Battery fluid contains sulfuric acid. Do not
allow this fluid to come in contact with eyes,
skin or clothing. In case it does, immediately
flush affected area with water and seek
medical help if necessary.
A battery will also produce hydrogen gas,
which is flammable and explosive. Keep
flames or sparks away from battery, avoid
improper connection of jumper cables,
smoking etc.GWarning!
Do not place metal objects on the battery as
this could result in a short circuit.
Use leak-proof batteries only to avoid the risk
of acid burns in the event of an accident.
Take care that you do not become statically
charged, e.g. by wearing synthetic clothing or
rubbing against textiles. For this reason, you
also should not pull or push the battery over
carpets or other synthetic materials.
Never touch the battery first. First touch the
outside body of the vehicle in order to release
any possible electrostatic charges.
Do not rub the battery with rags or cloths. The
battery could explode if touched due to
electrostatic charge or due to spark
formation.
! The battery is a
Valve-Regulated Lead
Acid (VRLA) battery, also referred to as
“fleece” battery.
Such batteries do not require topping-up of
the electrolyte level. VRLA batteries
therefore do not have cell caps and the
battery cover is non-removable. Do not
attempt to open the battery as otherwise
the battery will be damaged.
VRLA batteries do not require topping-up of
the electrolyte level. They cannot be
opened to check the electrolyte level.
However, the battery condition must be
checked periodically by performing a
battery conductance test. Refer to
Maintenance Booklet for battery condition
testing intervals.
The factory-equipped battery may only be
replaced with a battery that
R has the same security features
R is of identical size
R is of identical voltage
R is of identical capacity
! As any other battery, the battery may
discharge if you do not operate the vehicle
for an extended period of time. Have the
battery disconnected at a qualified
workshop or an authorized Mercedes-Benz
Center in such a case. You may also
connect an accessory battery charge unit
expressly approved by Mercedes-Benz for
your vehicle model to maintain the battery
charge. Contact an authorized Mercedes-
Benz Center for further information.
The battery, the battery ventilation hose
and the lateral plug must always be
securely installed when the vehicle is in
operation.
! Never loosen or detach battery terminal
clamps while the engine is running or the
SmartKey is in the starter switch or
KEYLESS-GO button is in position 1.
Otherwise the alternator and other
electronic components could be severely
damaged.
Have the battery checked regularly at an
authorized Mercedes-Benz Center.
Refer to Maintenance Booklet for
maintenance intervals or contact an
authorized Mercedes-Benz Center for
further information.
i After battery power was interrupted, do
the following:
R Set the clock ( Y page 132).
Vehicles with COMAND system with
navigation module: Time and date are set
automatically.
R Synchronize the door windows
( Y page 102).Battery335Practical hints164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 335Z
Vehicle equipment
iThis Operator’s Manual describes all
features, standard or optional, potentially
available for your vehicle at the time of
purchase. Please be aware that your
vehicle might not be equipped with all
features described in this manual.
Parts service
All authorized Mercedes-Benz Centers
maintain a stock of Genuine Mercedes-Benz
Parts required for maintenance and repair
work. In addition, strategically located parts
distribution centers provide quick and
reliable parts service.
More than 300 000 different parts for
Mercedes-Benz models are available.
Genuine Mercedes-Benz Parts are subjected
to stringent quality inspections. Each part has
been specifically developed, manufactured or
selected for and adapted to Mercedes-Benz
vehicles.
Therefore, Genuine Mercedes-Benz Parts
should be installed.
! Do not use non-genuine Mercedes-Benz
parts and accessories not authorized by
Mercedes-Benz. Doing so could damage
the vehicle, which is not covered by the
Mercedes-Benz Limited Warranty. Also, it
could compromise the vehicle’s durability
or safety.
Warranty coverage
Your vehicle is covered under the terms of the
warranties printed in the Service and
Warranty Information booklet.
Your authorized Mercedes-Benz Center will
exchange or repair any defective parts
originally installed in the vehicle in
accordance with the terms of the following
warranties:RNew Vehicle Limited Warranty
REmission System Warranty
REmission Performance Warranty
RCalifornia, Connecticut, Maine,
Massachusetts, New York, Pennsylvania,
Rhode Island, and Vermont Emission
Control Systems Warranty33
RState Warranty Enforcement Laws (Lemon
Laws)
Replacement parts and accessories are
covered by the Mercedes-Benz Parts and
Accessories warranties, copies of which are
available at any authorized Mercedes-Benz
Center.
Loss of Service and Warranty
Information booklet
Should you lose your Service and Warranty
Information booklet, have an authorized
Mercedes-Benz Center arrange for a
replacement. It will be mailed to you.
Identification labels
33Applicable to vehicles with gasoline engine only.346Identification labelsTechnical data
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Rpoor handling characteristics
R increased noise
R increased fuel consumption
Moreover, tires and rims not approved by
Mercedes-Benz may, under load, exhibit
dimensional variations and different tire
deformation characteristics that could
cause them to come into contact with the
vehicle body or axle parts. Damage to the
tires or the vehicle may be the result.
i Further information on tires and rims is
available at any authorized Mercedes-Benz
Center. The Tire and Loading Information
placard with the recommended tire
inflation pressures for cold tires is located
on the driver’s door B-pillar. Supplemental
tire inflation pressure information for
driving at high speeds or for vehicle loads
less than the maximum loaded vehicle
condition can be found on the tire inflation
pressure label. The tire inflation pressure
label is located on the inside of the fuel filler
flap. The tire inflation pressure should be
checked regularly and should only be
adjusted on cold tires. Follow tire
manufacturer’s maintenance
recommendation included with the vehicle.
For information on recommended tire
inflation pressure and supplemental tire
inflation pressure information for special
driving situations, see ( Y page 219).
i Please keep in mind that the vehicle must
be equipped
R with wheels of identical dimensions on
each axle (left and right)
R with tires of identical characteristics all
around, i.e. summer tires, winter tires,
all-season tires, or MOExtended tires etc.
i The following pages also list the approved
rim and tire sizes for equipping your vehicle
with winter tires. Winter tires are not
available as standard or optional factoryequipment, but can be purchased from an
authorized Mercedes-Benz Center.
Equipping your vehicle with winter tires
approved for your vehicle model may
require the purchase of rims of the
recommended size for use with these
winter tires. This depends on vehicle model
and the standard or optional factory-
equipped wheel rim/tire configuration on
your vehicle. For more information contact
an authorized Mercedes-Benz Center.Rims and tires353Technical data164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 353Z
Approved engine oils
Engine oils are specifically tested for their
suitability in our engines and durability for our
service intervals. Therefore, only use
approved engine oils and oil filters required
for vehicles with the Maintenance System.
For a listing of approved engine oils and oil
filters, contact an authorized Mercedes-Benz
Center or visit www.mbusa.com (USA only).
! Using engine oils and oil filters of a
specification other than those expressly
required for the Maintenance System, or
changing of oil and oil filter at change
intervals longer than those called for by the
Maintenance System will result in engine or
emission control system damage not
covered by the Mercedes-Benz Limited
Warranty.
Please follow Maintenance System
recommendations for scheduled oil
changes. Failure to do so will result in
engine or emission control system damage
not covered by the Mercedes-Benz Limited
Warranty.
Mercedes-Benz recommends MOBIL OIL.
Use the table below to determine the
MB sheet number.
ModelEngine,
type
MB sheet
number
ML 350 BlueTEC
4MATIC
642229.51ML 350 4MATIC272229.5ML 350272229.3/
229.5
ML 550 4MATIC273229.5ML 63 AMG156229.562
iMB sheet numbers are printed on the
outside of oil containers.
Viscosity grades for engine oils
Using the chart below, select oil viscosity
according to the lowest air temperature
expected before the next oil change.
Engine oil additives
! Do not blend oil additives with engine oil.
They may damage the engine. Damage or
malfunctions resulting from blending oil
additives are not covered by the Mercedes-
Benz Limited Warranty.
Air conditioning refrigerant
R134a (HFC) refrigerant and special PAG
lubricating oil are used in the air conditioning
system.
! Never use R 12 (CFC) or mineral-based
lubricating oil. Otherwise damage to the
system will occur.
Brake fluid
GWarning!
During vehicle operation, the boiling point of
the brake fluid is continuously reduced
through the absorption of moisture from the
atmosphere.
Under extremely strenuous operating
conditions, this moisture content can lead to
62Restriction: Only SAE 0W-40/SAE 5W-40 engine oils may be used.Fuels, coolants, lubricants, etc.359Technical data164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 359Z
the formation of bubbles in the system, thus
reducing the system’s efficiency.
Therefore, the brake fluid must be replaced
regularly. Refer to your vehicle’s Maintenance
Booklet for replacement interval.
Only brake fluid approved by Mercedes-Benz
is recommended. Any authorized Mercedes-
Benz Center will provide you with additional
information.
Premium unleaded gasoline (gasoline
engine)
GWarning!
Gasoline is highly flammable and poisonous.
It burns violently and can cause serious
personal injury.
Never allow sparks, flames or smoking
materials near gasoline!
Turn off the engine before refueling.
Whenever you are around gasoline, avoid
inhaling fumes and any skin or clothing
contact. Extinguish all smoking materials.
Direct skin contact with fuels and the
inhalation of fuel vapors are damaging your
health.
! To maintain the engine’s durability and
performance, premium unleaded gasoline
must be used.
If premium unleaded gasoline is not
available and low octane gasoline is used,
follow these precautions:
R Have the fuel tank only partially filled
with unleaded regular gasoline and fill up
with premium unleaded gasoline as soon
as possible.
R Avoid full throttle driving and abrupt
acceleration.
R Do not exceed an engine speed of
3 000 rpm if the vehicle is loaded with a
light load such as two persons and no
luggage.
R Do not exceed 2
/ 3 of maximum
accelerator pedal position if the vehicle
is fully loaded or operating in
mountainous terrain.
Fuel requirements
Gasoline engine
Only use premium unleaded gasoline. The
octane number (posted at the pump) must be
91 min. It is an average of both the Research
Octane Number (RON) and the Motor Octane
Number (MON): (RON+MON)/2. This is also
known as the ANTI-KNOCK INDEX.
Reformulated gasolines (RFG) and/or
unleaded gasoline containing oxygenates
such as ethanol, TAME, ETBE, IPA, IBA, and
TBA can be used provided the ratio of any one
of these oxygenates to gasoline does not
exceed 10%; MTBE must not exceed 15%.
The ratio of methanol to gasoline must not
exceed 3% plus additional cosolvents.
Using mixtures of ethanol and methanol is not
allowed. Gasohol, which contains 10%
ethanol and 90% unleaded gasoline, can be
used.
These blends must also meet all other fuel
requirements, such as resistance to spark
knock, boiling range, vapor pressure, etc.
Diesel engine
Only use commercially available vehicular
ULTRA-LOW SULFUR HIGHWAY DIESEL FUEL
(ULSD, 15 ppm SULFUR MAXIMUM) that
meets the ASTM D975 standard. Failure to
use ULTRA-LOW SULFUR HIGHWAY DIESEL
FUEL (ULSD) can severely damage the
vehicle’s exhaust after-treatment device.
To prevent malfunctions, diesel fuel with
improved cold flow characteristics is offered
in the winter months. Check with your fuel
retailer.
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vapors may escape when opening the
AdBlue ®
tank.GWarning!
When opening the filler cap of the AdBlue ®
tank ammonia gas vapors may escape. Refill
AdBlue ®
in a well ventilated area only.
Ammonia gas vapors have a pungent odor and
are particularly irritating for your skin,
mucous membranes, and eyes. Inhaling
ammonia gas vapors will cause burning eyes,
nose, and throat, as well as coughing and
watering eyes.
Low ambient temperatures
AdBlue ®
freezes at a temperature of
approximately 12‡ (-11†). Your vehicle is
factory equipped with an AdBlue ®
preheating
system. The vehicle can thus be operated at
temperatures below 12‡ (-11†).
Special additives
! Only use AdBlue ®
complying with
ISO 22241. Do not add additives to
AdBlue ®
and do not dilute AdBlue ®
with
water. Otherwise, the BlueTEC exhaust gas
aftertreatment system could be damaged.
Damage caused by using additives or
diluting with water are not covered by the
Mercedes-Benz Limited Warranty.
Purity
The purity of AdBlue ®
is of particular
importance for avoiding malfunctions in the
exhaust gas aftertreatment.
If AdBlue ®
is pumped out of the tank, e.g.
during repair work, the same liquid must not
be used to refill the tank as its purity is no
longer guaranteed.
! Impurities caused for example by other
service products, cleaning agents, and dust
result in increased emissions,
malfunctions, catalyst damage, or engine
damage.
Coolants
The engine coolant is a mixture of water and
anticorrosion/antifreeze, which provides:
R Corrosion protection
R Freeze protection
R Boiling protection (by increasing the boiling
point)
The cooling system was filled at the factory
with a coolant providing freeze protection to
approximately -35‡ (-37†) and corrosion
protection.
! Add premixed coolant solution only.
Adding water and MB 325.0 Anticorrosion/
Antifreeze separately from each other,
could cause engine damage not covered by
the Mercedes-Benz Limited Warranty.
If the antifreeze mixture is effective to -35‡
(-37† ), the boiling point of the coolant in the
pressurized cooling system is reached at
approximately 266‡ (130†).
The coolant solution must be used year round
to provide the necessary corrosion protection
and increase boil-over protection. Refer to
the Maintenance Booklet for replacement
interval.
Coolant system design and coolant used
determine the replacement interval. The
replacement interval published in the
Maintenance Booklet is only applicable if
MB 325.0 Anticorrosion/Antifreeze solution
or other Mercedes-Benz approved products
of equal specification are used to renew the
coolant concentration or bring it back up to
the proper level.
For information on other Mercedes-Benz
approved products of equal specification,
contact an authorized Mercedes-Benz Center
or visit www.mbusa.com (USA only).
To provide important corrosion protection,
the solution must be at least 50%
anticorrosion/antifreeze (equivalent to
freeze protection to approximately -35‡
[-37†]).362Fuels, coolants, lubricants, etc.Technical data
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