2014 MERCEDES-BENZ M-Class fuel additives

Exhaus
tcheck ............................... 182
Fuel ................................................ 182
General .......................................... 182
Hydroplaning ................................. 186
Icy road surfaces ........................... 187
Limited braking efficiency on
salted road s................................... 184
Off-road driving .............................. 188
Off-road fording ............................. 186
Snow chains .................................. 401
Symmetrical low bea m.................. 120
Tire ruts ......................................... 190
Towing atrailer .............................. 253
Traveling uphill ............................... 190
Wet road surface ........................... 184
DSR (Downhill Spee dRegulation)
Display message ............................ 304
Function/notes ............................. 246
DVD audio
Operating (on-board computer) .....270
DVD video
Operating (on-board computer) .....270 E
EASY-ENTRY feature Activating/deactivating .................277
Function/notes ............................. 113
EASY-EXIT feature
Crash-responsive ........................... 114
Function/notes ............................. 113
Switching on/off ........................... 277
EASY-PACK load-securing kit ...........340
EBD (electronic brake force
distribution)
Display message ............................ 285
Function/notes ................................ 74
ECO display
Function/notes ............................. 183
On-board computer .......................267
ECO start/stop function
Automatic engine start ..................162
Automatic engine switch-off ..........162
Deactivating/activating .................163
General information .......................161
Important safety notes ..................161
Introduction ................................... 161Electronic Stability Program
see ESP ®
(Electroni cStability Program)
Emergenc yrelease
Driver's door .................................... 88
Vehicle ............................................. 88
Emergency spare wheel
General notes ................................ 436
Important safety notes ..................436
Removing ....................................... 436
Storage location ............................ 436
Technical data ............................... 438
Emergency Tensioning Devices
Function .......................................... .59
Safety guideline s............................. 43
Emergency unlocking
Tailgate ............................................ 93
Emissions control
Service and warranty information ....24
Engine
Check Engine warning lamp ........... 325
Display message ............................ 298
ECO start/stop function ................161
Engine number ............................... 443
Irregularr unning............................ 164
Jump-starting ................................. 389
Starting problems ..........................164
Starting the engine with the
SmartKey ....................................... 159
Starting with KEYLESS-GO .............160
Switching off .................................. 180
Tow-starting (vehicle) ..................... 394
Engine electronics
Problem (malfunction) ...................164
Engine oil
Adding ........................................... 366
Additives ........................................ 449
Checking the oil level ..................... 365
Checking the oil level using the
dipstick .......................................... 365
Display message ............................ 300
Filling capacity ............................... 449
Notes about oil grades ................... 448
Notes on oil level/consumption ....365
Temperature (on-board computer) .278
Viscosity ........................................ 44910
Index

ESP
®
(Electronic Stability
Program) AMG menu (on-board computer) ...279
Deactivating/activating ...................72
Display message ............................ 283
ETS/4ETS ........................................ 71
Function/notes ................................ 71
General notes .................................. 71
Important safety information ...........72
Trailer stabilization ........................... 73
Warning lamp ................................. 321
ETS/4ETS (Electronic Traction
System) ................................................ 71
Exhaus tcheck ................................... 182
Exhaus tpipe (cleaning instructions) 374
Exterior lighting see Lights
Exterior mirrors
Adjustin g....................................... 114
Dipping (automatic) .......................115
Folding in/ou t(automatically) .......115
Folding in/ou t(electrically) ...........115
Folding in whe nlocking (on-board
computer) ...................................... 277
Out of position (troubleshooting) ...115
Setting ........................................... 115
Storing settings (memory function) 117
Storing the parking position ..........116
Eyeglasses compartment .................334 F
Fille rcap
see Fuel filler flap
First-aid kit ......................................... 380
Flat tire MOExtended tires ..........................382
Preparing the vehicle .....................381
TIREFIT kit ...................................... 383
see Emergency spare wheel
Floormats ........................................... 362
Folding the rear bench seat
forwards/back .................................. 335
Fording Off-road ......................................... 186
On flooded road s........................... 186Fuel
Additives ........................................ 446
Consumption statistics ..................266
Displaying the current
consumption .................................. 267
Displaying the range ......................267
Driving tips .................................... 182
Flexible fuel vehicles ......................447
Fuel gauge ............................... 33, 263
Grade (gasoline) ............................ 445
Important safety notes ..................444
Low outside temperatures .............446
Premium-grade unleaded gasoline .445
Problem (malfunction) ...................176
Quality (diesel )............................... 446
Refueling ........................................ 173
Tank content/reserve fuel .............445
Fuel filler flap
Opening/closing ............................ 174
Fuel filte r(display message) ............301
Fuel level Calling up the range (on-board
computer) ...................................... 267
Fuel tank
Capacity ........................................ 445
Problem (malfunction) ...................176
Fuses
Allocation chart ............................. 395
Before changing ............................. 395
Dashboard fuse box .......................395
Fuse box in the engine
compartment ................................. 395
Fuse box unde rrear bench seat ....396
Important safety notes ..................394 G
Garage door opener Clearing the memory .....................361
Important safety notes ..................359
Opening/closing the garage door ..361
Programming (button in the rear-
view mirror) ................................... 359
Gear indicator (on-board computer) 278
Genuine parts ...................................... 23
Glove box ........................................... 333
GTW (Gross Trailer Weight)
(definition) ......................................... 419 Index
11

DEF (BlueTEC vehicles only)
Important notes on use To function properly, BlueTEC exhaus
tgas
aftertreatment must be operated with the
reducing agent DEF.
When the supply of DE Fis almost used up,
the Check Additive See Operator's Manual message is shown in the
multifunction display.
When the DEF supply drops to a minimum, the
Remaining Starts: 16 message is shown
in the multifunction display.
If the Remaining Starts: 16 message
appears in the multifunction display, you can
start the engine another 16 times. If DEF is
not refilled, you will subsequently be unable
to start the engine. Fill the DEF tank with
approximately 1gal (3. 8l) DEF. Have the DEF
tan krefilled at a qualified specialist
workshop.
i If you drive the vehicle faster than
10 mph (16 km/h), the Check Additive See Operator's Manual message goes
out after approximately one minute.
If the outside temperature is below 12 ‡
(001911 †) it may be difficult to top up. If DEF is
frozen and there is an active warning
indicator, it may not be possible to add DEF.
Park the vehicle in a warmer place, e.g. in a
garage, until DEF has become fluid again. It
will then be possible to add DEF again.
Alternatively, have the DEF tank refilled at a
qualified specialist workshop.
Further information about BlueTEC exhaust
gas aftertreatment and DEF is available at any
authorized Mercedes-Benz Center. Important safety notes on the refilling
procedure DEF is a water-soluble fluid for the exhaust
gas aftertreatment of diesel engines. It is:
R
not poisonous
R colorless and odorless
R not flammable
When you open the DEF container, small
amounts of ammonia vapor may be released.
Ammonia vapors have a pungent odor and are
particularly irritating to the skin, to mucous
membranes and to the eyes. You may
experience a burning sensation in you reyes,
nose and throat. Coughing and watering of
the eyes are possible.
Do not inhale ammonia vapors. Fill the DEF
tank only in well-ventilated areas.
DEF must not come into contact with your
skin, eyes or clothing and mus tnot be
swallowed. Keep DEFa way fromchildren.
If you or other persons come into contact with
DEF, observe the following:
R Rinse DEF from your skin immediately with
soap and water.
R If DEF comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance
without delay.
R If DEF has been swallowed, rinse your
mouth out immediately. Drink plenty of
water. Seek medical assistance without
delay.
R Change out of clothing contaminated with
DEF immediately.
! Only use DEF in accordance with
ISO 22241. Do not mix any additives with
DEF, and do not dilute DEF with water. This
may destroy the BlueTEC exhaust gas
aftertreatment system.
! The vehicle must be parked on level
ground to fill the DEF tank. The DEF tank
can only be filled as intended with the
vehicle parked on a level surface. This
avoids false level readings. Filling the tank Refueling
177Driving and parking Z

Service products and filling
capacities Important safety notes
G
WARNING
Service products may be poisonous and
hazardous to health. There is a risk of injury.
Comply with instructions on the use, storage
and disposal of service products on the labels
of the respective original containers. Always
store service products sealed in their original
containers. Always keep service products out
of the reach of children. H
Environmental note
Dispose of service products in an
environmentally responsible manner.
Service products include the following:
R Fuels (e.g. gasoline, diesel)
R Exhaust gas aftertreatment additives, e.g.
DEF
R Lubricants (e.g. engine oil, transmission oil)
R Coolant
R Brake fluid
R Windshield washer fluid
R Climate control system refrigerant
Comply with all valid regulations with respect
to handling, storing, and disposing of service
fluids.
Components and service products must be
matched. You should therefore only use
products that have been tested and approved
by Mercedes-Benz.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
You can recognize service products approved
by Mercedes-Benz by the following
inscription on the containers:
R MB-Freigabe (e.g. MB-Freigabe 229.51)
R MB Approval (e.g. MB Approval 229.51) Other designations or recommendations
indicate a level of quality or a specification in
accordance with an MB Sheet number (e.g.
MB 229.5). They have not necessarily been
approved by Mercedes-Benz. Fuel
Important safety notes G
WARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and
explosion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before
refueling. G
WARNING
Fuel is poisonous and hazardous to health.
There is a risk of injury.
You must make sure that fuel does not come
into contact with your skin, eyes or clothing
and that it is not swallowed. Do not inhale fuel
vapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
R Wash away fuel from skin immediately
using soap and water.
R If fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance
without delay.
R If fuel is swallowed, seek medical
assistance without delay.Don ot induce
vomiting.
R Immediately change out of clothing which
has come into contact with fuel. 444
Service products and filling capacitiesTechnical data

Tank capacity
Model Total
capacity All models
24.6 US gal
(93.0 l) Model Of which
reserve ML 63 AMG 4MATIC
Approx.
3.7 US gal (14.0 l) All other models
Approx.
3.2 US gal (12.0 l) Gasoline
Fuel grade
!
Do not use diesel to refuel vehicles with a
gasoline engine .Do not switch on the
ignition if you accidentally refuel with the
wrong fuel. Otherwise, the fuel will enter
the fuel system. Even small amounts of the
wrong fuel could result in damage to the
fuel system and the engine. Notify a
qualified specialist workshop and have the
fuel tank and fuel lines drained completely.
! Only refuel using unleaded gasoline with
a minimum octane rating of 91.
! Only use the fuel recommended.
Operating the vehicle with other fuels can
lead to engine failure.
! Do not use the following:
R E85 (gasoline with 85% ethanol)
R E100 (100% ethanol)
R M15 (gasoline with 15% methanol)
R M30 (gasoline with 30% methanol)
R M85 (gasoline with 85% methanol)
R M100 (100% methanol)
R Gasoline with metalliferous additives
R Diesel Do not mix such fuels with the fuel
recommended for your vehicle. Do not use
additives. This can otherwise lead to engine
damage. This does not include cleaning
additives for the removal and prevention of
residue build-up. gasoline may only be
mixed with cleaning additives
recommended by Mercedes-Benz; see
"Additives". You can obtain further
information from any authorized Mercedes-
Benz Center.
! To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline must be used.
If standard premium-grade unleaded
gasoline is unavailable and unleaded
gasoline of a lower grade is used for
refueling, observe the following
precautions:
R only fill the fuel tank to half full with
regular unleaded gasoline and fill the rest
with premium-grade unleaded gasoline
as soon as possible.
R do not drive at the maximum speed.
R avoid sudden acceleration and engine
speeds above 3000 rpm.
R never refuel using fuel with an octane
number lower than 87. Otherwise,
engine failure could occur.
Using mixtures of methanol and ethanol is not
permitted. E10 fuel or E15 fuel (unleaded
gasoline with 10% or 15% ethanol) can be
used.
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult a
qualified specialist workshop or on the
Internet at http://www.mbusa.com (USA
only).
Information on refueling (Y page 174). Service products and filling capacities
445Technical data Z

Additives
!
Operating the engine with fuel additives
added later can lead to engine failure. Do
no tm ix fuel additives with fuel. This does
not include additives for the removal and
prevention of residue buildup. gasoline
must only be mixed with additives
recommended by Mercedes-Benz. Comply
with the instructions for use on the product
label. More information about
recommended additives can be obtained
fro ma ny authorized Mercedes-Benz
Center.
Mercedes-Benz recommends tha tyou use
fuel brands that have the additives.
The quality of the fuel available in some
countries may not be sufficient .Residue
could build up as a result. In such cases, and
in consultation with an authorized Mercedes-
BenzC enter, the gasoline may be mixed with
the cleaning additive recommended by
Mercedes-Benz (part no. A000989254512).
You must observe the notes and mixing ratios
specified on the container.
Diesel Fuel grade
G
WARNING
If you mix diesel fuel with gasoline, the flash
point is lower than that of pure diesel fuel.
When the engine is running, exhaust system
components could overheat without being
noticed. There is a risk of fire.
Never refuel with gasoline. Never mix gasoline
with diesel fuel.
! Only use commercially available vehicular
ULTRA-LOW SULFUR DIESEL FUEL (ULSD,
15 ppm maximum sulfur content) that
meets the ASTM D975 standard. If you do
not refuel with ULSD ,you may damage the
BlueTEC exhaust gas aftertreatment
system of the vehicle.
! Do not use gasoline to refuel vehicles with
a diesel engine. Do not mix diesel fuel with gasoline, kerosene or paraffin. This may
otherwise result in damage to the fuel
system and engine.
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult a
qualified specialist workshop or on the
Internet at http://www.mbusa.com (USA
only).
Information on refueling (Y page 174).
Bio-diesel -FAME (fatt yacid methyl ester)
Mercedes-Ben zUSA approves the use of bio-
diesel B5 for all BlueTEC diesel engines. The
concentration of bio-diesel in the ULSD may
not exceed 5% by volume.
Pure bio-diesel and diesel fuel with a higher
percentage of bio-diesel, such as B20, can
damage the engine and the fuel system. For
this reason, they are not approved.
For more information, consult the gas station
staff. The bio-diesel B5 label on the gasoline
pump mus tclearly state that the standard for
ULS Dhas been fulfilled. If the label is not
clear, do no trefuel the vehicle.
Do not refuel your vehicle with fuels unless
they have been approved by Mercedes-Benz.
Information on refueling (Y page 174).
Low outside temperatures
i Diesel fuel with improved cold flow
properties is available during the winter
months. Further information about fuel
properties can be obtained from oil
companies, e.g. at gas stations.
Flow improver
To improve the low-temperature resistance of
diesel fuel, a flow improver can be attached.
The effectiveness of a flow improver is not
guaranteed for every fuel.
Only use flow improvers tested and approved
by Mercedes-Benz. Durin guse, please
observe the information on operation. 446
Service products and filling capacitiesTechnical data

The table shows which engine oils have been
approved for your vehicle. Model Engine
model MB
Approval ML 250 BlueTEC
4MATIC
651 228.51,
229.31,
229.51 ML 350
ML 350 4MATIC
276 229.5
ML 350 BlueTEC
4MATIC
642 228.51,
229.31,
229.51 ML 550 4MATIC
278 229.5
ML 63 AMG
4MATIC
157 229.5
i
MB approval is indicated on the oil
containers.
Filling capacities The following values refer to an oil change
including the oil filter.
Missing values were not available at time of
going to print. Model Capacity
ML 250 BlueTEC
4MATIC
6.9 US qt (6.5 l)
ML 350
ML 350 4MATIC
7.4 US qt (7.0 l)
ML 350 BlueTEC 4
MATIC
8.5 US qt (8.0 l)
ML 550 4MATIC
9.0 US qt (8.5 l)
ML 63 AMG
4MATIC
Without external oil
cooler: 9.0 US qt (8.5 l) Additives
!
Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity Viscosity describes the flow characteristics
of a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE classification
(viscosity) suitable for the prevailing outside
temperatures. The table shows you which
SAE classifications are to be used. The low-
temperature characteristics of engine oils
can deteriorate significantly, e.g. as a result
of aging, soot and fuel deposits. It is therefore
strongly recommended that you carry out
regular oil changes using an approved engine
oil with the appropriate SAE classification.
Brake fluid
G
WARNING
The brake fluid constantly absorbs moisture
from the air. This lowers the boiling point of
the brake fluid. If the boiling point of the brake
fluid is too low, vapor pockets may form in the
brake system when the brakes are applied
hard. This would impair braking efficiency.
There is a risk of an accident.
You should have the brake fluid renewed at
the specified intervals. Service products and filling capacities
449Technical data Z