2008 MERCEDES-BENZ C300 octane

12 Introduction
Operator’s Manual
Roadside Assistance
The Mercedes-Benz Roadside Assistance
Program provides factory trained technical
help in the event of a breakdown. Calls to
the toll-free Roadside Assistance number
1-800-FOR-MERCedes (in the USA)
1-800-387-0100 (in Canada)
will be answered by Mercedes-Benz
Customer Assistance Representatives
24 hours a day, 365 days a year.
For additional information refer to the
Mercedes-Benz Roadside Assistance Pro-
gram brochure in your vehicle literature
portfolio.
Change of address or ownership
If you change your address, be sure to
send in the “Change of Address Notice”
found in the Service and Warranty Informa-
tion Booklet, or simply call the
Mercedes-Benz Customer Assistance
Center (in the USA) at
1-800-FOR-MERCedes, or Customer Service (in Canada) at 1-800-387-0100. It
is in your own interest that we can contact
you should the need arise.
If you sell your Mercedes, please leave all
literature with the vehicle to make it avail-
able to the next operator.
If you bought this vehicle used, be sure to
send in the “Notice of Purchase of Used
Car” found in the Service and Warranty In-
formation Booklet, or call the
Mercedes-Benz Customer Assistance Cen-
ter (in the USA) at 1-800-FOR-MERCedes,
or Customer Service (in Canada) at
1-800-387-0100.
Operating your vehicle outside the USA or Canada
If you plan to operate your vehicle in for-
eign countries, please be aware that:

service facilities or replacement parts
may not be readily available,

unleaded gasoline for vehicles with cat-
alytic converters may not be available;
the use of leaded fuels will damage the
catalysts,

gasoline may have a considerably low-
er octane rating, and improper fuel can
cause engine damage.
Certain Mercedes-Benz models are avail-
able for delivery in Europe under our Euro-
pean Delivery Program. For details, consult
your authorized Mercedes-Benz Center or
write to:
In the USA:
Mercedes-Benz USA, LLC
European Delivery Department
One Mercedes Drive
Montvale, NJ 07645-0350
In Canada:
Mercedes-Benz Canada, Inc.
European Delivery Department
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9

322 Operation
At the gas station
Refueling
The fuel filler flap is located on the
right-hand side of the vehicle towards the
rear. Locking and unlocking the vehicle
with the SmartKey or the SmartKey with
KEYLESS-GO* (Canada only) automatically
locks and unlocks the fuel filler flap.1To open fuel filler flap
2To insert fuel filler cap
3Holder
Warning!G
Gasoline is highly flammable and poisonous.
It burns violently and can cause serious per-
sonal injury.
Never allow sparks, flame or smoking mate-
rials near gasoline!
Turn off the engine before refueling.
Whenever you are around gasoline, avoid in-
haling fumes and any skin or clothing con-
tact. Extinguish all smoking materials.
Direct skin contact with fuels and the inha-
lation of fuel vapors can damage your
health.
Warning!G
C 300/C 300 4MATIC/C 300 4MATIC Sport
and 300 Sport (with automatic transmis-
sion*):
Flexible Fuel Vehicles (identified by a label
reading Premium gasoline or E85 only! on
fuel filler flap):
Ethanol fuel (E85) and its vapors are highly
flammable, poisonous and burn easily. Etha-
nol fuel can cause serious injuries if ignited
or if you come into contact with it or inhale
fumes of it. Avoid inhalation of ethanol
fumes and skin contact with ethanol. Extin-
guish all open flames before refueling. Never
smoke or create sparks close to ethanol.
iIn case that the central locking system does
not release the fuel filler flap, or the opening
mechanism is clamping, notify Roadside Assis-
tance or an authorized Mercedes-Benz Center.
iOnly use premium unleaded gasoline with a
minimum Posted Octane Rating of 91 (average
of 96 RON / 86 MON). Information on gasoline
quality can normally be found on the fuel pump.
C 300/C 300 4MATIC/C 300 4MATIC Sport and
300 Sport (with automatic transmission*):
Flexible Fuel Vehicles are identified by a label
reading Premium gasoline or E85 only! on the
fuel filler flap.

465 Technical data
Engine
Engine
ModelC 230 (204.052)1,2
C 230 Sport (204.052)1
C 230 4MATIC (204.085)1,2
C 230 4MATIC Sport (204.085)1,2
1The quoted data apply only to the standard vehicle. See an authorized Mercedes-Benz Center for the corresponding data of all special bodies and special equipment.2Canada only.
C 300 (204.054)1
C 300 Sport (204.054)1
C 300 4MATIC (204.081)1
C 300 4MATIC Sport (204.081)1
Engine272272
Mode of operation4-stroke engine, gasoline injection4-stroke engine, gasoline injection
No. of cylinders66
Bore3.46 in (88.00 mm)3.46 in (88.00 mm)
Stroke2.69 in (68.40 mm)3.23 in (82.10 mm)
Total piston displacement152.3 cu in (2496 cm3)182.8 cu in (2996 cm3)
Compression ratio11.4:111.3:1
Output acc. to SAE J 13493
3Premium fuel required. Performance may vary with fuel octane rating.
201 hp/6 100 rpm
(150 kW/6 100 rpm)228 hp/6 000 rpm
(170 kW/6 000 rpm)
Maximum torque
acc. to SAE J 1349181 lb-ft/2 900 - 5 500 rpm
(245 Nm/2 900 - 5 500 rpm)221 lb-ft/2 500 - 5 000 rpm
(300 Nm/2 500 - 5 000 rpm)
Maximum engine speed6500 rpm6500 rpm
Firing order1-4-3-6-2-51-4-3-6-2-5
Poly-V-belt2404 mm2404 mm

466 Technical data
Engine
ModelC 350 (204.056)1,2
C 350 Sport (204.056)1
C 350 4MATIC (204.087)1,2
C 350 4MATIC Sport (204.087)1,2
1The quoted data apply only to the standard vehicle. See an authorized Mercedes-Benz Center for the
corresponding data of all special bodies and special equipment.
2Canada only.
Engine272
Mode of operation4-stroke engine, gasoline injection
No. of cylinders6
Bore3.66 in (92.90 mm)
Stroke3.39 in (86.00 mm)
Total piston displacement213.5 cu in (3498 cm3)
Compression ratio10.7:1
Output acc. to SAE J 13493
3Premium fuel required. Performance may vary with fuel octane rating.
268 hp/6 000 rpm
(200 kW/6 000 rpm)
Maximum torque
acc. to SAE J 1349258 lb-ft/2 400 - 5 000 rpm
(350 Nm/2 400 - 5 000 rpm)
Maximum engine speed6 500 rpm
Firing order1-4-3-6-2-5
Poly-V-belt2 404 mm

478 Technical data
Fuels, coolants, lubricants, etc.
ModelCapacityFuels, coolants, lubricants, etc.
Power steeringAll models0.85 US qt. (0.8 l)MB Power Steering Fluid
(Chevron Texaco PSF 9109)1
1For detailed information, please refer to the Factory Approved Service Products pamphlet (USA only) or contact an authorized Mercedes-Benz Center.
Front wheel hubsAll modelsapprox. 3.6 oz. (95 g) eachHigh-temperature roller bearing grease
Brake systemAll modelsapprox. 0.53 US qt. (0.5 l)MB Brake Fluid (DOT 4+)
Cooling systemAll models5.07 US qt. (4.8 l)MB 325.0 Anticorrosion/Antifreeze
Fuel tank
including a reserve ofAll models17.43 US gal (66.0 l)
2.11 US gal (8.0 l)Premium unleaded gasoline:
Minimum Posted Octane 91
(Avg. of 96 RON/86 MON)
C 300 and C 300 Sport (with automatic
transmission*), USA only:
Flexible Fuel Vehicle (identified by a label
reading Premium gasoline or E85 only!
on fuel filler flap).
Alternative fuel: Ethanol fuel (E85)
Air conditioning systemAll modelsR-134a refrigerant and special PAG
lubricant oil (never R-12)

481 Technical data
Fuels, coolants, lubricants, etc.
Premium unleaded gasolineGasoline additives
A major concern among engine manufac-
turers is carbon build-up caused by gaso-
line. Mercedes-Benz recommends only the
use of quality gasoline containing additives
that prevent the build-up of carbon
deposits.
After an extended period of using fuels
without such additives, carbon deposits
can build up especially on the intake valves
and in the combustion area, leading to
engine performance problems such as:

Warm-up hesitation

Unstable idle

Knocking/pinging

Misfire

Power loss
Warning!G
Gasoline is highly flammable and poisonous.
It burns violently and can cause serious
personal injury.
Never allow sparks, flame or smoking mate-
rials near gasoline!
Turn off the engine before refueling.
Whenever you are around gasoline, avoid in-
haling fumes and skin or clothing contact,
extinguish all smoking materials.
Direct skin contact with fuels and the inha-
lation of fuel vapors can damage your
health.
!To maintain the engine’s durability and per-
formance, premium unleaded gasoline must be
used. If premium unleaded gasoline is not avail-
able and low octane fuel is used, follow these
precautions:

Have the fuel tank only partially filled with
unleaded regular gasoline and fill up with
premium unleaded gasoline as soon as
possible.

Avoid full throttle driving and abrupt
acceleration.

Do not exceed an engine speed of 3 000 rpm
if the vehicle is loaded with a light load such
as two persons and no luggage.

Do not exceed 2/3 of maximum accelerator
pedal position if the vehicle is fully loaded or
operating in mountainous terrain.

482 Technical data
Fuels, coolants, lubricants, etc.
In areas where carbon deposits may be
encountered due to lack of availability of
gasolines which contain these additives,
Mercedes-Benz recommends the use of
additives approved by us for use on
Mercedes-Benz vehicles.
Refer to Factory Approved Service Prod-
ucts pamphlet (USA only), or contact an
authorized Mercedes-Benz Center for a
listing of approved product(s). Follow
directions on product label.
Do not blend other fuel additives with fuel.
This only results in unnecessary cost and
may be harmful to the engine operation.Fuel requirements
Only use premium unleaded fuel:

The octane number (posted at the
pump) must be 91 min. It is an average
of both the Research Octane Number
(RON) and the Motor Octane Number
(MON): (RON+MON)/2. This is also
known as the ANTI-KNOCK INDEX.
Unleaded gasoline containing oxygenates
such as ethanol, IPA, IBA and TBA can be
used provided the ratio of any one of these
oxygenates to gasoline does not exceed
10%; MTBE must not exceed 15%.
The ratio of methanol to gasoline must not
exceed 3% plus additional co-solvents.
Using mixtures of ethanol and methanol is
not allowed. Gasohol, which contains
10% ethanol and 90% unleaded gasoline,
can be used.
These blends must also meet all other fuel
requirements, such as resistance to spark
knock, boiling range, vapor pressure, etc.
Flexible Fuel Vehicles (USA only)
C 300 and C 300 Sport (with automatic
transmission*) are Flexible Fuel Vehicles.
Flexible Fuel Vehicles are identified by a
label reading Premium gasoline or E85
only! on fuel filler flap).
These vehicles are designed to operate on
premium unleaded gasoline or Ethanol fuel
(E85), or on any mixture of these two.
Ethanol fuel (E85) is a mixture of approxi-
mately 85% Ethanol and 15% unleaded
gasoline.
!Damage or malfunction resulting from poor
fuel quality or from blending additional fuel addi-
tives other than those tested and approved by us
for use on Mercedes-Benz vehicles are not cov-
ered by the Mercedes-Benz Limited Warranty.
For a listing of approved products, refer to the
Factory Approved Service Products pamphlet
(USA only) or contact an authorized
Mercedes-Benz Center.Warning!G
Ethanol fuel (E85) and its fumes are highly
flammable, poisonous and burn easily. Etha-
nol fuel can cause serious injuries if ignited
or if you come into contact with it or inhale
fumes of it. Avoid inhalation of Ethanol
fumes and skin contact with Ethanol. Extin-
guish all open flames before fueling. Never
smoke or create sparks close to Ethanol.

493 Index
ESP®62
Four wheel electronic traction system
with ESP
®65
Messages in display 389, 397, 398
Warning lamp 27, 376, 379, 380
ETD 49
Safety guidelines 38
Ethanol fuel
At the gas station 322
Switching fuels 483
Exterior rear view mirrors
Adjusting 97
Auto-dimming on the driver’s
side 99, 100
Fold-in settings 175
Power folding* 98F
Fahrenheit see Temperature display
mode 167
First aid kit 420
Flat tire 440
Lowering the vehicle 445
Mounting the Minispare wheel 441
Preparing the vehicle 440
Flexible fuel vehicles 482
At the gas station 322
Switching fuels 483
Floormats* 294
Fluids
Automatic transmission fluid 476,
477
Brake fluid 478, 480
Capacities 476
Engine coolant 329, 478, 484
Engine oil 328, 476, 480
Power steering fluid 478
Windshield washer and headlamp
cleaning system 479, 486
Fog lamps 431
Messages in display 410
Replacing bulbs 431, 432, 436Four wheel electronic traction system
(4MATIC) with ESP
®65
4MATIC 65
Front air bags 39
Front lamps see headlamps
Front passenger front air bag 39
Messages in display 393
Front passenger front air bag off indicator
lamp 29, 45, 385
Front seats
Heating* 91
Fuel 322, 478, 481
Additives 481
Capacity, Fuel tank 478
Cruising range 483
E85 (Ethanol fuel) 478, 483
Filling the tank 322
Fuel filler flap and cap 322
Fuel reserve warning lamp 27, 150,
380
Gauge 27, 150
Premium unleaded gasoline 478,
481
Requirements, Octane rating 482
Switching (Flexible fuel vehicle) 483