering wheel paddle shifters ...... 174
Transmission position display ........ 172
Transmission positions .................. 172
Automatic transmission emer-
gency mode ....................................... 177
B
BAS (Brake Assist System) ................. 69
BAS PLUS (Brake Assist System
PLUS) with Cross-Traffic Assist
Function/notes ................................ 69
BAS PLUS with Cross-Traffic Assist
(Brake Assist PLUS with Cross-
Traffic Assist)
Important safety notes .................... 69
Battery (high-voltage)
see High-voltage battery
Battery (SmartKey)
Checking .......................................... 82
Important safety notes .................... 82
Replacing ......................................... 82
Battery (vehicle)
Charging ........................................ 374
Display message ............................ 295
Important safety notes .................. 372
Jump starting ................................. 376
Belt
see Seat belts
Belt bag ................................................ 48
Blind Spot Assist
see Active Blind Spot Assist
4Index

Removing...................................... .185
Storing ...........................................1 83
Warming up ................................... 182
Charging the high-voltage battery
(important safety notes) ................... 180
Chauffeur mode
Display message ............................ 310
Fully reclined position .................... 114
General notes ................................ 111
Installing the head restraint ........... 113
Moving front-passenger seat into
the chauffeur position .................... 112
Moving the front-passenger seat
into the normal position ................. 113
Removing the head restraint .......... 113
Child
Restraint system .............................. 62
Child seat
Forward-facing restraint system ...... 66
LATCH-type (ISOFIX) child seat
anchors ............................................ 63
On the front-passenger seat ............ 65
Rearward-facing restraint system .... 66
Top Tether ....................................... 64
Child-proof locks
Important safety notes .................... 66
Rear doors ....................................... 67
Children
Special seat belt retractor ............... 62
Cigarette lighter ................................ 335
Cleaning
Mirror turn signal ........................... 362
Climate control
Automatic climate control ............. 141
Controlling automatically ............... 147
Cooling with air dehumidification .. 146
Defrosting the windows ................. 151
Defrosting the windshield .............. 151
ECO start/stop function ................ 145
General notes ................................ 140
Immediate pre-entry climate con-
trol ................................................. 158
Indicator lamp ................................ 147
Ionization ....................................... 155
Notes on using the automatic cli-
mate control .................................. 145
Overview of systems ...................... 140
Perfume atomizer .......................... 153 Pre-entry climate control at
departure time ............................... 157
Pre-entry climate control via
key ... 155
P

roblem with the rear window
defroster ........................................ 152
Problems with cooling with air
dehumidification ............................ 147
Rear control panel ......................... 141
Refrigerant ..................................... 432
Refrigerant filling capacity ............. 432
Setting the air distribution ............. 149
Setting the air vents ...................... 158
Setting the airflow ......................... 150
Setting the climate mode ............... 148
Setting the temperature ................ 148
Switching air-recirculation mode
on/off ............................................ 152
Switching on/off ........................... 145
Switching residual heat on/off ...... 152
Switching the rear window
defroster on/off ............................ 151
Switching the synchronization
function on and off ........................ 150
Climate control system
Climate control .............................. 145
Cockpit
Overview .......................................... 32
COLLISION PREVENTION ASSIST
PLUS
Activating/deactivating ................. 270
Display message ............................ 284
Operation/notes .............................. 71
COMAND display
Cleaning ......................................... 364
Combination switch .......................... 131
Consumption statistics (on-board
computer) .......................................... 262
Convenience closing feature .............. 96
Convenience opening feature ............ 95
Coolant (engine)
Checking the level ......................... 356
Display message ............................ 294
Displaying the temperature (on-
board computer) ............................ 269
Filling capacity ............................... 431
Important safety notes .................. 431
Temperature gauge ........................ 257
Warning lamp ................................. 320
6Index

ECO displayFunction/notes ............................ .193
On-board computer ....................... 262
ECO start/stop function
Automatic engine start .................. 167
Automatic engine switch-off .......... 166
Deactivating/activating ................. 167
General information ....................... 166
Important safety notes .................. 166
Introduction ................................... 166
Electronic Stability Program
see ESP
®(Electronic Stability Program)
Emergency
Automatic measures after an acci-
dent ................................................. 61
Emergency release
Driver's door ....................................8 7
Trunk ............................................... 94
Vehicle ............................................. 87
Emergency Tensioning Devices
Activation ......................................... 57
Emissions control
Service and warranty information ....2 5
Engine
Check Engine warning lamp .......... .320
Display message ............................ 294
ECO start/stop function ................ 166
Engine number ............................... 427
Irregular running ............................ 169
Jump-starting ................................. 376
Starting (important safety notes) ... 164
Starting problems .......................... 169
Starting the engine with the
SmartKey ....................................... 164
Starting via smartphone ................ 164
Starting with the Start/Stop but-
ton ................................................. 164
Switching off .................................. 190
Switching off with the Start/Stop
button ............................................ 190
Switching off with the vehicle key .. 190
Tow-starting (vehicle) ..................... 381
Engine electronics
Problem (malfunction) ................... 169
Engine oil
Adding ...........................................3 55
Additives ........................................ 430
Checking the oil leve l ..................... 353 C
hecking the oil level using the
dipstick .......................................... 353
Checking the oil level using the
on-board computer ........................ 355
Display message ............................ 296
Filling capacity ............................... 430
General notes ................................ 429
Notes about oil grades ................... 429
Notes on oil level/consumption .... 353
Temperature (on-board computer,
Mercedes-AMG vehicles) ...............2 75
Viscosity ........................................ 430
ESP
®(Electronic Stability Pro-
gram)
AMG menu (on-board computer) ... 276
Characteristics ................................. 73
Deactivating/activating ................. 269
Deactivating/activating (notes) ....... 74
Display message ............................ 278
Function/notes ................................ 73
General notes .................................. 73
Important safety information ........... 73
Trailer stabilization ........................... 74
Warning lamp ................................. 317
ETS/4ETS (Electronic Traction Sys-
tem) ...................................................... 73
Exhaust
see Exhaust pipe
Exhaust check ................................... 193
Exhaust pipe
Cleaning ......................................... 363
Exhaustive discharging (high-volt-
age battery) ....................................... 374
Exterior lighting
Cleaning ......................................... 362
see Lights
Exterior mirrors
Adjusting ....................................... 123
Dipping (automatic) ....................... 124
Folding in/out (automatically) ....... 124
Folding in/out (electrically) ........... 124
Out of position (troubleshooting) ... 124
Setting ........................................... 124
Storing settings (memory func-
tion) ............................................... 126
Storing the parking position .......... 125
Eyeglasses compartment ................. 326
Index9

F
Features............................................ .330
Filling capacities (Technical data) ... 427
Flat tire
Changing a wheel/mounting the
spare wheel ................................... 405
MOExtended tires .......................... 368
Preparing the vehicle ..................... 367
TIREFIT kit ...................................... 369
Floormats ...........................................3 50
Folding table ...................................... 328
Frequencies
Mobile phone ................................. 425
Two-way radio ................................ 425
Front-passenger seat
Adjusting from the driver's seat ..... 108
Adjusting from the rear compart-
ment .............................................. 108
Fuel
Additives ........................................ 429
Consumption statistics .................. 262
Displaying the current consump-
tion ................................................ 261
Displaying the range ......................2 61
Driving tips ....................................1 92
Fuel gauge ....................................... 33
Grade (gasoline) ............................ 428
Important safety notes .................. 428
Problem (malfunction) ................... 180
Refueling ........................................ 177
Tank content/reserve fuel ............. 428
Fuel level
Calling up the range (on-board
computer) ...................................... 261
Fuel tank
Capacity ........................................ 428
Problem (malfunction) ................... 180
Fuses
Allocation chart ..................... 381, 383
Before changing .............................3 82
Dashboard fuse box ....................... 382
Fuse box in the engine compart-
ment .............................................. 383
Fuse box in the front-passenger
footwell .......................................... 382
Fuse box in the trunk ..................... 383
Important safety notes .................. 381
G
Garage door opener
Clearing the memory ..................... 350
General notes ................................ 347
Important safety notes .................. 348
Opening/closing the garage door .. 350
Problems when programming ........3 49
Programming (button in the rear-
view mirror) ................................... 348
Synchronizing the rolling code ....... 349
Gasoline ............................................. 428
Gear indicator (on-board com-
puter, Mercedes-AMG vehicles) ....... 275
Genuine parts ...................................... 24
Glove box ...........................................3 26
H
Handbrake
see Parking brake
HANDS-FREE ACCESS .......................... 91
Hazard warning lamps ......................132
Head restraints
Adjusting ....................................... 114
Adjusting (manually) ......................1 15
Adjusting (rear) .............................. 116
EASY ADJUST luxury head
restraint ......................................... 115
Luxury ............................................ 115
Supplementary cushion ................. 116
Head-up display
Adjusting the brightness ................ 273
Displays and operating .................. 259
Function/notes .............................2 59
Important safety notes .................. 259
Selecting displays .......................... 273
Setting the position ....................... 273
Headlamps
Fogging up ..................................... 134
see Automatic headlamp mode
Heating
see Climate control
High beam flasher .............................1 32
High-beam headlamps
Adaptive Highbeam Assist PLUS .... 133
Display message ............................ 292
Switching on/off ........................... 132
10Index

High-voltage batteryBattery care ................................... 182
Charging (charging station) ............ 186
Charging (mains socket) ................1 83
Charging (wallbox) ......................... 185
Charging cable warming ................ 182
Cruise range .................................. 182
Energy consumption ......................1 82
General notes .................................. 43
Method of operation ......................1 81
Outside temperatures .................... 182
Overvoltage protection .................. 182
Problems with the charging proc-
ess ................................................. 187
Terms of use .................................. 182
Vehicle fire ....................................... 43
Hill start assist .................................. 165
HOLD function
Activating ....................................... 209
Activation conditions ..................... 209
Deactivating ................................... 209
Display message ............................ 303
Function/notes .............................2 08
General notes ................................ 208
Hood
Closing ...........................................3 53
Display message ............................ 310
Important safety notes .................. 352
Opening ......................................... 352
Horn ...................................................... 32
HUD
see Head-up display
Hybrid drive system
Automatic switch off ........................ 42
Danger of electric shock .................. 42
Display message ............................ 297
General notes .................................. 42
High-voltage battery ........................ 43
Important safety notes .................... 42
Manual switch off ............................ 42
Opening the hood ............................ 43
Warning lamp ................................. 315
Hybrid vehicles
Important safety notes .................... 42
Hydroplaning ..................................... 196I
Ignition lock
see Key positions
Immobilizer .......................................... 78
Indicator and warning lamps
COLLISION PREVENTION ASSIST
PLUS .............................................. 322
Indicator lamps
see Warning and indicator lamps
Indicators
see Turn signals
Instrument cluster
Overview .......................................... 33
Warning and indicator lamps ........... 34
Instrument cluster lighting .............. 256
Interior lighting
Control ...........................................1 35
Emergency lighting ........................ 135
Overview ........................................ 134
Reading lamp ................................. 134
J
Jack
Using ............................................. 406
Jump starting (engine) ......................376
K
Key positions
SmartKey ....................................... 162
Start/Stop button .......................... 162
KEYLESS-GO
Convenience closing feature ............ 96
Deactivation ..................................... 80
Locking ............................................ 80
Start function ................................... 81
Unlocking ......................................... 80
Kickdown
Driving tips ....................................1 73
Knee bag .............................................. 52
L
Lamps
see Warning and indicator lamps
Lane Keeping Assist
see Active Lane Keeping Assist
Index11

Position of exterior mirror, front-
passenger side ...............................125
Rear view camera .......................... 220
Switching off the engine ................ 190
see PARKTRONIC
Parking aid
see 360° camera
see Active Parking Assist
see Exterior mirrors
see PARKTRONIC
see Rear view camera
Parking assistance
see PARKTRONIC
Parking brake
Applying automatically ................... 191
Applying or releasing manually ...... 191
Display message ............................ 281
Electric parking brake .................... 190
Emergency braking ........................ 192
General notes ................................ 190
Releasing automatically ................. 191
Warning lamp ................................. 319
Parking lamps
Switching on/off ........................... 131
PARKTRONIC
Deactivating/activating ................. 215
Driving system ............................... 214
Function/notes .............................2 14
Important safety notes .................. 214
Problem (malfunction) ................... 216
Range of the sensors ..................... 214
Warning display ............................. 215
PASSENGER AIR BAG
Display message ............................ 289
Indicator lamps ................................ 46
Problem (malfunction) ................... 289
Perfume atomizer
Operating ....................................... 153
Problem (malfunction) ................... 155
Vial ................................................ 153
Pets in the vehicle ............................... 67
Plastic trim (cleaning instruc-
tions) .................................................. 364
PLUG-IN HYBRID operating
Electrical energy generated ........... 249
PLUG-IN HYBRID operation
Automatic engine start (ECO
start/stop function) ....................... 253 Automatic engine switch-off (ECO
start/stop function) ....................... 252
Charge level of the high-voltage
battery ........................................... 245
Charging the high-voltage battery .. 246
Displaying the total range and
electric range ................................. 248
Driving tip
s .................................... 251
EC

O start/stop function ................ 252
Electric motor (power display) ....... 242
Electrical energy generated
(COMAND) ..................................... 249
Energy flow display ........................ 245
Fuel consumption .......................... 249
Fuel consumption (COMAND) ........ 249
General notes ................................ 240
Haptic accelerator pedal ................ 251
High-voltage battery (condition of
charge) .......................................... 245
Hybrid drive system overview ........ 241
HYBRID menu ................................ 272
Important safety notes .................. 240
Instrument cluster (power dis-
play) ............................................... 242
Instrument cluster overview .......... 242
Manual drive program .................... 250
Noiseless start ............................... 249
Operating (on-board computer) ..... 245
Operating mode ............................. 243
Overrun mode ................................ 253
Parking .......................................... 253
Power display ................................ 244
Power display (electric motor) ....... 242
Problems ....................................... 254
Problems with SRS (supplemental
restraint system) ............................ 255
Problems with the combustion
engine ............................................ 254
Problems with the hybrid drive
system ........................................... 255
Problems with the Recuperative
Brake System ................................ 254
Program selector button ................ 250
Pulling away ................................... 250
READY display ............................... 249
Recuperative Brake System ........... 240
Resetting the values (COMAND) .... 249
Route-based operating strategy ..... 253
Index15

Starting .......................................... 249
When the vehicle is stationary ....... 251
Power locks ......................................... 87
Power washers .................................. 360
Power windows
see Side windows
Pre-entry climate control (via
SmartKey)
Problems (malfunctions) ................ 157
Pre-entry climate control at depar-
ture time
General notes ................................ 157
Pre-entry climate control at time of
departure
Setting departure time ................... 158
Pre-entry climate control via key
General notes ................................ 155
PRE-SAFE
®(anticipatory occupant
protection)
Display message ............................ 284
Operation ......................................... 59
PRE-SAFE
®Brake
Activating/deactivating ................. 271
Display message ............................ 284
Function/notes ................................ 75
Important safety notes .................... 76
Warning lamp ................................. 322
PRE-SAFE
®PLUS (anticipatory
occupant protection PLUS)
Display message ............................ 284
Operation ......................................... 60
Program selector button .................. 173
Protection against theft
ATA (Anti-Theft Alarm system) ......... 78
Immobilizer ...................................... 78
Protection of the environment
General notes .................................. 24
Pulling away
Automatic transmission ................. 165
General notes ................................ 165
Hill start assist ............................... 165
Q
QR codeMercedes-Benz Guide App ................. 1
Rescue card ..................................... 29
Qualified specialist workshop ........... 28
R
Radio
Selecting a station ......................... 265
Radio-wave reception/transmis-
sion in the vehicle
Declaration of conformity ................ 28
Rain closing feature
Panorama sliding sunroof ................ 99
RBS (Recuperative Brake System)
Warning lamp ................................. 315
Reading lamp ..................................... 134
Rear compartment
Activating/deactivating climate
control ........................................... 145
Setting the air distribution ............. 149
Setting the air vents ...................... 160
Setting the airflow ......................... 150
Setting the temperature ................ 148
Stowage compartment .................. 327
Rear lamps
see Lights
Rear seats
Adjusting ....................................... 107
Adjusting a rear reclining seat ....... 107
Overview .......................................... 41
Setting the reclined position .......... 107
Rear view camera
Cleaning instructions ..................... 363
Displays in the COMAND display ... 221
Function/notes ............................. 220
Rear window blind ............................ 334
Rear window defroster
Problem (malfunction) ................... 152
Switching on/off ........................... 151
Rear-view mirror
Anti-glare (manual) ........................ 123
Dipping (automatic) ....................... 124
Recuperative Brake System
Driving safety systems ..................... 44
Important safety notes .................... 44
Refrigerant (air-conditioning sys-
tem)
Important safety notes .................. 432
Refueling
Fuel gauge ....................................... 33
Important safety notes .................. 177
16Index