2013 MERCEDES-BENZ S-Class fuel cap

Important safety information
...........75
Warning lamp ................................. 430
ETS/4ETS (Electronic Traction
System) ................................................ 76
Exhaus tcheck ................................... 331
Exhaus ttail pipe (cleaning
instructions) ...................................... 474
Exterior lighting see Exterior lighting
Exterior mirror parking position
Adjusting (COMAND) .....................266
Exterior mirrors
Adjusting ....................................... 116
Dipping (automatic) .......................117
Folding in/ou t(automatically) .......116
Folding in/ou t(electrically) ...........116
Out of position (troubleshooting) ...116
Storing settings (memory
function) ........................................ 118
Storing the parking position ..........117
Eyeglasses compartment .................439 F
Factory setting (reset function) .......154
Fader, setting .................................... 139
Fast forward Audio mode (CD, DVD, MP3) .........230
Rear Seat Entertainment System ...260
Video DVD ..................................... 247
Fast rewind
Audio mode (CD, DVD, MP3) .........230
Rear Seat Entertainment System ...260
Video DVD ..................................... 247
Favorites (COMAND) .........................124
Fille rcap
see Fuel filler flap
Filling capacities (Technical data) ...530
First-aid kit ......................................... 478
Flat tire Changing a wheel/mounting the
spare wheel ................................... 479
MOExtended run-fla tsystem ......... 483
Preparing the vehicle .....................479
Raising the vehicle .........................480
Floormat ............................................ .460
Freeway information .........................191Front fog lamps
................................. 282
Display message ............................ 406
Switching on/off ........................... 282
Front-passenger seat
Adjusting from the driver's seat ..... 109
Adjusting from the rear
compartment ................................. 109
Fron twindshield
see Windshield
Fuel
Additives ........................................ 532
Displaying the current
consumption .................................. 378
Displaying the range ......................378
Driving tips .................................... 330
Fuel gauge ....................................... 37
Grade (gasoline) ............................ 531
Important safety notes ..................531
Premium-grade unleaded gasoline .531
Problem (malfunction) ...................324
Quality (diesel )............................... 532
Refueling ........................................ 321
Tank content/reserve fuel .............531
Fuel filler flap, opening/closing ....... 322
Fuel filte r(display message) ............412
Fuel level Calling up the range (on-board
computer) ...................................... 378
Fuel tank
Capacity ........................................ 531
Problem (malfunction) ...................324
Function buttons (COMAND) ............123
Fuses Allocation chart ............................. 493
Before changing ............................. 493
Dashboard fuse box .......................493
Engine emergency stop .................495
Fuse box in the engine
compartment ................................. 494
Fuse box in the rear compartment .493
Important safety notes ..................492 G
Garage door opener Clearing the memory .....................459
Important safety notes ..................45612
Index

Switching between picture
formats (TV, video)
............................245
Switching between summer time
and standard time .............................148
Switching off the alarm (ATA) ............79
Switching the hands-free
microphone on/off ............................ 205
Switching wavebands (radio) ...........216
Syste msettings
Bluetooth ®
..................................... 151
Date ............................................... 148
Language ....................................... 153
Programmable button (COMAND) ..124
Text reader spee d.......................... 149
Time ............................................... 148
Time zone ...................................... 148
Voice Control System ....................149 T
Tachometer ........................................ 375
Tail lamps Display message ............................ 406
Tank
see Fuel tank
Tank content
Fuel gauge ....................................... 37
Technical data
Capacities ...................................... 530
Notes ............................................. 528
Tires/wheels ................................. 521
Vehicle data ................................... 537
TELEAID
Automatic retrieval of vehicle data
(service due date ).......................... 456
Call priority .................................... 453
Display message ............................ 399
Downloading destinations
(COMAND) ..................................... 453
Emergency call .............................. 450
Important safety notes ..................449
Locating astolen vehicl e............... 456
MB info call button ........................452
Remote vehicle locking ..................455
Roadside Assistance button ..........452
Search &Send ............................... 454
Self-test ......................................... 450System
.......................................... 450
Vehicle remote unlocking ..............455
Telephone
Accepting/ending acall................ 203
Accepting acall............................. 384
Adjusting the volume for calls .......138
Basi cmenu (Bluetooth ®
interface) ....................................... 202
Calling (outgoing call ).................... 204
Calling voicemai l............................ 205
Conference connection .................. 205
Connecting a mobile phone
(general information) .....................199
De-authorizing a mobile phone ......202
Ending an active call ......................205
Entering anumbe r......................... 204
External authorization
(Bluetooth ®
) ................................... 201
Function restrictions ......................198
General notes ................................ 197
Keypad .......................................... .124
Menu (on-board computer) ............384
Number from the phone book ....... .384
Operating options ..........................198
Overview of functions ....................205
Reception and transmission
volume ........................................... 203
Redialing ........................................ 385
Rejecting/ending acall................. 384
Rejecting acall.............................. 203
Rejecting or accepting a waiting
call ................................................. 205
Safety notes .................................. 197
Sending DTMF tones ..................... .207
Switching hands-free microphone
on/off ............................................ 205
Toggling ......................................... 205
Using the telephone ....................... 203
see Bluetooth ®
see Call lists
Telephone mode
Redialing ........................................ 204
Telephone module with
Bluetooth ®
SIM Access Profile
see separate installation instructions Index
23

pump nozzle, which could cause personal
injury. G
WARNING
Hybrid vehicles: be sure to read the "HYBRID"
supplement .Otherwise, you could fail to
recognize dangers. G
WARNING
Do not fill diesel tanks with gasoline .Do not
mix diesel fuel with gasoline. Otherwise the
fuel system and engine could be damaged. In
addition, the vehicle could catch fire.
! Do not use gasoline to refuel vehicles with
a diesel engine. Do not use diesel to refuel
vehicles with a gasoline engine. Even a
small quantity of the wrong fuel will
damage the fuel system and engine.
! Do not switch on the ignition if you
accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel lines.
Notify a qualified specialist workshop and
have the fuel tank and fuel lines drained
completely.
! Overfilling the fuel tank could damage the
fuel system.
! Take care not to spill any fuel on painted
surfaces. You could otherwise damage the
paintwork.
! Use a filter when refueling from a fuel can.
Otherwise, the fuel lines and/or injection
system could be blocked by particles from
the fuel can.
Further information on fuel and on fuel grades
can be found in the "Fuel" section
(Y page 531). Refueling
Fuel filler flap 0002
To open the fuel filler flap
0003 To insert the fuel filler cap
0026 Tire pressure table
0025 Fuel type
The fuel filler flap is unlocked or locked
automatically when you open or close the
vehicle with the SmartKey or with KEYLESS-
GO.
The position of the fuel filler cap 000Fis
displayed in the instrument cluster. The arrow
next to the filling pump indicates the side of
the vehicle.
Opening X
Switch off the engine.
X Remove the SmartKey from the ignition
lock.
X KEYLESS-GO: open the driver’s door.
This corresponds to SmartKey position 0:
"SmartKey removed".
The driver’s door can be closed again.
X Press the fuel filler flap in the direction of
arrow 0002.
The fuel filler flap opens slightly.
X Open the fuel filler flap fully.
X Turn the fuel filler flap counter-clockwise
and remove it.
X Insert the fuel filler cap into the holder
bracket on the inside of filler flap 0003.322
RefuelingDriving and parking

X
Completely insert the fille rneck of the fuel
pump nozzle into the tank and refuel.
X Only fill the tank until the pump nozzle
switches off.
i Do not add any more fuel after the pump
stops filling for the first time. Otherwise,
fuel may leak out.
Closing X
Replace the cap on the filler necka nd turn
clockwise until it engages audibly.
X Close the fuel fille rflap.
i If you drive with the fuel filler cap open,
the reserve fuel warning lamp flashes .In
addition, the 000ECheck Engine warning
lamp may light up. Amessage appears in
the multifunction display (Y page 411).
For further information on warning and
indicator lamps in the instrument cluster,
see (Y page 434).
i Close the fuel filler flap before locking the
vehicle. Otherwise, the locking pin of the
central locking prevents the fuel filler flap
from closing. Refueling
323Driving and parking Z

DEF (BlueTEC vehicles only)
Important notes on use To function properly, BlueTEC exhaus
tgas
aftertreatment must be operated with the
reducing agen tDEF. Adding DEF is one of the
tasks performed during maintenance. Under
normal operating conditions, a tank of DEF
lasts until the next service due date.
When the DEF level is too low, the CheckAdditive See Operator's Manual
message is shown in the multifunction
display.
When the DEF supply sinks to a minimum
level, the Remaining Starts: 16 message
is shown in the multifunctio ndisplay.
When the Remaining Starts: 16 message
is shown in the multifunction display, you can
start the engine 16 more times. If DEF is not
added, it will the nnot be possible to restart
the engine. Fill the DEFt ank with about1gal
(3.8l) of DEF or have the DEF tank refilled at
a qualified specialist workshop.
Use the special DE Frefill bottle when filling
between maintenance intervals. Contact an
authorized Mercedes-BenzC enter with any
questions or, if necessary, contact Roadside
Assistance (Y page 29).
If the outside temperature is lower than 12 ‡
(002711 †), damage may occur when adding
DEF. If DEF is frozen and there is an active
warning indicator, adding may not be
possible. Park the vehicle in a warmer place,
e.g. in a garage, until DEFh as become fluid
again .Itwill the nbe possible to add DEF
again. Alternatively, have the DEFt ank refilled
at a qualified specialist workshop.
Further informatio nabout BlueTEC exhaust
gas aftertreatment and DEFi s available at any
authorized Mercedes-Benz Center. Adding DEF G
WARNING
Make sure
R DEF does not come into contact with skin,
eyes, or clothing
R to keep DEF out of the reach of children
If you and/or others have come into contact
with DEF:
R If DEF has gotten into contact with eyes,
flush with plenty of water immediately and
seek medical help.
R Cleana ffected skin immediately with plenty
of water.
R If DEF was swallowed, rinse mouth
immediately with plenty of water and drink
plenty of water. Consult a physician. G
WARNING
If you open the DEF tank cap, small amounts
of ammonia vapo rmay be released. This
depends in particular upon the age of the DEF.
Ammonia vapors have a pungent odor and are
particularly irritating to:
R skin
R mucous membranes
R eyes
You may experience a burning sensation in
your eyes, nose and throat, as well as
coughing and watering of the eyes.
Do not inhale any ammonia vapors that may
be released. Fill the DE Ftank only in well-
ventilated areas.
! Only use DEF in accordance with
ISO 22241. Do not mix any additives with
DEF, and do no tdilute DE Fwith water .This
may destroy the BlueTEC exhaust gas
aftertreatment system.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF Refueling
325Driving and parking Z

residues crystallize after time and
contaminate the affected surfaces.
! DEF is not a fuel additive and must not be
added to the fuel tank. If DEF is added to
the fuel tank, this can lead to engine
damage.
! Only screw on the DEF refill bottle hand-
tight. It could otherwise be damaged.
The filler neck for DEF is located under the
"Minispare" emergency spare wheel in the
trunk floor.
X Switch off the ignition.
X Open the trunk.
X Lift the trunk floor up ( Ypage 442). X
Turn the "Minispare" emergency spare
wheel fastening in the direction of the
arrow and remove it.
X Remove the "Minispare" emergency spare
wheel. X
Turn DEF cap 0002counter-clockwise and
remove it. X
Turn DEF filler cap 0003counter-clockwise
and open it.
Filler cap 0003is secured with a plastic strap. X
Unscrew the covering cap from DEF refill
bottle 0026.
X Place DEF refill bottle 0026on the filler neck
as show nand screw on clockwise hand-
tight.
X Press DEF refill bottle 0026down.
The DEF tank is filled. This may take up to
one minute.
i To add between service intervals, fill the
DEF tank with approximately 1gal (3. 8l) of
DEF. 1 gal (3.8 l) of DEF is equivalent to
approximately 2DEF refill bottles. Then
have the DEF supply checked at a qualified
specialis tworkshop and completely refilled
if necessary.
X Release DEFr efill bottle0026.
Refilling stops when the DEFr efill bottle is
no longer pressed down. The DEFr efill
bottle can be removed when it has been
only partially emptied. 326
RefuelingDriving and parking

Display messages Possible causes/consequences and
0004 Solutions
0011
Engine Oil Level
Low Stop Vehicle
Turn Engine Off Vehicles without an oil dipstick
:the engine oil level is too low.
There is a risk of engine damage.
X Pull over and stop the vehicle safely and switch off the engine,
paying attention to road and traffic conditions.
X Apply the parking brake.
X Add engine oil (Y page 466) and check the oil level
(Y page 463). 0011
Engine Oil Level
Too High Vehicles without an oil dipstick: you have added too much engine
oil. There is a risk of damage to the engine or to the catalytic
converter.
X
Have the excess oil siphoned off at a qualified specialist
workshop. Observe the legal requirements. 0011
Engine Oil Level
Cannot measure
eng. oil level Vehicles without an oil dipstick: the measuring system is
defective.
X
Visit a qualified specialist workshop. 000F
Reserve fuel level The fuel level has dropped into the reserve range.
X
Refuel at the nearest gas station. 0009 There is only a very small amount of fuel in the fuel tank.
X
Refuel at the nearest gas station without fail. 000F
Fuel filler cap
open The fuel system pressure is too low. The fuel filler cap is not closed
correctly or the fuel system is leaking.
X
Check that the fuel filler cap is correctly closed.
If the fuel filler cap is not correctly closed:
X Close the fuel filler cap.
If the fuel filler cap is correctly closed:
X Visit a qualified specialist workshop. 000F
Ultra Low-sulfur
Diesel Fuel Only Vehicles with a diesel engine: the fuel level has fallen below the
reserve range.
X Refuel at the nearest gas station.
X Only use commercially available vehicular ULTRA-LOW SULFUR
HIGHWAY DIESEL FUEL (ULSD, 15ppm SULFUR MAXIMUM). 00060005
Replace air
cleaner element Vehicles with a diesel engine: the engine air filter is dirty and must
be replaced.
X
Visit a qualified specialist workshop. Display messages
411On-board computer and displays Z

Engine
Problem Possible causes/consequences and
0004 Solutions
000E
The yellow Check
Engine warning lamp
lights up while the
engine is running. There may be a malfunction, for example:
R
in the engine management
R in the fuel injection system
R in the exhaust system
R in the ignition system (for vehicles with a gasoline engine)
R in the fuel system
The emission limit values may be exceeded and the engin emay
be running in emergency mode.
X Have the vehicle checked as soon as possible at a qualified
specialist workshop.
i In some states, you must immediately visit a qualified
specialist workshop as soon as the yellow Chec kEngine warning
lamp lights up .This is due to the legal requirements in effect in
these states. If in doubt, check whether such legal regulations
apply in the state in which you are currently driving. Vehicles with a diesel engine: the fuel tank has been run dry
(Y
page 324).
X Start the engine three to four times after refueling.
If the yellow Check Engine warning lamp goes out, emergency
running mode is canceled. The vehicle need not be checked. The yellow reserve fuel
warning lamp flashes
while the vehicle is in
motion.
In addition, the 000E
Check Engine warning
lamp may light up. The fuel system pressure is too low. The fuel filler cap is not closed
correctly or the fuel system is leaking.
X
Observe the additional display messages in the multifunction
display.
X Check that the fuel filler cap is correctly closed.
X If the fuel filler cap is not correctly closed: close the fuel filler
cap.
X If the fuel filler cap is closed: visit a qualified specialist
workshop. The yellow reserve fuel
warning lamp lights up
while the engine is
running. The fuel level has dropped into the reserve range.
X
Refuel at the nearest gas station. 434
Warning and indicator lamps in the instrument clusterOn-board computer and displays