2012 MERCEDES-BENZ S-Class oil

XMake sure that the base of the jack is
positioned directly under the jacking point.XTurn crank ? clockwise until jack = sits
completely on jacking point ; and the
base of the jack lies evenly on the ground.XTurn crank ? until the tire is raised a
maximum of 1.2 inches (3 cm) off the
ground.
Removing a wheel
XUnscrew the uppermost wheel bolt
completely.XScrew alignment bolt : into the thread
instead of the wheel bolt.XUnscrew the remaining wheel bolts fully.
! Do not place wheel bolts in sand or on a
dirty surface. The bolt and wheel hub
threads could otherwise be damaged when
you screw them in.
XRemove the wheel.Mounting a new wheelGWARNING
Always replace wheel bolts that are damaged
or rusted.
Never apply oil or grease to wheel bolts.
Damaged wheel hub threads should be
repaired immediately. Do not continue to
drive under these circumstances! Contact an
authorized Mercedes-Benz Center or call
Roadside Assistance.
Incorrect wheel bolts or improperly tightened
wheel bolts can cause the wheel to come off.
This could cause an accident. Make sure to
use the correct wheel bolts.
GWARNING
Only use genuine Mercedes-Benz wheel bolts.
Other wheel bolts may come loose.
Do not tighten the wheel bolts when the
vehicle is raised. Otherwise, the vehicle could
fall off the jack.
GWARNING
Make sure to use the original length wheel
bolts when remounting the original wheel
after it has been repaired.
Wheel bolts for:
:All alloy wheels and the "Minispare"
emergency spare wheel for alloy wheels;"Minispare" emergency spare wheel for
steel wheels
! Always use wheel bolts : to fit the
"Minispare" emergency spare wheel with
476Flat tireBreakdown assistance

Kilopascal (kPa)
Metric unit for tire pressure. 6.9 kPa is the
equivalent of 1 psi. Another unit for tire
pressure is bar. There are 100 kilopascals
(kPa) to 1 bar.
Load index
In addition to the load bearing index, the load
index may also be imprinted on the sidewall
of the tire. This specifies the load bearing
capacity more precisely.
Curb weight
The weight of a vehicle with standard
equipment including the maximum capacity
of fuel, oil and coolant. It also includes the air-
conditioning system and optional equipment
if these are installed in the vehicle, but does
not include passengers or luggage.
Maximum load rating
The maximum load rating in kilograms or
pounds is the maximum weight for which a
tire is approved.
Maximum permissible tire pressure
Maximum permissible tire pressure for one
tire.
Maximum load on one tire
Maximum load on one tire. This is calculated
by dividing the maximum axle load of one axle
by two.
PSI (pounds per square inch)
A standard unit of measure for tire pressure.
Aspect ratio
Relationship between tire height and tire
width in percent.
Tire pressure
This is pressure inside the tire applying an
outward force to each square inch of the tire's
surface. The tire pressure is specified in
pounds per square inch (psi), in kilopascal
(kPa) or in bar. The tire pressure should only
be corrected when the tires are cold.
Tire pressure of cold tires
The tires are cold:
R if the vehicle has been parked without
direct sunlight on the tires for at least three
hours and
R if the vehicle has not been driven more than
1 mile (1.6 km).
Tread
The part of the tire that comes into contact
with the road.
Bead
The tire bead ensures that the tire sits
securely on the wheel. There are several steel
wires in the bead to prevent the tire from
coming loose from the wheel rim.
Sidewall
The part of the tire between the tread and the
bead.
Weight of optional extras
The combined weight of those optional extras
that weigh more than the replaced standard
part and more than 2.3 kilograms (5 lbs).
512Definition of terms for tires and loadingWheels and tires

! On vehicles equipped with a tire pressure
monitor, electronic components are
located in the wheel.
Tire-mounting tools should not be used
near the valve. This could damage the
electronic components.
Always have the tires changed at a qualified
specialist workshop, e.g. an authorized
Mercedes-Benz Center.
Direction of rotation
Tires with a specified direction of rotation
have additional benefits, e.g. if there is a risk
of hydroplaning. You will only gain these
benefits if the correct direction of rotation is
maintained.
An arrow on the sidewall of the tire indicates
its correct direction of rotation.
You may mount a spare wheel/emergency
spare wheel against the direction of rotation.
Observe the time restriction on use as well as
the speed limit specified on the spare wheel/
emergency spare wheel.
Storing wheels
Store wheels that are not being used in a cool,
dry and preferably dark place. Protect the
tires from oil, grease, gasoline and diesel.
Cleaning the wheels
GWARNING
Do not use power washers with circular-jet
nozzles (dirt grinders) to clean your vehicle, in
particular the tires. You could otherwise
damage the tires and cause an accident.
Wheel and tire combinations
Please bear the following in mind
! For safety reasons, Mercedes-Benz
recommends that you only use Tires and
wheels which have been approved by
Mercedes-Benz specifically for your
vehicle.
These tires have been specially adapted for
use with the control systems, such as ABS
or ESP ®
, and are marked as follows:
R MO = Mercedes-Benz Original
R MOE = Mercedes-Benz Original Extended
(tires featuring run-flat characteristics)
R MO1 = Mercedes-Benz Original (only
certain AMG tires)
Mercedes-Benz Original Extended tires
may only be used on wheels that have been
specifically approved by Mercedes-Benz.
Only use tires, wheels or accessories
tested and approved by Mercedes-Benz.
Certain characteristics, e.g. handling,
vehicle noise emissions or fuel
consumption, may otherwise be adversely
affected. In addition, when driving with a
load, tire dimension variations could cause
the tires to come into contact with the
bodywork and axle components. This could
result in damage to the tires or the vehicle.
Mercedes-Benz accepts no liability for
damage resulting from the use of tires,
wheels or accessories other than those
tested and approved.
Further information about tires, wheels and
approved combinations can be obtained
from any authorized Mercedes-Benz
Center.
i The Tire and Load Information placard
with the recommended tire pressures is
attached to the B-pillar on the driver's side.
Further information about driving at high
speeds or driving with vehicle loads that are
lighter than the maximum vehicle load can
be found in the tire pressure table on the
inside of the fuel filler flap. Check tire
pressures regularly, and only when the tires
are cold. Comply with the maintenance
recommendations of the tire manufacturer
in the vehicle document wallet.514Wheel and tire combinationsWheels and tires

iThe data shown on the identification plate
is example data. This data is different for
every vehicle and can deviate from the data
shown here. You can find the data
applicable to your vehicle on the vehicle's
identification plate.
Vehicle identification number (VIN)
The vehicle identification number (VIN) can
be found in the following locations:
R on the vehicle identification plate
( Y page 521)
R at the lower edge of the windshield
( Y page 522)
In addition to being stamped on the vehicle
identification plate, the vehicle identification
number (VIN) is also stamped onto the vehicle
body. It is under the trim behind the rear seat
armrest.
XFold down the rear seat armrest.XOpen the trim.
You will see vehicle identification number
(VIN) :.Engine number:Emission control information plate,
including the certification of both federal
and Californian emissions standards;Engine number (stamped into the
crankcase)=VIN (on the lower edge of the windshield)
Service products and capacities
Important safety notes
Service products include the following:
R fuels (e.g. gasoline, diesel)
R additives for exhaust gas aftertreatment
(DEF)
R lubricants (e.g. engine oil, transmission oil)
R coolant
R brake fluid
R windshield washer fluid
Vehicle components and their respective
lubricants must match. You should therefore
only use products that have been tested and
approved by Mercedes-Benz.
Information on tested and approved products
can be obtained at a Mercedes-Benz Center
or on the Internet at http://
www.mbusa.com (USA only).
GWARNING
Comply with all valid regulations with respect
to handling, storing and disposing of service
fluids. Otherwise, you could endanger
persons or the environment.
522Service products and capacitiesTechnical data

CapacitiesModelCapacityFuel, coolant,
lubricants, etc.Engine oil and
filterS 550 34
S 550 4MATIC 34
S 63 AMG9.0 US qt (8.5 l)Approved engine
oilsS 600
S 65 AMG9.5 US qt (9.0 l)S 350 BlueTEC
4MATIC8.5 US qt (8.0 l)Cooling systemS 550 34
S 550 4MATIC 34Approximately 14.5 US qt
(13.7 l)MB 325.0 or
MB 326.0
anticorrosion/
antifreezeS 600Approximately 15.3 US qt
(14.5 l)S 63 AMGApproximately 12.2 US qt
(11.5 l)S 65 AMGApproximately 14.7 US qt
(13.9 l)S 350 BlueTEC
4MATICApproximately 12.0 US qt
(11.4 l)Tank capacityS 550 34
S 550 4MATIC 34
S 350 BlueTEC
4MATIC21.9 US gal (83.0 l)Gasoline engines:
premium-grade
unleaded gasoline
(at least 91 octane,
average value
between 96 RON/
86 MON)
Diesel engines:
ULTRA-LOW
SULFUR HIGHWAY
DIESEL FUEL (ULSD,
maximum sulfur
content 15 ppm)S 600
S 63 AMG
S 65 AMG23.8 US gal (90.0 l)ReserveAll models except
AMG vehicles2.9 US gal (11.0 l)AMG vehicles3.7 US gal (14.0 l)34 BlueEFFICIENCY.524Service products and capacitiesTechnical data

RIPA
R TBA
For MTBE, the concentration should not
exceed 15%.
The concentration of methanol in gasoline
including other additives must not exceed 3%.
Using mixtures of methanol and ethanol is not
permitted. Gasohol, a mixture of 10% ethanol
and 90% unleaded gasoline, can be used.
All of these mix fuels must fulfill the fuel
requirements, e.g.:
R knock resistance
R boiling point
R vapor pressure
Diesel engines – important safety notes
! Only use commercially available ULTRA-
LOW SULFUR DIESEL FUEL (ULSD, 15 ppm
MAXIMUM SULFUR) that meets the
ASTM D975 standard. Failure to use
ULTRA-LOW SULFUR DIESEL FUEL (ULSD)
can severely damage the vehicle's exhaust
gas aftertreatment system.
! Do not fill the tank with gasoline. Do not
blend diesel fuel with gasoline or kerosene.
Otherwise, the fuel system and the engine
could be damaged.
To prevent malfunctions, diesel fuel with
improved flow characteristics is available in
the winter months. Check with your gas
station.
Information on the fuel grade can usually be
found on the gas pump. If the information
cannot be found on the gas pump, ask the gas
station personnel. For further information,
consult an authorized Mercedes-Benz Center
or go to the Internet site
http://www.mbusa.com (USA only).
Diesel engines – fuels containing
biodiesel (FAME [fatty acid methyl ester])
Mercedes-Benz USA approves the use of B5
(ULSD with a maximum of up to five percent
by volume biodiesel) for all diesel engineswith common rail direct injection (CDI) and
BlueTEC.
Pure biodiesel and diesel fuels that have a
higher percentage of biodiesel, e.g. B20, can
damage the fuel system and the engine and
are therefore not approved.
For further information, please ask the gas
station personnel. The label on the gas pump
must indicate clearly that the B5 biodiesel
blend fulfills the ULSD standard. If the label
is not clear, do not refuel the vehicle.
Do not refuel your vehicle with fuels unless
they have been approved by Mercedes-Benz.
Additives in gasoline
One of the main problems of poor fuel quality
is the forming of deposits that are caused
during the gasoline combustion process.
Mercedes-Benz recommends that you use
fuel brands that have the additives.
If you use fuels without these additives for an
extended period of time, there may be a
buildup of carbon deposits, especially on the
inlet valves and in the combustion chamber.
This could lead to engine problems, e.g.:
R longer engine warm-up phase
R uneven idle
R engine noise
R misfiring
R loss of power
Carbon deposits may form if the availability
of gasoline with relevant additives is
insufficient (in certain regions). In this case,
Mercedes-Benz recommends the use of
additives that have been approved for
Mercedes-Benz vehicles.
Consult an authorized Mercedes-Benz Center
or go to the Internet site
http://www.mbusa.com (USA only) for a list
of approved products. Observe the
instructions for use on the product label.
Do not mix other fuel additives with fuel. This
causes unnecessary costs and could damage
the engine.
526Service products and capacitiesTechnical data

! Do not refuel with low-grade fuel and do
not use fuel additives that are not tested
and approved for Mercedes-Benz vehicles.
Damage to or malfunctions of the fuel
system may otherwise occur.
DEF
Important safety notes
i For BlueTEC vehicles only.
DEF is a non-flammable, non-toxic, colorless,
odorless and water-soluble fluid.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF
residues crystallize after time and
contaminate the affected surfaces.
High outside temperatures
If DEF heats up to over 122 ‡ (50 †) for
extended periods, e.g. as a result of direct
sunlight on the DEF reservoir, DEF can
decompose. Ammonia vapors develop as a
result.
GWARNING
When opening the filler cap of the DEF tank
ammonia gas vapors may escape. Refill DEF
in a well ventilated area only. Ammonia gas
vapors have a pungent odor and are
particularly irritating for your skin, mucous
membranes, and eyes. Inhaling ammonia gas
vapors will cause burning eyes, nose, and
throat, as well as coughing and watering eyes.
Low outside temperatures
DEF freezes at a temperature of
approximately 12 ‡ (–11 †). The vehicle is
equipped with a DEF preheating system when
it leaves the factory. Winter operation is
therefore also guaranteed at temperatures
below 12 ‡ (–11 †).
Additives
! Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity
Assuring the purity of DEF is particularly
important with respect to avoiding
malfunctions in the exhaust gas
aftertreatment system.
If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
! Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC exhaust gas
aftertreatment system
Engine oil
Please bear the following in mind
The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz Center
or go to the Internet site
http://www.mbusa.com (USA only).
! Never use engine oil or an oil filter of a
specification other than is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
Service products and capacities527Technical dataZ

intervals than those prescribed. You could
otherwise cause engine damage or damage
to the exhaust gas aftertreatment.
Follow the instructions in the service
interval display regarding the oil change.
Otherwise, you may damage the engine and
the exhaust gas aftertreatment.
The table shows which engine oils have been
approved for your vehicle.ModelEngine
modelMB
ApprovalS 550 36
S 550 4MATIC 36278229.5S 600275S 63 AMG157229.537S 65 AMG275S 350 BlueTEC
4MATIC642228.51,
229.31,
229.51
i MB approval is indicated on the oil
containers.
Additives
! Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity
Viscosity describes the flow characteristics
of a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE (viscosity)
classification suitable for the prevailing
outside temperatures. The following table
shows the correct SAE classification to be
used. The low-temperature characteristics of
engine oils can deteriorate significantly, e.g.
as a result of aging, soot and fuel deposits. It
is therefore strongly recommended that you
carry out regular oil changes using an
approved engine oil with the appropriate SAE
classification.
Refrigerant of the air-conditioning
system
The air-conditioning system is filled with
R134a refrigerant and a special PAG
lubricant.
! Never use refrigerant R 12 (CFC) or
mineral lubricants. Otherwise, you could
damage the air-conditioning system.
Brake fluid
GWARNING
Over a period of time, the brake fluid absorbs
moisture from the air; this lowers its boiling
point.
If the boiling point of the brake fluid is too low,
vapor pockets may form in the brake system
when the brakes are applied hard (e.g. when
driving downhill). This would impair braking
efficiency.
You should have the brake fluid renewed at
regular intervals. The brake fluid change
intervals can be found in the Service Booklet.
Only use brake fluid approved by Mercedes-
Benz. Information about approved brake
36 BlueEFFICIENCY
37 Restriction: only SAE 0W-40 or SAE 5W-40 engine oils may be used.528Service products and capacitiesTechnical data