2013 MERCEDES-BENZ S-CLASS SEDAN key

Low outside temperatures
!
Do not use gasoline to refuel vehicles with
a diesel engine. Never mix diesel with
gasoline or kerosene, as this may result in
damage to the engine or fuel system.
Diesel fuel with improved cold flow properties
is available during the winter months. Further
information on fuel properties can be
obtained from oil companies, e.g. at gas
stations. Refueling
Fuel filler flap The fuel filler flap is unlocked or locked
automatically when you open or close the
vehicle

with the SmartKey or using KEYLESS-
GO.
The position of the fuel filler cap is displayed
in the instrument cluster 8. The arrow
next to the filling pump indicates the side of
the vehicle. :
To open the fuel filler flap
; To insert the fuel filler cap
= Tire pressure table
? Fuel type
Opening X
Switch off the engine.
X Remove the SmartKey from the ignition
lock. KEYLESS-GO: open the driver’s door. This
switches the ignition to position
0, which
corresponds to having removed the
SmartKey. The driver’s door can be closed
again.
X Press the fuel filler flap in the direction of
arrow :.
The fuel filler flap opens slightly.
X Open the fuel filler flap.
X Turn the fuel filler cap counter-clockwise
and remove it.
X Insert the fuel filler cap into the holder
bracket on the inside of filler flap ;.
X Completely insert the pump nozzle into the
filler neck and refuel.
X Only fill the tank until the pump nozzle
switches off.
! Overfilling
the fuel tank could damage the
fuel system.
Closing X
Replace the fuel filler cap and turn it
clockwise. The fuel filler cap audibly
engages.
X Close the fuel filler flap.
i If you drive with the fuel filler cap open,
the reserve fuel warning lamp flashes. In
addition, the ; Check Engine warning
lamp may light up. A message appears in
the multifunction display

(Y page 407).
For further information on warning and
indicator lamps in the instrument cluster,
see ( Y page 427).
i Close the fuel filler flap before locking the
vehicle. A locking pin otherwise prevents
the fuel filler flap from closing after the
vehicle has been locked. Refueling
319
Driving and parking Z

Problems with fuel and the fuel tank
Problem Possible causes/consequences and
M SolutionsFuel is leaking from the
vehicle.
G
Risk of explosion or fire
The fuel line or the fuel tank is defective.
X Turn the SmartKey to position 0(Y page 303) in the ignition lock
immediately and remove it.
X Do not restart the engine under any circumstances.
X Consult a qualified specialist workshop. The fuel filler flap
cannot be opened. The fuel filler flap is not unlocked.
or
The SmartKey battery is discharged.
X
Unlock the vehicle (Y page 78).
or
X Unlock the vehicle using the mechanical key ( Y page 81).The fuel filler flap is unlocked, but the opening mechanism is
jammed.
X
Consult a qualified specialist workshop. The engine will not
start. The fuel tank of a vehicle with a diesel engine has been run
completely dry.
X
Refuel the vehicle with at least 5.3 US qt (5 liters) of diesel.
X Turn the ignition on for at least 10 seconds (Y page 303).
X Start the engine continuously for up to 10 seconds until it runs
smoothly.
or
X Start the engine via the touch-start function. To do this, turn the
SmartKey to position 3 (Y page 303) in the ignition lock and
then release it immediately.
If the engine does not start:
X Turn the ignition on again for approximately 10 seconds
(Y page 303).
X Start the engine again continuously for up to 10 seconds until
it runs smoothly.
or
X Start the engine again via the touch-start function.
If the engine does not start after three attempts:
X Consult a qualified specialist workshop.320
Refueling
Driving and parking

X
Press DEF refill bottle = down.
The DEF tank is filled. This may take up to
one minute.
i If the DEF refill bottle is no longer pressed
down, the filling process stops and the
partially emptied bottle can be removed.
X Release DEF refill bottle =.
X Turn DEF refill bottle = counter-clockwise
and remove it.
X Place DEF filler cap ;
on the filler neck and
turn it clockwise. X
Insert DEF cap : as shown and turn it
clockwise as far as it will go.
X Place the "Minispare" emergency spare
wheel in the emergency spare wheel well
above the DEF tank.
X Insert the "Minispare" emergency spare
wheel fastening and tighten clockwise.
X Fold the trunk floor down.
X Close the trunk lid.
X Drive at a speed above 10 mph (16 km/h)
.
The Check Additive See Operator's
Manual message goes out after
approximately one minute.
i If the Check Additive See
Operator's Manual message remains
shown in the multifunction display, add an
additional bottle of DEF.
i Then, have the DEF supply checked at a
qualified specialist workshop and
completely refilled if necessary. Parking
Important safety notes
G
WARNING
Do not park this vehicle in areas where
combustible
materials can come into contact
with the hot exhaust system. Combustible
materials, such as grass, hay or leaves could
be ignited by the hot exhaust system and
cause a vehicle fire. Do not park the vehicle
on dry grassland or harvested grain fields.
Unintended vehicle movement can cause
serious personal injury or damage to the
vehicle or the vehicle drivetrain. To reduce
such risks, always do the following before
turning off the engine and leaving the vehicle:
R keep your right foot on the brake pedal.
R engage the electric parking brake.
R shift the automatic transmission into park
position P.
R slowly release the brake pedal.
R when parked on an incline, always turn the
front wheels towards the road curb.
R turn the SmartKey in the ignition lock to
position 0 and remove the SmartKey from
the ignition lock, or press the KEYLESS-GO
Start/Stop button.
R take the SmartKey with you and lock the
vehicle when leaving. Switching off the engine
Important safety notes G
WARNING
Do not turn off the engine before the vehicle
has
come to a complete stop. With the engine
not running, there is no power assistance for
the brake and steering systems. In this case,
it is important to keep in mind that a
considerably higher degree of effort is
necessary to brake and steer the vehicle. Parking
323
Driving and parking Z

G
WARNING
Keep in mind that turning off the engine alone
only will shift the automatic transmission into
neutral position N automatically.
Always shift the automatic transmission into
park position P before turning off the engine.
Otherwise the vehicle could roll away which
could result in an accident and/or serious
personal injury.
i If you cannot turn off the engine as
described here, see "Engine emergency
stop" ( Y page 487).
Vehicles with automatic transmission X
Apply the electric parking brake.
X Shift the transmission to position P.
Using the SmartKey
X Turn the SmartKey to position 0 in the
ignition lock and remove it.
The immobilizer is activated.
i If you turn off the engine with the
SmartKey and then remove it from the
ignition lock or open a front door, the
automatic transmission shifts to P
automatically.
Using KEYLESS-GO
X Press the Start/Stop button (Y page
303).
The engine stops and all the indicator
lamps in the instrument cluster go out.
i When the driver's door is closed, this
corresponds

to SmartKey position 1. When
the driver's door is open, it corresponds to
SmartKey position 0 or "SmartKey
removed".
i If you use the Start/Stop button to switch
off the engine, the automatic transmission
shifts to N automatically. If you then open
the driver's or front-passenger door, the
automatic transmission shifts to P.
i In an emergency, the engine can be
turned off while the vehicle is in motion by pressing and holding the Start/Stop button
for three seconds. This function operates
independently from the ECO start/stop
automatic engine switch-off function.
Electric parking brake
General information G
WARNING
When leaving the vehicle, always remove the
SmartKey
from the starter switch, take it with
you, and lock the vehicle. Do not leave
children unattended in the vehicle, or with
access to an unlocked vehicle. Children could
release the parking brake and/or shift the
automatic transmission out of park position
P, either of which could result in an accident
and/or serious personal injury. Applying/releasing manually
X
To apply: press handle :.
The red F (USA only) or ! (Canada
only) indicator lamp in the instrument
cluster lights up.
i The electric parking brake can also be
applied when the SmartKey is removed.
X To release: switch on the ignition.
X Pull handle :.
The red F (USA only) or ! (Canada
only) indicator lamp in the instrument
cluster goes out.
i The electric parking brake cannot be
released

unless the SmartKey is in position324
Parking
Driving and parking

more firmly. Maintain a safe distance from
vehicles in front.
After driving on a wet road or having the
vehicle washed, brake firmly while paying
attention to the traffic conditions. This will
warm
up the brake discs, thereby drying them
more quickly and protecting them against
corrosion.
Limited braking performance on salt
treated roads G
WARNING
The layer of salt on the brake discs and the
brake pads/linings may cause a delay in the
braking effect, resulting in a significantly
longer braking distance, which could lead to
an accident.
To avoid this danger, you should:
R occasionally brake carefully, without
putting other road users at risk, when you
are driving on salted roads. This helps to
remove any salt that may have started to
build up on the brake discs and the brake
pads/linings.
R maintain a greater distance to the vehicle
ahead and drive with particular care.
R carefully apply the brakes at the end of a
trip and immediately after commencing a
new

trip, so that salt residues are removed
from the brake discs.
Servicing the brakes !
If
the red brake warning lamp lights up in
the instrument cluster and you hear a
warning tone while the engine is running,
the brake fluid level may be too low.
Observe additional warning messages in
the multifunction display.
The brake fluid level may be too low due to
brake pad wear or leaking brake lines.
Have the brake system checked
immediately. This work should be carried
out at an authorized Mercedes-Benz
Center. All checks and maintenance work on the
brake system must be carried out at a
qualified specialist workshop. This work
should be carried out at an authorized
Mercedes-Benz Center.
Have the brake pads replaced and the brake
fluid renewed at a qualified specialist
workshop,

e.g. an authorized Mercedes-Benz
Center. G
WARNING
If brake pads or brake fluid other than those
recommended are used, the braking
properties of the vehicle can be degraded to
an extent that safe braking is substantially
impaired. This could result in an accident.
! Vehicles with 4MATIC: function or
performance

tests may only be carried out
on a 2-axle dynamometer. If you are
planning to have the vehicle tested on such
a dynamometer, contact an authorized
Mercedes-Benz Center to obtain further
information first. Otherwise, you could
damage the drive train or the brake system.
! Vehicles with 4MATIC: as the ESP®
system operates automatically, the engine
and the ignition must be switched off
(SmartKey in position 0 or 1 in the ignition
lock or Start/Stop button in position 0 or
1) when the electric parking brake is being
tested on a brake dynamometer.
Braking maneuvers triggered automatically
by ESP ®
may seriously damage the brake
system.
! Vehicles with 4MATIC: as the ESP®
system operates automatically, the engine
and the ignition system must be switched
off (SmartKey in position 0 or 1 in the
ignition lock or Start/Stop button in
position 0 or 1) when:
R testing the electric parking brake on a
brake dynamometer.
R you intend to have the vehicle towed with
one of the axles raised.328
Driving tips
Driving and parking

The "Lowered” vehicle level is set
automatically:
R
in vehicles without 4MATIC at speeds
above 60 mph (100 km/h)
R in vehicles with 4MATIC at speeds above
50 mph (80 km/h)
Setting the vehicle level
Select the "Normal" setting for normal road
surfaces and "Raised" for driving with snow
chains or on particularly poor road surfaces.
Your selection remains stored even if you
remove the SmartKey from the ignition lock. G
WARNING
To help avoid personal injury, keep hands and
feet away from wheel housing area, and stay
away from under the vehicle when lowering
the vehicle chassis. Setting raised level
X
Start the engine.
If indicator lamp ; is not lit:
X Press button :.
Indicator lamp ; lights up. The vehicle
height is adjusted to raised level.
The Vehicle rising message appears in
the multifunction display.
The "Raised level" setting is canceled if you:
R drive at speeds above approximately
75 mph (120 km/h)
R drive about 3 minutes at speeds above
50 mph (80 km/h) The "Raised level" remains active when you
are not driving within these speed ranges.
Setting the normal level
X
Start the engine.
If indicator lamp ; is lit:
X Press button :.
Indicator lamp ; goes out. The vehicle is
adjusted to normal level.
Suspension tuning General notes
The Adaptive Damping System (ADS)
automatically controls the calibration of the
dampers and springs.
The damping is tuned individually to each
wheel and depends on:
R
your driving style, e.g. sporty
R the road surface condition, e.g. bumps
R your individual selection, i.e. sports or
comfort
Your selection remains stored even if you
remove the SmartKey from the ignition lock. Sports tuning
The firmer suspension tuning in Sport mode
ensures even better contact with the road.
Select this mode when employing a sporty
driving style, e.g. on winding country roads.
X
If indicator lamp ; is not lit: press
button :.
Indicator lamp ; lights up. Sports
suspension tuning is selected. 344
Driving systemsDriving and parking

The AIRMATIC SPORT message appears in
the multifunction display.
Comfort tuning
In Comfort mode, the driving characteristics
of your vehicle are more comfortable. Select
this mode if you prefer a more comfortable
driving style, but also when driving fast on
straight roads, e.g. highways.
X If indicator lamp ; is lit: press
button :.
Indicator
lamp ; goes out. Comfort tuning
is selected.
The AIRMATIC COMFORT message appears
in the multifunction display. Active Body Control (ABC)
Vehicle level Your vehicle automatically adjusts its ride
height to improve driving safety and reduce
fuel consumption.
Depending on the vehicle height that has
been

set, the vehicle automatically adjusts its
height dependent on the current speed. As
speed increases, the vehicle is lowered by up
to 0.6 in (15 mm). As the speed is reduced,
the vehicle is raised up to the set vehicle
height. G
WARNING
The vehicle is lowered when the engine is
switched off. Therefore, make sure that
nobody

is in the vicinity of the wheel housing
or under the vehicle when you switch off the
engine. Otherwise, limbs could become
trapped.
! The vehicle is lowered when the engine is
switched off. Make sure when parking that
you position your vehicle so that it does not
make contact with the curb as the vehicle
is lowered. Your vehicle could otherwise be
damaged. i
For AMG vehicles: when the engine is
switched off, the vehicle is lowered by
approx. 0.4 in (10 mm).
Setting the vehicle level
Select the "Normal" setting for normal road
surfaces and "Raised" for driving with snow
chains or on particularly poor road surfaces. G
WARNING
To help avoid personal injury, keep hands and
feet away from wheel housing area, and stay
away from under the vehicle when lowering
the vehicle chassis.
Your selection remains stored even if you
remove the SmartKey from the ignition lock. Setting raised level
X
Start the engine.
If indicator lamp ; is not lit:
X Press button :.
Indicator lamp ; lights up. The vehicle
height is adjusted to raised level.
Setting the normal level
X Start the engine.
If indicator lamp ; is lit:
X Press button :.
Indicator lamp ; goes out. The vehicle is
adjusted to normal level. Driving systems
345
Driving and parking Z

Suspension tuning
The electronically controlled ABC suspension
system works continuously. This improves
driving safety and comfort.
The ABC suspension system is tuned
individually to each wheel and depends on:
R
your driving style, e.g. sporty
R the road surface condition, e.g. bumps
R your individual selection, i.e. sports or
comfort
R the vehicle load
Your selection remains stored even if you
remove the SmartKey from the ignition lock. Sports tuning
The firmer suspension tuning in Sport mode
ensures even better contact with the road.
Select this mode if you prefer a firmer
suspension tuning.
X
If indicator lamp ; is not lit: press
button :.
Indicator lamp ; lights up. You have
selected
the suspension for a sporty driving
style.
The ABC Active Body Control SPORT
message appears in the multifunction
display.
Comfort tuning
In Comfort mode, the driving characteristics
of your vehicle are more comfortable. Select
this mode if you prefer a more comfortable
driving style. X
If indicator lamp ; is lit: press
button :.
Indicator lamp ; goes out. You have
selected the suspension for a comfortable
driving style.
The ABC Active Body Control
COMFORT message appears in the
multifunction display. 4MATIC (permanent four-wheel drive)
4MATIC ensures that all four wheels are
permanently driven. Together with ESP ®
, it
improves the traction of your vehicle
whenever a drive wheel spins due to
insufficient grip. G
WARNING
If a drive wheel is spinning due to insufficient
traction:
R While driving off, apply as little throttle as
possible.
R While driving, ease up on the accelerator
pedal.
R Adapt your speed and driving style to the
prevailing road conditions.
Failure to observe these guidelines could
cause the vehicle to skid.
The 4MATIC cannot prevent accidents
resulting from excessive speed.
! Never tow the vehicle with one axle
raised.

This may damage the transfer case.
Damage of this sort is not covered by the
Mercedes-Benz Limited Warranty. All
wheels must remain either on the ground
or be fully raised. Observe the instructions
for towing the vehicle with all wheels in full
contact with the ground.
i In wintry driving conditions, the maximum
effect of 4MATIC can only be achieved if
you use winter tires (M+S tires), with snow
chains if necessary. 346
Driving systems
Driving and parking