Off-road driving .............................. 166
Off- roadfording ............................. 164
Running-i ntips ............................... 138
Sno wchains .................................. 358
Symmetrical di pped bea m............. 106
To wing atrailer .............................. 226
Travelling uphill .............................. 168
Tyr egrip ........................................ 164
Tyr eruts ........................................ 168
We troad surf ace. .......................... 163
DSR (Downhi llSpeed Regulation)
Display message ............................ 271
Function/notes ............................. 220
DVD audio (on-b oard computer) ......242 E
EASY- ENTRY feature
Activating/deactivating .................251
Function/notes ................................ 99
EASY- EXIT feature
Crash-responsive ........................... 100
Function/notes ................................ 99
Switch ingo n/off ........................... 251
EASY- PACK load-securing kit ........... 303
EBD (electronic brake force distri-
buti on)
Disp laym essage ............................ 256
Function/notes ................................ 65
EC Os tart/stop function
Deactivating/activating .................143
Gen eral information ....................... 142
Electri calfuses
se eF uses
Electroni cbrake force distribution
see EBD (electronic brake force
distribution)
Electroni cStability Program
see ESP ®
(Electroni cStability Program)
Electronic Tracti onSystem
se e4 ETS (Electroni cTracti onSystem)
Emergenc ykey
Unlocking the driver's door ..............79
Emergency key element
Function/notes ................................ 74
Locking veh icle ................................ 79
Emergency rel ease
Driver's door .................................... 79Emergency spar
ewheel
Notes/d ata. ................................... 366
Storage locatio n............................ 334
Emergency unl ocking
Ta ilgate ............................................ 82
Veh icle ............................................ .79
Engine
Display message ............................ 266
ECO start/stop function ................142
Emergency starting ........................352
Engine numb er............................... 373
Running irregularl y......................... 144
Starting pro blems .......................... 144
Starting the engine wit hthe key ....140
Starting with KEYLESS GO .............140
Stopp ing. ....................................... 160
Warn ingl am p(engine diagnos-
tics) ............................................... 290
En gine electronics
Notes ............................................. 371
Problem (fault) ............................... 144
En gine oil
Additives ........................................ 376
Checking the oil level ...... ............... 320
Checking the oil leve lusing the
dipstick .......................................... 320
Display message ............................ 267
Fil ling capacity ............................... 376
Note sabout oil grades ...... ............. 375
Notes on oil level/cons umption.... 320
Topping up ..................................... 320
Viscosity ........................................ 376
En vironmental protection
Note ................................................ .22
Retur ningan end-of-life vehicl e....... 22
ESP ®
(Electronic Stability Pro-
gram) 4ETS ................................................ 64
Deactivating/activating ...................64
Display message ............................ 254
Function/notes ................................ 63
Important safety gu idelines ............. 63
Traile rstabilisatio n.......................... 65
Warn ingl am p................................. 288
Exterior lighting
seeL ights 10
Index
R
M85 (petrol with 85 %methanol)
R M10 0(100% methanol)
R Petrol wit hmetallic additives
R Diesel
Do not mix fuel ssuch as this with petrol
and do not use any additives. Doing so may
cause engine damage. This does not
include additives for the removal and pre-
vention of residue build-up. Petrol must
only be mixed with additives recommended
by Mercedes-Benz. More information about
recommended additives can be obtained
from any Mercedes-Ben zService Centre.
! Use afilter when adding fuel from afuel
can. The fuel lines and/or the diesel injec-
tion system could otherwis ebeblocked by
particles from the fuel can.
i E10 fuel contains up to 10% bioethanol.
Your vehicle is E10 compatible. You can
refuel your vehicle using E10 premium-
grade petrol.
i If the recommended fuel is not available,
but only as atemporary measure, you may
also use regula runleaded petrol,
91 RON/82.5 MON. Thi smay reduce
engine performance and increase fuel con-
sumption. Avoid driving at full throttle.
In some countries, the fuel grade available
may not be adequate and could cause
deposits to build up. In consultation with a
Mercedes-Ben zService Cent re,this petrol
ma ybem ixed with the additive recommen-
ded by Mercedes-Ben z(part no.
A0009 89254510). Yo umust observe the
notes and mixin gratios specified on the
container.
For further information on "Fuel", see
(Y page 374). !
Only refuel using unleaded, sulphur-free
premium-grade petrol with at least
95 RON/85 MON, which conform stoEuro- pean standar
dEN2 28or an equivalent
specifi cation.
You can otherwise impair engine output or
damage the emission contro lsystem.
i In some countries, the available petrol
may not be sufficiently low in sulphur. This
fuel can temporarily produce unpleasant
odours, especially on short journeys. As
soo nassulphur-free fuel (sulphur content
<10p pm) is used for refuelling, the odours
are reduced. Diesel (EN 590)
Fuel grade !
When refuelling, only use diesel fuel that
confor ms to th eEuropean standard EN 590
or is of equivalent quality. You can other-
wise impair engine output or damage the
engine.
! Vehicles with diesel particle filters: in
countries outsid ethe EU ,only use low sul-
phu rEuro diesel with asulphu rcontent of
under 50 ppm. Otherwise, the emission
con trol system coul dbedamaged.
! Vehicles without adiesel particle fil-
ter: in countries where only diesel fuels
with ahigher sulphur conten tare avail able,
the vehicle's oil change intervals are
shorter. More information about intervals
for changing the oil can be obtained from
any Mercedes-Benz Service Centre.
! Only use fuel that complies with the EN
590 European standard. Fuel that does not
compl ywithEN5 90can lea dtoincreased
wear, engin edamag eand damage to the
exhaust system.
Do not use the following:
R marine diesel
R heating oil
R bio-diesel
R vegetable oil
R petrol Refuelling
153Drivingand park ing Z
ML 350 4MATIC
R
paraffin
R kerosene
Do not mix these fuels with diesel fuels and
do not use any special additives. Other-
wise, this can lead to damage to the engine.
This excludes flow improver ;see "Low out-
side temperatures".
! Use afilter when adding fuel from afuel
can. Otherwise, the fuel lines and/or the
diesel injection system could be blocked by
particles from the fuel can.
For further information on "Fuel", see
(Y page 374).
Low outsid etemperatures Diesel fuel with improved cold flow qualities
is available during the winter months. In
Europe, various climate-dependent low-tem-
peratur eclasses are defined in EN 590 .Refu-
elling with diesel fuel which complies with the
climatic specification sofstandard EN 590
can hel ptoprevent operatin gproblems. At
exceptionall ylow tempera tures, it is possible
that the flow properties of the fuel ma ybe
inadequate. This also applies to fuel that has
not been adapted to suit the climatic condi-
tions, e.g. diesel fuel from warmer regions.
i Further information about country-spe-
cific fuel properties can be obtained from
oil companies, e.g. at filling stations.
Flow improver Flow improvers can be added to improv
ethe
cold resistan ceof diesel fuel. The effective-
ness of aflow improver is not guaranteed with
every diesel fuel.
Correc tdosage and thorough mixing ar edeci-
sive factor sinensuring improvement in low-
temperature resistance. Avoid excessive dos-
age .Exce ssiv edosage ma yactuall ydecrease
low-temperature resistanc eunder certain cir-
cumstances. Follo wthe manufacturer's dos-
ing inst ructions. Mix the additive with the diese
ling ood time,
befor ethe flo wproperties of th ediesel
become inadequate. Malfunction scan other-
wise only be rectified by heating the entire
fuel system, e.g. by parking the vehicle in a
heated garage.
Observe the information provided by the man-
ufacturer when using aflow improver. Only
use flow improvers that have been tested and
approved by Mercedes-Benz. You can obtain
further information from any Mercedes-Benz
Servic eCentre. Refuelling
Fuel filler flap The fuel filler fla
pisunlocke dorlockedauto-
matically when you open or close the vehicle
with the key or using KEYLESS-GO.
The position of the fuel filler cap is displayed
in the instrument cluster 8.The arrow
nex ttot he filling pum pindicate sthe side of
the vehicle. :
To open the fuel filler flap
; To inser tthe fuel filler cap
= Fue ltype
? Tyre pressure table
Opening X
Switch off the engine.
X Remove the key from the ignitio nlock. 154
RefuellingDriving and parking
AdBlue
®
Important notes on use To function properly, BlueTE
Cexhaust gas
aftertreatmen tmust be ope rated with the
reducin gagen tAdBlue ®
.
When the supply of AdBlue ®
is almost used
up, the Refill AdBlue See Owner's Man‐
ual message is shown in the multifunction
display.
When the AdBlue ®
supply drops to amini-
mum ,the Refill AdBlue No star tinXXXX km message is show
ninthe multifunc-
tion display.
If the Refill AdBlue No star tinXXXX km message is show
ninthe multifunction dis-
play ,you can still drive the vehicle over the
distance shown. If the AdBlue ®
is not topped
up, you will subsequen tlybeu nable to start
the engi ne.R efill the AdBlue ®
tank or have
the AdBlue ®
tank refilled at aqualified spe-
cialist workshop. If the Refill AdBlueEng. star
tnot possible message
appears in th emultifunction display and the
engine does not start ,you must top up with
at least 3. 8lAdBlue ®
(approximately 2
AdBlue ®
refill bottles).
i If you drive the vehicl efaster than
15 km/h, the Refill AdBlue Se eOwn‐ er's Manual message goes ou
tafter
approximately one minute.
Further info rmation about BlueTEC exhaust
gas aftertreatment and about AdBlue ®
can
be obtained from any Mercedes-Benz Service
Centre. Topping up AdBlue
® G
WARNING
AdBlue ®
must not come int ocontac twith
skin ,eyes or clothing.
R If AdBlue ®
comes into contact with your
eyes or skin, rinse affected areas with clean
water immediately.
R If AdBlue ®
is swallowed ,immediatel yrinse
your mouth out with alot of clea nwater and
drink plenty of water.
R Change clothing that is soile dwith
AdBlue ®
immediately.
R If allergic reactions occur, consult adoctor
immediately.
Keep AdBlue ®
out of the reach of children. G
WAR
NING
If you ope nthe AdBlue ®
tan kcap, small
amount sofammonia vapou rmay be released.
This depends in particular upon the age of the
AdBlue ®
.
Ammonia vapours have apungent odour and
are particularly irritating to:
R skin
R mucous membranes
R eyes
You may experienc eaburnin gsensation in
your eyes, nose and throat, as well as cough-
ing and waterin gofthe eyes.
Do not inhale any ammonia vapour sthat may
be released. Fil lthe AdBlue ®
tan konly in well-
ventilate dareas.
! Only us eAdBlue ®
in accordanc ewith
ISO 22241. Do not mix any additives with
AdBlue ®
,a nd do not dilute AdBlue ®
with
water. Thi smay destroy the BlueTEC
exhaust gas aftertreatment system.
! In order to fill the AdBlue ®
tank ,the vehi-
cle must be parked on alevel surface. The
AdBlue ®
tank can only be filled as intended
with the vehicle parked on alevel surface.
Fluc tuations in capacit ywill thus be avoi- Refuelling
157Drivingand park ing Z
?
Vehicl eidentification number (VIN)
A Maximum permissible gross vehicle
weight
B Gross combination mass
C Maximum permissible front axle load
D Maximum permissible rear axle load
E Paint code Vehicle identification number (VIN)
In addition to being stamped on the vehicle
identification plate, the vehicle identification
number (VIN) is also stamped onto the vehicle
body. It is located in the lower part of the
right-han dA-pillar. X
Ope nthe front right-hand door.
X Open cover :in the direction of the arrow
and remove it.
You will see the vehicle identification num-
ber (VIN). Engine number
The engin enumber is stamped into the crank-
case. More information can be obtained from
any Mercedes-Benz Service Centre. Service products and capacities
Important safety notes
Service products include the following:
R fuels (e.g. petrol, diesel)
R additives for exhaust gas aftertreatment
(AdBlue ®
)
R lubricants (e.g. engine oil, transmission oil)
R coolant
R brake fluid
R windscreen washe rfluid
Vehicle component sand thei rrespective
lubricants must match. Mercedes-Ben zrec-
ommends that you use products that have
been tested and specially approved by
Mercedes-Ben z.These product sare listed in
this Mercedes-Be nzOwner's Manual in the
relevant section.
You can recognise service product sapproved
by Mercedes-Ben zbythe fol lowinginscrip-
tion on the cont ainers:
R MB-Freigabe (e.g. MB-Freigabe 229.51)
R MB Approva l(e.g. MB Approval 229.51)
Other designation sorrecommendations
relat etoal evel of qualit yoras pecification in
accordance wit hanMBSheet number (such
as MB 229.5). They hav enot necessaril ybeen
approved by Mercedes-Benz.
You can obtain further information from any
Mercedes-Benz Ser vice Centre. G
WARNING
Whe nhandling, storing and disposing of any
servic eproducts, please observe th erelevant
regulations, as you could otherwise endanger
yourself and others.
Keep servic eproducts awa yfrom children.
To protect your health ,donot allow service
products to com einto contact with your eyes
or ope nwounds. See adoctor immediately if
any service product is swallowed. H
Environmental note
Dispose of service products in an environ-
men tally-responsible manner. Service products and capacities
373Technicaldata Z
AdBlue
®
residue crystallises afte racertain
amount of time and soils the affecte dsur-
faces.
Hig houtside temperatures If AdBlue
®
is heate dtoabove 50 †for an
extended perio doftime,AdBlue ®
may start
to decom pose,e .g.d ue to direc tsunlight on
the AdBlue ®
tank. Ammonia vapour sdevelop
as aresult. G
WARNING
Ammonia vapours may escape if the
AdBlue ®
tan kcap is opened at high tempera-
tures. Ammonia vapours have apungent
odour and are particularly irritating to the
skin, to mucous membranes and to the eyes.
You may experienc eaburning sensation in
your eyes, nose and throat ,aswell as cough-
ing and waterin goftheeyes.
Do no tinhale ammoni avapours.
Lo wo utside temperatures AdBlue
®
freezes at atemperatur eofapp rox-
imatel y–11 †. Th evehicle is equip pedw ith
an AdBlue ®
preheating system at the factory.
Winter operatio ncan thus be guaranteed
even at temperatures below –11 †.
Additives !
Only use AdBlue ®
in accordan cewit hISO
22241. Do not us eadditives wit hAdBlue ®
an ddon ot dilute AdBlue ®
with water. This
may destroy th eBlueTEC exhaust gas after-
treatmen tsystem.
Purity Assuring the purity of AdBlue
®
is particularly
important with respect to avoiding malfunc-
tions in the exhaus tgas aftertreatment sys-
tem.
If AdBlue ®
is pumped out of the AdBlue ®
tank,
e.g. during repair work, do not use this fluid to refill the tank
.The purity of the fluid can no
longer be guaranteed.
! Impuritie sinAdBlue ®
(e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R ®
exhaust
Tota lcapacity of the AdBlue ®
tank Model Total
capacity 27.5 l
Engine oil
Th
eq uality of engine oils is decisive for the
function and service life of an engine. After
extensive tests, Mercedes-Benz approves
engine oils that correspond to the current
technical standard.
Therefore, only Mercedes-Benz approved
engine oils may be used in Mercedes-Benz
engines.
Further information on tested and approved
engine oils can be obtained from any
Mercedes-Benz Service Centre. Mercedes-
Benz recommends that you have the oil
change carried out at aMercedes-Benz
Ser vice Centre. Mercedes-Ben zapproval is
indicated on the oil container by the inscrip-
tion "MB Approval" and the cor respondi ng
designation, e.g. MB Approval 22 9.51.
Th et able shows which engine oils have been
approved for your vehicle. Petrol engines MB Approval
M3
50 4MATIC 22
9.3, 229.5 Servic
eproducts and capacities
375Technicaldata Z
malfunctions in the BlueTEC
gas aftertreatment system
ML 250 BlueTEC 4MATIC
Please bear the following in mind ML
350 BlueTEC 4MATIC
Diesel engines MB Approval
228.51,
229.31 ,229.51 engine oils on the Interne
tat
http:/ /bevo. mercedes -benz.com by enter-
ing the designation, e.g. 22 9.5.
i If the engine oils listed in the table are not
available ,you ma yadd the followin gengine
oil su ntil the next oil change:
R vehi cles with apetrol engine: MB
Approval 22 9.1orA CEAA3
R vehicles wit hadiesel engine: MB
Approval 229.1 or ACE AC3
Engine oil may only be adde donce, and no
mor ethan 1. 0lmay be added.
Capacities The following values refer to an oil change
including the oil filter. Model Capacity
7.0 l
7.8 l
8.0 l
Additives
!
Do not use additive sinengine oil .This
could damage the engine.
Engine oil viscosity Viscosit
ydescribes the flow characteristi cs
of afluid. If an engin eoil has ahigh viscosity
rating, it flows slowly; the lower the viscosity,
the faster it flows.
Engine oil selection is based on the respective
outside temperatures and in accordance with
the SA Eclassification (viscosity). The table
below shows you which SA Eclassifications are to be used. The low-temperature proper-
ties of engin eoils can be significantly
impaired durin goperation due to, for exam-
ple, ageing or soot and fuel accretion. It is
therefore strongly recommende dtoobserve
regula roil changes using an approved engine
oil with the appropriate SA Eclassification. Brake fluid
G
WAR
NING
Over aperiod of time, the brak efluid absorbs
moisture fro mthe air ;This lower sits boiling
point.
If the boiling point of the brake fluid is too low,
vapour pockets may form in the brake system
when the brakes are applied hard (e.g. when
driving downhill). Thi simpairs brakin geffi-
ciency.
Yo us hould hav ethe brake fluid renewed at
regular intervals. The brake fluid change inter-
vals can be found in the Servic eBooklet.
Only use brak efluid approved by Mercedes-
Benz .Information abou tapproved brak eflu-
ids can be obtained from any Mercedes-Benz
Service Centr eoronthe Internet at
http://bevo. mercedes-benz.com
i There is usuall yanoticeint he engine
compartmen ttoremin dyou when the next
brake fluid change is due. 376
Service products and capacitiesTechnical data
You can cal
lupanoverview of ap proved
ML
350 BlueTEC 4MATIC
Vehicles wit
hadiesel particle filter
ML 250 BlueTEC 4MATIC
ML 350 4MATIC
ML 350 BlueTEC 4MATIC
ML
250 BlueTEC 4MATIC