2016 MERCEDES-BENZ S-Class SEDAN fuel

Restarting the tire pressure loss warn-
ing system
Restart the tire pressure loss warning system if
you have:
Rchanged the tire pressure
Rchanged the wheels or tires
Rmounted new wheels or tires
XBefore restarting, make sure that the tire
pressures are set properly on all four tires for
the respective operating conditions.
The recommended tire pressure can be foundon the Tire and Loading Information placard
on the B-pillar on the driver's side. Addition-
ally, a tire pressure table is attached to the
fuel filler flap. The tire pressure loss warning
system can only give reliable warnings if you
have set the correct tire pressure. If an incor-
rect tire pressure is set, these incorrect val-
ues will be monitored.
XAlso observe the notes in the section on tire
pressures (Ypage 387).
XMake sure that the SmartKey is in position 2
in the ignition lock (Ypage 162).
XUse ò on the steering wheel to call up the
list of menus.
XPress 9or: on the steering wheel to
select the Servicemenu.
XPress theabutton.
XPress 9or: to select Tire Pres‐sure.
XPress the abutton.
The Run Flat Indicator ActivePress
'OK' to Restartmessage appears in the
multifunction display.
If you wish to confirm the restart:
XPress the abutton.
The Tire Pressure Now OK?message
appears in the multifunction display.
XPress 9or: to select Yes.
XPress the abutton.
The Run Flat Indicator Restartedmes-
sage appears in the multifunction display.
After a teach-in period, the tire pressure loss
warning system will monitor the set tire pres- sures of all four tires. If you wish to cancel the restart:
XPress the
%button.
or
XIf the Tire Pressure Now OK?message
appears, select Cancelby pressing9
or :.
XPress the abutton.
The tire pressure values stored at the last
restart will continue to be monitored.
Loading the vehicle
Instruction labels for tires and loads
GWARNING
Overloaded tires can overheat, causing a
blowout. Overloaded tires can also impair the steering and driving characteristics and lead
to brake failure. There is a risk of accident.
Observe the load rating of the tires. The load
rating must be at least half of the GAWR of
your vehicle. Never overload the tires by
exceeding the maximum load.
Two instruction labels on your vehicle show the maximum possible load.
(1) The Tire and Loading Information placard is on the B-pillar on the driver's side. The Tire
and Loading Information placard shows the
maximum permissible number of occu-
pants and the maximum permissible vehicle
load. It also contains details of the tire sizes
and corresponding pressures for tires
mounted at the factory.
(2) The vehicle identification plate is on the B- pillar on the driver's side. The vehicle iden-
tification plate informs you of the gross
vehicle weight rating. It is made up of the
vehicle weight, all vehicle occupants, the
fuel and the cargo. You can also find infor-
mation about the maximum gross axle
weight rating on the front and rear axle.
The maximum gross axle weight rating is
the maximum weight that can be carried by
one axle (front or rear axle). Never exceed
the maximum load or the maxi mum g
ross
axle weight rating for the front or rear axle.
394Loading the vehicle
Wheels and tires

manufacture, starting with "01" for the first cal-
endar week. Positions three and four represent
the year of manufacture. For example, a tire that
is marked with "3208", was manufactured in
week 32 in 2008.
iTire data is vehicle-specific and may deviate
from the data in the example.
Tire characteristics
This information describes the type of tire cord
and the number of layers in sidewall :and
under tire tread ;.
iTire data is vehicle-specific and may deviate
from the data in the example.
Definition of terms for tires and loading
Tire ply composition and material used
Describes the number of plies or the number of
layers of rubber-coated fabric in the tire tread
and sidewall. These are made of steel, nylon,
polyester and other materials.
Bar
Metric unit for tire pressure. 14.5038 pounds
per square inch (psi) and 100 kilopascals (kPa)
are the equivalent of 1 bar.
DOT (Department of Transportation)
DOT-marked tires fulfill the requirements of the
U S Department of Transportation.
Normal occupant weight
The number of occupants for which the vehicle
is designed multiplied by 68 kilograms (150 lbs).
Uniform Tire Quality Grading Standards
A uniform standard to grade the quality of tires
with regards to tread quality, tire traction and
temperature characteristics. The quality grad-
ing assessment is made by the manufacturer
following specifications from the U.S. govern-
ment. The ratings are molded into the sidewall of the tire.
Recommended tire pressures
The recommended tire pressure applies to the
tires mounted at the factory.
The Tire and Loading Information placard con-
tains the recommended tire pressures for cold
tires on a fully loaded vehicle and for the maxi-
mum permissible vehicle speed.
The tire pressure table contains the recommen-
ded pressures for cold tires for various operat-
ing conditions, i.e. differing load and speed con-
ditions.
Increased vehicle weight due to optional
equipment
The combined weight of all standard and
optional equipment available for the vehicle,
regardless of whether it is actually installed on
the vehicle or not.
Rim
This is the part of the wheel on which the tire is
mounted.
GAWR (Gross Axle Weight Rating)
The GAWR is the maximum gross axle weight
rating. The actual load on an axle must never
exceed the gross axle weight rating. The gross
axle weight rating can be found on the vehicle
identification plate on the B-pillar on the driver's
side.
Speed rating
The speed rating is part of the tire identification.
It specifies the speed range for which the tire is
approved.
GVW (Gross Vehicle Weight)
The gross vehicle weight includes the weight of
the vehicle including fuel, tools, the spare wheel,
accessories installed, occupants, luggage and
the drawbar noseweight, if applicable. The gross
vehicle weight must not exceed the gross vehi-
cle weight rating GVWR as specified on the vehi-
cle identification plate on the B-pillar on the
driver's side.
All about wheels and tires403
Wheels and tires
Z

GVWR (Gross Vehicle Weight Rating)
The GVWR is the maximum permissible gross
weight of a fully loaded vehicle (the weight of thevehicle including all accessories, occupants,
fuel, luggage and the drawbar noseweight, if
applicable). The gross vehicle weight rating is
specified on the vehicle identification plate on
the B-pillar on the driver's side.
Maximum loaded vehicle weight
The maximum weight is the sum of:
Rthe curb weight of the vehicle
Rthe weight of the accessories
Rthe load limit
Rthe weight of the factory installed optional
equipment
Kilopascal (kPa)
Metric unit for tire pressure. 6.9 kPa corre-
sponds to 1 psi. Another unit for tire pressure is
bar. 100 kilopascals (kPa) are the equivalent of
1 bar.
Load index
In addition to the load-bearing index, the load
index may also be imprinted on the sidewall of
the tire. This specifies the load-bearing capacity
more precisely.
Curb weight
The weight of a vehicle with standard equipment
including the maximum capacity of fuel, oil and
coolant. It also includes the air-conditioning sys-
tem and optional equipment if these are instal-
led in the vehicle, but does not include passen-
gers or luggage.
Maximum load rating
The maximum tire load is the maximum permis-
sible weight in kilograms or lbs for which a tire is
approved.
Maximum permissible tire pressure
Maximum permissible tire pressure for one tire.
Maximum load on one tire
Maximum load on one tire. This is calculated bydividing the maximum axle load of one axle by
two.
PSI (pounds per square inch)
A standard unit of measure for tire pressure.
Aspect ratio
Relationship between tire height and tire width
in percent.
Tire pressure
This is pressure inside the tire applying an out-
ward force to each square inch of the tire's sur-
face. The tire pressure is specified in pou

nds per
square inch (psi), in kilopascal (kPa) or in bar.
The tire pressure should only be corrected when
the tires are cold.
Cold tire pressure
The tires are cold:
Rif the vehicle has been parked with the tires
out of direct sunlight for at least three hours
and
Rif the vehicle has not been driven further than
1 mile (1.6 km)
Tread
The part of the tire that comes into contact with
the road.
Bead
The tire bead ensures that the tire sits securely
on the wheel. There are several steel wires in the
bead to prevent the tire from coming loose from
the wheel rim.
Sidewall
The part of the tire between the tread and the
bead.
Weight of optional extras
The combined weight of those optional extras
that weigh more than the replaced standard
parts and more than 5 lbs (2.3 kg). These
optional extras, such as high-performance
brakes, level control, a roof rack or a high-per-
formance battery, are not included in the curb
weight and the weight of the accessories.
TIN (Tire Identification Number)
This is a unique identifier which can be used by
a tire manufacturer to identify tires, for example
for a product recall, and thus identify the pur-
chasers. The TIN is made up of the manufactur- er's identity code, tire size, tire type code and
the manufacturing date.
404All about wheels and tires
Wheels and tires

XTighten the wheel bolts evenly in a crosswisepattern in the sequence indicated (: toA).
The tightening torque must be 110 lb-ft
(150 Nm).
XTurn the jack back to its initial position.
XStow the jack and the rest of the vehicle tools
in the trunk again.
XMercedes-AMG vehicles and vehicles
with AMG equipment: insert the cover into
the outer sill.
XCheck the tire pressure of the newly mounted
wheel and adjust it if necessary.
Observe the recommended tire pressure
(
Ypage 387).
iVehicles with a tire pressure control system:
all mounted wheels must be equipped with
functioning tire pressure control sensors.
Wheel and tire combinations
General notes
!
For safety reasons, Mercedes-Benz recom-
mends that you only use tires and wheels
which have been approved by Mercedes-Benz
specifically for your vehicle.
These tires have been specially adapted for
use with the control systems, such as ABS or
ESP
®, and are marked as follows:
RMO = Mercedes-Benz Original
RMOE = Mercedes-Benz Original Extended
(tires featuring run-flat characteristics)
RMO1 = Mercedes-Benz Original (only cer-
tain AMG tires)
Mercedes-Benz Original Extended tires may
only be used on wheels that have been spe-
cifically approved by Mercedes-Benz.
Only use tires, wheels or accessories tested
and approved by Mercedes-Benz. Certain
characteristics, e.g. handling, vehicle noise
emissions or fuel consumption, may other-
wise be adversely affected. In addition, when
driving with a load, tire dimension variations
could cause the tires to come into contact
with the bodywork and axle components. This
could result in damage to the tires or the vehi- cle.
Mercedes-Benz accepts no liability for dam-
age resulting from the use of tires, wheels or accessories other than those tested and
approved.
Information on tires, wheels and approved
combinations can be obtained from any quali-
fied specialist workshop.
!Retreaded tires are neither tested nor rec-
ommended by Mercedes-Benz, since previ-
ous damage cannot always be detected on
retreaded tires. As a result, Mercedes-Benz
cannot guarantee vehicle safety if retreaded
tires are mounted. Do not mount used tires if
you have no information about their previous
usage.
Overview of abbreviations used in the following
tire tables:
RBA: both axles
RFA: front axle
RRA: rear axle
The recommended pressures for various oper-
ating conditions can be found:
Ron the Tire and Loading Information placard
on the B-pillar on the driver's side
Rin the tire pressure table in the fuel filler flap
Observe the notes on recommended tire pres-
sures under various operating conditions
(
Ypage 387).
Check tire pressures regularly, and only when
the tires are cold. Comply with the maintenance
recommendations of the tire manufacturer in
the vehicle document wallet.
Notes on the vehicle equipment – always equip
the vehicle with:
Rwith tires of the same size on a given axle (left
and right)
Rthe same type of tires at a given time (summer
tires, winter tires, MOExtended tires)
Exception: it is permissible to install a differ-
ent type or make in the event of a flat tire.
Observe the "MOExtended tires (tires with
run-flat characteristics" section (
Ypage 368).
Vehicles equipped with MOExtended tires are
not equipped with a TIREFIT kit at the factory. It
is therefore recommended that you additionally
equip your vehicle with a TIREFIT kit if you mount
tires that do not feature run-flat properties, e.g.
winter tires. A TIREFIT kit may be obtained from a qualified specialist workshop.
iNot all wheel and tire combinations are
available at the factory for all countries.
410Wheel and tire combinations
Wheels and tires

iThe data shown on the vehicle identification
plate is used only as an example. This data is
different for every vehicle and can deviate
from the data shown here. You can find the
data applicable to your vehicle on the vehicle
identification plate.
Vehicle identification number (VIN)
XOpen the front right-hand door.
XFold cover :down and remove it.
You will see the VIN.
The VIN can also be found in the following loca-
tions:
Ron the lower edge of the windshield
(Ypage 427)
Ron the vehicle identification plate
(Ypage 426)
Engine number
:Engine number (stamped into the crank-
case)
;VIN (on the lower edge of the windshield)
=Emission control information plate, includ-
ing the certification of both federal and Cali-
fornian emissions standards
Service products and filling capaci-
ties
Important safety notes
GWARNING
Service products may be poisonous and haz-
ardous to health. There is a risk of injury.
Comply with instructions on the use, storage
and disposal of service products on the labels
of the respective original containers. Always
store service products sealed in their original
containers. Always keep service products out
of the reach of children.
HEnvironmental note
Dispose of service products in an environ-
mentally responsible manner.
Service products include the following:
RFuels
RLubricants (e.g. engine oil, transmission oil)
RCoolant
RBrake fluid
RWindshield washer fluid
RClimate control system refrigerant
Components and service products must be
matched. Only use products recommended by
Mercedes-Benz. Damage which is caused by the
use of products which have not been recom-
mended is not covered by the Mercedes-Benz
warranty or goodwill gestures. They are listed in
this Mercedes-Benz Operator's Manual in the
appropriate section.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
You can recognize service products approved by
Mercedes-Benz by the following inscription on
the containers:
RMB-Freigabe (e.g. MB-Freigabe 229.51)
RMB-Approval (e.g. MB-Approval 229.51)
Other designations or recommendations indi-
cate a level of quality or a specification in
accordance with an MB Sheet Number (e.g. MB 229.5). They have not necessarily been
approved by Mercedes-Benz.
Service products and filling capacities427
Technical data
Z

Other identifications, for example:
R0 W-30
R5 W-30
R5 W-40
Fuel
Important safety notes
GWARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and explo-
sion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before refueling.
GWARNING
Fuel is poisonous and hazardous to health.
There is a risk of injury.
You must make sure that fuel does not come into contact with your skin, eyes or clothing
and that it is not swallowed. Do not inhale fuel
vapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
RWash away fuel from skin immediately
using soap and water.
RIf fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance with-
out delay.
RIf fuel is swallowed, seek medical assis-
tance without delay. Do not induce vomit-
ing.
RImmediately change out of clothing which
has come into contact with fuel.
Tank capacity
Missing values were not available at time of
going to print.
ModelTotal capacity
S 400 4MATIC
PLUG-IN HYBRID vehi-
cles16.6 US gal (63.0 l)
Allot her models21.1 US gal
(80.0 l)
ModelOf which
reserve
S 400 4MATIC
Mercedes‑AMG vehiclesApprox.
3.2 US gal (12.0 l)
Allot her modelsApprox.
2.1 US gal (8.0 l)
Gasoline
Fuel grade
!Do not use diesel to refuel vehicles with a
gasoline engine. Do not switch on the ignition
if you accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel system.
Even small amounts of the wrong fuel could
result in damage to the fuel system and the
engine. Notify a qualified specialist workshop
and have the fuel tank and fuel lines drained
completely.
!Only refuel using unleaded premium grade
gasoline with at least 91 AKI/95 RON.
iE10 fuel contains up to 10% bioethanol.
Your vehicle is E10-compatible. You can
refuel your vehicle using E10 fuel.
!Only use the fuel recommended. Operating
the vehicle with other fuels can lead to engine
failure.
!Do not use the following:
RE15 (gasoline with 15% ethanol)
RE85 (gasoline with 85% ethanol)
RE100 (100% ethanol)
RM15 (gasoline with 15% methanol)
428Service products and filling capacities
Technical data

RM30 (gasoline with 30% methanol)
RM85 (gasoline with 85% methanol)
RM100 (100% methanol)
RGasoline with metalliferous additives
RDiesel
Do not mix such fuels with the fuel recom-
mended for your vehicle.
!To ensure the longevity and full perform-
ance of the engine, only premium-grade
unleaded gasoline must be used.
If standard unleaded gasoline is unavailable
and you have to refuel with unleaded gasoline
of a lower grade, observe the following pre-
cautions:
ROnly fill the fuel tank to half full with regular
unleaded gasoline and fill the rest with pre-
mium-grade unleaded gasoline as soon as
possible.
RDo not drive at the maximum speed.
RAvoid sudden acceleration and engine
speeds over 3,000 rpm.
You will usually find information about the fuel
grade on the pump. If you cannot find the label
on the pump, ask the staff for assistance.
iFor further information, consult a qualified
specialist workshop or visit
http://www.mbusa.com (USA only).
As a temporary measure, if the recommended
fuel is not available, you may also use regular
unleaded gasoline with an octane rating of
87 AKI/91 RON. This may reduce engine per-
formance and increase fuel consumption. Avoid
driving at full throttle and sudden acceleration.
Never refuel using fuel with a lower AKI.
Information on refueling .
Additives
!Operating the engine with fuel additives
added later can lead to engine failure. Do not
mix fuel additives with fuel. This does not
include additives for the removal and preven-
tion of residue buildup. gasoline must only be
mixed with additives recommended by
Mercedes-Benz. Comply with the instructions
for use on the product label. More information
about recommended additives can be
obtained from any authorized Mercedes-Benz
Center.
Mercedes-Benz recommends that you use bran- ded fuels that have additives. The quality of the fuel available in some coun-
tries may not be sufficient. Residue could build
up in the injection system as a result. In such
cases, and in consultation with an authorized
Mercedes-Benz Center, the gasoline may be
mixed with the cleaning additive recommended
by Mercedes-Benz. You must observe the notes
and mixing ratios specified on the container.
Engine oil
General notes
!Never use engine oil or an oil filter of a spec-
ification other than is necessary to fulfill the
prescribed service intervals. Do not change
the engine oil or oil filter in order to achieve
longer replacement intervals than those pre-
scribed. You could otherwise cause engine
damage or damage to the exhaust gas after-
treatment.
Follow the instructions in the service interval
display regarding the oil change. Otherwise,
you may damage the engine and the exhaust
gas aftertreatment.
When handling engine oil, observe the important
safety notes on service products (
Ypage 427).
The engine oils are matched to the performance
of Mercedes-Benz engines and service intervals.
You should therefore only use engine oils and oil
filters that are approved for vehicles with main- tenance systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz Center.
Or visit the website
http://bevo.mercedes-benz.com.
The table shows which engine oils have been
approved for your vehicle.
Service products and filling capacities429
Technical data
Z

ModelMB-Freigabe orMB-Approval
All models229.5
Use only SAE 0W-40 or SAE 5W-40 engine oils
for Mercedes-AMG vehicles.
iMB approval is indicated on the oil contain-
ers.
Filling capacities
The following values refer to an oil change
including the oil filter.
Missing values were not available at time of
going to print.
ModelCapacity
S 400 4MATIC
S 550 e6.9 US qt (6.5 l)
S 600
Mercedes‑May-
bach S 600
Mercedes‑AMG
S 6511.1 US qt (10.5 l)
Mercedes‑AMG
S 63 4MATIC9.0 US qt (8.5l)
Allot her models8.5 US qt (8.0 l)
Additives
!Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity
Viscosity describes the flow characteristics of a
fluid. If an engine oil has a high viscosity, this
means that it is thick; a low viscosity means that it is thin.
Select an engine oil with an SAE classification
(viscosity) suitable for the prevailing outside
temperatures. The table shows you which SAE
classifications are to be used. The low-temper-
ature characteristics of engine oils can deterio-
rate significantly, e.g. as a result of aging, soot
and fuel deposits. It is therefore strongly rec-
ommended that you carry out regular oil
changes using an approved engine oil with the
appropriate SAE classification.
Brake fluid
GWARNING
The brake fluid constantly absorbs moisture
from the air. This lowers the boiling point of
the brake fluid. If the boiling point of the brake
fluid is too low, vapor pockets may form in the
brake system when the brakes are applied
hard. This would impair braking efficiency.
There is a risk of an accident.
You should have the brake fluid renewed at
the specified intervals.
Comply with the important safety notes for ser-
vice products when handling brake fluid
(
Ypage 427).
The brake fluid change intervals can be found in
the Maintenance Booklet.
Only use brake fluid approved by Mercedes-
Benz according to MB-Freigabe or MB-Approval
331.0.
Information about approved brake fluid can be
obtained at any qualified specialist workshop or on the Internet at
http://bevo.mercedes-benz.co m.
iHave the brake fluid regularly replaced at a
qualified specialist workshop and the replace-
ment confirmed in the Maintenance Booklet.
430Service products and filling capacities
Technical data