2015 MERCEDES-BENZ S-Class refrigerant

Charging the high-voltage battery
(important safety notes) ...................209
Chauffeur mode
Display message ............................ 352
Fully reclined position .................... 131
General notes ................................ 127
Installing the head restraint ........... 129
Moving front-passenger seat into
the chauffeur position .................... 128
Moving the front-passenger seat
into the normal position ................. 130
Removing the head restraint .......... 129
Child
Restraint system .............................. 70
Child seat
Forward-facing restraint system ...... 74
LATCH-type (ISOFIX) child seat
anchors ............................................ 71
On the front-passenger sea t............ 74
Rearward-facing restraint system .... 74
Top Tether ....................................... 73
Child-proof locks
Important safety notes .................... 74
Rear doors ....................................... 75
Children
In the vehicle ................................... 69
Special seat belt retractor ............... 69
Cigarette lighter ................................ 383
Cleaning
Mirror turn signal ........................... 415
Climate control
Automatic climate control ............. 165
Controlling automaticall y............... 171
Cooling with air dehumidification .. 170
Defrosting the windows ................. 176
Defrosting the windshield .............. 175
ECO start/stop function ................ 169
General notes ................................ 164
Immediate pre-entry climate con-
trol ................................................. 183
Indicator lamp ................................ 171
Ionization ....................................... 180
Notes on using the automatic cli-
mate control .................................. 169
Overview of systems ...................... 164
Perfume atomizer .......................... 178 Pre-entry climate control at
departure time (REMOTE CLI-
MATE CONTROL) ........................... 182
Pre-entry climate control via key ... 180
Problem with the rear window
defroster ........................................ 177
Problems with cooling with air
dehumidification ............................ 171
Rear control panel ......................... 165
Refrigerant ..................................... 494
Refrigerant filling capacity ............. 495
Setting the air distribution ............. 174
Setting the air vents ...................... 184
Setting the airflow ......................... 174
Setting the climate mod e............... 173
Setting the temperature ................ 173
Switching air-recirculation mode
on/of f............................................ 177
Switching on/of f........................... 169
Switching residual heat on/off ...... 177
Switching the rear window
defroster on/of f............................ 176
Switching the synchronization
function on and off ........................ 175
Climate control system
Climate control .............................. 169
Cockpit
Overview .......................................... 34
COLLISION PREVENTION ASSIST
PLUS
Activating/deactivating ................. 309
Display message ............................ 325
Operation/note s.............................. 79
COMAND display
Cleaning ......................................... 417
Combination switch .......................... 152
Consumption statistics (on-board
computer) .......................................... 300
Convenience closing feature ............ 108
Convenience opening feature .......... 107
Coolant (engine)
Checking the level ......................... 408
Display message ............................ 336
Displaying the temperature (on-
board computer) ............................ 307
Filling capacity ............................... 493
Important safety notes .................. 493
Temperature gaug e........................ 294 Index
7

RBS (Recuperative Brake System)
Warning lamp ................................. 366
Reading lamp ..................................... 155
Rear compartment
Activating/deactivating climate
control ........................................... 169
Setting the air distribution ............. 174
Setting the air vents ...................... 185
Setting the airflow ......................... 174
Setting the temperature ................ 173
Stowage compartment .................. 374
Rear lamps
see Lights
Rear seats
Adjusting ....................................... 123
Adjusting a rear reclining seat ....... 123
Overview .......................................... 43
Setting the reclined position .......... 123
Rear view camera
Cleaning instructions ..................... 416
Function/notes ............................ .256
Switching on/off ........................... 257
Rear window blind ............................ 381
Rear window defroster
Problem (malfunction) ................... 177
Switching on/off ........................... 176
Rear-view mirror
Anti-glare (manual) ........................ 140
Dipping (automatic) ....................... 142
Recuperation display ........................ 299
Recuperative Brake System
Driving safety systems ..................... 48
Important safety notes .................... 48
Refrigerant (air-conditioning sys-
tem)
Important safety notes .................. 494
Refueling
Fuel gauge ....................................... 35
Important safety notes .................. 205
Refueling process .......................... 206
see Fuel
Remote control
Garage door opene r....................... 397
Programming (garage door
opener) .......................................... 398
Replacing bulbs
General notes ................................ 157
Reporting safety defects .................... 30Rescue card
......................................... 30
Reserve (fuel tank)
see Fuel
Reserve fuel
Display message ............................ 339
Warning lamp ................................. 363
Residual heat (climate control) ........ 177
Restraint system
Display message ............................ 328
Introduction ..................................... 49
Warning lamp ................................. 362
Warning lamp (function) ................... 50
Reversing feature
Panorama sliding sunroo f.............. 111
Roller sunblind s............................. 112
Side windows ................................. 106
Trunk lid ......................................... 100
Reversing lamps (display mes-
sage) ................................................... 335
ROAD SURFACE SCAN ....................... 245
Roadside Assistance (breakdown) .... 26
Roller sunblind
Panorama roof with power tilt/
sliding panel .................................. 112
Rear side window s......................... 381
Rear window .................................. 381
Roller sunblind of the panorama
roof with power tilt/sliding panel
Operating (front roller sunblind) .... 113
Operating (rear roller sunblind )...... 113
Roof carrier ........................................ 377
Roof lining and carpets (cleaning
guidelines) ......................................... 419
Roof load (maximum) ........................ 495 S
Safety Occupant Classification System
(OCS) ............................................... 59
see Operating safety
Safety notes
Hybrid vehicles ................................ 46
Safety system
see Driving safety systems
Seat
Multicontour seat in the rear com-partment ........................................ 134 Index
17

Seat belt buckle extender
Display message ............................3 27
Seat belt extender
Function/notes ................................ 55
Seat belts
Adjusting the driver's and front-
passenger seat bel t......................... 55
Adjusting the height ......................... 54
Cleaning ......................................... 419
Correct usage .................................. 53
Fastening ......................................... 54
Important safety guidelines ............. 51
Introduction ..................................... 51
Releasing ......................................... 55
Seat belt extender ........................... 55
Warning lamp ................................. 355
Warning lamp (function) ................... 56
Seating
Seating comfort packag e............... 134
Seating comfort package ................. 134
Seats
Active multicontour seat ................ 134
Adjusting (electrically) ................... 122
Adjusting (rear compartment) ........ 123
Adjusting the 4-way lumbar sup-
port ................................................ 134
Adjusting the head restraint .......... 131
Chauffeur mod e............................. 127
Cleaning the cover ......................... 418
Correct driver's seat position ........ 120
Display message ............................ 352
EASY-ENTRY/EXIT system ............. 139
Important safety notes .................. 121
Multicontour seat .......................... 134
Seat heating .................................. 134
Seat heating problem .................... 136
Seat ventilation .............................. 136
Seat ventilation problem ................ 137
Storing settings (memory func-
tion) ............................................... 144
Switching seat heating on/of f....... 134
Switching seat ventilation on/of f.. 136
Section
Wheels and tires ............................ 442
Selector lever
Cleaning ......................................... 418
see Automatic transmission
Sensors (cleaning instructions) ....... 415Service menu (on-board com-
puter)
.................................................. 307
Service products
Brake fluid ..................................... 492
Coolant (engine) ............................ 493
Engine oil ....................................... 491
Fuel ................................................ 490
Important safety notes .................. 489
Refrigerant (air-conditioning sys-
tem) ............................................... 494
Washer fluid ................................... 494
Setting the charge current (on-
board computer) ............................... 310
Setting the departure time (on-
board computer) ............................... 310
Settings
Factory (on-board computer) ......... 314
On-board computer ....................... 308
SETUP (on-board computer) ............. 314
Side impact air bag ............................. 58
Side marker lamp (display mes-
sage) ................................................... 335
Side windows
Cleaning ......................................... 415
Convenience closing feature .......... 108
Convenience opening feature ........ 107
Important safety information ......... 106
Opening/closing ............................ 106
Problem (malfunction) ................... 110
Resetting ....................................... 109
Sliding sunroof
see Panorama roof with power
tilt/sliding panel
SmartKey
Changing the battery ....................... 94
Changing the programming ............. 92
Checking the battery ....................... 94
Convenience closing feature .......... 108
Convenience opening feature ........ 107
Display message ............................ 354
Door central locking/unlocking ....... 91
Important safety notes .................... 90
KEYLESS-GO start function .............. 92
Loss ................................................. 95
Mechanical key ................................ 93
Overview .......................................... 90
Positions (ignition lock) ................. 189 18
Index

R
you switch on the turn signals. In this
event, the warnings are suppressed for a
certain period of time.
R a driving safety system intervenes, e.g.
ABS, BAS or ESP ®
.
R you accelerate hard, e.g. kickdown.
R you brake hard.
R you steer actively, e.g. swerve to avoid an
obstacle or change lanes quickly.
R you cut the corner on a sharp bend.
In order that you are warned only when nec-
essary and in good time if you cross the lane marking, the system recognizes certain con-
ditions and warns you accordingly.
The warning vibration occurs earlier if:
R you approach the outer lane marking on a
bend.
R the road has very wide lanes, e.g. a high-
way.
R the system recognizes solid lane markings.
The warning vibration occurs later if:
R the road has narrow lanes.
R you cut the corner on a bend. PLUG-IN HYBRID operation
Points to remember
General notes Hybrid technology combines a fuel efficient
internal combustion engine with a powerful
electric motor. In HYBRIDmode, the hybrid
system automatically selects the most effi-
cient operating mode for every driving situa-
tion. Drive the vehicle in the usual manner.
To save fuel, in HYBRIDmode, the hybrid
system switches off the combustion engine
as often as possible during the journey when power output requirements are low. When
power output requirements are low, the elec-
tric motor powers the vehicle. The engine is
switched on, even while the vehicle is in
motion, when a higher power output is
required. The engine is usually switched off when the vehicle is stationary. Consequently,
there is usually no engine idling as with com-
bustion engine vehicles.
For pulling away and accelerating, the electric motor supports the internal combustion
engine using the power stored in the high-
voltage battery. This energy is also used for
driving in partially electric mode, to operate
the electric refrigerant compressor and sup-
port the 12 V on-board electrical system. In
this way the hybrid drive helps to reduce your
vehicle's fuel consumption.
Observe the driving tips on PLUG-IN HYBRID
operation (Y page 287).
Recuperative Brake System If you release the accelerator pedal when the
vehicle is in motion, overrun recuperation is
initiated. The electric motor is operated as a
generator when in overrun mode and when
you brake. Hybrid technology converts the
kinetic energy of the vehicle into electricity
and stores it in the high-voltage battery.
Observe the important safety notes for the
Recuperative Brake System (Y page 48). Important safety notes
If the engine is switched off by the ECO start/
stop function and you open the driver's door:
R a message appears in the multifunction dis-
play and
R a warning tone sounds
Further information (Y page 340).
All of the vehicle's systems remain active, if:
R the vehicle is stationary
R the combustion engine is switched off and
R the READY indicator in the instrument clus-
ter lights up
If you remove your foot from the brake pedal
while in transmission position D or R, the
vehicle may pull away automatically.
Observe the notes on the READY display of
the ECO start/stop function (Y page 288).276
PLUG-IN HYBRID operationDriving and pa
rking

Hybrid system overview
:
12 V battery
; Transmission with electric motor
= Electric heater
? High-voltage electrical system cables
A High-voltage battery
B Recuperative Brake System
C Electric refrigerant compressor
D Vehicle socket
E Charger
F Voltage transformer
G Power electronics
You can deactivate the hybrid system manually. For further information on the high-voltage
switch-off device, see (Y page 47).278
PLUG-IN HYBRID operationDriving and parking

Vehicle identification plate with vehi-
cle identification number (VIN) X
Open the front right-hand door.
X Fold cover :down and remove it.
You will see the VIN.
The VIN can also be found in the following
locations:
R on the lower edge of the windshield
(Y page 489)
R on the vehicle identification plate
(Y page 488) Engine number
:
Engine number (stamped into the crank-
case)
; VIN (on the lower edge of the windshield)
= Emission control information plate,
including the certification of both federal
and Californian emissions standards Service products and filling capaci-
ties
Important safety notes
G
WARNING
Service products may be poisonous and haz-
ardous to health. There is a risk of injury.
Comply with instructions on the use, storage
and disposal of service products on the labels of the respective original containers. Always
store service products sealed in their original containers. Always keep service products out
of the reach of children. H
Environmental note
Dispose of service products in an environ-
mentally responsible manner.
Service products include the following:
R Fuels
R Lubricants (e.g. engine oil, transmission oil)
R Coolant
R Brake fluid
R Windshield washer fluid
R Climate control system refrigerant
Components and service products must be
matched. Only use products recommended
by Mercedes-Benz. Damage which is caused
by the use of products which have not been
recommended is not covered by the
Mercedes-Benz warranty or goodwill ges-
tures. They are listed in this Mercedes-Benz
Operator's Manual in the appropriate section.
Information on tested and approved products can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
You can recognize service products approved
by Mercedes-Benz by the following inscrip-
tion on the containers:
R MB-Freigabe (e.g. MB-Freigabe 229.51)
R MB Approval (e.g. MB Approval 229.51)
Other designations or recommendations indi- cate a level of quality or a specification in Service products and filling capacities
489Technical data Z

Model Capacity
S 63 AMG 4MATIC
8.5 US qt (8.0
l) S 65 AMG
11.3 US qt (10.7
l) S 550 PLUG-IN
HYBRID
13.3 US qt (12.6
l) All ot
her models 12.8 US qt (12.1
l) Windshield washer system
Important safety notes G
WARNING
Windshield washer concentrate could ignite if it comes into contact with hot engine compo-
nents or the exhaust system. There is a risk of
fire and injury.
Make sure that no windshield washer con-
centrate is spilled next to the filler neck.
! Do not add distilled or de-ionized water to
the washer fluid container. Otherwise, the
level sensor may be damaged.
! Only MB SummerFit and MB WinterFit
washer fluid should be mixed together. The
spray nozzles may otherwise become
blocked.
At temperatures above freezing: X Fill the washer fluid reservoir with a mixture
of water and windshield washer fluid, e.g.
MB SummerFit.
Add 1 part MB SummerFit to 100 parts water.
At temperatures below freezing:
X Fill the washer fluid reservoir with a mixture
of water and washer fluid, e.g. MB Winter-
Fit.
For the correct mixing ratio refer to the
information on the antifreeze reservoir.
i Add windshield washer fluid, e.g. MB
SummerFit or MB WinterFit, to the washer
fluid all year round. Climate control system refrigerant
Important safety notes The climate control system of your vehicle is
filled with refrigerant R‑134a.
The instruction label regarding the refrigerant
type used can be found on the radiator cross
member.
! Only the refrigerant R‑134a and the PAG
oil approved by Mercedes-Benz may be
used. The approved PAG oil may not be
mixed with any other PAG oil that is not
approved for R-134a refrigerant. Other-
wise, the climate control system may be
damaged.
Service work, such as topping up refrigerant
or replacing components, may only be carried out by a qualified specialist workshop. All
applicable regulations must be adhered to,
SAE standard J639 included.
Always have work on the climate control sys-
tem carried out at a qualified specialist work-
shop.
Refrigerant instruction label Example: refrigerant instruction label
: Warning symbol
; Refrigerant filling capacity
= Applicable SAE standards
? PAG oil part number
A Type of refrigerant 494
Service products and filling capacitiesTechnical data

Warning symbols
:indicate:
R possible dangers
R having service work carried out at a quali-
fied specialist workshop
Filling capacities Missing values were not available at time of
going to print. Model Refrigerant
S 550 PLUG-IN HYBRID
25.0 ± 0.4 oz
(710 ± 10 g) S 63 AMG 4MATIC
Model PAG oil
S 550 PLUG-IN HYBRID
4.3 oz
(120 g) S 63 AMG 4MATIC
Vehicles without rear-
compartment air-condi-
tioning system Capacity
Refrigerant
23.3 ± 0.4 oz
(660 ± 10 g) PAG oil
3.9 oz
(110 g) Vehicles with rear-com-
partment air-condition-
ing system Capacity
Refrigerant
27.1 ± 0.4 oz
(770 ± 10 g) PAG oil
4.2 oz
(120 g) Vehicle data
General notes
Please note that for the specified vehicle
data: R the heights specified may vary as a result
of:
- tires
- load
- condition of the suspension
- optional equipment
R optional equipment reduces the maximum
payload. Dimensions and weights
Trunk lid opening dimensions (example: S
‑Class
MAYBACH)
Missing values were not available at time of
going to print. Model
: :
Opening height S 550 PLUG-IN
HYBRID
S 600
S 600 MAYBACH
71.1 in
(1806 mm) AMG vehicles
71.2 in
(1808 mm) All other models
71.0 in
(1803 mm) Vehicle data
495Technical data Z