2013 MERCEDES-BENZ S-CLASS SEDAN warning

Switching the rear-compartment
climate control on/off using the rear
control panel
X
Turn the SmartKey to position 2 in the
ignition lock.
X To switch on: press rocker switch
K(Y page 291) up or down and select
AUTO.
or
X Press rocker switch K(Y page 291) up or
down and select MAN.
X To switch off: press rocker switch
K(Y page 291) up or down and select
OFF. Activating/deactivating cooling with
the air dehumidification function
Important information The cooling with air dehumidification function
is only available when the engine is running.
The air inside the vehicle is cooled and
dehumidified according to the temperature
selected.
G
WARNING
If you switch off the cooling function, the
vehicle will not be cooled when weather
conditions
are warm. The windows can fog up
more quickly. Window fogging may impair
visibility and endanger you and others.
Condensation may drip from the underside of
the vehicle when it is in cooling mode. This is
normal and not a sign that there is a
malfunction.
You can activate or deactivate the cooling
with air dehumidification function via
COMAND (Y page 267).
i The cooling with air dehumidification
function uses refrigerant R134a. This
coolant does not contain
chlorofluorocarbons, and therefore does
not damage the ozone layer. Problems with the cooling with air
dehumidification function If you can no longer switch on the cooling with
air dehumidification function via COMAND,
the

cooling with air dehumidification function
is switched off due to a malfunction.
X Consult a qualified specialist workshop. Setting climate control to automatic
G
WARNING
If you switch off the cooling function, the
vehicle will not be cooled when weather
conditions

are warm. The windows can fog up
more quickly. Window fogging may impair
visibility and endanger you and others.
In automatic mode, the set temperature is
maintained automatically at a constant level.
The system automatically regulates the
temperature of the dispensed air, the airflow
and the air distribution.
Automatic mode will achieve optimal
operation if cooling with air dehumidification
is also activated. If desired, cooling with air
dehumidification can be deactivated.
Controlling the front climate control
using the front control panel X
Turn the SmartKey to position 2 in the
ignition lock.
X Set the desired temperature.
X To switch on: press the à rocker
switch up or down.
The indicator lamp in the à rocker
switch lights up. Operating the climate control system
293
Climate control Z

Windows fogged up on the outside
X
Switch on the windshield wipers.
X Activate automatic climate control.
i You should only select this setting until
the windshield is clear again. Rear window defroster
Activating/deactivating G
WARNING
Any accumulation of snow and ice should be
removed from the rear window before driving.
Visibility could otherwise be impaired,
endangering you and others.
The rear window defroster has a high current
draw. You should therefore switch it off as
soon as the window is clear as it only switches
off automatically after several minutes.
If the battery voltage is too low, the rear
window defroster may switch off.
X Turn the SmartKey to position 2 in the
ignition lock.
X Press the ¤ rocker switch up or down.
The indicator lamp in the ¤ rocker
switch lights up or goes out.
Problems with the rear window
defroster The rear window defroster has deactivated
itself prematurely or cannot be activated.
X
Switch off any consumers that are not
required, e.g. reading lamps or interior
lighting.
When the battery is sufficiently charged,
the rear window defroster is activated
again automatically. Activating/deactivating air-
recirculation mode
You can deactivate the flow of fresh air if
unpleasant odors are entering the vehicle from outside. The air already inside the
vehicle will then be recirculated. G
WARNING
Fogged windows impair visibility,
endangering you and others. If the windows
begin to fog on the inside, switching off the
air recirculation mode immediately should
clear interior window fogging. If interior
window fogging persists, make sure the air
conditioning is activated, or press the ¬
button.
X Turn the SmartKey to position 2 in the
ignition lock.
X To activate: press the g rocker switch
up or down.
The indicator lamp in the g rocker
switch lights up.
i Air-recirculation mode is activated
automatically at high outside
temperatures. The indicator lamp in the
g rocker switch is not lit when
automatic air-recirculation mode is
activated.
Outside air is added after about 30
minutes.
X To deactivate: press the g rocker
switch up or down.
The indicator lamp in the g rocker
switch goes out.
i Air-recirculation mode deactivates
automatically:
R after approximately five minutes if
outside

temperatures are less than about
41 ‡ (5 †)
R after approximately five minutes if
cooling with air dehumidification is
deactivated
R after approximately 30 minutes if outside
temperatures are over about
41 ‡ (5 †) Operating the climate control system
297
Climate control Z

Activating/deactivating the residual
heat function
It
is possible to make use of the residual heat
of the engine to continue heating the
stationary vehicle for up to 30 minutes after
the engine has been switched off. The heating
time depends on the temperature that has
been set.
i The blower will run at a low speed
regardless of the airflow setting.
i If you activate the residual heat function
at high temperatures, only the ventilation
will be activated. The blower runs at
medium speed.
X Turn the SmartKey to position 0 in the
ignition lock or remove it.
X To activate: press the Ì rocker switch
up or down.
The indicator lamp in the Ì rocker
switch lights up.
X To deactivate: press the Ì rocker
switch up or down.
The indicator lamp in the Ì rocker
switch goes out.
i Residual heat is deactivated
automatically:
R after about 30 minutes
R when the ignition is switched on
R if the battery voltage drops
R if the coolant temperature is too low Setting the air vents
Important safety notes
G
WARNING
When operating the climate control, the air
that enters the passenger compartment
through the air vents can be very hot or very
cold

(depending on the set temperature). This
could cause burns or frostbite to unprotected
skin in the immediate area of the air vents. Always keep sufficient distance between
unprotected parts of the body and the air
vents. If necessary, use the air distribution
adjustment

to direct the air to air vents in the
vehicle interior that are not in the immediate
area of unprotected skin.
In order to ensure the direct flow of fresh air
through the air vents into the vehicle interior,
please observe the following notes:
R keep the air intake grille on the hood free
of blockages, such as ice, snow or leaves
R never cover the air vents or air intake grille
in the vehicle interior.
i For virtually draft-free ventilation, adjust
the sliders of the air vents to the center
position. Setting the center air vents
:
Fixed center air vent
; Center air vent, right
= Center vent thumbwheel, right
? Center vent thumbwheel, left
A Center air vent, left
X To open/close: turn thumbwheels =
and ? up or down. 298
Setting the air vents
Climate control

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible.
Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Please read the information on qualified
specialist workshops (Y page 31). Breaking-in notes
The first 1000 miles (1500 km)
The
more you look after the engine when it is
new, the more satisfied you will be with its
performance in the future.
R Drive at varying vehicle speeds and engine
speeds for the first 1000 miles (1500 km)
for this reason.
R Avoid overstraining the vehicle during this
period, e.g. driving at full throttle.
R Change gear in good time, at the latest
when the tachometer needle is 2
/ 3 of the
way to the red area in the tachometer
display.
R Do not manually shift to a lower gear to
brake the vehicle.
R If possible, do not depress the accelerator
pedal past the point of resistance
(kickdown).
R Only select shift ranges 3, 2 or 1 when
driving slowly, e.g. in mountainous terrain.
R If possible, drive in drive program E (in AMG
vehicles in drive program C) for the first
1000 miles (1500 km).
After 1000 miles (1500 km), you can increase
the engine speed gradually and bring the
vehicle up to full speed. Additional breaking-in notes for AMG
vehicles:
R
do not drive faster than 85 mph
(140 km/h) in the first 1000 miles
(1500 km).
R only allow the engine to reach a maximum
engine speed of 4500 rpm briefly.
R change gear in good time.
i You should also observe these notes on
running

in if the engine or parts of the drive
train on your vehicle have been replaced.
i Always observe the respective speed
restrictions. Driving
Important safety notes
G
WARNING
Make sure absolutely no objects are
obstructing the pedals' range of movement.
Keep the driver's footwell clear of all
obstacles. If there are any floormats or
carpets

in the footwell, make sure the pedals
still have sufficient clearance.
During sudden driving or braking maneuvers
the objects could get caught between the
pedals. You could then no longer brake or
accelerate. This could lead to accidents and
injury. G
WARNING
On slippery road surfaces, never downshift in
order to obtain braking action. This could
result

in drive wheel slip and reduced vehicle
control. Your vehicle's ABS will not prevent
this type of loss of control. G
WARNING
It is dangerous to shift the automatic
transmission out of parking position P or
neutral position N if the engine speed is
higher

than idle speed. If your foot is not firmly
on the brake pedal, the vehicle could
accelerate quickly forward or in reverse. You 302
Driving
Driving and parking

could lose control of the vehicle and hit
someone or something. Only shift into gear
when the engine is idling normally and when
your right foot is firmly on the brake pedal.
G
WARNING
HYBRID vehicles: It is imperative that you read
the HYBRID Supplemental Operating
Instructions
included in your vehicle literature
portfolio. You may otherwise not receive all
necessary safety information and warning for
the operation of your vehicle.
! Warm up the engine quickly. Do not use
the engine's full performance until it has
reached operating temperature.
Only shift the automatic transmission to
the desired drive position when the vehicle
is stationary.
Where possible, avoid spinning the drive
wheels when pulling away on slippery
roads. You could otherwise damage the
drive train.
! S 63 AMG: at low engine oil temperatures
below 68 ‡ (+20 †), the maximum engine
speed is restricted in order to protect the
engine. To protect the engine and maintain
smooth engine operation, avoid driving at
full throttle when the engine is cold. SmartKey positions
SmartKey g
To remove the SmartKey
1 Power supply for some consumers, such
as the windshield wipers
2 Ignition (power supply for all consumers)
and drive position
3 To start the engine
i The SmartKey can be turned in the
ignition lock even if it is not the correct
SmartKey

for the vehicle. The ignition is not
switched on. The engine cannot be started.
KEYLESS-GO General information
Vehicles

with KEYLESS-GO are equipped with
a SmartKey featuring an integrated KEYLESS-
GO function and a detachable Start/Stop
button.
The Start/Stop button must be inserted into
the ignition lock and the SmartKey must be in
the vehicle.
Pressing the Start/Stop button several times
in succession corresponds to the different
SmartKey positions in the ignition lock. This
is only the case if you are not depressing the
brake pedal.
If you depress the brake pedal and press the
Start/Stop button, the engine starts
immediately.
The Start/Stop button can be removed from
the ignition lock. Then, you can insert the
SmartKey into the ignition lock. Driving
303
Driving and parking Z

i
You do not have to remove the Start/Stop
button from the ignition lock when you
leave the vehicle. However, you should
always take the SmartKey with you when
leaving the vehicle. The vehicle can be
started with the Start/Stop button and the
electrical equipment can be operated while
the SmartKey is in the vehicle. :
Start/Stop button
; Ignition lock
X Insert Start/Stop button : into ignition
lock ;.
i When you insert Start/Stop button :
into

ignition lock ;, the system requires a
detection time of approximately two
seconds before you can use Start/Stop
button :. Start/Stop button
=
USA only
? Canada only X
Position 0:
if Start/Stop button : has not
yet been pressed, this corresponds to the
SmartKey being removed from the ignition.
X Position 1: press Start/Stop button :.
You can now activate the windshield
wipers, for example.
i If
you then open the driver's door when in
this position, the power supply is
deactivated.
X Position 2 (ignition): press Start/Stop
button : twice.
i If you press Start/Stop button : once
when in this position and the driver's door
is open, the power supply is deactivated
again.
As

soon as the ignition is switched on, all the
indicator lamps in the instrument cluster light
up. If an indicator lamp does not go out after
the engine is started or if it lights up while the
vehicle is in motion, see ( Y page 422). Starting the engine
Important safety notes G
WARNING
Inhalation of exhaust gas is hazardous to your
health. All exhaust gas contains carbon
monoxide (CO), and inhaling it can cause
unconsciousness and possible death.
Do

not run the engine in confined areas (such
as a garage) which are not properly ventilated.
If you think that exhaust gas fumes are
entering the vehicle while driving, have the
cause determined and corrected
immediately. If you must drive under these
conditions, drive only with at least one
window fully open at all times.
! Do not depress the accelerator pedal
when starting the engine.
i Vehicles with a gasoline engine: the
catalytic converter is preheated for up to 304
Driving
Driving and parking

30 seconds after a cold start. The sound of
the engine may change during this time.
Automatic transmission X
Shift the transmission to position P.
The transmission position display in the
multifunction display shows P.
i You can also start the engine when the
transmission is in position N.
Starting procedure with the SmartKey i
To start the engine using the SmartKey
instead of KEYLESS-GO, pull the Start/
Stop button out of the ignition lock.
X To start a gasoline engine: turn the
SmartKey to position 3 in the ignition lock
(Y page 303) and release it as soon as the
engine is running.
X To start a diesel engine: turn the
SmartKey to position 2 in the ignition lock
(Y page 303).
The % preglow indicator lamp in the
instrument cluster lights up.
X When the % preglow indicator lamp
goes out, turn the SmartKey to position 3
(Y page 303) and release it as soon as the
engine is running.
i You can start the engine without preglow
if the engine is warm.
Using KEYLESS-GO to start the engine G
WARNING
As long as the SmartKey is in your vehicle, the
vehicle
can be started. Therefore, never leave
children unattended in the vehicle, as they
could otherwise accidentally start the engine.
When leaving the vehicle, always take the
SmartKey with you and lock the vehicle. Do
not leave children unattended in the vehicle,
or with access to an unlocked vehicle. A
child's unsupervised access to a vehicle could
result in an accident and/or serious personal
injury. i
The Start/Stop button can be used to
start

the vehicle manually without inserting
the SmartKey into the ignition lock. The
Start/Stop button must be inserted into
the ignition lock and the SmartKey must be
in the vehicle. This mode for starting the
engine operates independently of the ECO
start/stop automatic engine start function.
X Depress the brake pedal and keep it
depressed.
X To start a gasoline engine: press the
Start/Stop button
(Y page 303) once.
The engine starts.
X To start a diesel engine:
press the Start/
Stop button (Y page 303) once.
Preglow is activated and the engine starts.
i If
the engine is warm, the preglow time is
shortened. Pulling away
Automatic transmission G
WARNING
It is dangerous to shift the automatic
transmission out of parking position P or
neutral position N if the engine speed is
higher

than idle speed. If your foot is not firmly
on the brake pedal, the vehicle could
accelerate quickly forward or in reverse. You
could lose control of the vehicle and hit
someone or something. Only shift into gear
when the engine is idling normally and when
your right foot is firmly on the brake pedal.
i It is only possible to shift the transmission
from position P to the desired position if
you depress the brake pedal. Only then is
the parking lock released. If you do not
depress the brake pedal, you can move the
DIRECT SELECT lever but the parking lock
remains engaged.
X Depress the brake pedal and keep it
depressed.
X Shift the transmission to position D or R. Driving
305
Driving and parking Z

X
Release the brake pedal.
X Carefully depress the accelerator pedal.
The electric parking brake (Y page 324) is
automatically released.
The red F (USA only) or ! (Canada
only) indicator lamp in the instrument
cluster goes out.
i The vehicle locks centrally once you have
pulled away. The locking knobs in the doors
drop down.
You can open the doors from the inside at
any time.
You can also deactivate the automatic
locking feature (Y page 264).
i Upshifts take place at higher engine
speeds after a cold start. This helps the
catalytic converter to reach its operating
temperature more quickly.
Hill start assist Hill start assist helps you when pulling away
forwards or in reverse on an uphill gradient.
It holds the vehicle for a short time after you
have

removed your foot from the brake pedal.
This gives you enough time to move your foot
from the brake pedal to the accelerator pedal
and depress it before the vehicle begins to
roll. G
WARNING
Never leave the vehicle when it is held by hill
start assist. After approximately one second,
hill start assist will no longer brake your
vehicle and it could roll away.
X Take your foot off the brake pedal.
i Once you have taken your foot off the
brake pedal, the vehicle is held for around
one second.
X Pull away.
Hill start assist will not function if:
R you are pulling away on a level road or a
downhill gradient.
R the transmission is in position N. R
the electric parking brake is applied.
R ESP ®
is malfunctioning. ECO start/stop function
General information The ECO start/stop function is only available
for the S 63 AMG.
The

ECO start/stop function is only available
in drive program C.
The ECO start/stop function switches the
engine off automatically when the vehicle
stops moving.
The engine starts automatically when the
driver wants to pull away again. The ECO
start/stop function thereby helps you to
reduce the fuel consumption and emissions
of your vehicle.
The ECO start/stop function is activated each
time the engine is switched on. If all the
requirements are fulfilled for automatic
engine switch-off ( Y page 307), the green
¤ ECO symbol is shown in the
multifunction display and Stop/Start
active appears. If not all of the requirements
are fulfilled, the ¤ ECO symbol is shown
in yellow and Stop/Start inactive
appears.
If the ECO start/stop function is deactivated
(Y page 307), the ¤ symbol is not shown. G
WARNING
If the engine is switched off and the ECO
symbol
is shown in green in the multifunction
display, the engine has been switched off
automatically. All of the vehicle's systems
remain active. If you open the door, unfasten
your seat belt or remove your foot from the
brake pedal, the engine will automatically
start. The vehicle may begin moving. You
could suffer serious or even fatal injury or
cause an accident resulting in injury or death.
Never leave the vehicle while the ECO symbol
in the multifunction display is shown in green 306
Driving
Driving and parking