2012 MERCEDES-BENZ S-Class octane

Selecting your home address ........159
Setting route options (avoiding:
highways, toll roads, tunnels,
ferries) ........................................... 152
Setting the route type (short
route, fast route, dynamic route or
economic route) ............................ 152
Showing/hiding the menu .............152
Starting route calculation ..............156
Switching announcements on/off . 170
Switching to ................................... 151
Traffic report .................................. 174
Troubleshooting ............................. 192
NECK-PRO head restraints
Operation ......................................... 55
Resetting after being triggered ........56
NECK-PRO luxury head restraints
Operation ......................................... 55
Resetting after being triggered ........56
Night View Assist Plus
Activating/deactivating .................357
Cleaning ......................................... 467
Display message ............................ 408
Function/notes ............................. 357
Problem (malfunction) ...................360
North orientation (navigation) ......... 184
Notes on breaking-in a new
vehicle ................................................ 302
Number keypad ................................. 129
O
Occupant Classification System
(OCS) Faults ............................................... 54
Operation ......................................... 50
System self-test ............................... 53
Occupant safety
Children in the vehicle .....................62
System overview .............................. 44
Octane number (fuel) ........................ 525
Odometer ........................................... 376
see Trip odometer
Off-road .............................................. 173
Oil see Engine oil
On-board computer
AMG menu ..................................... 379
Assistance menu ........................... 383
Audio menu ................................... 378
Displaying a service message ........462
Display messages ..........................388
DISTRONIC PLUS ........................... 339
Important safety notes ..................372
Menu overview .............................. 375
Message memory .......................... 388
Navigation menu ............................ 377
Operating video DVD .....................379
Operation ....................................... 373
RACETIMER ................................... 380
Service menu ................................. 385
Settings menu ............................... 385
Standard display ............................ 376
Telephone menu ............................ 382
Trip menu ...................................... 376
Opening height restriction for
trunk lid .............................................. 265
Operating system see On-board computer
Outside lighting
Delayed switch-off (COMAND) .......263
Outside temperature display ........... 373
Overhead control panel ...................... 39
Override feature Rear side windows ...........................67
Own address (navigation)
see Home address
P
Paint code number ............................ 521
Paintwork (cleaning instructions) ... 465
Panic alarm .......................................... 68
Panorama roof with power tilt/
sliding panel Opening/closing .............................. 97
Problem (malfunction) ...................100
Resetting ......................................... 99
Panorama sliding sunroof
Important safety notes ....................95
Parcel net ........................................... 435
Parking ............................................... 323
Important safety notes ..................323
Index17

If you bought this vehicle used, be sure to
send in the "Notice of Purchase of Used Car"
found in the Service and Warranty
Information Booklet, or call the Mercedes-
Benz Customer Assistance Center (in the
USA) at
1-800-FOR-MERCedes(1-800-367-6372) or
Customer Service (in Canada) at
1-800-387-0100.
Vehicle operation outside the USA
and Canada
If you plan to operate your vehicle in foreign
countries, please be aware that:
R service facilities or replacement parts may
not be readily available.
R unleaded fuel for vehicles with a catalytic
converter may not be available. Leaded fuel
may cause damage to the catalytic
converter.
R the fuel may have a considerably lower
octane rating. Unsuitable fuel can cause
engine damage.
Some Mercedes-Benz models are available
for delivery in Europe through our European
Delivery Program. For details, consult an
authorized Mercedes-Benz Center or write to
one of the following addresses.
In the USA
Mercedes-Benz USA, LLC
European Delivery Department
One Mercedes Drive
Montvale, NJ 07645-0350
In Canada
Mercedes-Benz Canada, Inc.
European Delivery Department
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9
Operating safety
Safety notes
GWARNING
Work improperly carried out on electronic
components and associated software could
cause them to cease functioning. Because the
vehicle's electronic components are
interconnected, any modifications made may
produce an undesired effect on other
systems. Electronic malfunctions could
seriously impair the operating safety of your
vehicle.
Contact an authorized Mercedes-Benz Center
for repairs or modifications to electronic
components.
Other improper work or modifications on the
vehicle could also have a negative impact on
the operating safety of the vehicle.
Some safety systems only function when the
engine is running. You should therefore never
turn off the engine while driving.
GWARNING
Heavy blows against the vehicle underbody or
tires/wheels may cause serious damage and
impair the operating safety of your vehicle.
Such blows can be caused, for example, by
running over an obstacle, road debris or a
pothole.
If you feel a sudden significant vibration or
ride disturbance, or you suspect that damage
to your vehicle has occurred:
R turn on your hazard warning flashers.
R slow down carefully.
R drive with caution to an area which is a safe
distance from the road.
Inspect the vehicle underbody and tires/
wheels for possible damage. If the vehicle
appears unsafe, have it towed to the nearest
authorized Mercedes-Benz Center or other
qualified maintenance or repair facility for
further inspection or repairs.
30Introduction

GWARNING
Overfilling of the fuel tank may create
pressure in the system which could cause a
gas discharge. This could cause the gasoline
to spray back out when removing the fuel
pump nozzle, which could cause personal
injury.
GWARNING
Hybrid vehicles: be sure to read the "HYBRID"
supplement. Otherwise, you could fail to
recognize dangers.
GWARNING
Do not fill diesel tanks with gasoline. Do not
mix diesel fuel with gasoline. Otherwise the
fuel system and engine could be damaged. In
addition, the vehicle could catch fire.
! Do not use gasoline to refuel vehicles with
a diesel engine. Do not use diesel to refuel
vehicles with a gasoline engine. Even a
small quantity of the wrong fuel will
damage the fuel system and engine.
! Do not switch on the ignition if you
accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel lines.
Notify a qualified specialist workshop and
have the fuel tank and fuel lines drained
completely.
Gasoline
Fuel grade
! You should only refuel with unleaded
premium-grade gasoline as this avoids
damaging the catalytic converter.
If engine running problems are apparent,
have the cause checked immediately and
repaired. Excess unburned fuel can
otherwise enter the catalytic converter,
leading to overheating and possibly
causing a fire.
! Use a filter when refueling from a fuel can.
Otherwise, the fuel lines and/or injection
system could be blocked by particles from
the fuel can.
i Only refuel with premium-grade unleaded
gasoline with a specified minimum octane
number of 91 (average value of 96 RON/
86 MON).
You will usually find information about the
fuel grade on the pump. If you cannot find
the label on the pump, ask the staff for
assistance.
You can find more information under "Fuel"
( Y page 525), or by contacting an
authorized Mercedes-Benz Service Center
or visiting http://www.mbusa.com (USA
only).
Diesel
Fuel grade
! Only refuel with ULTRA-LOW SULFUR
DIESEL FUEL (ULSD, 15 ppm SULFUR
MAXIMUM). Using other diesel fuels could
result in increased wear and damage to the
engine and/or exhaust system.
Never refuel with marine diesel or heating
oil.
Do not mix these fuels with diesel fuels and
do not use any special additives, as this
may result in damage.
! Use a filter when adding fuel from a fuel
can. Otherwise, the fuel lines and/or the
fuel injection system could be blocked by
particles from the fuel can.
i Usually, you will find information about
the fuel grade on the pump. If you cannot
find the label on the gasoline pump, ask the
gas station staff.
You can find more information under “Fuel”
( Y page 525), or by contacting an
authorized Mercedes-Benz Service Center
or visiting http://www.mbusa.com (USA
only).
318RefuelingDriving and parking

CapacitiesModelCapacityFuel, coolant,
lubricants, etc.Engine oil and
filterS 550 34
S 550 4MATIC 34
S 63 AMG9.0 US qt (8.5 l)Approved engine
oilsS 600
S 65 AMG9.5 US qt (9.0 l)S 350 BlueTEC
4MATIC8.5 US qt (8.0 l)Cooling systemS 550 34
S 550 4MATIC 34Approximately 14.5 US qt
(13.7 l)MB 325.0 or
MB 326.0
anticorrosion/
antifreezeS 600Approximately 15.3 US qt
(14.5 l)S 63 AMGApproximately 12.2 US qt
(11.5 l)S 65 AMGApproximately 14.7 US qt
(13.9 l)S 350 BlueTEC
4MATICApproximately 12.0 US qt
(11.4 l)Tank capacityS 550 34
S 550 4MATIC 34
S 350 BlueTEC
4MATIC21.9 US gal (83.0 l)Gasoline engines:
premium-grade
unleaded gasoline
(at least 91 octane,
average value
between 96 RON/
86 MON)
Diesel engines:
ULTRA-LOW
SULFUR HIGHWAY
DIESEL FUEL (ULSD,
maximum sulfur
content 15 ppm)S 600
S 63 AMG
S 65 AMG23.8 US gal (90.0 l)ReserveAll models except
AMG vehicles2.9 US gal (11.0 l)AMG vehicles3.7 US gal (14.0 l)34 BlueEFFICIENCY.524Service products and capacitiesTechnical data

ModelCapacityFuel, coolant,
lubricants, etc.DEF tankS 350 BlueTEC
4MATIC6.6 US gal (25.0 l)DEF in accordance
with ISO 22241Windshield/
headlamp
cleaning
systemAll models6.9 US qt (6.5 l)MB windshield
washer
concentrate 35
( Y page 529)
Mixing ratio for
washer fluid
( Y page 529)Fuel
Important safety notesGWARNING
Gasoline and diesel fuels are highly flammable
and poisonous. They burn violently and can
cause serious injury.
Never allow sparks, flames or smoking
materials near gasoline or diesel fuel!
Turn off the engine before refueling.
Whenever you are around gasoline or diesel
fuel, avoid inhaling fumes and any skin or
clothing contact. Extinguish all smoking
materials.
Direct skin contact with fuels and the
inhalation of fuel vapors are damaging your
health.
Premium-grade unleaded gasoline
! To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline may be used.
If there is no premium-grade unleaded
gasoline available and regular-grade
unleaded gasoline may be used; please
observe the following precautions:
R only fill the fuel tank to half full with
regular-grade unleaded gasoline and fill
the rest with premium-grade unleaded
gasoline as soon as possible.
R do not drive at the maximum speed.
R avoid sudden acceleration.
R if the vehicle is carrying a light load, e.g.
two passengers without luggage, do not
allow the engine to rev above
3,000 rpm.
R if the vehicle is fully loaded or is being
operated in mountainous terrain, do not
depress the accelerator pedal further
than Ô of the pedal travel.
Fuel requirements
Gasoline engines
Use only premium-grade unleaded gasoline.
The octane number should be at least 91.
Details can be found on the gas pump. The
octane number is the average value of the
Research Octane Number (RON) and the
Motor Octane Number (MON): (RON +
MON) / 2, also known as knock resistance.
Reformulated Gasoline (RFG) and/or
unleaded gasoline with additives can be used
if the concentration of the additives in the fuel
does not exceed 10%, e.g.:
R Ethanol
R TAME
R ETBE
35Mixed with water or premixed washer fluid with antifreeze protection.Service products and capacities525Technical dataZ