Page 7 of 338

5
12
508RXH_en_Chap00b_vue-ensemble_ed01-2014
Presentation of the HYbrid4 system
thank you for choosing this HYbrid4 vehicle, 
which has characteristics that are different from 
conventional vehicles.
Study this handbook to learn about the specific 
hybrid functions and for more information, refer 
to the "Hybrid System" section.
th
e HYbrid4 technology allows two sources of 
energy to be associated in an effective manner: 
the Diesel HDi engine, which drives the front 
wheels and the electric motor, which drives the 
rear wheels.
th
ese two motors can operate alternately or 
simultaneously, according to the hybrid mode 
selected and the driving conditions.
th
e electric motor alone provides power for 
the vehicle in "Z
eV
" (Zero  e
m
 issions Vehicle) 
mode, and in "Auto" mode for running at slow 
speed and low load. It also assists the Diesel 
engine when moving off, accelerating and 
changing gear.
th
e battery that powers the electric motor is 
recharged during phases of deceleration and 
stores the energy for subsequent use. 1.
 D
iesel HDi engine (front wheel drive).
2.
 
e
l
 ectric motor (rear wheel drive).
3.
 2
00 V battery.
4.
 
e
le
 ctronic power supervisor.5.
 A
lternator-starter motor (Stop & Start).
6.
 
e
le
 ctronic gearbox.
7.
 
e
le
 ctrical flow.
8.
 H
Ybrid4 mode selector.
. 
Over view  
         
        
        
     
        
        Page 11 of 338
9
90
75 131 148117
68, 79, 80 242 15 171
115
140
29
129 179 84
508RXH_en_Chap00b_vue-ensemble_ed01-2014
Illumination of the lamp indicates the state of 
the corresponding function.
Switch panels
electric parking brake.
Opening the boot.
Massage.
Alarm.
el
ectric child lock.
Programmable heating warning lamp.
Deactivation of parking sensors.
Inhibition of internal combustion 
engine stop.
Head-up display 
(on/off, settings).
Peuge
O
t
 Connect SOS
Starting/stopping using the electronic 
key.
Blind spot monitoring. Deactivation of the DSC system. Opening the fuel filler flap.
Adaptive lighting
. 
Over view  
         
        
        
     
        
        Page 14 of 338

12
508RXH_en_Chap00c_systeme-hybride_ed01-2014
Presentation
the HYbrid4 technology allows two sources of 
energy to be associated in an effective manner: 
the Diesel HDi engine, which drives the front 
wheels and the electric motor, which drives the 
rear wheels.
th
ese two motors can operate alternately or 
simultaneously, according to the hybrid mode 
selected and the driving conditions.
th
e electric motor alone provides power for 
the vehicle in "Z
eV
" (Zero  e
m
 issions Vehicle) 
mode, and in "Auto" mode for running at slow 
speed and low load. It also assists the Diesel 
engine when moving off, accelerating and 
changing gear.
th
e battery that powers the electric motor is 
recharged during phases of deceleration and 
stores the energy for subsequent use.
1.
 D
iesel HDi engine (front wheel drive).
2.
 
e
l
 ectric motor (rear wheel drive).
3.
 2
00 V battery.
4.
 
e
le
 ctronic power supervisor.
5.
 A
lternator-starter motor (Stop & Start).6.
 
e
le
 ctronic gearbox.
7.
 
e
le
 ctrical flow.
8.
 H
Ybrid4 mode selector. 
Hybrid system  
         
        
        
     
        
        Page 15 of 338

13
508RXH_en_Chap00c_systeme-hybride_ed01-2014
Main parts of the HYbrid4 system
the HDi Diesel engine - 1, located at the front, drives the front wheels and provides most of the 
power needed to drive the vehicle.
It is fitted with an alternator-starter motor  (Stop & Star t ) - 5 which recharges the batteries and 
provides additional power when needed (in 4x4 mode).
th
e electric motor - 2 , located at the rear, drives the rear wheels on its own, or supplements the 
Diesel engine, according to the hybrid mode selected.
It recovers energy and charges the batteries during phases of deceleration of the vehicle and is 
active up to 70 mph (120 km/h).
A 200 V NI-MH high voltage batter y - 3 , provides a source of energy for the rear electric motor.
Its charging rate is managed automatically by the vehicle during phases of deceleration.
It is located in a compartment in the boot, access to which is restricted to trained service 
technicians.
th
e battery state of charge  is indicated by 8 horizontal or vertical bars (depending on the screen).
th
e conventional battery , located under the bonnet, powers the vehicle's 12 V systems. It is 
recharged automatically by the high voltage network.
. 
Hybrid system  
         
        
        
     
        
        Page 16 of 338

14
508RXH_en_Chap00c_systeme-hybride_ed01-2014
the electronic power super visor - 4 automatically manages the operation of the two power units 
(Diesel and electric) to provide the lowest consumption.
An inverter and a transformer are needed to manage the electric power.
th
e inverter acts on the torque of the electric motor, by regulating the current coming from the high 
voltage battery pack. Its operating range is between 150 and 270 volts.
th
e transformer converts the 200 V of the battery pack to 12 V, to power the vehicle's ancillary 
systems.
th
e alternator-starter motor - 5  assures the Stop & Star t function which allows the Diesel 
engine to be put into standby during stops (traffic lights, a stop, or in a traffic jam, for example) or 
during phases of running in all-electric mode.
th
e stopping and restarting of the Diesel engine is done in a way that is instantaneous and 
transparent for the driver.
It also provides additional charging of the batteries (4x4 mode for example or under-charged high 
voltage battery).
th
e electronic gearbox - 6 provides, in automatic mode, significant savings in fuel consumption 
compared to a conventional manual gearbox, thanks to its electronic control system.
It also offers improved driving pleasure with the possibility at any time of choosing the gear 
changing mode: automatic or manual, using the paddles located behind the steering wheel. 
Hybrid system  
         
        
        
     
        
        Page 17 of 338
15
508RXH_en_Chap00c_systeme-hybride_ed01-2014
Starting - stopping the engine
Before startingStarting the HYbrid4 
system
- Press the brake pedal.
-
 M ake a single short press (about 
one
  second) on the START/STOP  button 
or turn the key fully towards the dashboard 
to position 3 (Starting).
-
  t
h
 e steering column unlocks (noise and 
noticeable movement).
-
 P
lace the gear selector in position N
.
-
 I
f the vehicle has Keyless 
en
try and 
Starting, simply having the key inside the 
vehicle is sufficient.
-
 
O
ther wise, it is necessary to place the key 
in the ignition switch.
-
 
I
f the Diesel preheater indicator lamp is on 
(ambient temperature below zero) wait until 
it goes off before starting. -
 
K
 eep your foot on the brake pedal until the 
HYbrid4 system starts up (the instrument 
panel and the Ready  lamp come on, 
confirmed by an audible signal).
th
 e hybrid system determines whether it is 
necessary to start the Diesel engine.
. 
Hybrid system  
         
        
        
     
        
        Page 18 of 338
16
508RXH_en_Chap00c_systeme-hybride_ed01-2014
- Before switching off the HYbrid4 system, place the gear selector in position N .
-
 
M
 ake a short press on the START/STOP  
button or turn the key fully off to  
position
 
1 (Stop) then remove the key from 
the ignition switch.
-
  t
h
 e system shuts down and the steering 
column locks.
Switching the HYbrid4 system off
For more information, refer to the 
"un derbonnet precautions / warnings" 
section.
When stationary, ensure that the ignition is 
switched off and check that the Ready  lamp 
is off when you want to leave the vehicle, 
other wise the hybrid system will still be active.When your vehicle  moves off in 
electric mode, it makes no noise. Be 
ver y careful of pedestrians as they 
will not hear you coming.
Switching off the engine leads to a loss 
of braking assistance. 
Hybrid system  
         
        
        
     
        
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18
508RXH_en_Chap00c_systeme-hybride_ed01-2014
Emergency starting with the 
electronic key
When the electronic key is in the recognition 
zone and your vehicle does not start after 
pressing the "S
tA
R
t/
 S
tO
 P" button:
F
 
O
 pen the housing below the "S
tA
 R
t/
St
OP " button.
F
 
I
 nsert the electronic key in the location A .
F
 
P
 ress the "S
tA
 R
t/
 S
tO
 P" button.
Emergency switch-off using the 
electronic key
In the event of an emergency only, the engine 
can be switched of without conditions.  to d o 
this, press and hold the "S
tA
R
t/
 S
tO
 P" button 
for about 3 seconds.
In this case the steering column locks as soon 
as the vehicle stops.
If the electronic key is no longer in the 
recognition zone when you request switching 
off the engine, a message appears in the 
instrument panel.
F
 
P
 ress and hold the "S
tA
 R
t/
 S
tO
 P" button 
for about 3 seconds if you want to force 
switching off the engine (note that restarting 
will not be possible without the key).
Electronic key not recognised by 
the "Keyless Entry and Starting" 
system
If the electronic key is no longer in the 
recognition zone when driving or when you 
(later) request switching off of the hybrid 
system, a message appears in the instrument 
panel.
Once the engine has started, you can 
remove the electronic key and close the 
housing. F
 
P
 ress and hold the "S
tA
 R
t/
 S
tO
 P" button 
for about 3 seconds if you want to force 
switching off of the hybrid system (note that 
restarting will not be possible without the 
electronic key in the recognition zone).
th
e electronic key must always remain 
inside the vehicle while in use. 
Hybrid system