2016 MERCEDES-BENZ S-Class COUPE fuel

the Service and Guarantee booklet or simply
call the Mercedes-Benz Customer Assistance
Center (USA) at the hotline number
1-800-FOR-MERCedes(1-800-367-6372) or
Customer Service (Canada) at
1-800-387-0100.
Vehicle operation outside the USA
and Canada
If you plan to operate your vehicle in foreign
countries, please be aware that:
Rservice facilities or replacement parts may
not be readily available.
Runleaded fuel for vehicles with a catalytic
converter may not be available. Leaded fuel may cause damage to the catalytic con-
verter.
Rthe fuel may have a considerably lower
octane rating. Unsuitable fuel can cause
engine damage.
Some Mercedes-Benz models are available
for delivery in Europe through our European
Delivery Program. For details, consult an
authorized Mercedes-Benz Center or write to
one of the following addresses.
In the USA
Mercedes-Benz USA, LLC
European Delivery Department
One Mercedes Drive
Montvale, NJ 07645-0350
In Canada
Mercedes-Benz Canada, Inc.
European Delivery Department
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9
Operating safety
Important safety notes
GWARNING
If you do not have the prescribed service/
maintenance work or any required repairs
carried out, this can result in malfunctions or system failures. There is a risk of an accident.
Always have the prescribed service/mainte-
nance work as well as any required repairs
carried out at a qualified specialist workshop.
GWARNING
Flammable material such as leaves, grass or
twigs may ignite if they come into contact with
hot parts of the exhaust system. There is a risk of fire.
When driving off road or on unpaved roads,
check the vehicle's underside regularly. In
particular, remove parts of plants or other
flammable materials which have become
trapped. In the case of damage, contact a
qualified specialist workshop.
GWARNING
Modifications to electronic components, their software as well as wiring can impair their
function and/or the function of other net-
worked components. In particular, systems
relevant to safety could also be affected. As a
result, these may no longer function as inten-
ded and/or jeopardize the operating safety of
the vehicle. There is an increased risk of an
accident and injury.
Never tamper with the wiring as well as elec-
tronic components or their software. You
should have all work to electrical and elec-
tronic equipment carried out at a qualified
specialist workshop.
!There is a risk of damage to the vehicle if:
Rthe vehicle becomes stuck, e.g. on a high
curb or an unpaved road
Ryou drive too fast over an obstacle, e.g. a
curb or a hole in the road
Ra heavy object strikes the undercarriage
or parts of the chassis
In situations like this, the body, the under-
carriage, chassis parts, wheels or tires
could be damaged without the damage
being visible. Components damaged in this
way can unexpectedly fail or, in the case of
Introduction25
Z

QR codes for the rescue card
The QR codes are secured in the fuel filler flap
and on the opposite side on the B-pillar. In the event of an accident, rescue services can use
the QR code to quickly find the appropriate
rescue card for your vehicle. The current res-
cue card contains the most important infor-
mation about your vehicle in a compact form,
e.g. the routing of the electric cables.
You can find more information under http://
portal.aftersales.i.daimler.com/public/
content/asportal/en/communication/
informationen_fuer/QRCode.html.
Data stored in the vehicle
Data recording
This vehicle is capable of recording diagnostic
information relating to vehicle operation, mal-
functions, and user settings. This may include information about the performance or status
of various systems, including but not limited
to, engine, throttle, steering or brake sys-
tems, that is stored and can be read out with
suitable devices, particularly when the vehi-
cle is serviced. The data obtained is used to
properly diagnose and service your vehicle or
to further optimize and develop vehicle func-
tions.
COMAND/mbrace
If the vehicle is equipped with COMAND or
mbrace, additional data about the vehicle’s
operation, the use of the vehicle in certain
situations, and the location of the vehicle may
be compiled through COMAND or the mbrace
system.
For additional information please refer to the
COMAND User Manual and/or the mbrace
Terms and Conditions.
Event data recorders
This vehicle is equipped with an event data
recorder (EDR). The main purpose of an EDR
is to record data that will assist in under-
standing how a vehicle’s systems performed
in certain crash or near crash-like situations,
such as during air bag deployment or when
hitting a road obstacle. The EDR is designed
to record data related to vehicle dynamics
and safety systems for a short period of time,
typically 30 seconds or less.
The EDR in this vehicle is designed to record
such data as:
Rhow various systems in your vehicle are
operating
Rwhether or not the driver and passenger
seat belts are fastened
Rhow far (if at all) the driver is depressing the
accelerator and/or brake pedal and
Rhow fast the vehicle is traveling
This data can help provide a better under-
standing of the circumstances in which
crashes and injuries occur. NOTE: EDR data is
recorded by your vehicle only if a non-trivial
crash situation occurs; no data is recorded by the EDR under normal driving conditions and
no personal data (e.g., name, gender, age,
and crash location) are recorded. However,
other parties, such as law enforcement, can
combine the EDR data with the type of per-
sonal identification data routinely acquired
during a crash investigation.
To read data recorded by an EDR, special
equipment is required, and access to the vehi-
cle or the EDR is needed. In addition to the
vehicle manufacturer, other parties that have
the special equipment, such as law enforce-
ment, can read the information by accessing
the vehicle or the EDR.
EDR data may be used in civil and criminal
matters as a tool in accident reconstruction,
accident claims, and vehicle safety. Since the
Crash Data Retrieval CDR tool that is used to
extract data from the EDR is commercially
available, Mercedes-Benz USA, LLC
28Introduction

Instrument cluster
Displays
FunctionPage
:Speedometer
;Multifunction display232
=Tachometer230
?Coolant temperature231
FunctionPage
AFuel gauge
Fuel filler flap location ind i-
cator 8: the fuel filler
cap ison the right-hand
side.
iIn formation on displaying the outside
temperature inthe multifunction display
can befound under "Outside temperature
disp lay" (
Ypage 231).
Instrument cluster33
At a glance

emptive measures to protect the vehicle
occupants.
Important safety notes
The intervention of PRE-SAFE®PLUS cannot
prevent an imminent collision.
The driver is not warned when PRE-SAFE
®
PLUS intervenes.
PRE-SAFE
®PLUS does not intervene if the
vehicle is backing up.
When driving, or when parking or exiting a
parking space with assistance from Active
Parking Assist, PRE-SAFE
®PLUS will not
apply the brakes.
Function
PRE-SAFE®PLUS intervenes in certain situa-
tions if the radar sensor system detects an
imminent head-on or rear-end collision.
PRE-SAFE
®PLUS takes the following meas-
ures depending on the hazardous situation
detected:
Rif the radar sensor system detects that a
head-on collision is imminent, the seat
belts are pre-tensioned.
Rif the radar sensor system detects that a
rear-end collision is imminent:
-the brake pressure is increased if the
driver applies the brakes when the vehi-
cle is stationary.
-the seat belts are pre-tensioned.
The PRE-SAFE
®PLUS braking application is
canceled:
Rif the accelerator pedal is depressed when
a gear is engaged
Rif the risk of a collision passes or is no lon- ger detected
Rif DISTRONIC PLUS indicates an intention
to pull away
If the hazardous situation passes without
resulting in an accident, the original settings
are restored.
Automatic measures after an acci-
dent
Immediately after an accident, the following
measures are implemented, depending on
the type and severity of the impact:
Rthe hazard warning lamps are activated
Rthe emergency lighting is activated
Rthe vehicle doors are unlocked
Rthe front side windows are lowered
Rthe electrically adjustable steering wheel is
raised
Rthe engine is switched off and the fuel sup-
ply is cut off
Rvehicles with mbrace: automatic emer-
gency call
Children in the vehicle
Important safety notes
Accident statistics show that children
secured in the rear seats are safer than chil-
dren secured in the front-passenger seat. For
this reason, Mercedes-Benz strongly advises
that you install a child restraint system on a
rear seat. Children are generally better pro-
tected there.
If a child younger than twelve years old and
under 5 ft (1.50 m) in height is traveling in the
vehicle:
Ralways secure the child in a child restraint
system suitable for Mercedes-Benz vehi-
cles. The child restraint system must be
appropriate to the age, weight and size of
the child
Rbe sure to observe the instructions and
safety notes in this section in addition to
the child restraint system manufacturer's
installation instructions
Rbe sure to observe the instructions and
safety notes on the "Occupant Classifica-
tion System (OCS)" (
Ypage 53)
62Children in the vehicle
Safety

SmartKey functions
:&To lock the vehicle
;FTo open/close the trunk lid
=%To unlock the vehicle
XTo unlock centrally: press button=.
If you do not open the vehicle within
approximately 40 seconds of unlocking:
Rthe vehicle is locked again.
Rthe anti-theft alarm system is armed
again.
XTo lock centrally: press button:.
The key centrally locks/unlocks the following
components:
Rthe doors
Rthe trunk lid
Rthe fuel filler flap
The turn signals flash once when unlocking
and three times when locking.
You can also set an audible signal to confirm
that the vehicle has been locked. The audible
signal can be activated and deactivated using COMAND (see the separate operating
instructions).
The visual and audible confirmation is given
upon locking only if all components were suc-
cessfully locked.
When the surround lighting is activated in
COMAND, it comes on when it is dark after
the vehicle is unlocked using the remote con-
trol. Information on activating and deactivat-
ing the surround lighting can be found in the
separate operating instructions.
XTo open the trunk lid automatically
from outside the vehicle: press and hold
button ;until the trunk lid opens.
KEYLESS-GO
General notes
Bear in mind that the engine can be started by
any of the vehicle occupants if there is a
SmartKey in the vehicle.
Locking/unlocking centrally
You can start, lock or unlock the vehicle using KEYLESS-GO. To do this, you only need carry
the SmartKey with you. You can combine the
functions of KEYLESS-GO with those of a con-ventional SmartKey. Unlock the vehicle by
using KEYLESS-GO, for instance, and lock it
using the &button on the SmartKey.
The driver's door and the door at which the
handle is used, must both be closed. The
SmartKey must be outside the vehicle. When
locking or unlocking with KEYLESS-GO, the
distance between the SmartKey and the cor-
responding door handle must not be greater
than 3 ft (1 m).
A check which periodically establishes a radio
connection between the vehicle and the
SmartKey determines whether a valid Smart-
Key is in the vehicle. This occurs, for example:
Rwhen starting the engine
Rwhilst driving
Rwhen using HANDS-FREE ACCESS
Rwhen the external door handles are
touched
Rduring convenience closing
SmartKey83
Opening and closing
Z

XTo unlock the vehicle:touch the inner
surface of the door handle.
XTo lock the vehicle: touch sensor sur-
face :or;.
Make sure that you do not touch the inner
surface of the door handle.
XConvenience closing feature: touch
recessed sensor surface ;for an exten-
ded period.
Further information on the convenience
closing feature (
Ypage 99).
Deactivating
If you do not intend to use a SmartKey for an
extended period of time, you can deactivate
the KEYLESS-GO function of the SmartKey.
The SmartKey will then use very little power,
thereby conserving battery power. For the
purposes of activation/deactivation, the
vehicle must not be nearby.
XTo deactivate: press the&button on
the SmartKey twice in rapid succession.
The battery check lamp of the SmartKey
flashes twice briefly and lights up once,
then KEYLESS-GO is deactivated .
XTo activate: press any button on the
SmartKey or insert the SmartKey into the
ignition lock.
KEYLESS-GO and all of its associated fea-
tures are available again.
KEYLESS-GO start function
Bear in mind that the engine can be started by
any of the vehicle occupants if there is a
SmartKey in the vehicle.
Changing the settings of the locking
system
You can change the settings of the locking
system. This means that only the driver's door
and the fuel filler flap are unlocked when the
vehicle is unlocked. This is useful if you fre-
quently travel on your own.
XTo change the setting: press and hold
down the %and& buttons simulta-
neously for approximately six seconds until
the battery check lamp flashes twice
(
Ypage 86).
iIf the setting of the locking system is
changed within the signal range of the vehi-
cle, pressing the &or% button:
Rlocks or
Runlocks the vehicle
The SmartKey now functions as follows:
XTo unlock the driver's door: press the
% button once.
XTo unlock centrally: press the%but-
ton twice.
XTo lock centrally: press the&button.
The KEYLESS-GO function is changed as fol-
lows:
XTo unlock the driver's door: touch the
inner surface of the door handle on the
driver's door.
XTo unlock centrally: touch the inner sur-
face of the front-passenger door handle.
XTo lock centrally: touch the outer sensor
surface on one of the door handles.
XTo restore the factory settings: press
and hold down the %and& buttons
simultaneously for app
roximately six sec-
84SmartKey
Opening and closing

onds until the battery check lamp flashes
twice (
Ypage 86).
Mechanical key
General notes
If the vehicle can no longer be locked or
unlocked with the SmartKey or KEYLESS-GO,
use the mechanical key.
If you use the mechanical key to unlock and
open the driver's door, the anti-theft alarm
system will be triggered. Switch off the alarm
(
Ypage 78).
If you unlock the vehicle using the mechanical
key, the fuel filler flap will not be unlocked
automatically.
XTo unlock the fuel filler flap: insert the
SmartKey into the ignition lock.
Removing the mechanical key
XPush release catch :in the direction of
the arrow and at the same time remove
mechanical key ;from the SmartKey.
For further information about:
Runlocking the driver's door (Ypage 90)
Runlocking the trunk (Ypage 96)
Rlocking the vehicle (Ypage 91)
Inserting the mechanical key
XPush mechanical key ;completely into
the SmartKey until it engages and release
catch :is back in its basic position.
SmartKey battery
Important safety notes
GWARNING
Batteries contain toxic and corrosive substan- ces. If batteries are swallowed, it can result in
severe health problems. There is a risk of fatalinjury.
Keep batteries out of the reach of children. If
a battery is swallowed, seek medical attention
immediately.
HEnvironmental note
Batteries contain dangerous
substances. It is against the
law to dispose of them with
the household rubbish. They
must be collected separately and recycled to protect the
environment.
Dispose of batteries in an
environmentally friendly
manner. Take discharged
batteries to a qualified spe-
cialist workshop or a special
collection point for used bat-
teries.
The SmartKey batteries contain perchlorate
material, which may require special handling
and regard for the environment. National
guidelines must be observed during disposal.
In California, see www.dtsc.ca.gov/
HazardousWaste/Perchlorate/
index.cfm.
Mercedes-Benz recommends that you have
the batteries replaced at a qualified specialist
workshop.
SmartKey85
Opening and closing
Z

XInsert the mechanical key into the Smart-
Key (
Ypage 85).
XCarefully press the protective cap onto thelock cylinder until it engages and is seated
firmly. Do not pull the door handle when
doing so.
iIf you lock the vehicle as described above,
the fuel filler flap is not locked. The anti-
theft alarm system is not armed.
Trunk
Important safety notes
GWARNING
If objects, luggage or loads are not secured or
not secured sufficiently, they could slip, tip
over or be flung around and thereby hit vehicle
occupants. There is a risk of injury, particu-
larly in the event of sudden braking or a sud-
den change in direction.
Always store objects so that they cannot be
flung around. Secure objects, luggage or
loads against slipping or tipping before the
journey.
!The trunk lid swings upwards when
opened. Therefore, make sure that there is
sufficient clearance above the trunk lid.
iYou can limit the opening angle of the
trunk lid in COMAND; see the separate
operating instructions.
iThe opening dimensions of the trunk lid
can be found in the "Vehicle data" section
(
Ypage 406).
Do not leave the SmartKey in the trunk. You
could otherwise lock yourself out.
You should preferably place luggage or loads
in the trunk. Observe the loading guidelines
(
Ypage 300).
Obstacle recognition with trunk lid
reversing feature
On vehicles with trunk lid remote closing fea- ture, the trunk lid is equipped with automatic
obstacle recognition with reversing feature. If
a solid object blocks or restricts the trunk lid
when automatically opening or closing, this
procedure is stopped. If the trunk lid is stop-
ped during the closing procedure, it will open again automatically. The automatic obstacle
recognition with reversing feature is only an
aid. It is not a substitute for your attentive-
ness when opening and closing the trunk lid.
GWARNING
The reversing feature does not react:
Rto soft, light and thin objects, e.g. small fin-
gers
Rover the last 1/3 in (8 mm) of the closing
movement
This means that the reversing feature cannot
prevent someone being trapped in these sit-
uations. There is a risk of injury.
Make sure that no body parts are in close
proximity during the closing procedure.
If somebody becomes trapped:
Rpress the Fbutton on the SmartKey, or
Rpull or press the remote operating switch
on the driver's door or
Rpress the closing or locking button on the
trunk lid
Opening/closing automatically from
outside
Important safety notes
GWARNING
Parts of the body could become trapped dur-
ing automatic closing of the trunk lid. More-
over, people, e.g. children, may be standing in the closing area or may enter the closing area
during the closing process. There is a risk of
injury.
92Trunk
Opening and closing