2013 MERCEDES-BENZ S-Class heating

exhaust pipe and from around the vehicle as
long as the engine is running. Otherwise,
poisonous carbon monoxide (CO) may enter
the vehicle, resulting in loss of consciousness
and even death.
To assure sufficien
tfresh air ventilation, open
a window slightly on the side of the vehicle
not facing the wind.
Have yourv ehicle winterproofed at a qualified
specialist workshop at the onset of winter.
Observe the notes in the "Winter operation"
section (Y page 500).
Driving with summer tires Observe the notes in the "Winter operation"
section (Y page 500).
Slippery road surfaces G
WARNING
The outside temperature indicator is not
designed to serve as an ice-warning device
and is therefore unsuitable for that purpose.
Indicated temperatures just above the
freezing point do not guarantee that the road
surface is free of ice. The road may still be icy,
especially in wooded areas or on bridges. G
WARNING
On slippery road surfaces, never downshift in
order to obtain braking action .This could
result in drive wheel slip and reduced vehicle
control. Your vehicle's ABS will not prevent
this type of loss of control.
Drive particularly carefully on slippery road
surfaces. Avoid sudden acceleration, steering
and braking maneuvers. Do not use the cruise
control or DISTRONIC PLUS.
If the vehicle threatens to skid or cannot be
stopped when moving at low speed:
X Shift the transmission to position N.
i For more information on driving with
snow chains, see (Y page 501). G
WARNING
Make sure that you do not endanger other
road users when you apply the brakes. Driving systems
Cruise control
Important safety notes Cruise control maintains a constant road
speed for you. It brakes automatically in order
to avoid exceeding the set speed. On long and
steep downhill gradients, especially if the
vehicle is laden, you must select shift range
1, 2or 3in good time. By doing so, you will
make use of the braking effect of the engine,
which relieves the load on the brake system
and prevents the brakes from overheating
and wearing too quickly.
Use cruise control only if road and traffic
conditions make it appropriate to maintain a
steady speed for a prolonged period. You can
store any road speed above 20 mph
(30 km/h). G
WARNING
The cruise control is a convenience system
designed to assist the driver during vehicle
operation. The driver is and must always
remain responsible for the vehicle's speed
and for safe brake operation.
Only use the cruise control if the road, traffic,
and weather conditions make it advisable to
travel at a constant speed.
R The use of the cruise control can be
dangerous on winding roads or in heavy
traffic because conditions do not allow safe
driving at a constant speed.
R The use of the cruise control can be
dangerous on slippery roads. Rapid
changes in tire traction can result in wheel
spin and loss of control.
R Deactivate the cruise control when driving
in fog. 334
Driving systemsDriving and parking

press the cruise control lever up
0002or
down 0003to the pressure point.
The last speed stored is increased or
decreased every time the cruise control
lever is pushed up 0002or down 0003.
X To adjust the speed in 5 mph
increments (10 km/h increments):
briefly press the cruise control lever
up 0002 or down 0003beyond the pressure
point.
The last speed stored is increased or
decreased every time the cruise control
lever is pushed up 0002or down 0003.
i Cruise control is not deactivated if you
depress the accelerator pedal. For
example, if you accelerate briefly to
overtake, cruise control adjusts the
vehicle's speed to the last speed stored
after you have finished overtaking.
Deactivating cruise control There are several ways to deactivate cruise
control:
X Briefly press the cruise control lever
forwards 0026.
or
X Brake.
Cruise control is automatically deactivated if:
R you engage the electric parking brake.
R you are driving at less than 20 mph
(30 km/h)
R ESP ®
intervenes or you deactivate ESP ®
.
R you shift the transmission to position N
while driving.
If cruise control is deactivated, you will hear
a warning tone. You will see the CruiseControl Off message in the multifunction
display for approximately five seconds.
i When you switch off the engine, the last
speed stored is cleared. DISTRONIC PLUS
Important safety notes DISTRONIC PLUS regulates the speed and
automatically helps you maintain the
distance to the vehicle detected in front.
DISTRONIC PLUS brakes automatically so
that the set speed is not exceeded.
On long and steep downhill gradients,
especially if the vehicle is laden, you must
select shift range
1,2or 3in good time. By
doing so, you will make use of the braking
effec tofthe engine, which relieves the load
on the brake system and prevents the brakes
from overheating and wearing too quickly.
If DISTRONIC PLUS detects a slower-moving
vehicle in front, your vehicle is braked in order
to maintain the preset distance to the vehicle
in front. G
WARNING
HYBRID vehicles: It is imperative that you read
the HYBRID Supplemental Operating
Instructions included in your vehicle literature
portfolio. You may otherwise not receive all
necessary safety information and warning for
the operation of your vehicle. G
WARNING
The DISTRONIC PLUS requires familiarity with
its operational characteristics. We strongly
recommend that you review the following
information carefully before operating the
system. G
WARNING
When DISTRONIC brakes, the brake pedal is
pulled back (i.e. operated automatically) .The
area around the pedal must not be blocked by
obstacles:
R do not place any objectsint he footwell.
R ensure that floormats and carpets are fixed
securely. In particular, do not place several
floormats on top of one another.
R do not place your foot under the brake
pedal, as it could become trapped. 336
Driving systemsDriving and parking

If childre
nopen a door, they could injure other
persons or get out of the vehicle and injure
themselves or be injured by following traffic.
Do not expose the child restraint system to
direct sunlight .The child restraint system's
metal parts, for example, could become very
hot, and the child could be burned on these
parts. G
WARNING
Never touch the heating element or sides of
the lighter; they are extremely hot. Hold the
knob only.
Make sure any children traveling with you do
not injure themselves or start a fire with the
hot cigarette lighter. Center console, front
X
Turn the SmartKey to position 2in the
ignition lock.
X To open: slide cover 0002forwards until it
engages.
X Press in cigarette lighter 0003.
Cigarette lighter 0003will pop out
automatically when the heating element is
red-hot.
X To close: press cover 0002briefly at the
front.
The cover moves back. Center console, rear compartment
X
Press in cigarette lighter 0002.
Cigarette lighter 0002will pop out
automatically when the heating element is
red-hot. 12
Vsockets
Points to observe before use The sockets can be used for accessories with
a maximum draw of 180 W (15 A).
Accessories include such items as lamps or
chargers for mobile phones.
If you use the sockets for long periods when
the engine is switched off
,the battery may
discharge.
X Turn the SmartKey to position 1in the
ignition lock.
i An emergency cut-out ensures that the
on-board voltage does not drop too low. If
the on-board voltage is too low, the power
to the sockets is automatically cut. This
ensures that there is sufficient power to
start the engine. Features
447Stowage and features Z

position
Pautomatically and locks the
wheels. You can preven tthis by shifting
the automatic transmission to N
beforehand.
R Vehicles with KEYLESS-GO:
Do not open the driver's door or front-
passenger door when the engine is
switched off. Otherwise, the automatic
transmission selects park position P
automatically and locks the wheels.
Observe the following to make sure that the
automatic transmission stays in position N:
X Make sure the vehicle is stationary and the
ignition is switched off.
X Turn the key to position 2(Ypage 307) in
the ignition lock.
Use the SmartKey instead of the Start/
Stop button on vehicles with KEYLESS-GO.
X Depress and hold the brake pedal.
X Shift the automatic transmission to
position N.
X Release the brake pedal.
X Release the electric parking brake.
X Switch off the ignition and leave the
SmartKey in the ignition lock.
! Make sure that:
R the side windows and the sliding sunroof
are fully closed.
R the ventilation/heating is switched off
(the OFF button has been pressed).
R the windshield wiper switch is in position
0.
Otherwise, the vehicle might be damaged.
After using an automatic car wash, wipe off
wax from the windshield and the wiper
blades. This will prevent smears and reduce
wiping noises caused by residue on the
windshield.
Washing by hand In some countries, washing by hand is only
allowed at specially equipped washing bays. Observe the legal requirements in all
countries concerned.
X
Do not use hot water and do not wash the
vehicle in direct sunlight.
X Use a soft sponge to clean.
X Use a mild cleaning agent, such as a car
shampoo approved by Mercedes-Benz.
X Thoroughly hose down the vehicle with a
gentle jet of water.
X Do not point the water jet directly towards
the air inlet.
X Use plenty of water and rinse out the
sponge frequently.
X Rinse the vehicle with clean water and dry
thoroughly with a chamois.
X Do not let the cleaning agent dry on the
paintwork.
When using the vehicle in winter, remove all
traces of road salt deposits carefully and as
soon as possible.
Powerw ashers G
WARNING
Do not use power washers with circular-jet
nozzles (dirt grinders) to clea nyour vehicle, in
particular the tires. You could otherwise
damage the tires and cause an accident.
! Always maintain a distance of at least
11.8 in (30 cm) between the vehicle and the
power washer nozzle. Information about
the correc tdistance is available fro mthe
equipment manufacturer.
Move the power washer nozzle around
when cleaning your vehicle.
Do not aim directly at any of the following:
R tires
R door gaps, roof gaps, joints, etc.
R electrical components
R battery
R connectors
R lights
R seals Care
471Maintenance and care Z

Cleaning the steering wheel and gear or
selector lever
X
Thoroughly wipe with a damp cloth or use
leather care agents that have been
recommended and approved by Mercedes-
Benz.
Cleaning genuine wood and trim
elements X
Wipe the woode ntrim and trim pieces with
a damp, lint-free cloth, e.g. a microfiber
cloth.
X Heavy soiling: use car care and cleaning
products recommended and approved by
Mercedes-Benz.
! Do not use solvent-based cleaning agents
such as tar remover, whee lcleaners,
polishes or waxes. There is otherwise a risk
of damaging the surface.
! Do not use chrome polish on trim pieces.
The trim pieces have a chrome look but are
mostly made of anodized aluminum and
can lose their shine if chrome polish is
used. Use a damp, lint-free cloth instead
when cleaning the trim pieces.
If the chrome-plated trim pieces are very
dirty, you can use a chrome polish. If you
are unsure as to whether the trim pieces
are chrome-plated or not, consult an
authorized Mercedes-Ben zCenter.
Cleaning the seat covers !
Do not use microfiber cloths to clean
genuine leather, artificial leather or
Alcantara® covers. If used often, these can
damage the cover.
! Observe the following when cleaning:
R clean genuine leather cover scarefully
with a damp cloth and then wipe the
covers down with a dry cloth .Make sure
that the leather does no tbecome
soaked. It may otherwise become rough
and cracked. Only use leather care agents that have been tested and
approved by Mercedes-Benz. You can
obtain these from a qualified specialist
workshop.
R clean artificial leather covers with a cloth
moistened with a solution containing 1%
detergen t(e.g. dish washing liquid).
R clean cloth covers with a microfiber cloth
moistened with a solution containing 1%
detergen t(e.g. dish washing liquid). Rub
carefully and always wipe entire seat
sections to avoid leaving visible lines.
Leave the seat to dry afterwards.
Cleaning results depend on the type of
dirt and how long it has been there.
R clean Alcantara® covers with a damp
cloth. Make sure that you wipe entire
seat sections to avoid leaving visible
lines.
i Note that regular care is essential to
ensure that the appearance and comfort of
the covers is retained over time.
Cleaning the seat belts X
Use clean, lukewarm water and soap
solution.
! Do not clean the seat belts using chemical
cleaning agents .Do not dry the seat belts
by heating at temperatures above 176 ‡
(80 †) or in direct sunlight. G
WARNING
Do not bleach or dye seat belts as this may
severely weaken them. In a crash, they may
not be able to provide adequate protection.
Cleaning the headliner and carpets X
Headliner: use a soft brush or a cleaning
agent recommended and approved by
Mercedes-Benz to remove heavy soiling.
X Carpets: use the carpet and textile
cleaning agents recommended and
approved by Mercedes-Benz. 476
CareMaintenance and care

R
lubricants (e.g .engine oil, transmission oil)
R coolant
R brake fluid
R windshield washe rfluid
R climate control system refrigerant
Components and service products must be
matched .You should therefor eonly use
products tha thave been tested and approved
by Mercedes-Benz.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.co m.
You can recognize service products approved
by Mercedes-Ben zby the following
inscription on the containers:
R MB approval (e.g. MB approval 229.51)
R MB Approval (e.g. MB Approval 229.51)
Other designations or recommendations
indicate a level of quality or a specification in
accordance with an MB Sheet number (e.g.
MB 229.5). The yhave no tnecessarily been
approved by Mercedes-Benz. Fuel
Important safety notes G
WARNING
Gasoline and diesel fuels are highly flammable
and poisonous. They burn violently and can
cause serious injury.
Never allow sparks, flames or smoking
materials near gasoline or diesel fuel!
Turn off the engine before refueling.
Whenever you are around gasoline or diesel
fuel, avoid inhaling fumes and any skin or
clothing contact. Extinguish all smoking
materials.
Direct skin contact with fuels and the
inhalation of fuel vapors are damaging your
health. Tank capacity Total capacity
S 550
30
S 550 4MATIC 30
S 350 BlueTEC 4MATIC 21.9 US gal
(83.0 l) S 600
AMG vehicles
23.8 US gal
(90.0 l) Of which reserve
Approx.
2.9 US gal (11.0 l) Of which reserve fuel in
AMG vehicles
Approx.
3.7 US gal (14.0 l) Gasoline
Fuel grade
!
Do not use diesel to refuel vehicles with a
gasoline engine. Even small amounts of the
wrong fuel result in damage to the fuel
system and engine.
! You should only refuel with unleaded
premium-grade gasoline as this avoids
damaging the catalytic converter.
If engine running problems are apparent,
have the cause checked immediately and
repaired. Excess unburned fuel can
otherwise enter the catalytic converter,
leading to overheating and possibly
causing a fire.
! To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline may be used.
If there is no premium-grade unleaded
gasoline available and regular unleaded
gasoline must be used, please observe the
following precautions:
R only fill the fuel tank to half full with
regular unleaded gasoline and fill the rest
30 BlueEFFICIENCY Service products and filling capacities
531Technical data Z

engine and could result in the vehicle catching
fire.
! Only use commercially available vehicular
ULTRA-LOW SULFUR DIESEL FUEL (ULSD,
15 ppm maximum sulfur content) that
meets the ASTM D975 standard. If you do
not refuel with ULSD ,you may damage the
BlueTEC exhaust gas aftertreatment
system of the vehicle.
! Do not use gasoline to refuel vehicles with
a diesel engine. Do not mix diesel fuel with
gasoline, kerosene or paraffin. This may
otherwise result in damage to the fuel
system and engine.
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult a
qualified specialist workshop or on the
Internet at http://www.mbusa.com (USA
only).
Information on refueling (Y page 321).
Bio-diesel -FAME (fatt yacid methyl ester)
Mercedes-Ben zUSA approves the use of bio-
diesel B5 for all BlueTEC diesel engines. The
concentration of bio-diesel in the ULSD may
not exceed 5%by volume.
Pure biodiesel and diesel fuel with a higher
percentage of biodiesel, such as B20, can
damage the engine and the fuel system. For
this reason, they are not approved.
For more information, consult the gas station
staff .The bio-diesel B5 label on the gasoline
pump must clearly state that the standard for
ULSD has been fulfilled. If the label is not
clear, do not refuel the vehicle.
Do not refuel your vehicle with fuels unless
they have been approved by Mercedes-Benz.
Information on refueling (Y page 321).Low outside temperatures
i
Diesel fuel with improved cold flow
properties is available during the winter
months. Further information about fuel
properties can be obtained from oil
companies, e.g. at gas stations.
Flow improver
To improve the low-temperature resistance of
diesel fuel, a flow improver can be attached.
The effectiveness of a flow improver is not
guaranteed for every fuel.
Only use flow improvers tested and approved
by Mercedes-Benz. During use, please
observe the information on operation.
Correct dosage and sufficient mixing are
decisive in improving low-temperature
resistance with the flow improver.
Overdosage can potentially even decrease
low-temperature resistance and must
therefore be avoided. Follow the
manufacturer's guidelines on dosage.
Mix the additive into the diesel in good time,
before the flow characteristics of the diesel
become insufficient .Otherwise, malfunctions
can arise through heating the fuel system,
e.g .through parking in a heated garage.
More information about recommended flow
improvers can be obtained from any qualified
specialist workshop. DEF
Please bear the following in mind DEF is a non-flammable, non-toxic, colorless,
odorless and water-soluble fluid.
High outside temperatures
G
WARNING
If you open the DEF tank cap, small amounts
of ammonia vapor may be released. This
depends in particular upon the age of the DEF. Service products and filling capacities
533Technical data
Z

Ammonia vapors have a pungent odor and are
particularly irritating to:
R skin
R mucous membranes
R eyes
You may experience a burning sensation in
your eyes, nose and throat, as well as
coughing and watering of the eyes.
Do not inhale any ammonia vapors that may
be released .Fill the DE Ftank only in well-
ventilated areas.
Low outside temperatures DEF freezes at a temperature of
approximately 12
‡(-11 †). The vehicl eis
equipped with a DEFp reheating system when
it leaves the factory. Winter operation is
therefore also guaranteed at temperatures
below 12 ‡ (-11 †).
Additives !
Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity !
Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC exhaust gas
aftertreatment system
Assuring the purity of DEF is particularly
important with respect to avoiding
malfunctions in the BlueTEC exhaust gas
aftertreatment system. If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
Total capacity of the DEF tank Model Total capacity
S 350 BlueTEC 4MATIC
6.6 US gal
(25.0 l) Engine oil
Points to note !
Never use engine oil or an oil filter of a
specificatio nothe rthan is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
intervals than those prescribed. You could
otherwise cause engine damage or damage
to the exhaust gas aftertreatment.
Follow the instructions in the service
interval display regarding the oil change.
Otherwise, you may damage the engine and
the exhaust gas aftertreatment.
The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz
Center. Or visit the website
http://bevo.mercedes-benz.com.
The table shows which engine oils have been
approved for your vehicle. 534
Service products and fillingc
apacitiesTechnical data