2016 MERCEDES-BENZ S CLASS ignition

If you come into contact with the electrolyte,
observe the following: R
Rinse off the electrolyte from your skin
immediately with water. R
Immediately rinse the electrolyte out of
your eyes thoroughly with clean water. R
If the electrolyte is swallowed, immediately
rinse your mouth out thoroughly. Do not
induce vomiting. R
If electrolyte comes into contact with your
skin or hair or is swallowed, seek medical
attention immediately. R
Immediately change out of clothing which
has come into contact with electrolyte. R
If an allergic reaction occurs, seek medical
attention immediately.
The rear-view mirror and the exterior mirror on
the driver's side automatically go into anti-glare
mode if the following conditions are met simul-
taneously: R
the ignition is switched on R
incident light from headlamps strikes the sen-
sor in the rear-view mirror.
The mirrors do not go into anti-glare mode if
reverse gear is engaged or if the interior lighting
is switched on.
Parking position for the exterior mir-
ror on the front-passenger side
Setting and storing the parking position You can position the front-passenger side exte-
rior mirror in such a way that you can see the
rear wheel on that side as soon as you engage
reverse gear. You can store this position. Using reverse gear
C
Memory button MD
Adjustment button

X
Press memory button M C and one of the
arrows on adjustment button D within three
seconds.
The parking position is stored if the exterior
mirror does not move. X
If the mirror moves out of position, repeat the
steps.
Calling up a stored parking position set-
ting X
Turn the SmartKey to position 2 in the ignition
lock ( Y
page 162).X
Adjust the exterior mirror on the front-
passenger side using button

Vehicles without rear reclining seat
The SmartKey must be in the ignition lock and in
position 1 or 2 , in order for the front-passenger
seat to be selected ( Y
page 162).
Selecting a rear-compartment seat X
Press the

Calling up a stored setting
General notes The memory positions in the area for the chauf-
feur mode can only be set when the conditions
for the chauffeur mode are fulfilled
( Y
page 111).
Vehicles without rear reclining seat The SmartKey must be in the ignition lock and in
position 1 or 2 , in order for the front-passenger
seat to be selected ( Y
page 162).X
To call up the stored rear seat setting:
press the

Useful information
i This Operator's Manual describes all models
and all standard and optional equipment of
your vehicle available at the time of publica-
tion of the Operator's Manual. Country-spe-
cific differences are possible. Please note
that your vehicle may not be equipped with all
features described. This also applies to
safety-related systems and functions.
i Read the information on qualified specialist
workshops ( Y
page 28).
Exterior lighting
General notes For reasons of safety, Mercedes-Benz recom-
mends that you drive with the lights switched on
even during the daytime. In some countries,
operation of the headlamps varies due to legal
requirements and self-imposed obligations.
Setting the exterior lighting
Setting options Exterior lighting can be set using: R
the light switch R
the combination switch ( Y
page 131)R
the on-board computer ( Y
page 274)
Light switch
Operation
G c
Left-hand standing lamps
H d
Right-hand standing lamps I `
Parking lamps, license plate and
instrument cluster lightingJ X
Automatic headlamp mode, controlled
by the light sensorK X
Low-beam/high-beam headlamps
If you hear a warning tone when you leave the
vehicle, the lights may still be switched on. X
Turn the light switch to the X position.
The exterior lighting (except the parking/stand-
ing lamps) switches off automatically if you: R
remove the SmartKey from the ignition lock R
open the driver's door with the SmartKey in
position 0 in the ignition lock
Automatic headlamp mode
G WARNING
When the light switch is set to X , the low-
beam headlamps may not be switched on
automatically if there is fog, snow or other
causes of poor visibility due to the weather
conditions such as spray. There is a risk of an
accident.
In such situations, turn the light switch to
X .
The automatic headlamp feature is only an aid.
The driver is responsible for the vehicle's light-
ing at all times.
Canada only:
The daytime running lamps improve the visibility
of your vehicle during the day. The daytime run-
ning lamps function is required by law in Can-
ada. It cannot therefore be deactivated.
When the engine is running and the vehicle is
stationary: if you move the selector lever from a
drive position to P , the daytime running lamps/
low-beam headlamps go out after three
minutes.
When the engine is running, the vehicle is sta-
tionary and in bright ambient light: if you turn the
light switch to the ` position, the daytime
running lamps and parking lamps switch on.
If the engine is running and you turn the light
switch to the X position, the manual settings
take precedence over the daytime running
lamps.
USA only:
The daytime running lamps improve the visibility
of your vehicle during the day. Here, the Day‐130
Exterior lighting
Lights and windshield wipers

time Running Lights function must be
switched on via the on-board computer
( Y
page 274).
If the engine is running and you turn the light
switch to the ` or X position, the manual
settings take precedence over the daytime run-
ning lamps.
X is the favored light switch setting. The light
setting is automatically selected according to
the brightness of the ambient light (exception:
poor visibility due to weather conditions such as
fog, snow or spray): R
SmartKey in position 1 in the ignition lock: the
parking lamps are switched on or off auto-
matically depending on the brightness of the
ambient light. R
With the engine running: if you have switched
on the Daytime Running Lights function in
the on-board computer, the daytime running
lamps or the parking lamps and low-beam
headlamps are switched on or off automati-
cally depending on the brightness of the ambi-
ent light. X
To switch on the automatic headlamps:
turn the light switch to the X position.
Low-beam headlamps Even if the light sensor does not detect that it is
dark, the parking lamps and low-beam head-
lamps switch on when the ignition is switched on
and the light switch is set to the X position.
This is a particularly useful function in the event
of rain and fog. X
To switch on the low-beam headlamps:
turn the SmartKey in the ignition lock to posi-
tion 2 or start the engine.X
Turn the light switch to the X position.
The green X indicator lamp in the instru-
ment cluster lights up.
Parking lamps
! If the battery charge is very low, the parking
lamps or standing lamps are automatically
switched off to enable the next engine start.
Always park your vehicle safely and suffi-
ciently lit according to legal standards. Avoid
using the parking lamps ` over a period of
several hours. If possible, switch on the right-
hand d or left-hand c standing lamp. X
To switch on: turn the light switch to the
` position.
The green ` indicator lamp in the instru-
ment cluster lights up.
Standing lamps Switching on the standing lamps ensures the
corresponding side of the vehicle is illuminated. X
To switch on the standing lamps: the
SmartKey should not be in the ignition lock or
it should be in position 0 .X
Turn the light switch to the c (left-hand
side of the vehicle) or d ((right-hand side
of the vehicle) position.
Combination switch
Turn signal
C
High-beam headlamps D
Turn signal, right

High-beam headlamps X
To activate manually: turn the SmartKey in
the ignition lock to position 2 or start the
engine. X
Vehicles without Adaptive Highbeam Assist
Plus: turn the light switch to position X or
X .X
Vehicles with Adaptive Highbeam Assist Plus:
turn the light switch to the X position.X
Press the combination switch beyond the
pressure point in the direction of arrow C .
In the X position, the high-beam head-
lamps are only switched on when it is dark and
the engine is running.
The blue W indicator lamp in the instru-
ment cluster lights up when the high-beam
headlamps are switched on. X
To switch off: move the combination switch
back to its normal position.
The blue W indicator lamp in the instru-
ment cluster goes out.
Vehicles with Adaptive Highbeam Assist
Plus: if Adaptive Highbeam Assist Plus is acti-
vated, it automatically controls activation and
deactivation of the high-beam headlamps
( Y
page 133).
High-beam flasher X
To switch on: turn the SmartKey in the igni-
tion lock to position 1 or 2 , or start the engine.X
Pull the combination switch in the direction of
arrow

Useful information
i This Operator's Manual describes all models
and all standard and optional equipment of
your vehicle available at the time of publica-
tion of the Operator's Manual. Country-spe-
cific differences are possible. Please note
that your vehicle may not be equipped with all
features described. This also applies to
safety-related systems and functions.
i Read the information on qualified specialist
workshops ( Y
page 28).
Overview of climate control systems
General notes Observe the settings recommended on the fol-
lowing pages. The windows could otherwise fog
up.
To prevent the windows from fogging up: R
switch off climate control only briefly R
switch on air-recirculation mode only briefly R
switch on the cooling with air dehumidifica-
tion function R
switch on the defrost windshield function
briefly, if required
Climate control regulates the temperature and
air humidity in the vehicle interior. The air filter
cleans the air, thus improving the interior cli-
mate.
For vehicles with a combustion engine, the
"Cooling with air dehumidification" function is
only available when the engine is running. For
hybrid vehicles, the "Cooling with air dehumidi-
fication" function is also available via the elec-
tric refrigerant compressor when the engine is
not running. Optimum climate control is only
achieved with the side windows and roof closed.
If you start the engine using your smartphone,
the last selected climate control setting is reac-
tivated ( Y
page 164).
The residual heat function can only be activated
or deactivated with the ignition switched off
( Y
page 152).
i Ventilate the vehicle for a brief period during
warm weather, e.g. using the convenience
opening feature ( Y
page 95). This will speed
up the cooling process and the desired inte- rior temperature will be reached more
quickly.
i The integrated filter filters out most parti-
cles of dust and soot and completely filters
out pollen. It also reduces gaseous pollutants
and odors. A clogged filter reduces the
amount of air supplied to the vehicle interior.
For this reason, you should always observe
the interval for replacing the filter, which is
specified in the Maintenance Booklet. As it
depends on environmental conditions, e.g.
heavy air pollution, the interval may be
shorter than stated in the Maintenance Book-
let.
i It is possible that the blower may be activa-
t ed automatically 60 minutes after the Smart-
Key has been removed depending on various
factors, e.g. the outside temperature. The
vehicle is then ventilated for 30 minutes to dry
the climate control system.140
Overview of climate control systems
Climate control