2015 MERCEDES-BENZ M-Class fuel additives

Engine
Check Engine warning lamp .......... .327
Display message ............................ 300
ECO start/stop function ................ 162
Engine number ............................... 447
Irregular running ............................ 167
Jump-starting ................................. 391
Starting problems .......................... 167
Starting the engine with the
SmartKey ....................................... 160
Starting with KEYLESS-GO ............. 160
Switching off .................................. 183
Tow-starting (vehicle) ..................... 396
Engine electronics
Problem (malfunction) ................... 167
Engine jump starting
see Jump starting (engine)
Engine oil
Adding .......................................... .368
Additives ........................................ 453
Checking the oil level ..................... 367
Checking the oil level using the
dipstick .......................................... 367
Display message ............................ 302
Filling capacity ............................... 452
Notes about oil grades ................... 452
Notes on oil level/consumption .... 367
Temperature (on-board com-
puter) ............................................. 281
Viscosity ........................................ 453
ESP ®
(Electronic Stability Pro-
gram) AMG menu (on-board computer) ... 281
Characteristics ................................. 73
Deactivating/activating ................... 73
Display message ............................ 285
ETS/4ETS ........................................ 72
Function/notes ................................ 72
General notes .................................. 72
Important safety information ........... 73
Trailer stabilization ........................... 74
Warning lamp ................................. 323
ETS/4ETS (Electronic Traction Sys-
tem) ...................................................... 72
Exhaust check ................................... 186
Exhaust pipe (cleaning instruc-
tions) ................................................. .376 Exterior lighting
see Lights
Exterior mirrors
Adjusting ....................................... 114
Dipping (automatic) ....................... 115
Folding in/out (automatically) ....... 115
Folding in/out (electrically) ........... 115
Folding in when locking (on-board computer) ...................................... 280
Out of position (troubleshooting) ... 115
Setting ........................................... 115
Storing settings (memory func-
tion) ............................................... 116
Storing the parking position .......... 116
Eyeglasses compartment ................. 336 F
Filler cap see Fuel filler flap
Flat tire
MOExtended tire s.......................... 383
Preparing the vehicle ..................... 383
TIREFIT kit ...................................... 384
see Emergency spare wheel
Floormats ........................................... 364
Folding the rear bench seat for-
wards/back ....................................... 337
Fording Off-road ......................................... 190
On flooded roads ........................... 190
Fuel
Additives ........................................ 449
Consumption statistics .................. 269
Displaying the current consump-
tion ................................................ 270
Displaying the range ...................... 270
Driving tips .................................... 186
Flexible fuel vehicles ...................... 450
Fuel gaug e....................................... 35
Grade (gasoline )............................ 448
Important safety notes .................. 448
Low outside temperature s............. 450
Premium-grade unleaded gaso-
line ................................................. 448
Problem (malfunction) ................... 180
Quality (diesel )............................... 449 Index
11

Important safety guidelines .............46
Introduction .....................................46
Releasin g......................................... 49
Switching belt adjustment on/off
(on-board computer) ...................... 280
Warning lamp ................................. 318
Warning lamp (function) ................... 49
Seats
Adjusting (electrically) ................... 106
Adjusting the head restraint .......... 106
Cleaning the cover ......................... 378
Correct driver's seat position ........ 104
Folding the rear bench seat for-
wards/back ................................... 337
Important safety notes .................. 105
Overview ........................................ 105
Seat heating problem .................... 110
Seat ventilation problem ................ 111
Storing settings (memory func-
tion) ............................................... 116
Switching seat heating on/of f....... 109
Switching seat ventilation on/of f.. 110
Securing hooks .................................. 340
Selector lever Cleaning ......................................... 378
Sensors (cleaning instructions) ....... 375
Service menu (on-board com-
puter) .................................................. 276
Service products Brake fluid ..................................... 453
Coolant (engine) ............................ 453
DEF special additives ..................... 451
Engine oil ....................................... 452
Fuel ................................................ 448
Important safety notes .................. 447
Refrigerant (air-conditioning sys-
tem) ............................................... 455
Washer fluid ................................... 454
Settings
Factory (on-board computer) ......... 281
On-board computer ....................... 277
Setting the air distribution ............... 148
Setting the airflow ............................ 148
SETUP (on-board computer) ............. 281
Side impact air bag ............................. 52
Side marker lamp (display mes-
sage) ................................................... 299 Side marker lamps (changing
bulbs)
................................................. 131
Side windows Cleaning ......................................... 375
Convenience closing feature ............ 95
Convenience opening feature .......... 95
Important safety information ........... 93
Opening/closing .............................. 94
Overview .......................................... 93
Problem (malfunction) ..................... 97
Resetting ......................................... 96
Sliding sunroof
Important safety notes .................... 97
Opening/closing .............................. 98
Problem (malfunction) ................... 101
Resetting ......................................... 98
see Panorama roof with power
tilt/sliding panel
SmartKey
Changing the battery ....................... 83
Changing the programming ............. 81
Checking the battery ....................... 83
Convenience closing feature ............ 95
Convenience opening feature .......... 95
Display message ............................ 317
Door central locking/unlocking ....... 80
Important safety notes .................... 80
Loss ................................................. 85
Mechanical key ................................ 82
Overview .......................................... 80
Positions (ignition lock) ................. 157
Problem (malfunction) ..................... 85
Starting the engine ........................ 160
Snow chains
Information .................................... 403
Snow drive program ....................... 248
Sockets
Center console .............................. 349
General notes ................................ 349
Luggage compartment ................... 350
Rear compartment ......................... 350
Specialist workshop ............................ 29
Special seat belt retractor .................. 61
Speed, controlling see Cruise control
Speedometer
Digital ............................................ 270 18
Index

Important safety notes on the refilling
procedure DEF is a water-soluble fluid for the exhaust
gas aftertreatment of diesel engines. It is:
R not poisonous
R colorless and odorless
R not flammable
When you open the DEF container, small
amounts of ammonia vapor may be released. Ammonia vapors have a pungent odor and are
particularly irritating to the skin, to mucous
membranes and to the eyes. You may expe-
rience a burning sensation in your eyes, nose and throat. Coughing and watering of the
eyes are possible.
Do not inhale ammonia vapors. Fill the DEF
tank only in well-ventilated areas.
DEF must not come into contact with your
skin, eyes or clothing and must not be swal-
lowed. Keep DEF away from children.
If you or other persons come into contact with
DEF, observe the following:
R Rinse DEF from your skin immediately with
soap and water.
R If DEF comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance with-
out delay.
R If DEF has been swallowed, rinse your
mouth out immediately. Drink plenty of
water. Seek medical assistance without
delay.
R Change out of clothing contaminated with
DEF immediately.
! Only use DEF in accordance with
ISO 22241. Do not mix any additives with
DEF, and do not dilute DEF with water. This
may destroy the BlueTEC exhaust gas after- treatment system.
! The vehicle must be parked on level
ground to fill the DEF tank. The DEF tank
can only be filled as intended with the vehi-
cle parked on a level surface. This avoids
false level readings. Filling the tank is not permitted if the vehicle is not parked on a
level surface. There is a danger of overfill-
ing, which could result in damage to com-
ponents of the BlueTEC exhaust gas after-
treatment.
! Rinse surfaces that have come into con-
tact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF
residues crystallize after time and contam- inate the affected surfaces.
! DEF is not a fuel additive and must not be
added to the fuel tank. If DEF is added to
the fuel tank, this can lead to engine dam-
age.
For further information on DEF, see
(Y page 451).
You will find further information on DEF in the printed Operator's Manual under "Technical
data".
Opening the DEF filler cap The fuel filler flap is unlocked or locked auto-
matically when you open or close the vehicle
with the SmartKey or with KEYLESS-GO.
X Switch the ignition off.
X Press the fuel filler flap in the direction of
arrow 0043.
The fuel filler flap swings up.
X Turn blue DEF filler cap 0044counter-clock-
wise and remove it.
DEF filler cap 0044is secured with a plastic
strip. Refueling
181Driving and pa rking Z

VIN
X
Open the front right-hand door.
X Open cover 0043in the direction of the arrow
and remove it.
You will see the VIN.
The VIN can also be found in the following
locations:
R on the lower edge of the windshield
(Y page 447)
R on the vehicle identification plate
(Y page 446) Engine number
0043
Emission control information plate,
including the certification of both federal
and Californian emissions standards
0044 Engine number (stamped into the crank-
case)
0087 VIN (on the lower edge of the windshield) Service products and filling capaci-
ties
Important safety notes
G
WARNING
Service products may be poisonous and haz-
ardous to health. There is a risk of injury.
Comply with instructions on the use, storage
and disposal of service products on the labels of the respective original containers. Always
store service products sealed in their original containers. Always keep service products out
of the reach of children. H
Environmental note
Dispose of service products in an environ-
mentally responsible manner.
Service products include the following:
R Fuels
R Exhaust gas aftertreatment additives, e.g.
DEF
R Lubricants (e.g. engine oil, transmission oil)
R Coolant
R Brake fluid
R Windshield washer fluid
R Climate control system refrigerant
Comply with all valid regulations with respect to handling, storing, and disposing of service
fluids.
Components and service products must be
matched. You should therefore only use prod- ucts that have been tested and approved by
Mercedes-Benz.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
You can recognize service products approved by Mercedes-Benz by the following inscrip-
tion on the containers:
R MB-Freigabe (e.g. MB-Freigabe 229.51)
R MB Approval (e.g. MB Approval 229.51) Service products and filling capacities
447Technical data Z

R
Gasoline with metalliferous additives
R Diesel
Do not mix such fuels with the fuel recom-
mended for your vehicle. Do not use addi-
tives. This can otherwise lead to engine
damage. This does not include cleaning
additives for the removal and prevention of residue build-up. gasoline may only be
mixed with cleaning additives recommen-
ded by Mercedes-Benz; see "Additives".
You can obtain further information from
any authorized Mercedes-Benz Center.
! To ensure the longevity and full perform-
ance of the engine, only premium-grade
unleaded gasoline must be used.
If standard unleaded gasoline is unavaila-
ble and you have to refuel with unleaded
gasoline of a lower grade, observe the fol-
lowing precautions:
R Only fill the fuel tank to half full with reg-
ular unleaded gasoline and fill the rest
with premium-grade unleaded gasoline
as soon as possible.
R Do not drive at the maximum speed.
R Avoid sudden acceleration and engine
speeds over 3,000 rpm.
Using mixtures of methanol and ethanol is not permitted. E10 fuel or E15 fuel (unleaded gas-
oline with 10% or 15% ethanol) can be used.
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for assis-
tance.
i For further information, consult a quali-
fied specialist workshop or visit
http://www.mbusa.com (USA only).
All other models: as a temporary measure, if
the recommended fuel is not available, you
may also use regular unleaded gasoline with
an octane rating of 87 RON/91 MON. This
may reduce engine performance and increase fuel consumption. Avoid driving at full throttle
and sudden acceleration. Never refuel using
fuel with a lower AKI. Information on refueling (Y
page 178).
Additives ! Operating the engine with fuel additives
added later can lead to engine failure. Do
not mix fuel additives with fuel. This does
not include additives for the removal and
prevention of residue buildup. gasoline
must only be mixed with additives recom-
mended by Mercedes-Benz. Comply with
the instructions for use on the product
label. More information about recommen-
ded additives can be obtained from any
authorized Mercedes-Benz Center.
Mercedes-Benz recommends that you use
branded fuels that have additives.
The quality of the fuel available in some coun- tries may not be sufficient. Residue could
build up in the injection system as a result. In
such cases, and in consultation with an
authorized Mercedes-Benz Center, the gaso-
line may be mixed with the cleaning additive
recommended by Mercedes-Benz. You must
observe the notes and mixing ratios specified
on the container.
Diesel Fuel grade
G
WARNING
If you mix diesel fuel with gasoline, the flash
point is lower than that of pure diesel fuel.
When the engine is running, exhaust system
components could overheat without being
noticed. There is a risk of fire.
Never refuel with gasoline. Never mix gasoline with diesel fuel.
! Refuel only using diesel fuel that con-
forms to European standard EN 590 or an
equivalent specification. Fuel that does not conform to EN 590 can lead to increased
wear and damage the engine and exhaust
system. Service products and filling capacities
449Technical data Z

!
Do not use the following:
R marine diesel
R heating oil
R bio-diesel
R vegetable oil
R gasoline
R paraffin
R kerosene
Do not mix such fuels with diesel fuel and
do not use any special additives. This can
otherwise lead to engine damage.
! Vehicles with diesel particle filters:
in
countries outside the EU, only use low sul- fur Euro diesel with a sulfur content of
under 50 ppm. Otherwise, the emission
control system could be damaged.
! Vehicles without a diesel particle fil-
ter: in countries where only diesel fuel with
a high sulfur content is available, you will
need to carry out your vehicle's oil change
at shorter intervals. Further information on
oil change intervals can be obtained at a
qualified specialist workshop.
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for assis-
tance.
Information on refueling (Y page 178).
Bio-diesel – FAME (fatty acid methyl ester) Mercedes-Benz USA approves the use of bio-diesel B5 for all BlueTEC diesel engines. The
concentration of bio-diesel in the ULSD may
not exceed 5% by volume.
Pure bio-diesel and diesel fuel with a higher
percentage of bio-diesel, such as B20, can
damage the engine and the fuel system. For
this reason, they are not approved.
For more information, consult the gas station
staff. The bio-diesel B5 label on the gasoline
pump must clearly state that the standard for ULSD has been fulfilled. If the label is not
clear, do not refuel the vehicle. Do not refuel your vehicle with fuels unless
they have been approved by Mercedes-Benz.
Information on refueling (Y page 178).
Low outside temperatures
i Diesel fuel with improved cold flow prop-
erties is available during the winter months.
Further information about fuel properties
can be obtained from oil companies, e.g. at gas stations.
Flexible Fuel vehicles Important safety notes
G
WARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and explo-
sion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before refueling. G
WARNING
Fuel is poisonous and hazardous to health.
There is a risk of injury.
You must make sure that fuel does not come into contact with your skin, eyes or clothing
and that it is not swallowed. Do not inhale fuel
vapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
R Wash away fuel from skin immediately
using soap and water.
R If fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance with-
out delay.
R If fuel is swallowed, seek medical assis-
tance without delay. Do not induce vomit-
ing.
R Immediately change out of clothing which
has come into contact with fuel. 450
Service products and filling capacitiesTechnical data

Flexible Fuel vehicles can be refueled with the
following fuel types:
R premium-grade unleaded gasoline
R E85 fuel
R a mixture of E85 fuel and premium-grade
unleaded gasoline
i Flexible Fuel vehicles can be recognized
by the Ethanol up to E85 sticker on the
inside of the fuel filler flap.
Fuel consumption
The energy content of E85 fuel is less than
that of the same amount of premium-grade
gasoline. The amount of fuel consumed when operating the vehicle with E85 fuel is there-
fore higher than with premium-grade gaso-
line.
Maintenance
Inform your authorized Mercedes-Benz Cen-
ter that you are operating or have operated
the vehicle with E85 fuel.
Low outside temperatures
If the outside temperature is below 32 ‡
(0 †), the starting procedure can take notice-
ably longer when operating with E85 fuel.
E85 fuel is not suitable for use at outside
temperatures under -4 ‡ (-20 †). DEF
Important safety notes Comply with the important safety notes for
service products when handling DEF
(Y
page 447).
DEF is a water-soluble fluid for the exhaust
gas aftertreatment of diesel engines. It is:
R not poisonous
R colorless and odorless
R not flammable
When you open the DEF container, small
amounts of ammonia vapor may be released. Ammonia vapors have a pungent odor and are
particularly irritating to the skin, to mucous
membranes and to the eyes. You may expe-
rience a burning sensation in your eyes, nose and throat. Coughing and watering of the
eyes are possible.
Do not inhale ammonia vapors. Fill the DEF
tank only in well-ventilated areas.
Low outside temperatures DEF freezes at a temperature of approx-
imately 12
‡(-11 †). The vehicle is delivered
from the factory equipped with a DEF pre-
heating system. Winter operation can thus be
guaranteed even at temperatures below 12 ‡
(-11 †).
Additives !
Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas after-
treatment system.
Purity !
Impurities in DEF (e.g. due to other ser-
vice products, cleaning agents or dust) lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC exhaust gas
aftertreatment system
Assuring the purity of DEF is particularly
important with respect to avoiding malfunc-
tions in the BlueTEC exhaust gas aftertreat-
ment system.
If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to the tank. The purity of the fluid can no longer
be guaranteed. Service products and filling capacities
451Technical data Z

Model Capacity
ML 350 Blue-
TEC 4MATIC
8.5 US qt (8.0
l) AM
G vehicles Without external oil
cooler: 9.0 US qt (8.5l) Ad
ditives !
Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity Viscosity describes the flow characteristics
of a fluid. If an engine oil has a high viscosity, this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE classification (viscosity) suitable for the prevailing outside
temperatures. The table shows you which
SAE classifications are to be used. The low-
temperature characteristics of engine oils
can deteriorate significantly, e.g. as a result
of aging, soot and fuel deposits. It is therefore
strongly recommended that you carry out reg- ular oil changes using an approved engine oil
with the appropriate SAE classification. Brake fluid
G
WARNING
The brake fluid constantly absorbs moisture
from the air. This lowers the boiling point of
the brake fluid. If the boiling point of the brake fluid is too low, vapor pockets may form in the
brake system when the brakes are applied
hard. This would impair braking efficiency.
There is a risk of an accident.
You should have the brake fluid renewed at
the specified intervals.
Comply with the important safety notes for
service products when handling brake fluid
(Y page 447).
The brake fluid change intervals can be found
in the Maintenance Booklet.
Only use brake fluid approved by Mercedes-
Benz according to MB Approval 331.0.
Information about approved brake fluid can
be obtained at any qualified specialist work-
shop or on the Internet at
http://bevo.mercedes-benz.com.
i Have the brake fluid regularly replaced at
a qualified specialist workshop and the
replacement confirmed in the Maintenance Booklet. Coolant
Important safety notes G
WARNING
If antifreeze comes into contact with hot com- ponents in the engine compartment, it may
ignite. There is a risk of fire and injury.
Let the engine cool down before you add anti-
freeze. Make sure that antifreeze is not spilled
next to the filler neck. Thoroughly clean the
antifreeze from components before starting
the engine.
! Only add coolant that has been premixed
with the desired antifreeze protection. You
could otherwise damage the engine.
Further information on coolants can be
found in the Mercedes-Benz Specifications for Service Products, MB BeVo 310.1, e.g.
on the Internet at
http://bevo.mercedes-benz.com. Or con-
tact a qualified specialist workshop. Service products and filling capacities
453Technical data Z