2013 MERCEDES-BENZ S-CLASS SEDAN warning

These optional extras, such as high-
performance
brakes, level control, a roof rack
or a high-performance battery, are not
included in the curb weight and accessory
weight. TIN (Tire Identification Number)
This is a unique identifier which can be used
by a tire manufacturer to identify tires, for
example

for a product recall, and thus identify
the purchasers. The TIN is made up of the
manufacturer's identity code, tire size, tire
type code and the manufacturing date. Load bearing index
The load bearing index (also load index) is a
code

that contains the maximum load bearing
capacity of a tire. Traction
Traction is the result of friction between the
tires and the road surface. Treadwear indicators
Narrow bars (tread wear bars) that are
distributed

over the tire tread. If the tire tread
is level with the bars, the wear limit of 1
/ 16 in
(1.6 mm) has been reached. Occupant distribution
The distribution of occupants in a vehicle at
their designated seating positions. Total load limit
Rated cargo and luggage load plus
68 kilograms (150 lbs) times the vehicle's
designated seating capacity. Changing a wheel
Flat tire
The "Breakdown assistance" section
(Y

page 473) contains information and notes
on how to deal with a flat tire. It also provides
instructions on changing a wheel or mounting
the spare wheel/emergency spare wheel. Interchanging the wheels
G
WARNING
Rotate front and rear wheels only if the tires
are of the same dimension.
If your vehicle is equipped with mixed-size
tires

(different tire dimensions front vs. rear),
tire rotation is not possible. G
WARNING
Have the tightening torque checked after
changing a wheel. The wheels could come
loose if they are not tightened to a torque of
110 lb-ft

(150 Nm).
Only use genuine Mercedes-Benz wheel bolts
specified for your vehicle's rims.
The wear patterns on the front and rear tires
differ, depending on the operating conditions.
Rotate the wheels before a clear wear pattern
has formed on the tires. Front tires typically
wear more on the shoulders and the rear tires
in the center.
If your vehicle's tire configuration allows, you
can rotate the wheels according to the
intervals in the tire manufacturer's warranty
book in your vehicle documents. If this is not
available, the tires should then be replaced
every 3000 to 6000 miles
(5000 to 10,000 km), or earlier if the tire wear
requires this. Do not change the direction of
wheel rotation.
Clean the contact surfaces of the wheel and
the brake disc thoroughly every time a wheel
is interchanged. Check the tire pressures.
Information on changing a wheel and
mounting the spare wheel ( Y page 473). Changing a wheel
513
Wheels and tires Z

!
On vehicles equipped with a tire pressure
monitor, electronic components are
located in the wheel.
Tire-mounting tools should not be used
near the valve. This could damage the
electronic components.
Always have the tires changed at a qualified
specialist workshop, e.g. an authorized
Mercedes-Benz Center. Direction of rotation
Tires with a specified direction of rotation
have

additional benefits, e.g. if there is a risk
of hydroplaning. You will only gain these
benefits if the correct direction of rotation is
maintained.
An arrow on the sidewall of the tire indicates
its correct direction of rotation.
You may mount a spare wheel/emergency
spare wheel against the direction of rotation.
Observe the time restriction on use as well as
the speed limit specified on the spare wheel/
emergency spare wheel. Storing wheels
Store
wheels that are not being used in a cool,
dry and preferably dark place. Protect the
tires from oil, grease, gasoline and diesel. Cleaning the wheels
G
WARNING
Do not use power washers with circular-jet
nozzles
(dirt grinders) to clean your vehicle, in
particular the tires. You could otherwise
damage the tires and cause an accident. Wheel and tire combinations
Please bear the following in mind
! For safety reasons, Mercedes-Benz
recommends that you only use Tires and wheels which have been approved by
Mercedes-Benz specifically for your
vehicle.
These

tires have been specially adapted for
use with the control systems, such as ABS
or ESP ®
, and are marked as follows:
R MO = Mercedes-Benz Original
R MOE = Mercedes-Benz Original Extended
(tires featuring run-flat characteristics)
R MO1 = Mercedes-Benz Original (only
certain AMG tires)
Mercedes-Benz Original Extended tires
may only be used on wheels that have been
specifically approved by Mercedes-Benz.
Only use tires, wheels or accessories
tested and approved by Mercedes-Benz.
Certain characteristics, e.g. handling,
vehicle noise emissions or fuel
consumption, may otherwise be adversely
affected. In addition, when driving with a
load, tire dimension variations could cause
the tires to come into contact with the
bodywork and axle components. This could
result in damage to the tires or the vehicle.
Mercedes-Benz accepts no liability for
damage resulting from the use of tires,
wheels or accessories other than those
tested and approved.
Further information about tires, wheels and
approved combinations can be obtained
from any authorized Mercedes-Benz
Center.
i The Tire and Load Information placard
with the recommended tire pressures is
attached to the B-pillar on the driver's side.
Further information about driving at high
speeds or driving with vehicle loads that are
lighter than the maximum vehicle load can
be found in the tire pressure table on the
inside of the fuel filler flap. Check tire
pressures regularly, and only when the tires
are cold. Comply with the maintenance
recommendations of the tire manufacturer
in the vehicle document wallet. 514
Wheel and tire combinations
Wheels and tires

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible.
Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Please read the information on qualified
specialist workshops (Y page 31). Notes on technical data
i The

data stated here specifically refers to
a vehicle with standard equipment. Consult
an authorized Mercedes-Benz Center for
the data for all vehicle variants and trim
levels. Genuine Mercedes-Benz parts
All
Mercedes-Benz Centers maintain a supply
of genuine Mercedes-Benz parts for
necessary service and repair work. In
addition, strategically located parts delivery
centers provide for quick and reliable parts
service.
There are more than 300,000 different
genuine Mercedes-Benz parts available for
Mercedes-Benz models.
Genuine Mercedes-Benz parts are subject to
strict quality control. Each part has been
specially developed, manufactured or
selected for Mercedes-Benz vehicles and
fine-tuned for them.
Therefore, only genuine Mercedes-Benz parts
should be used. G
WARNING
Driving safety may be impaired if non-
approved parts, tires and wheels or safety-
relevant accessories are used.
This could lead to malfunctions in safety-
relevant

systems, e.g. the brake system. This
could cause you to lose control of your vehicle
and cause an accident.
For this reason, Mercedes-Benz recommends
that you use genuine Mercedes-Benz parts or
parts of equal quality. Only use tires, wheels
and accessories that have been specifically
approved for your vehicle.
! Air bags and Emergency Tensioning
Devices, as well as control units and
sensors for these restraint systems may be
installed in the following areas of your
vehicle:
R doors
R door pillars
R door sills
R seats
R dashboard
R instrument cluster
R center console
Do not install accessories such as audio
systems in these areas. Do not carry out
repairs or welding. You could impair the
operating efficiency of the restraint
systems.
Have aftermarket accessories installed at
a qualified specialist workshop. Mercedes-
Benz recommends that you use an
authorized Mercedes-Benz Center for this
purpose. H
Environmental note
Daimler AG also supplies reconditioned major
assemblies and parts which are of the same
quality

as new parts. They are covered by the
same Limited Warranty entitlements as new
parts.
Always specify the vehicle identification
number (VIN) ( Y page 521) and the engine520
Genuine Mercedes-Benz parts
Technical data

i
The data shown on the identification plate
is example data. This data is different for
every vehicle and can deviate from the data
shown here. You can find the data
applicable to your vehicle on the vehicle's
identification plate. Vehicle identification number (VIN)
The vehicle identification number (VIN) can
be found in the following locations:
R on the vehicle identification plate
(Y page 521)
R at the lower edge of the windshield
(Y page 522)
In addition to being stamped on the vehicle
identification plate, the vehicle identification
number

(VIN) is also stamped onto the vehicle
body. It is under the trim behind the rear seat
armrest. X
Fold down the rear seat armrest.
X Open the trim.
You will see vehicle identification number
(VIN) :. Engine number
:
Emission control information plate,
including the certification of both federal
and Californian emissions standards
; Engine number (stamped into the
crankcase)
= VIN (on the lower edge of the windshield) Service products and capacities
Important safety notes
Service products include the following:
R fuels (e.g. gasoline, diesel)
R additives for exhaust gas aftertreatment
(DEF)
R lubricants

(e.g. engine oil, transmission oil)
R coolant
R brake fluid
R windshield washer fluid
Vehicle components and their respective
lubricants must match. You should therefore
only use products that have been tested and
approved by Mercedes-Benz.
Information on tested and approved products
can be obtained at a Mercedes-Benz Center
or on the Internet at http://
www.mbusa.com (USA only). G
WARNING
Comply with all valid regulations with respect
to handling, storing and disposing of service
fluids. Otherwise, you could endanger
persons or the environment. 522
Service products and capacities
Technical data

Model Capacity Fuel, coolant,
lubricants, etc.
DEF tank
S 350 BlueTEC
4MATIC 6.6 US gal (25.0 l) DEF in accordance
with ISO 22241
Windshield/
headlamp
cleaning
system
All models 6.9 US qt (6.5 l) MB windshield
washer
concentrate
35
(Y page 529)
Mixing ratio for
washer fluid
(Y page 529) Fuel
Important safety notes G
WARNING
Gasoline and diesel fuels are highly flammable
and poisonous. They burn violently and can
cause serious injury.
Never allow sparks, flames or smoking
materials near gasoline or diesel fuel!
Turn off the engine before refueling.
Whenever you are around gasoline or diesel
fuel, avoid inhaling fumes and any skin or
clothing contact. Extinguish all smoking
materials.
Direct skin contact with fuels and the
inhalation of fuel vapors are damaging your
health.
Premium-grade unleaded gasoline !
To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline may be used.
If there is no premium-grade unleaded
gasoline available and regular-grade
unleaded gasoline may be used; please
observe the following precautions:
R only fill the fuel tank to half full with
regular-grade unleaded gasoline and fill the rest with premium-grade unleaded
gasoline as soon as possible.
R do not drive at the maximum speed.
R avoid sudden acceleration.
R if
the vehicle is carrying a light load, e.g.
two passengers without luggage, do not
allow the engine to rev above
3,000 rpm.
R if the vehicle is fully loaded or is being
operated in mountainous terrain, do not
depress the accelerator pedal further
than Ô of the pedal travel.
Fuel requirements Gasoline engines
Use only premium-grade unleaded gasoline.
The octane number should be at least 91.
Details can be found on the gas pump. The
octane number is the average value of the
Research Octane Number (RON) and the
Motor Octane Number (MON): (RON +
MON) / 2, also known as knock resistance.
Reformulated Gasoline (RFG) and/or
unleaded

gasoline with additives can be used
if the concentration of the additives in the fuel
does not exceed 10%, e.g.:
R Ethanol
R TAME
R ETBE
35 Mixed with water or premixed washer fluid with antifreeze protection. Service products and capacities
525
Technical data Z

!
Do not refuel with low-grade fuel and do
not use fuel additives that are not tested
and approved for Mercedes-Benz vehicles.
Damage to or malfunctions of the fuel
system may otherwise occur. DEF
Important safety notes i
For BlueTEC vehicles only.
DEF
is a non-flammable, non-toxic, colorless,
odorless and water-soluble fluid.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF
residues crystallize after time and
contaminate the affected surfaces.
High outside temperatures If DEF heats up to over 122 ‡ (50 †) for
extended periods, e.g. as a result of direct
sunlight on the DEF reservoir, DEF can
decompose. Ammonia vapors develop as a
result.
G
WARNING
When opening the filler cap of the DEF tank
ammonia gas vapors may escape. Refill DEF
in a well ventilated area only. Ammonia gas
vapors have a pungent odor and are
particularly irritating for your skin, mucous
membranes,

and eyes. Inhaling ammonia gas
vapors will cause burning eyes, nose, and
throat, as well as coughing and watering eyes.
Low outside temperatures DEF freezes at a temperature of
approximately 12 ‡ (–11 †). The vehicle is
equipped

with a DEF preheating system when
it leaves the factory. Winter operation is
therefore also guaranteed at temperatures
below 12 ‡ (–11 †). Additives !
Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity Assuring the purity of DEF is particularly
important with respect to avoiding
malfunctions in the exhaust gas
aftertreatment system.
If DEF is pumped out of the DEF tank, e.g.
during

repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
! Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC exhaust gas
aftertreatment system Engine oil
Please bear the following in mind The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For

a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz Center
or go to the Internet site
http://www.mbusa.com (USA only).
! Never use engine oil or an oil filter of a
specification other than is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement Service products and capacities
527Technical data Z

intervals than those prescribed. You could
otherwise
cause engine damage or damage
to the exhaust gas aftertreatment.
Follow the instructions in the service
interval display regarding the oil change.
Otherwise, you may damage the engine and
the exhaust gas aftertreatment.
The table shows which engine oils have been
approved for your vehicle. Model Engine
model MB
Approval
S 550
36
S 550 4MATIC 36 278 229.5
S 600
275
S 63 AMG
157
229.5
37 S 65 AMG
275
S 350 BlueTEC
4MATIC
642 228.51,
229.31,
229.51
i
MB approval is indicated on the oil
containers.
Additives !
Do
not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity Viscosity describes the flow characteristics
of

a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE (viscosity)
classification suitable for the prevailing
outside temperatures. The following table
shows the correct SAE classification to be
used. The low-temperature characteristics of
engine oils can deteriorate significantly, e.g.
as a result of aging, soot and fuel deposits. It is therefore strongly recommended that you
carry out regular oil changes using an
approved

engine oil with the appropriate SAE
classification. Refrigerant of the air-conditioning
system
The air-conditioning system is filled with
R134a refrigerant and a special PAG
lubricant.
! Never use refrigerant R 12 (CFC) or
mineral lubricants. Otherwise, you could
damage the air-conditioning system. Brake fluid
G
WARNING
Over a period of time, the brake fluid absorbs
moisture from the air; this lowers its boiling
point.
If

the boiling point of the brake fluid is too low,
vapor pockets may form in the brake system
when the brakes are applied hard (e.g. when
driving downhill). This would impair braking
efficiency.
You should have the brake fluid renewed at
regular intervals. The brake fluid change
intervals can be found in the Service Booklet.
Only use brake fluid approved by Mercedes-
Benz. Information about approved brake
36 BlueEFFICIENCY
37 Restriction: only SAE 0W-40

or SAE 5W-40 engine oils may be used.528
Service products and capacities
Technical data

fluids can be obtained from any authorized
Mercedes-Benz Center or on the Internet at
http://bevo.mercedes-benz.com
.Coolant
Important safety notes The coolant is a mixture of water and
antifreeze/corrosion inhibitor. It performs
the following tasks:
R
corrosion protection
R antifreeze protection
R raising the boiling point
The engine cooling system is filled at the
factory with coolant that contains an
antifreeze/corrosion inhibitor that ensures
protection down to approximately -35 ‡
(-37 †).
! Only

add coolant that has been premixed
with the desired antifreeze protection.
Otherwise, the engine could be damaged.
Further information on coolants and on
filling can be found in the Mercedes-Benz
Specifications for Service Products, MB
Approval 310.1, e.g. on the Internet at
http://bevo.mercedes-benz.com. You can
also consult an authorized Mercedes-Benz
Center.
! Always use a suitable coolant mixture,
even in countries where high temperatures
prevail.
Otherwise, the engine cooling system is not
sufficiently protected from corrosion and
overheating.
If the coolant has antifreeze protection down
to -35 ‡ (-37 †), the boiling point of the
coolant under operating conditions is
approximately 266 ‡ (130 †).
Your vehicle has a range of aluminum
components. Aluminum components in the
engine make it necessary to use antifreeze/
corrosion inhibitor coolant that has been
specifically formulated to protect the
aluminum parts. Using other antifreeze/ corrosion inhibitors without these
characteristics affects the service life.
The

coolant must be used throughout the year
in order to maintain the necessary corrosion
protection and to provide protection from
overheating. In the Service Booklet, you can
find information on the intervals for renewal.
The renewal interval is determined by the
coolant type and the engine cooling system
design. The renewal interval in the Service
Booklet is only valid if the coolant is renewed
or filled up with Mercedes-Benz approved
products. Therefore, only use MB 325.0 or
326.0 anticorrosion/antifreeze or another
Mercedes-Benz approved product of the
same specification.
Information on other products with the same
specifications that are approved by
Mercedes-Benz can be obtained at an
authorized Mercedes-Benz Center or on the
Internet at http://bevo.mercedes-benz.com.
The coolant is checked at every maintenance
interval at an authorized Mercedes-Benz
Center.
The antifreeze/corrosion inhibitor
concentration in the engine cooling system
should:
R be at least 50%. This will protect the engine
cooling system against freezing down to
approximately -35 ‡ (-37 † ).
R not exceed 55% (antifreeze protection to
-49 ‡ [-45 † ]); otherwise, heat will not
dissipate as effectively.
If the coolant level is too low, MB 325.0 or
326.0 anticorrosion/antifreeze should be
added. Have the engine cooling system
checked for possible leaks. Windshield/headlamp cleaning
system
G
WARNING
Washer solvent/antifreeze is highly
flammable. Do not spill washer solvent/
antifreeze

on hot engine parts, because it may Service products and capacities
529
Technical data
Z