
Wooden trim ................................. .3 25
CD
see also Digital Operator's Man-
ual ................................................. .2 69
CD player (on-board computer) ....... .2 18
Center console
Overview .......................................... 38
Stowage space .............................. 282
Center console in the rear com-
partment
Stowage compartment .................. 283
Central locking
Locking/unlocking (SmartKey) ....... .7 7
Changing the media source ............ .2 18
Chauffeur mode
Display message ............................ 256
Fully reclined position .................... 109
General notes ................................ 106
Installing the head restraint ........... 108
Moving front-passenger seat into
the chauffeur position .................... 106
Moving the front-passenger seat
into the normal position ................. 108
Removing the head restraint .......... 108
Child
Restraint system .............................. 60
Child seat
Forward-facing restraint system ...... 63
LATCH-type (ISOFIX) child seat
anchors ............................................ 61
On the front-passenger seat ............ 63
Rearward-facing restraint system .... 63
Top Tether ....................................... 62
Child-proof locks
Important safety notes .................... 64
Rear doors ....................................... 65
Children
Special seat belt retractor ............... 59
Cigarette lighter ................................ 294
Cleaning
Mirror turn signal ........................... 323
Climate control
Adjusting the footwell tempera-
ture (multimedia system) ............... 275
Automatic climate control ............. 133
Controlling automatically ............... 136
Cooling with air dehumidification .. 135 Cooling with air dehumidification
(multimedia system) ...................... 275
Defrosting the window s ................. 139
De frosti ng the windshield .............. 139
ECO start/stop function ................ 134
General notes ................................ 132
Indicator lamp ................................ 136
Ionization ....................................... 142
Ionization (multimedia system) ...... 274
Notes on using the automatic cli-
mate control .................................. 134
Overview ........................................ 273
Overview of systems ...................... 132
Perfume atomizer .......................... 141
Perfume atomizer (multimedia
system) .......................................... 274
Pre-entry climate control (via key)
(multimedia system) ...................... 274
Pre-entry climate control at
departure time (multimedia sys-
tem) ............................................... 275
Problem with the rear window
defroster ........................................ 140
Problems with cooling with air
dehumidification ............................ 136
Rear control panel ......................... 133
Refrigerant ..................................... 375
Refrigerant filling capacity ............. 376
Setting the air distribution ............. 138
Setting the air vents ...................... 143
Setting the airflow ......................... 138
Setting the climate mode ............... 137
Setting the climate mode (multi-
media system) ............................... 274
Setting the temperature ................ 137
Switching air-recirculation mode
on/off ............................................ 140
Switching on/off ........................... 135
Switching residual heat on/off ...... 140
Switching the rear window
defroster on/off ............................ 139
Switching the synchronization
function on and off ........................ 138
Synchronization function (multi-
media system) ............................... 275
Climate control settings
Multimedia system ........................ 273 Index 7

Q QR code
Mercedes-Benz Guide App ................. 1
Rescue card .................................... .3 1
Qualified specialist workshop ........... 30
Quick access for telephone
Sending DTMF tones ..................... .2 72
R Radiator cover ................................... 313
Radio
Selecting a station ......................... 217
Radio mode
see also Digital Operator's Man-
ual ................................................. .2 69
Radio-wave reception/transmis-
sion in the vehicle
Declaration of conformity ................ 29
Rain closing feature
Panorama sliding sunroof ................ 96
Reading lamp ..................................... 127
Rear compartment
Activating/deactivating climate
control .......................................... .1 35
Setting the air distribution ............. 138
Setting the air vents ..................... .1 43
Setting the airflow ......................... 138
Setting the temperature ................ 137
Stowage compartment .................. 283
Rear Seat Entertainment System
AUX jacks ...................................... 280
AUX jacks CD/DVD drive .............. 279
Rear seats
Adjusting ....................................... 102
Adjusting a rear reclining seat ....... 102
Overview .......................................... 41
Setting the reclined position .......... 103
Rear view camera
Cleaning instructions ..................... 323
Displays in the COMAND display ... 191
Function/notes ............................. 190
Rear window blind ............................ 293
Rear window defroster
Problem (malfunction) ................... 140
Switching on/off ........................... 139 Rear-view mirror
Anti-glare (manual) ........................ 117
Dipping (automatic) ....................... 118
Refrigerant (air-conditioning sys-
tem)
Important safety notes .................. 375
Refueling
Fuel gauge ....................................... 35
Important safety notes .................. 159
see Fuel
Remote control
Garage door opener ....................... 307
Programming (garage door
opener) .......................................... 308
Replacing bulbs
General notes ................................ 128
Reporting safety defects .................... 30
Rescue card ......................................... 31
Reserve (fuel tank)
see Fuel
Reserve fuel
Display mes sage ............................ 244
Warni ng lamp ................................. 264
Residual heat (climate control) ........ 140
Restraint system
Display message ............................ 237
Introduction ..................................... 42
Warning lamp ................................. 263
Warning lamp (function) ................... 43
Reversing feature
Panorama sliding sunroof ................ 95
Roller sunblinds ............................... 96
Side windows ................................... 91
Trunk lid ........................................... 85
ROAD SURFACE SCAN ....................... 181
Roadside Assistance (breakdown) .... 28
Roller sunblind
Panorama roof with power tilt/
sliding panel ..................................... 96
Rear side windows ......................... 293
Rear window .................................. 293
Roller sunblind of the panorama
roof with power tilt/sliding panel
Operating (front roller sunblind) ....... 96
Operating (rear roller sunblind) ........ 97
Roof carrier ........................................ 289 Index 17

Roof lining and carpets (cleaning
guidelines) ......................................... 326
Roof load (maximum) ........................ 376
Route guidance
see also Digital Operator's Man-
ual .................................................. 269
SSafety
Children in the vehicle ..................... 59
see Occupant safety
see Operating safety
Safety system
see Driving safety systems
SD card
Inserting/removing ........................ 278
SD memory card
see also Digital Operator's Man-
ual .................................................. 269
Selecting ........................................ 218
Search & Send
see also Digital Operator's Man-
ual .................................................. 269
Seat
Adjusting the front-passenger
seat from the driver's seat ............. 103
Adjusting the front-passenger
seat from the rear .......................... 104
Multicontour seat in the rear com-
partment ........................................ 112
Seat belt buckle extender
Display message ............................ 235
Seat belt extender
Function/notes ................................ 47
Seat belts
Adjusting the driver's and front-
passenger seat belt ......................... 47
Adjusting the height ......................... 46
Cleaning ......................................... 325
Correct usage .................................. 45
Fastening ......................................... 46
Important safety guidelines ............. 44
Introduction ..................................... 43
Releasing ......................................... 47
Seat belt extender ........................... 47
Warning lamp ................................. 259
Warning lamp (function) ................... 47 Seating
Seating comfort package ............... 112
Seating comfort package ................. 112
Seats
Active multicontour seat ................ 112
Adjusting (electrically) ................... 101
Adjusting (rear compartment) ........ 102
Adjusting the 4-way lumbar sup-
port ................................................ 112
Adjusting the head restraint .......... 109
Calling up a stored setting (mem-
ory function) .................................. 120
Chauffeur mode ............................. 106
Cleaning the cover ......................... 325
Correct driver's seat position ........ 100
Display message ............................ 256
EASY-ENTRY/EXIT system ............. 116
Important safety notes .................. 100
Seat heating .................................. 112
Se at
heating problem .................... 114
Seat ventilation .............................. 113
Storing settings (memory func-
tion) ............................................... 120
Switching seat heating on/off ....... 112
Switching seat ventilation on/off .. 113
Section
Wheels and tires ............................ 343
Securing a load
see Securing cargo
Securing cargo .................................. 288
Selector lever
Cleaning ......................................... 325
see Automatic transmission
Sensors (cleaning instructions) ....... 323
Service menu (on-board com-
puter) .................................................. 221
Service message
see ASSYST PLUS
Service products
Brake fluid ..................................... 374
Coolant (engine) ............................ 374
Engine oil ....................................... 373
Fuel ................................................ 372
Important safety notes .................. 371
Refrigerant (air-conditioning sys-
tem) ............................................... 375
Washer fluid ................................... 37518
Index

The antifreeze concentrate/corrosion inhibitor
concentration in the engine cooling system
should: R
be at least 50%. This will protect the engine
cooling system against freezing down to
approximately -35 ‡ (-37 †). R
not exceed 55% (antifreeze protection down
to -49 ‡[ -45 †]). Otherwise, heat will not be
dissipated as effectively.
Mercedes-Benz recommends an antifreeze/
corrosion inhibitor concentrate in accordance
with
MB Specifications for Service Products 310.1.
i When the vehicle is first delivered, it is filled
with a coolant mixture that ensures adequate
antifreeze and anti-corrosion protection.
i The coolant is checked with every mainte-
nance interval at a qualified specialist work-
shop.
Filling capacities Model Capacity
S 600
Mercedes ‑ May-
bach S 600 15.7 US qt (14.9 l)
S 400 4MATIC
Mercedes ‑ AMG
S 63 4MATIC 13.0 US qt (12.3 l)
Mercedes ‑ AMG
S 65 16.1 US qt (15.2 l)
Al l ot her models
12.8 US qt (12.1 l)
Windshield washer system
Important safety notes
G WARNING
Windshield washer concentrate could ignite if
it comes into contact with hot engine compo-
nents or the exhaust system. There is a risk of
fire and injury.
Make sure that no windshield washer con-
centrate is spilled next to the filler neck.
! Only MB SummerFit and MB WinterFit
washer fluid should be mixed together. The spray nozzles may otherwise become
blocked.
Do not use distilled or de-ionized water. Other-
wise, the level sensor may give a false reading.
At temperatures above freezing: X
Fill the washer fluid reservoir with a mixture of
water and windshield washer fluid, e.g. MB
SummerFit.
Add 1 part MB SummerFit to 100 parts water.
At temperatures below freezing: X
Fill the washer fluid reservoir with a mixture of
water and washer fluid, e.g. MB WinterFit.
For the correct mixing ratio refer to the infor-
mation on the antifreeze reservoir.
i Add windshield washer fluid, e.g. MB Sum-
merFit or MB WinterFit, to the washer fluid all
year round.
Climate control system refrigerant
Important safety notes The climate control system of your vehicle is fil-
led with refrigerant R ‑ 134a.
The instruction label regarding the refrigerant
type used can be found on the radiator cross
member.
! Only the refrigerant R ‑ 134a and the PAG oil
approved by Mercedes-Benz may be used.
The approved PAG oil may not be mixed with
any other PAG oil that is not approved for
R-134a refrigerant. Otherwise, the climate
control system may be damaged.
Service work, such as refilling with refrigerant or
replacing component parts, may only be carried
out by a qualified specialist workshop. All appli-
cable regulations, as well as SAE standard J639,
must be adhered to.
Always have work on the climate control system
carried out at a qualified specialist workshop.Service products and filling capacities 375
Technical data Z