2016 MERCEDES-BENZ S-Class SEDAN Filter

Useful information
i
This Operator's Manual describes all models
and all standard and optional equipment of
your vehicle available at the time of publica-
tion of the Operator's Manual. Country-spe-
cific differences are possible. Please note
that your vehicle may not be equipped with all
features described. This also applies to
safety-related systems and functions.
iRead the information on qualified specialist
workshops (Ypage 28).
Overview of climate control systems
General notes
Observe the settings recommended on the fol-
lowing pages. The windows could otherwise fog
up.
To prevent the windows from fogging up:
Rswitch off climate control only briefly
Rswitch on air-recirculation mode only briefly
Rswitch on the cooling with air dehumidifica-
tion function
Rswitch on the defrost windshield function
briefly, if required
Climate control regulates the temperature and
air humidity in the vehicle interior. The air filter
cleans the air, thus improving the interior cli-
mate.
For vehicles with a combustion engine, the
"Cooling with air dehumidification" function is
only available when the engine is running. For
hybrid vehicles, the "Cooling with air dehumidi-
fication" function is also available via the elec-
tric refrigerant compressor when the engine is
not running. Optimum climate control is only
achieved with the side windows and roof closed.
If you start the engine using your smartphone,
the last selected climate control setting is reac-
tivated (
Ypage 164).
The residual heat function can only be activated
or deactivated with the ignition switched off
(
Ypage 152).
iVentilate the vehicle for a brief period during
warm weather, e.g. using the convenience
opening feature (
Ypage 95). This will speed
up the cooling process and the desired inte- rior temperature will be reached more
quickly.
iThe integrated filter filters out most parti-
cles of dust and soot and completely filters
out pollen. It also reduces gaseous pollutants
and odors. A clogged filter reduces the
amount of air supplied to the vehicle interior.
For this reason, you should always observe
the interval for replacing the filter, which is
specified in the Maintenance Booklet. As it
depends on environmental conditions, e.g.
heavy air pollution, the interval may be
shorter than stated in the Maintenance Book- let.
iIt is possible that the blower may be activa-
ted automatically 60 minutes after the Smart-
Key has been removed depending on various
factors, e.g. the outside temperature. The
vehicle is then ventilated for 30 minutes to dry
the climate control system.
140Overview of climate control systems
Climate control

and that it is not swallowed. Do not inhale fuelvapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
RWash away fuel from skin immediately
using soap and water.
RIf fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance with-
out delay.
RIf fuel is swallowed, seek medical assis-
tance without delay. Do not induce vomit-
ing.
RImmediately change out of clothing which
has come into contact with fuel.
GWARNING
Electrostatic buildup can create sparks and
ignite fuel vapors. There is a risk of fire and
explosion.
Always touch the vehicle body before opening
the fuel filler flap or touching the fuel pump
nozzle. Any existing electrostatic buildup is
thereby discharged.
Do not get into the vehicle again during the refu-
eling process. Otherwise, electrostatic charge
could build up again.
!Do not use diesel to refuel vehicles with a
gasoline engine. Do not switch on the ignition
if you accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel system. Even small amounts of the wrong fuel could
result in damage to the fuel system and the
engine. Notify a qualified specialist workshop
and have the fuel tank and fuel lines drained
completely.
!Overfilling the fuel tank could damage the
fuel system.
!Take care not to spill any fuel on painted
surfaces. You could otherwise damage the
paintwork.
!Use a filter when refueling from a fuel can.
Otherwise, the fuel lines and/or injection sys-
tem could be blocked by particles from the
fuel can. If you overfill the fuel tank, fuel could spray out
when the fuel pump nozzle is removed.
For further information on fuel and fuel quality
(
Ypage 428).
Refueling
General information
Pay attention to the important safety notes
(Ypage 177).
PLUG-IN HYBRID vehicles: pressure in the fuel
tank must be released before refueling.
Except PLUG-IN HYBRID vehicles: if you
unlock/lock the vehicle from the outside, the
fuel filler flap also unlocks/locks.
The position of the fuel filler cap is displayed in
the instrument cluster 8. The arrow next to
the filling pump indicates the side of the vehicle.
Preparing to refuel
XSwitch off the engine.
XOpen the driver's door.
The on-board electronics now have status 0.
This is the same as the SmartKey having been
removed.
or, if the SmartKey is inserted in the ignition
lock:
XRemove the SmartKey from the ignition lock.
Opening the fuel filler flap (except
PLUG-IN HYBRID vehicles)
:To open the fuel filler flap
;To insert the fuel filler cap
=Tire pressure table
?Fuel type to be used
178Refueling
Driving and parking

Important safety notes
GWARNING
DISTRONI CPLU Sdoes no treac tto :
Rpeople or animals
Rstationary obstacles on th eroad ,e.g. stop-
ped or parked vehicles
Roncomin gand crossing traffic
As aresult ,DISTRONI CPLU Smay neither giv e
warning sno rinterven ein suc hsituations.
Ther eis aris kof an accident.
Always pay careful attention to th etraffic sit -
uation and be read yto brake.
GWARNIN G
DISTRONI CPLU Scanno talways clearly iden -
tify other road user sand comple xtraffic sit -
uations.
In suc hcases, DISTRONI CPLU Smay:
Rgiv ean unnecessary warning and then
brak eth evehicl e
Rneither giv e awarning no rinterven e
Raccelerate or brak eunexpectedly
Ther eis aris kof an accident.
Continue to driv ecarefully and be read yto
brake, in particular when warned to do so by
DISTRONI CPLUS.
GWARNIN G
DISTRONI CPLU Sbrakes your vehicl ewit hup
to 50 %of the maximum possible deceleration.
If this braking force is insufficient, DISTRONIC
PLUS warns you visually and audibly. There is a risk of an accident.
In such cases, apply the brakes yourself and
try to take evasive action.
!If DISTRONIC PLUS or the HOLD function is
activated, the vehicle brakes automatically in
certain situations.
To prevent damage to the vehicle, deactivate
DISTRONIC PLUS and the HOLD function in
the following or other similar situations:
Rwhen towing the vehicle
Rin the car wash If you fail to adapt your driving style, DISTRONIC
PLUS can neither reduce the risk of accident nor
override the laws of physics. DISTRONIC PLUS
cannot take into account the road, traffic and
weather conditions. DISTRONIC PLUS is only an
aid. You are responsible for the distance to the
vehicle in front, for vehicle speed, for braking in good time and for staying in your lane.
Do not use DISTRONIC PLUS:
Rin road and traffic conditions which do not
allow you to maintain a constant speed, e.g. in
heavy traffic or on winding roads
Ron slippery road surfaces. Braking or accel-
erating could cause the drive wheels to lose
traction and the vehicle could then skid
Rwhen there is poor visibility, e.g. due to fog,
heavy rain or snow
DISTRONIC PLUS may not detect narrow vehi-
cles driving in front, e.g. motorcycles, or vehi-
cles driving on a different line.
In particular, the detection of obstacles can be
impaired if:
Rthere is dirt on the sensors or anything else
covering the sensors
Rthere is snow or heavy rain
Rthere is interference by other radar sources
Rthere are strong radar reflections, for exam-
ple, in parking gara ges
If DISTR
ONIC PLUS no longer detects a vehicle
in front, DISTRONIC PLUS may unexpectedly
accelerate the vehicle to the stored speed.
This speed may:
Rbe too high if you are driving in a filter lane or an exit lane
Rbe so high in the right lane that you pass vehi-cles driving on the left (left-hand drive coun-
tries)
Rbe so high in the left lane that you pass vehi-
cles driving on the right (right-hand drive
countries)
If there is a change of drivers, advise the new
driver of the speed stored.
200Driving systems
Driving and parking

Head-up display
General notes
The head-up display projects information from
the navigation system and the driver assistance
system above the dashboard into the driver's
field of vision. The head-up display allows the
driver to see all of the information without hav-
ing to take their eyes off the road.
A requirement for the display of the contents is
that the following functions are available in the
vehicle and are switched on:
RCruise control
RDISTRONIC PLUS
RTraffic Sign Assist
RNavigation
Important safety notes
The head-up display is only an aid and is not a
substitute for attentive driving.
Speed limits and overtaking restrictions are not
always correctly displayed. Traffic signs always
have priority over the Traffic Sign Assist display.
The visibility of the head-up display is influenced
by the following conditions:
Rthe driver's seat position
Rthe positioning of the display image
Rthe general ambient light
Rsunglasses with polarization filters
Rwet roads
Rblocking of sunlight by objects on the display
cover
In the event of extreme sunlight, sections of the
display may fade. This can be reversed by
switching the head-up display off and on again.
iVehicles with the head-up display are equip-
ped with a special windshield. Should repairs
be necessary, have the windshield replaced at
a qualified specialist workshop.
Displays and operation
Switching the head-up display on/off
XPress button :.
When the head-up display is switched on, the display appears in the driver's field of vision.
Displays and operation259
On-board computer and displays
Z

GWARNING
If engine oil comes into contact with hot com- ponents in the engine compartment, it may
ignite. There is a risk of fire and injury.
Make sure that engine oil is not spilled next to
the filler neck. Let the engine cool down and
thoroughly clean the engine oil off the com-
ponents before starting the engine.
HEnvironmental note
When adding oil, take care not to spill any. If
oil enters the soil or waterways, it is harmful to
the environment.
!Only use engine oils and oil filters that have
been approved for vehicles with a service sys-
tem. You can obtain a list of the engine oils
and oil filters tested and approved in accord- ance with the Mercedes-Benz Specifications
for Service Products at any Mercedes-Benz
Service center.
Damage to the engine or exhaust system is
caused by the following:
Rusing engine oils and oil filters that have notbeen specifically approved for the service
system
Rreplacing engine oil and oil filters after the
interval for replacement specified by the
service system has been exceeded
Rusing engine oil additives.
!Do not add too much oil. adding too much
engine oil can result in damage to the engine
or to the catalytic converter. Have excess
engine oil siphoned off.
Example
XTurn cap :counter-clockwise and remove it.
XAdd engine oil.
If the oil level is at or below the MIN mark on
the oil dipstick, add 1.1 US qt (1.0 liter) of
engine oil.
XReplace cap :on the filler neck and tighten
clockwise.
Ensure that the cap locks into place securely.
XCheck the oil level again with the oil dipstick
(Ypage 353).
Further information on engine oil (
Ypage 429).
Additional service products
Checking coolant level
GWARNING
Certain components in the engine compart-
ment, such as the engine, radiator and parts
of the exhaust system, can become very hot.
Working in the engine compartment poses a
risk of injury.
Where possible, let the engine cool down and touch only the components described in the
following.
GWARNING
The cooling system is pressurized, particularly
when the motor is warm. If you open the cap,
you could be scalded if hot coolant sprays out.
There is a risk of injury.
Let the engine cool down before you open the
cap. Wear gloves and eye protection. Slowly
open the cap to relieve pressure.
356Engine compartment
Maintenance and care

iThe ASSYST PLUS service interval display
does not show any information on the engine
oil level. Observe the notes on the engine oil
level (
Ypage 353).
The multifunction display shows a service mes-
sage for several seconds, e.g.:
RService A in XX Days
RService A Due
RService A Overdue by XX Days
Depending on the operating conditions of the
vehicle, the remaining time or distance until the
next service due date is displayed.
The letter A
orB, possibly in connection with a
number or another letter, indicates the type of
service. A
stands for a minor service and Bfor a
major service.
You can obtain further information from an
authorized Mercedes-Benz Center.
The ASSYST PLUS service interval display does
not take into account any periods of time during
which the battery is disconnected.
Maintaining the time-dependent service sched-
ule:
XNote down the service due date displayed in
the multifunction display before disconnect-
ing the battery.
or
XAfter reconnecting the battery, subtract the
battery disconnection periods from the ser-
vice date shown on the display.
Hiding a service message
XPress the aor% button on the steering
wheel.
Displaying service messages
XSwitch the ignition on.
XUse ò on the steering wheel to call up the
list of menus.
XPress 9or: on the steering wheel to
select the Servicemenu and confirm with
a.
XPress 9or: on the steering wheel to
select the ASSYST PLUSsubmenu and con-
firm with a.
The service due date appears in the multi-
function display.
Information about Service
Resetting the ASSYST PLUS service
interval display
!If the ASSYST PLUS service interval display
has been inadvertently reset, this setting can
be corrected at a qualified specialist work-
shop.
Have service work carried out as described in
the Maintenance Booklet. This may otherwise
lead to increased wear and damage to the
major assemblies or the vehicle.
A qualified specialist workshop, e.g. an author-
ized Mercedes-Benz Center, will reset the
ASSYST PLUS service interval display after the
service work has been carried out. You can also
obtain further information on maintenance
work, for example.
Special service requirements
The specified maintenance interval takes only
the normal operation of the vehicle into
account. Under arduous operating conditions or
increased load on the vehicle, maintenance
work must be carried out more frequently, for
example:
Rregular city driving with frequent intermediate
stops
Rif the vehicle is primarily used to travel short
distances
Ruse in mountainous terrain or on poor road
surfaces
Rif the engine is often left idling for long periods
Under these or similar conditions, have, for
example, the air filter, engine oil and oil filter
replaced or changed more frequently. Under
arduous operating conditions, the tires must be
checked more often. Further information can be obtained at a qualified specialist workshop, e.g.
an authorized Mercedes-Benz Center.
Driving abroad
An extensive Mercedes-Benz Service network is
also available in other countries. You can obtain
further information from any authorized
Mercedes-Benz Center.
358ASSYST PLUS
Maintenance and care

RM30 (gasoline with 30% methanol)
RM85 (gasoline with 85% methanol)
RM100 (100% methanol)
RGasoline with metalliferous additives
RDiesel
Do not mix such fuels with the fuel recom-
mended for your vehicle.
!To ensure the longevity and full perform-
ance of the engine, only premium-grade
unleaded gasoline must be used.
If standard unleaded gasoline is unavailable
and you have to refuel with unleaded gasoline
of a lower grade, observe the following pre-
cautions:
ROnly fill the fuel tank to half full with regular
unleaded gasoline and fill the rest with pre-
mium-grade unleaded gasoline as soon as
possible.
RDo not drive at the maximum speed.
RAvoid sudden acceleration and engine
speeds over 3,000 rpm.
You will usually find information about the fuel
grade on the pump. If you cannot find the label
on the pump, ask the staff for assistance.
iFor further information, consult a qualified
specialist workshop or visit
http://www.mbusa.com (USA only).
As a temporary measure, if the recommended
fuel is not available, you may also use regular
unleaded gasoline with an octane rating of
87 AKI/91 RON. This may reduce engine per-
formance and increase fuel consumption. Avoid
driving at full throttle and sudden acceleration.
Never refuel using fuel with a lower AKI.
Information on refueling .
Additives
!Operating the engine with fuel additives
added later can lead to engine failure. Do not
mix fuel additives with fuel. This does not
include additives for the removal and preven-
tion of residue buildup. gasoline must only be
mixed with additives recommended by
Mercedes-Benz. Comply with the instructions
for use on the product label. More information
about recommended additives can be
obtained from any authorized Mercedes-Benz
Center.
Mercedes-Benz recommends that you use bran- ded fuels that have additives. The quality of the fuel available in some coun-
tries may not be sufficient. Residue could build
up in the injection system as a result. In such
cases, and in consultation with an authorized
Mercedes-Benz Center, the gasoline may be
mixed with the cleaning additive recommended
by Mercedes-Benz. You must observe the notes
and mixing ratios specified on the container.
Engine oil
General notes
!Never use engine oil or an oil filter of a spec-
ification other than is necessary to fulfill the
prescribed service intervals. Do not change
the engine oil or oil filter in order to achieve
longer replacement intervals than those pre-
scribed. You could otherwise cause engine
damage or damage to the exhaust gas after-
treatment.
Follow the instructions in the service interval
display regarding the oil change. Otherwise,
you may damage the engine and the exhaust
gas aftertreatment.
When handling engine oil, observe the important
safety notes on service products (
Ypage 427).
The engine oils are matched to the performance
of Mercedes-Benz engines and service intervals.
You should therefore only use engine oils and oil
filters that are approved for vehicles with main- tenance systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz Center.
Or visit the website
http://bevo.mercedes-benz.com.
The table shows which engine oils have been
approved for your vehicle.
Service products and filling capacities429
Technical data
Z

ModelMB-Freigabe orMB-Approval
All models229.5
Use only SAE 0W-40 or SAE 5W-40 engine oils
for Mercedes-AMG vehicles.
iMB approval is indicated on the oil contain-
ers.
Filling capacities
The following values refer to an oil change
including the oil filter.
Missing values were not available at time of
going to print.
ModelCapacity
S 400 4MATIC
S 550 e6.9 US qt (6.5 l)
S 600
Mercedes‑May-
bach S 600
Mercedes‑AMG
S 6511.1 US qt (10.5 l)
Mercedes‑AMG
S 63 4MATIC9.0 US qt (8.5l)
Allot her models8.5 US qt (8.0 l)
Additives
!Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity
Viscosity describes the flow characteristics of a
fluid. If an engine oil has a high viscosity, this
means that it is thick; a low viscosity means that it is thin.
Select an engine oil with an SAE classification
(viscosity) suitable for the prevailing outside
temperatures. The table shows you which SAE
classifications are to be used. The low-temper-
ature characteristics of engine oils can deterio-
rate significantly, e.g. as a result of aging, soot
and fuel deposits. It is therefore strongly rec-
ommended that you carry out regular oil
changes using an approved engine oil with the
appropriate SAE classification.
Brake fluid
GWARNING
The brake fluid constantly absorbs moisture
from the air. This lowers the boiling point of
the brake fluid. If the boiling point of the brake
fluid is too low, vapor pockets may form in the
brake system when the brakes are applied
hard. This would impair braking efficiency.
There is a risk of an accident.
You should have the brake fluid renewed at
the specified intervals.
Comply with the important safety notes for ser-
vice products when handling brake fluid
(
Ypage 427).
The brake fluid change intervals can be found in
the Maintenance Booklet.
Only use brake fluid approved by Mercedes-
Benz according to MB-Freigabe or MB-Approval
331.0.
Information about approved brake fluid can be
obtained at any qualified specialist workshop or on the Internet at
http://bevo.mercedes-benz.co m.
iHave the brake fluid regularly replaced at a
qualified specialist workshop and the replace-
ment confirmed in the Maintenance Booklet.
430Service products and filling capacities
Technical data