2013 MERCEDES-BENZ S-Class fuel additives

Important safety information
...........75
Warning lamp ................................. 430
ETS/4ETS (Electronic Traction
System) ................................................ 76
Exhaus tcheck ................................... 331
Exhaus ttail pipe (cleaning
instructions) ...................................... 474
Exterior lighting see Exterior lighting
Exterior mirror parking position
Adjusting (COMAND) .....................266
Exterior mirrors
Adjusting ....................................... 116
Dipping (automatic) .......................117
Folding in/ou t(automatically) .......116
Folding in/ou t(electrically) ...........116
Out of position (troubleshooting) ...116
Storing settings (memory
function) ........................................ 118
Storing the parking position ..........117
Eyeglasses compartment .................439 F
Factory setting (reset function) .......154
Fader, setting .................................... 139
Fast forward Audio mode (CD, DVD, MP3) .........230
Rear Seat Entertainment System ...260
Video DVD ..................................... 247
Fast rewind
Audio mode (CD, DVD, MP3) .........230
Rear Seat Entertainment System ...260
Video DVD ..................................... 247
Favorites (COMAND) .........................124
Fille rcap
see Fuel filler flap
Filling capacities (Technical data) ...530
First-aid kit ......................................... 478
Flat tire Changing a wheel/mounting the
spare wheel ................................... 479
MOExtended run-fla tsystem ......... 483
Preparing the vehicle .....................479
Raising the vehicle .........................480
Floormat ............................................ .460
Freeway information .........................191Front fog lamps
................................. 282
Display message ............................ 406
Switching on/off ........................... 282
Front-passenger seat
Adjusting from the driver's seat ..... 109
Adjusting from the rear
compartment ................................. 109
Fron twindshield
see Windshield
Fuel
Additives ........................................ 532
Displaying the current
consumption .................................. 378
Displaying the range ......................378
Driving tips .................................... 330
Fuel gauge ....................................... 37
Grade (gasoline) ............................ 531
Important safety notes ..................531
Premium-grade unleaded gasoline .531
Problem (malfunction) ...................324
Quality (diesel )............................... 532
Refueling ........................................ 321
Tank content/reserve fuel .............531
Fuel filler flap, opening/closing ....... 322
Fuel filte r(display message) ............412
Fuel level Calling up the range (on-board
computer) ...................................... 378
Fuel tank
Capacity ........................................ 531
Problem (malfunction) ...................324
Function buttons (COMAND) ............123
Fuses Allocation chart ............................. 493
Before changing ............................. 493
Dashboard fuse box .......................493
Engine emergency stop .................495
Fuse box in the engine
compartment ................................. 494
Fuse box in the rear compartment .493
Important safety notes ..................492 G
Garage door opener Clearing the memory .....................459
Important safety notes ..................45612
Index

DEF (BlueTEC vehicles only)
Important notes on use To function properly, BlueTEC exhaus
tgas
aftertreatment must be operated with the
reducing agen tDEF. Adding DEF is one of the
tasks performed during maintenance. Under
normal operating conditions, a tank of DEF
lasts until the next service due date.
When the DEF level is too low, the CheckAdditive See Operator's Manual
message is shown in the multifunction
display.
When the DEF supply sinks to a minimum
level, the Remaining Starts: 16 message
is shown in the multifunctio ndisplay.
When the Remaining Starts: 16 message
is shown in the multifunction display, you can
start the engine 16 more times. If DEF is not
added, it will the nnot be possible to restart
the engine. Fill the DEFt ank with about1gal
(3.8l) of DEF or have the DEF tank refilled at
a qualified specialist workshop.
Use the special DE Frefill bottle when filling
between maintenance intervals. Contact an
authorized Mercedes-BenzC enter with any
questions or, if necessary, contact Roadside
Assistance (Y page 29).
If the outside temperature is lower than 12 ‡
(002711 †), damage may occur when adding
DEF. If DEF is frozen and there is an active
warning indicator, adding may not be
possible. Park the vehicle in a warmer place,
e.g. in a garage, until DEFh as become fluid
again .Itwill the nbe possible to add DEF
again. Alternatively, have the DEFt ank refilled
at a qualified specialist workshop.
Further informatio nabout BlueTEC exhaust
gas aftertreatment and DEFi s available at any
authorized Mercedes-Benz Center. Adding DEF G
WARNING
Make sure
R DEF does not come into contact with skin,
eyes, or clothing
R to keep DEF out of the reach of children
If you and/or others have come into contact
with DEF:
R If DEF has gotten into contact with eyes,
flush with plenty of water immediately and
seek medical help.
R Cleana ffected skin immediately with plenty
of water.
R If DEF was swallowed, rinse mouth
immediately with plenty of water and drink
plenty of water. Consult a physician. G
WARNING
If you open the DEF tank cap, small amounts
of ammonia vapo rmay be released. This
depends in particular upon the age of the DEF.
Ammonia vapors have a pungent odor and are
particularly irritating to:
R skin
R mucous membranes
R eyes
You may experience a burning sensation in
your eyes, nose and throat, as well as
coughing and watering of the eyes.
Do not inhale any ammonia vapors that may
be released. Fill the DE Ftank only in well-
ventilated areas.
! Only use DEF in accordance with
ISO 22241. Do not mix any additives with
DEF, and do no tdilute DE Fwith water .This
may destroy the BlueTEC exhaust gas
aftertreatment system.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF Refueling
325Driving and parking Z

i
The data shown on the identification plate
is example data. This data is different for
every vehicle and can deviate from the data
shown here. You can find the data
applicable to your vehicle on the vehicle's
identification plate. Vehicle identification number (VIN)
The vehicle identification number (VIN) can
be found in the following locations:
R on the vehicle identification plate
(Y page 529)
R at the lower edge of the windshield
(Y page 530)
In addition to being stamped on the vehicle
identification plate, the vehicle identification
number (VIN) is also stamped onto the vehicle
body. It is under the trim behind the rear seat
armrest. X
Fold down the rear seat armrest.
X Open the trim.
You will see vehicle identification number
(VIN) 0002. Engine number
0002
Emission control information plate,
including the certification of both federal
and Californian emissions standards
0003 Engine number (stamped into the
crankcase)
0026 VIN (on the lower edge of the windshield) Service products and filling
capacities
Important safety notes
G
WARNING
Comply with all valid regulations with respect
to handling, storing and disposing of service
fluids. Otherwise, you could endanger
persons or the environment.
Keep service fluids out of the reach of
children.
For health reasons, you should prevent
service fluids from coming into direct contact
with your skin or clothing.
If a service fluid is swallowed, contact a
physician immediately. H
Environmental note
Dispose of service products in an
environmentally responsible manner.
Service products include the following:
R fuels (e.g. gasoline, diesel)
R exhaust gas aftertreatmen tadditives, e.g.
DEF 530
Service products and filling capacitiesTechnical data

with premium-grade unleaded gasoline
as soon as possible.
R do not drive at the maximum speed.
R avoid sudden acceleration.
R if the vehicle is carrying a light load, e.g.
two passengers without luggage, do not
allow the engine to rev above 3000 rpm.
R if the vehicle is fully loaded or is being
operated in mountainous terrain, do not
depress the accelerator pedal further
than 0001of the pedal travel.
Only refuel using premium-grade unleaded
gasoline with a minimum octane rating of 91.
Reformulated Gasoline (RFG) and/or
unleaded gasoline with additives can be used.
The concentratio nofadditives in the fuel,
however, must not exceed 10 %, e.g.:
R Ethanol
R TAME
R ETBE
R IPA
R TBA
For MTBE, the concentration should not
exceed 15 %.
The concentration of methanol in gasoline,
including other additives, must not exceed
3 %.
Using mixtures of methanol and ethanol is not
permitted. Gasohol, a mixture of 10 % ethanol
and 90 % unleaded gasoline, may be used.
All of these mix fuels must fulfill the fuel
requirements, e.g.:
R knock resistance
R boiling point
R vapor pressure
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult an
authorized Mercedes-Benz Cente roron
the Internet at http://www.mbusa.com
(USA only). Information on refueling (
Ypage 321).
Additives
! Do not refuel with low-grade fuel and do
not use fuel additives tha tare not tested
and approved for Mercedes-Benz vehicles.
Damage to or malfunctions of the fuel
system may otherwise occur.
One of the main problems of poor fuel quality
is the forming of deposits that are created
during the gasoline combustion process.
Mercedes-Benz recommends that you use
branded fuels that have additives.
If you use fuels without these additives over
a longer period of time, carbon deposits may
build up. These deposits form at the inlet
valves and in the combustion chambe rin
particular.
This could lead to engine problems, e.g.:
R longer engine warm-up phase
R uneven idle
R engine noise
R misfiring
R loss of power
Carbon deposits may form if the availability
of gasoline with relevant additives is
insufficient (in certain regions). In this case,
Mercedes-Benz recommends additives
approved for use in Mercedes-Benz vehicles;
see http://bevo.mercedes-benz.com.
For a list of approved products, consult an
authorized Mercedes-Benz Center. Comply
with the instructions for use on the product
label.
Do not mix other fuel additives with fuel. This
causes unnecessary costs and could damage
the engine.
Diesel Fuel grade
G
WARNING
Do not use gasoline to refuel vehicles with a
diesel engine. Never mix diesel with gasoline.
This causes damage to the fuel system and 532
Service products and filling capacitiesTechnical data

Model Engine
model MB
Approval
S 550
31
S 550 4MATIC 31 278 229.5
S 600
275
S 63 AMG
32 157
S 65 AMG
32 275
S 350 BlueTEC
4MATIC
642 228.51,
229.31,
229.51
i
MB approval is indicated on the oil
containers.
Filling capacities The following values refer to an oil change
including the oil filter. Model Capacity
S 550
33
S 550 4MATIC 33 9.0 US qt (8.5 l)
S 63 AMG
10.0 US qt (9.5 l)
34 S 600
S 65 AMG
9.5 US qt (9.0 l)
S 350 BlueTEC
4MATIC
8.5 US qt (8.0 l)
Additives
!
Do not use any additives in the engine oil.
This could damage the engine. Engine oil viscosity Viscosity describes the flow characteristics
of a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE (viscosity)
classification suitable for the prevailing
outside temperatures. The table shows you
which SAE classifications are to be used. The
low-temperature characteristics of engine
oils can deteriorate significantly, e.g. as a
result of aging, soot and fuel deposits. It is
therefore strongly recommended that you
carry out regular oil changes using an
approved engine oil with the appropriate SAE
classification.
Brake fluid
G
WARNING
Over a period of time, the brake fluid absorbs
moisture from the air; this lowers its boiling
point.
If the boiling point of the brake fluid is too low,
vapor pockets may form in the brake system
when the brakes are applied hard (e.g. when
driving downhill). This would impair braking
efficiency.
You should have the brake fluid renewed at
regular intervals. The brake fluid change
31 BlueEFFICIENCY
32 Only SAE 0W-40/SAE 5W-40 engine oils may be used.
33 BlueEFFICIENCY
34 Including external oil cooler. Service products and filling capacities
535Technical data
Z