2012 MERCEDES-BENZ S-Class oil capacities

Servicesee ASSYST PLUS service interval
display
Service interval display
Displaying service messages .........462
Hiding service messages ...............462
Notes ............................................. 462
Service messages ..........................462
Service menu (on-board computer) . 385
Service products Brake fluid ..................................... 528
Capacities ...................................... 524
Coolant (engine) ............................ 529
DEF special additives .....................527
Engine oil ....................................... 527
Fuel ................................................ 525
Important safety notes ..................522
Refrigerant (air-conditioning
system) .......................................... 528
Washer fluid ................................... 529
Setting a station (radio)
Via manual frequency entry ...........212
Settings
Display ........................................... 143
Menu overview .............................. 121
On-board computer .......................385
Picture (COMAND) .........................240
Picture (Rear Seat Entertainment
System) ......................................... 249
Sound settings ............................... 135
System settings ............................. 143
Setting the language
COMAND ....................................... 149
Rear Seat Entertainment System ...258
Setting the night design ................... 143
Setting the text reader speed .......... 145
Setting the vehicle level ................... 345
Setting the volume Telephone calls .............................. 134
Video AUX ..................................... 246
Side impact air bag ............................. 48
Side marker lamp (display
message) ............................................ 403
Side windows Convenience closing feature ............94
Convenience opening feature ..........93
Important safety information ...........92
Opening/closing .............................. 93Problem (malfunction) .....................95
Resetting ......................................... 95
Sliding sunroof
Important safety notes ....................95
Opening/closing .............................. 96
Problem (malfunction) ...................100
Resetting ......................................... 97
see Panorama roof with power
tilt/sliding panel
SmartKey
Changing the battery .......................82
Changing the programming .............81
Checking the battery .......................82
Convenience closing feature ............94
Convenience opening feature ..........93
Display message ............................ 419
Door central locking/unlocking .......78
Important safety notes ....................78
Loss ................................................. 84
Mechanical key ................................ 81
Positions (ignition lock) .................303
Problem (malfunction) .....................84
Starting the engine ........................305
SMS message
see Text message
Snow chains ...................................... 493
Socket Glove box ....................................... 442
Sockets
Points to observe before use .........441
Rear compartment .........................442
Trunk ............................................. 442
Sound menu ....................................... 135
Sounds see Sound settings
Sound settings
Balance and fader ..........................135
Calling up the sound menu ............135
Rear Seat Entertainment System ...248
Surround sound ............................. 136
Treble and bass ............................. 135
Spare wheel
Storage location ............................ 472
see Emergency spare wheel
Specialist workshop ............................ 31
Speech control see Voice Control System Index21

iThe data shown on the identification plate
is example data. This data is different for
every vehicle and can deviate from the data
shown here. You can find the data
applicable to your vehicle on the vehicle's
identification plate.
Vehicle identification number (VIN)
The vehicle identification number (VIN) can
be found in the following locations:
R on the vehicle identification plate
( Y page 521)
R at the lower edge of the windshield
( Y page 522)
In addition to being stamped on the vehicle
identification plate, the vehicle identification
number (VIN) is also stamped onto the vehicle
body. It is under the trim behind the rear seat
armrest.
XFold down the rear seat armrest.XOpen the trim.
You will see vehicle identification number
(VIN) :.Engine number:Emission control information plate,
including the certification of both federal
and Californian emissions standards;Engine number (stamped into the
crankcase)=VIN (on the lower edge of the windshield)
Service products and capacities
Important safety notes
Service products include the following:
R fuels (e.g. gasoline, diesel)
R additives for exhaust gas aftertreatment
(DEF)
R lubricants (e.g. engine oil, transmission oil)
R coolant
R brake fluid
R windshield washer fluid
Vehicle components and their respective
lubricants must match. You should therefore
only use products that have been tested and
approved by Mercedes-Benz.
Information on tested and approved products
can be obtained at a Mercedes-Benz Center
or on the Internet at http://
www.mbusa.com (USA only).
GWARNING
Comply with all valid regulations with respect
to handling, storing and disposing of service
fluids. Otherwise, you could endanger
persons or the environment.
522Service products and capacitiesTechnical data

CapacitiesModelCapacityFuel, coolant,
lubricants, etc.Engine oil and
filterS 550 34
S 550 4MATIC 34
S 63 AMG9.0 US qt (8.5 l)Approved engine
oilsS 600
S 65 AMG9.5 US qt (9.0 l)S 350 BlueTEC
4MATIC8.5 US qt (8.0 l)Cooling systemS 550 34
S 550 4MATIC 34Approximately 14.5 US qt
(13.7 l)MB 325.0 or
MB 326.0
anticorrosion/
antifreezeS 600Approximately 15.3 US qt
(14.5 l)S 63 AMGApproximately 12.2 US qt
(11.5 l)S 65 AMGApproximately 14.7 US qt
(13.9 l)S 350 BlueTEC
4MATICApproximately 12.0 US qt
(11.4 l)Tank capacityS 550 34
S 550 4MATIC 34
S 350 BlueTEC
4MATIC21.9 US gal (83.0 l)Gasoline engines:
premium-grade
unleaded gasoline
(at least 91 octane,
average value
between 96 RON/
86 MON)
Diesel engines:
ULTRA-LOW
SULFUR HIGHWAY
DIESEL FUEL (ULSD,
maximum sulfur
content 15 ppm)S 600
S 63 AMG
S 65 AMG23.8 US gal (90.0 l)ReserveAll models except
AMG vehicles2.9 US gal (11.0 l)AMG vehicles3.7 US gal (14.0 l)34 BlueEFFICIENCY.524Service products and capacitiesTechnical data

RIPA
R TBA
For MTBE, the concentration should not
exceed 15%.
The concentration of methanol in gasoline
including other additives must not exceed 3%.
Using mixtures of methanol and ethanol is not
permitted. Gasohol, a mixture of 10% ethanol
and 90% unleaded gasoline, can be used.
All of these mix fuels must fulfill the fuel
requirements, e.g.:
R knock resistance
R boiling point
R vapor pressure
Diesel engines – important safety notes
! Only use commercially available ULTRA-
LOW SULFUR DIESEL FUEL (ULSD, 15 ppm
MAXIMUM SULFUR) that meets the
ASTM D975 standard. Failure to use
ULTRA-LOW SULFUR DIESEL FUEL (ULSD)
can severely damage the vehicle's exhaust
gas aftertreatment system.
! Do not fill the tank with gasoline. Do not
blend diesel fuel with gasoline or kerosene.
Otherwise, the fuel system and the engine
could be damaged.
To prevent malfunctions, diesel fuel with
improved flow characteristics is available in
the winter months. Check with your gas
station.
Information on the fuel grade can usually be
found on the gas pump. If the information
cannot be found on the gas pump, ask the gas
station personnel. For further information,
consult an authorized Mercedes-Benz Center
or go to the Internet site
http://www.mbusa.com (USA only).
Diesel engines – fuels containing
biodiesel (FAME [fatty acid methyl ester])
Mercedes-Benz USA approves the use of B5
(ULSD with a maximum of up to five percent
by volume biodiesel) for all diesel engineswith common rail direct injection (CDI) and
BlueTEC.
Pure biodiesel and diesel fuels that have a
higher percentage of biodiesel, e.g. B20, can
damage the fuel system and the engine and
are therefore not approved.
For further information, please ask the gas
station personnel. The label on the gas pump
must indicate clearly that the B5 biodiesel
blend fulfills the ULSD standard. If the label
is not clear, do not refuel the vehicle.
Do not refuel your vehicle with fuels unless
they have been approved by Mercedes-Benz.
Additives in gasoline
One of the main problems of poor fuel quality
is the forming of deposits that are caused
during the gasoline combustion process.
Mercedes-Benz recommends that you use
fuel brands that have the additives.
If you use fuels without these additives for an
extended period of time, there may be a
buildup of carbon deposits, especially on the
inlet valves and in the combustion chamber.
This could lead to engine problems, e.g.:
R longer engine warm-up phase
R uneven idle
R engine noise
R misfiring
R loss of power
Carbon deposits may form if the availability
of gasoline with relevant additives is
insufficient (in certain regions). In this case,
Mercedes-Benz recommends the use of
additives that have been approved for
Mercedes-Benz vehicles.
Consult an authorized Mercedes-Benz Center
or go to the Internet site
http://www.mbusa.com (USA only) for a list
of approved products. Observe the
instructions for use on the product label.
Do not mix other fuel additives with fuel. This
causes unnecessary costs and could damage
the engine.
526Service products and capacitiesTechnical data

! Do not refuel with low-grade fuel and do
not use fuel additives that are not tested
and approved for Mercedes-Benz vehicles.
Damage to or malfunctions of the fuel
system may otherwise occur.
DEF
Important safety notes
i For BlueTEC vehicles only.
DEF is a non-flammable, non-toxic, colorless,
odorless and water-soluble fluid.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF
residues crystallize after time and
contaminate the affected surfaces.
High outside temperatures
If DEF heats up to over 122 ‡ (50 †) for
extended periods, e.g. as a result of direct
sunlight on the DEF reservoir, DEF can
decompose. Ammonia vapors develop as a
result.
GWARNING
When opening the filler cap of the DEF tank
ammonia gas vapors may escape. Refill DEF
in a well ventilated area only. Ammonia gas
vapors have a pungent odor and are
particularly irritating for your skin, mucous
membranes, and eyes. Inhaling ammonia gas
vapors will cause burning eyes, nose, and
throat, as well as coughing and watering eyes.
Low outside temperatures
DEF freezes at a temperature of
approximately 12 ‡ (–11 †). The vehicle is
equipped with a DEF preheating system when
it leaves the factory. Winter operation is
therefore also guaranteed at temperatures
below 12 ‡ (–11 †).
Additives
! Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity
Assuring the purity of DEF is particularly
important with respect to avoiding
malfunctions in the exhaust gas
aftertreatment system.
If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
! Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC exhaust gas
aftertreatment system
Engine oil
Please bear the following in mind
The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz Center
or go to the Internet site
http://www.mbusa.com (USA only).
! Never use engine oil or an oil filter of a
specification other than is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
Service products and capacities527Technical dataZ

intervals than those prescribed. You could
otherwise cause engine damage or damage
to the exhaust gas aftertreatment.
Follow the instructions in the service
interval display regarding the oil change.
Otherwise, you may damage the engine and
the exhaust gas aftertreatment.
The table shows which engine oils have been
approved for your vehicle.ModelEngine
modelMB
ApprovalS 550 36
S 550 4MATIC 36278229.5S 600275S 63 AMG157229.537S 65 AMG275S 350 BlueTEC
4MATIC642228.51,
229.31,
229.51
i MB approval is indicated on the oil
containers.
Additives
! Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity
Viscosity describes the flow characteristics
of a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE (viscosity)
classification suitable for the prevailing
outside temperatures. The following table
shows the correct SAE classification to be
used. The low-temperature characteristics of
engine oils can deteriorate significantly, e.g.
as a result of aging, soot and fuel deposits. It
is therefore strongly recommended that you
carry out regular oil changes using an
approved engine oil with the appropriate SAE
classification.
Refrigerant of the air-conditioning
system
The air-conditioning system is filled with
R134a refrigerant and a special PAG
lubricant.
! Never use refrigerant R 12 (CFC) or
mineral lubricants. Otherwise, you could
damage the air-conditioning system.
Brake fluid
GWARNING
Over a period of time, the brake fluid absorbs
moisture from the air; this lowers its boiling
point.
If the boiling point of the brake fluid is too low,
vapor pockets may form in the brake system
when the brakes are applied hard (e.g. when
driving downhill). This would impair braking
efficiency.
You should have the brake fluid renewed at
regular intervals. The brake fluid change
intervals can be found in the Service Booklet.
Only use brake fluid approved by Mercedes-
Benz. Information about approved brake
36 BlueEFFICIENCY
37 Restriction: only SAE 0W-40 or SAE 5W-40 engine oils may be used.528Service products and capacitiesTechnical data

fluids can be obtained from any authorized
Mercedes-Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
Coolant
Important safety notes
The coolant is a mixture of water and
antifreeze/corrosion inhibitor. It performs
the following tasks:
R corrosion protection
R antifreeze protection
R raising the boiling point
The engine cooling system is filled at the
factory with coolant that contains an
antifreeze/corrosion inhibitor that ensures
protection down to approximately -35 ‡
(-37 †).
! Only add coolant that has been premixed
with the desired antifreeze protection.
Otherwise, the engine could be damaged.
Further information on coolants and on
filling can be found in the Mercedes-Benz
Specifications for Service Products, MB
Approval 310.1, e.g. on the Internet at
http://bevo.mercedes-benz.com . You can
also consult an authorized Mercedes-Benz
Center.
! Always use a suitable coolant mixture,
even in countries where high temperatures
prevail.
Otherwise, the engine cooling system is not
sufficiently protected from corrosion and
overheating.
If the coolant has antifreeze protection down
to -35 ‡ (-37 †), the boiling point of the
coolant under operating conditions is
approximately 266 ‡ (130 †).
Your vehicle has a range of aluminum
components. Aluminum components in the
engine make it necessary to use antifreeze/
corrosion inhibitor coolant that has been
specifically formulated to protect the
aluminum parts. Using other antifreeze/
corrosion inhibitors without these
characteristics affects the service life.
The coolant must be used throughout the year
in order to maintain the necessary corrosion
protection and to provide protection from
overheating. In the Service Booklet, you can
find information on the intervals for renewal.
The renewal interval is determined by the
coolant type and the engine cooling system
design. The renewal interval in the Service
Booklet is only valid if the coolant is renewed
or filled up with Mercedes-Benz approved
products. Therefore, only use MB 325.0 or
326.0 anticorrosion/antifreeze or another
Mercedes-Benz approved product of the
same specification.
Information on other products with the same
specifications that are approved by
Mercedes-Benz can be obtained at an
authorized Mercedes-Benz Center or on the
Internet at http://bevo.mercedes-benz.com.
The coolant is checked at every maintenance
interval at an authorized Mercedes-Benz
Center.
The antifreeze/corrosion inhibitor
concentration in the engine cooling system
should:
R be at least 50%. This will protect the engine
cooling system against freezing down to
approximately -35 ‡ (-37 † ).
R not exceed 55% (antifreeze protection to
-49 ‡ [-45 † ]); otherwise, heat will not
dissipate as effectively.
If the coolant level is too low, MB 325.0 or
326.0 anticorrosion/antifreeze should be
added. Have the engine cooling system
checked for possible leaks.
Windshield/headlamp cleaning
system
GWARNING
Washer solvent/antifreeze is highly
flammable. Do not spill washer solvent/
antifreeze on hot engine parts, because it may
Service products and capacities529Technical dataZ