2013 MERCEDES-BENZ S-CLASS SEDAN key

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible.
Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Please read the information on qualified
specialist workshops (Y page 31). SmartKey
Important safety notes
G
WARNING
When leaving the vehicle, always remove the
SmartKey from the ignition lock. Always take
the SmartKey with you and lock the vehicle.
Do not leave children unsupervised in the
vehicle, even if they are secured in a child
restraint

system, and do not give them access
to an unlocked vehicle. A child's unsupervised
access to a vehicle could result in an accident
and/or serious personal injury. They could:
R injure themselves on vehicle parts
R be seriously or fatally injured by extreme
heat or cold
R injure themselves or have an accident with
vehicle equipment that may still be in
operation even after the SmartKey has
been removed from the ignition, such as the
seat adjustment, steering wheel
adjustment or memory function.
If children open a door, they could cause
severe or even fatal injury to other persons; if
they get out of the vehicle, they could injure
themselves when doing so or be seriously or
even fatally injured by any passing traffic.
Do not expose the child restraint system to
direct sunlight. The child restraint system's
metal parts, for example, could become very hot, and a child could be burned on these
parts.
G
WARNING
If a key ring is too heavy or too large, the
weight
acting on the key could cause it to turn
in the ignition lock or catch on the steering
wheel. This could cause the engine to be
switched off suddenly. You could lose control
of the vehicle and cause an accident. Do not
attach any heavy or large key rings to the key
that is inserted in the ignition. General notes
If you cannot lock or unlock the vehicle with
the SmartKey, either the battery in the
SmartKey is discharged, the SmartKey is
faulty or the starter battery is discharged.
X Check the battery in the SmartKey and
replace it if necessary

(Y page 82).
X Unlock the driver's door using the
mechanical key ( Y page 87).
X Lock the vehicle (Y page 88).
X Have the starter battery and the battery
contacts checked at a qualified specialist
workshop.
If the SmartKey is faulty, contact Roadside
Assistance
or a qualified specialist workshop. SmartKey functions
General notes i
USA only:
This device complies with Part 15 of the
FCC Rules. Operation is subject to the
following two conditions:
1. This device may not cause harmful
interference, and
2.

this device must accept any interference
received, including interference that may
cause undesired operation. 78
SmartKey
Opening/closing

Any unauthorized modification to this
device could void the user’s authority to
operate the equipment.
The Product label with FCC ID and IC
certification number can be found in the
battery case of the SmartKey.
i Canada only:
This device complies with RSS-210 of
Industry Canada. Operation is subject to
the following two conditions:
1. This device may not cause interference,
and
2.
this device must accept any interference
received, including interference that may
cause undesired operation of the device.
Any unauthorized modification to this
device could void the user’s authority to
operate the equipment.
The Product label with FCC ID and IC
certification number can be found in the
battery case of the SmartKey.
Locking and unlocking centrally The SmartKey centrally locks/unlocks:
R
the doors
R the trunk lid
R the fuel filler flap :
& Locks the vehicle
; F Unlocks the trunk lid
= % Unlocks the vehicle
When unlocking, the turn signals flash once.
When locking, they flash three times. When it is dark, the surround lighting also
comes on if it is activated in COMAND
(Y page 264).
If you activate the acoustic locking
confirmation function, you will hear the
following, depending on the date of
production of the vehicle:
R
an acoustic signal when locking
or
R one acoustic signal when unlocking and
three when locking.
The audible signal can be activated and
deactivated using the on-board computer
(Y page 386).
X To unlock centrally: press the %
button.
If you do not open the vehicle within
approximately 40 seconds of unlocking:
R the vehicle is locked again.
R the

theft deterrent locking system is armed
again.
X To lock centrally: press the & button. KEYLESS-GO
General notes i
USA only:
This device complies with Part 15 of the
FCC Rules. Operation is subject to the
following two conditions:
1. This device may not cause harmful
interference, and
2.

this device must accept any interference
received, including interference that may
cause undesired operation.
Any unauthorized modification to this
device could void the user’s authority to
operate the equipment.
The Product label with FCC ID and IC
certification number can be found in the
battery case of the SmartKey.
i Canada only: SmartKey
79
Opening/closing Z

This device complies with RSS-210 of
Industry Canada. Operation is subject to
the following two conditions:
1. This device may not cause harmful
interference, and
2.
this device must accept any interference
received, including interference that may
cause undesired operation.
Any unauthorized modification to this
device could void the user’s authority to
operate the equipment.
The Product label with FCC ID and IC
certification number can be found in the
battery case of the SmartKey.
Important notes on the use of KEYLESS-
GO R
The KEYLESS-GO key can be used like a
conventional key.
R You can combine KEYLESS-GO functions
with those of a conventional key, e.g.
unlock

with KEYLESS-GO and lock with the
& button.
R Always carry your KEYLESS-GO key on your
person.
R Do not keep the KEYLESS-GO key together
with:
-electronic devices, e.g. a mobile phone
or another key
- metallic objects, e.g. coins or metal foil.
This can affect the functionality of
KEYLESS-GO.
R When locking and unlocking using
KEYLESS-GO, the distance between the
SmartKey and the corresponding door
handle must not exceed 3 ft (1 m).
R If the vehicle is parked for more than
72 hours, the KEYLESS-GO function is
deactivated. Pull the outer door handle and
switch on the ignition to reactivate the
KEYLESS-GO function.
R If the KEYLESS-GO key is removed from the
vehicle, it is possible that the system may
not recognize the SmartKey. The vehicle can then not be locked or started using
KEYLESS-GO.
R If the KEYLESS-GO key has been removed
from

the vehicle, e.g. if a passenger leaves
the vehicle with a KEYLESS-GO key:
- if the start/stop button is pressed or if
an attempt is made to lock the vehicle
with the locking button on the outer door
handle, the Key Not Detected message
appears in the multifunction display
- when the engine is running, the red Key
Not Detected message appears in the
multifunction display as you pull away.
Find the KEYLESS-GO key and change its
position in the vehicle. Carry the
KEYLESS-GO key in your shirt pocket, for
example.
R If you have started the engine with the
Start/Stop button, you can switch it off
again by:
-pressing the Start/Stop button again
- inserting the KEYLESS-GO key into the
ignition lock if the vehicle is stationary
and the automatic transmission is in park
position P.
R You could unlock the vehicle by mistake if
the distance between the KEYLESS-GO key
and the vehicle is less than 3 ft (1 m) and:
-an exterior door handle is hit by a water
jet
or
- you clean an exterior door handle.
R Bear in mind that the engine can be started
by any of the vehicle occupants if there is
a KEYLESS-GO key in the vehicle.80
SmartKey
Opening/closing

X
To unlock the vehicle: pull the door
handle.
X To lock the vehicle: touch sensor
surface :.
X Convenience closing feature: touch
recessed sensor surface ; for an
extended period ( Y page 94).
If you pull on the handle of the trunk lid, only
the trunk of the vehicle is unlocked. Changing the settings of the locking
system
You can change the setting of the locking
system in such a way that only the driver's
door
and the fuel filler flap are unlocked. This
is useful if you frequently travel on your own.
X To change the setting: press and hold
down the % and & buttons
simultaneously for approximately six
seconds until the battery check lamp
(Y page 82) flashes twice.
i If the setting of the locking system is
changed within the signal range of the
vehicle, pressing the & or % button
locks or unlocks the vehicle.
The SmartKey now functions as follows:
X To unlock the driver's door: press the
% button once.
X To unlock centrally: press the %
button twice.
X To lock centrally: press the & button.
The KEYLESS-GO function is changed as
follows:
X To unlock the driver's door :
pull the door
handle on the driver's door.
X To unlock centrally: pull the door handle
on the front-passenger door or on the rear
doors.
X To lock centrally: touch the outer sensor
surface on one of the door handles. Restoring the factory settings
X Press the % and & buttons
simultaneously for approximately six
seconds until the battery check lamp
flashes twice. Mechanical key
General notes If you use the mechanical key to unlock and
open the driver's door or the trunk lid, the
anti-theft alarm system will be triggered
(Y page 75).
There are several ways to turn off the alarm:
X
To turn the alarm off with the
SmartKey:

press the % or & button
on the SmartKey.
or
X Insert the SmartKey into the ignition lock.
or
X To deactivate the alarm with KEYLESS-
GO: press the Start/Stop button in the
ignition lock. The SmartKey must be in the
vehicle.
or
X Lock or unlock the vehicle using KEYLESS-
GO. The SmartKey must be outside the
vehicle.
Removing the mechanical key SmartKey
81
Opening/closing Z

X
Push release catch : in the direction of
the arrow and at the same time, remove
mechanical key ; from the SmartKey.SmartKey battery
Important safety notes Have the batteries changed at a qualified
specialist workshop.
G
WARNING
Batteries contain toxic substances.
Swallowing batteries can lead to serious
health issues or death.
Keep batteries out of the reach of children.
Seek medical attention immediately if a
battery is swallowed. G
WARNING
The SmartKey batteries contain perchlorate
material, which may require special handling
and regard for the environment. Observe
government disposal guidelines. California
residents, see www.dtsc.ca.gov/
HazardousWaste/Perchlorate/
index.cfm.
Checking the battery X
Press the & or % button.
The battery is working properly if battery
check lamp : lights up briefly
If battery check lamp : does not light up
briefly during the test, the battery is
discharged. X
Changing the battery ( Y page 82)
i You can obtain the battery at a qualified
specialist workshop.
i If
the SmartKey battery is checked within
the signal reception range of the vehicle,
pressing the & or % button locks or
unlocks the vehicle.
Changing the battery You require a CR 2025 3 V cell battery.
X
Take the mechanical key out of the
SmartKey (Y page 81). X
Press mechanical key ; into the opening
in the SmartKey in the direction of the
arrow until battery tray cover : opens.
When

doing so, do not hold cover : shut.
X Remove battery tray cover :. X
Repeatedly tap the SmartKey against your
palm until battery = falls out.
X Insert the new battery with the positive
terminal facing upwards. Use a lint-free
cloth to do so.82
SmartKey
Opening/closing

X
Make sure that the surface of the battery is
free
from lint, grease and all other forms of
contamination.
X Insert the front tabs of battery tray
cover : and then press to close it.
X Insert the mechanical key into the
SmartKey.
X Check the function of all SmartKey buttons
on the vehicle. SmartKey
83
Opening/closing Z

Problems with the SmartKey
Problem Possible causes/consequences and
M SolutionsYou cannot lock or
unlock the vehicle
using the SmartKey. The SmartKey battery is discharged or nearly discharged.
X
Try again to lock/unlock the vehicle using the remote control
function of the SmartKey. Point the tip of the SmartKey at the
driver's door handle from close range and press the %/
& button.
If this does not work:
X Check the SmartKey battery (Y page 82) and replace it if
necessary ( Y page 82).
X Lock ( Y page 87) or unlock ( Y page 88) the vehicle using
the mechanical key. The SmartKey is faulty.
X
Lock ( Y page 87) or unlock ( Y page 88) the vehicle using
the mechanical key.
X Have the SmartKey checked at a qualified specialist workshop. You can no longer lock
or unlock the vehicle
using KEYLESS-GO. KEYLESS-GO is in standby mode because the vehicle has not been
unlocked for an extended period.
X
Pull the door handle twice and then insert the SmartKey into the
ignition lock. There is interference from a powerful source of radio waves.
X
Lock/unlock the vehicle using the remote control function of
the
SmartKey. Point the tip of the SmartKey at the driver's door
handle from close range and press the %/& button.There is a malfunction with KEYLESS-GO.
X
Lock/unlock the vehicle using the remote control function of
the

SmartKey. Point the tip of the SmartKey at the driver's door
handle from close range and press the %/& button.
X Have KEYLESS-GO checked at a qualified specialist workshop.
If this does not work:
X Check the SmartKey battery (Y page 82) and replace it if
necessary ( Y page 82).
X Lock ( Y page 87) or unlock ( Y page 88) the vehicle using
the mechanical key. You have lost a
SmartKey. X
Have the SmartKey deactivated at a qualified specialist
workshop.
X Report the loss immediately to the vehicle insurers.
X If necessary, have the locks changed as well.84
SmartKey
Opening/closing

Problem Possible causes/consequences and
M SolutionsYou have lost the
mechanical key. X
Report the loss immediately to the vehicle insurers.
X If necessary, have the locks changed as well. The engine cannot be
started using the
SmartKey. The on-board voltage is too low.
X
Remove the SmartKey and reinsert it into the ignition lock.
X Start the engine within 30 seconds of inserting the SmartKey in
the ignition lock.
X Repeat if necessary.
If the engine does not start after several attempts:
X Check the starter battery and charge it if necessary
(Y page 478).
or
X Jump-start the vehicle (Y page 481).
or
X Consult a qualified specialist workshop. The engine cannot be
started
using KEYLESS-
GO. The SmartKey is in
the vehicle. A door is open. Therefore, the SmartKey cannot be detected as
easily.
X
Close the door and try to start the vehicle again. There is interference from a powerful source of radio waves.
X
Start your vehicle with the SmartKey in the ignition lock. Doors
Important safety notes
G
WARNING
When leaving the vehicle, always remove the
SmartKey from the ignition lock. Always take
the SmartKey with you and lock the vehicle.
Do not leave children unsupervised in the
vehicle, even if they are secured in a child
restraint

system, and do not give them access
to an unlocked vehicle. A child's unsupervised
access to a vehicle could result in an accident
and/or serious personal injury. They could:
R injure themselves on vehicle parts
R be seriously or fatally injured by extreme
heat or cold
R injure themselves or have an accident with
vehicle equipment that may still be in operation even after the SmartKey has
been

removed from the ignition, such as the
seat adjustment, steering wheel
adjustment or memory function.
If children open a door, they could cause
severe or even fatal injury to other persons; if
they get out of the vehicle, they could injure
themselves when doing so or be seriously or
even fatally injured by any passing traffic.
Do not expose the child restraint system to
direct sunlight. The child restraint system's
metal parts, for example, could become very
hot, and a child could be burned on these
parts. Doors
85
Opening/closing Z