2013 MERCEDES-BENZ S-Class engine coolant

Display messages Possible causes/consequences and
0004 Solutions
0002
Malfunction See
Oper. Manual The exterio
rlighting is defective.
X Visit a qualified specialist workshop. 0002
AUTO
Lamp Function
Inoperative The light sensor is defective.
X
Visit a qualified specialist workshop.
USA only:
X Switch off the daytime running lamps in the on-board computer
(Y page 387).
X Switch the lights on and off using the light switch. 0002
Please Switch Off
Lights The lights are still switched on when you leave the vehicle. A
warning tone also sounds.
X
Turn the light switch to 000Eor000D.
or
X If the rear fog lamp is switched on: press the light switch in to
the stop. Adaptive High-beam
Assist Inoperative Adaptive Highbeam Assist is faulty.
X
Visit a qualified specialist workshop. Engine
Displa
ymessages Possible causes/consequences and
0004 Solutions
000D
Check Coolant
Level See Oper.
Manual The coolant level is too low.
!
Avoid making long journeys with too little coolant in the engine
cooling system. The engine will otherwise be damaged.
X Add coolant, observing the warning notes before doing so
(Y page 467).
X If coolant needs to be added more often than usual, have the
engine coolant system checked at a qualified specialist
workshop. 408
Displa
ymessagesOn-board computer and displays

Display messages Possible causes/consequences and
0004 Solutions
000C The fan motor is faulty.
X
At coolan ttemperatures under 248 ‡(120 †), drive to the next
qualified specialist workshop.
X Avoid subjecting the engine to heavy loads, e.g. driving in
mountainous terrain, and stop-and-go traffic. 000C
Coolant Low Stop
Vehicle Turn
Engine Off The coolant is too hot.
Aw
arning tone also sounds.
G WARNING
Do no tdrive when youre ngine is overheated. Thi scan cause some
fluids which may have leaked into the engine compartmen tto
catch fire.
Stea mfrom the overheated engine can also cause serious burns
which can occur just by opening the hood.
There is a risk of injury.
X Pull over and stop the vehicle safely and switch off the engine,
paying attention to road and traffic conditions.
X Secure the vehicle against rolling away (Y page 327).
X Leave the vehicle and keep a safe distance from the vehicle until
the engine has cooled down.
X Make sure that the air supply to the engine radiator is not
blocked, e.g. by snow, slush or ice.
X Do not start the engine again until the display message goes out
and the coolant temperature is under 248 ‡ (120 †).
Otherwise, the engine could be damaged.
X Pay attention to the coolant temperature display.
X If the temperature increases again, visit a qualified specialist
workshop immediately.
Under normal operating conditions and with the specified coolant
level, the coolant temperature may rise to 248 ‡ (120 †). Display messages
409On-board computer and displays Z

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible. Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Please read the information on qualified
specialist workshops (Y page 31).Engine compartment
Hood
Opening the hood G
WARNING
Do not pull the release lever while the vehicle
is in motion. Otherwise, the hood could be
forced open by passing air flow.
This could cause the hood to come loose and
injure you and/o rothers. G
WARNING
Hybrid vehicles :be sure to read the "HYBRID"
supplement .Otherwise, you could fail to
recognize dangers. G
WARNING
Do not open the hood when the engine is
overheated. You could be seriously injured.
Observe the coolant temperature gauge to
determine whether the engine may be
overheated. If you see flames or smoke
coming from the engine compartment, move
away fro mthe vehicle. Wait until the engine
has cooled. If necessary, call the fire
department. G
WARNING
There is a risk of injury if the hood is open,
even if the engine is not running. Some engine components can become very
hot.
To avoid the risk of burns, only touch those
components described in the Operator's
Manual and observe the relevant safety notes. G
WARNING
To avoid injury, stay clear of moving parts
when the hood is open and the engine is
running.
The radiator fan may continue to run for
approximately 30seconds or may even restart
after the engine has been switched off. For
this reason, you must not reach into the fan
rotation area. G
WARNING
Vehicles with gasoline engine:
The engine is equipped with a transistorized
ignition system. Because of the high voltage
it is dangerous to touch any components
(ignition coils, spark plug sockets, diagnostic
socket) of the ignition system
R with the engine running
R while starting the engine
R when the ignition is switched on and the
engine is turned manually G
WARNING
Vehicles with diesel engine:
The engine is equipped with a high-voltage
electronic control unit for the injection
system. Because of the high voltage it is
dangerous to touch any components of the
injection system (injectors, electrical wires)
R with the engine running
R while starting the engine
R when the ignition is switched on
X Make sure that the windshield wipers are
switched off. G
WARNING
The windshield wipers and wiper linkage
could be set in motion. 462
Engine compartmentMaintenance and care

H
Environmental note
When adding oil, take care not to spill any. If
oil enters the soil or waterways, it is harmful
to the environment.
! Only use engine oils and oil filters that
have been approved for vehicles with a
service system. You can obtain a list of the
engine oils and oil filters tested and
approved in accordance with the
Mercedes-Benz Specifications for Service
Products at any Mercedes-Benz Service
center.
Damage to the engine or exhaust system is
caused by the following:
R using engine oils and oil filters that have
not been specifically approved for the
service system
R replacing engine oil and oil filters after
the interval for replacemen tspecified by
the service system has been exceeded
R using engine oil additives.
! Do not add too much oil. adding too much
engine oil can result in damage to the
engine or to the catalytic converter. Have
excess engine oil siphoned off. Example: engine oil cap
X
Turn cap 0002counter-clockwise and remove
it.
X Add engine oil.
Vehicles with oil level measurement
function in the on-board computer: observe
the information in the on-board computer
when doing so. Vehicles with an oil
dipstick: if the oil level is at or below the MIN mark on the dipstick, add 1.1 US qt
(1.0 liters) of engine oil.
X Replace cap 0002on the filler neck and turn
clockwise.
Ensure that the cap locks into place
securely.
X Check the oil level again with the oil
dipstic k(Ypage 464) or the on-board
computer (Y page 464).
Further information on engine oil
(Y page 534). Checking and adding other service
products
Checking the coolant level G
WARNING
In order to avoid any potentially serious burns:
R use extreme caution when opening the
hood if there are any signs of steam or
coolant leaking from the cooling system, or
if the coolant temperature display indicates
that the coolant is overheated.
R do not remove the pressure cap on the
coolant reservoir if the coolant temperature
is above 158 ‡(70 †). Allow the engine to
cool dow nbefore removing the cap. The
coolant reservoir contains hot fluid and is
under pressure.
R using a rag, slowly turn the cap
approximately 1
/ 2 turn to relieve excess
pressure. If opened immediately, scalding
hot fluid and steam will be blown out under
pressure.
R do not spill antifreeze on hot engine parts.
Antifreeze contains ethylene glycol which
may burn if it comes into contact with hot
engine parts. Engine compartment
467Maintenance and care Z

X
Park the vehicle on a level surface.
Only check the coolant level when the
vehicle is on a level surface and the engine
has cooled down.
X Turn the SmartKey to position 2in the
ignition lock (Y page 307).
On vehicles with KEYLESS-GO, press the
Start/Stop button twice (Y page 307).
X Check the coolant temperature display in
the instrument cluster.
The coolant temperature must be below
158 ‡ (70 †).
X Turn the SmartKey to position
0(Y page 307) in the ignition lock.
X Slowly turn cap 0002half a turn counter-
clockwise to allow excess pressure to
escape.
X Turn cap 0002further counter-clockwise and
remove it.
If the coolant is at the level of marker bar
0026 in the filler neck when cold, there is
enough coolant in coolant expansion
tank 0003.
If the coolant level is approximately 0.6 in
(1.5 cm) above marker bar 0026in the filler
neck when warm, there is enough coolant
in coolant expansion tank 0003.
X If necessary, add coolant that has been
tested and approved by Mercedes-Benz.
X Replace cap 0002and turn it clockwise as far
as it will go.
For further information on coolant, see
(Y page 536). Adding washer fluid to the windshield
washer system/headlam
pcleaning
system G
WARNING
Washer solvent/antifreeze is highly
flammable. Do not spill washer solvent/
antifreeze on hot engin eparts, because it may
ignite and burn .You could be seriously
burned. Example: washer fluid reservoir
Depending on the engine, the washer fluid
reservoir may be installed in different
locations.
X
To open: pull cap0002upwards by the tab.
X Add the premixed washer fluid.
X To close: press cap 0002onto the filler neck
until it engages.
The washer fluid reservoir is used for both the
windshield washer system and the headlamp
cleaning system.
Further information on windshield washer
fluid/antifreeze (Y page 537).
Brake fluid level !
If the brake fluid level in the brake fluid
reservoir has fallen to the MIN mark or
below, check the brake system
immediately for leaks. Also check the
thickness of the brake linings. Visit a
qualified specialist workshop immediately.
Do not add brake fluid. This does not
correct the malfunction. 468
Engine compartmentMaintenance and care

R
lubricants (e.g .engine oil, transmission oil)
R coolant
R brake fluid
R windshield washe rfluid
R climate control system refrigerant
Components and service products must be
matched .You should therefor eonly use
products tha thave been tested and approved
by Mercedes-Benz.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.co m.
You can recognize service products approved
by Mercedes-Ben zby the following
inscription on the containers:
R MB approval (e.g. MB approval 229.51)
R MB Approval (e.g. MB Approval 229.51)
Other designations or recommendations
indicate a level of quality or a specification in
accordance with an MB Sheet number (e.g.
MB 229.5). The yhave no tnecessarily been
approved by Mercedes-Benz. Fuel
Important safety notes G
WARNING
Gasoline and diesel fuels are highly flammable
and poisonous. They burn violently and can
cause serious injury.
Never allow sparks, flames or smoking
materials near gasoline or diesel fuel!
Turn off the engine before refueling.
Whenever you are around gasoline or diesel
fuel, avoid inhaling fumes and any skin or
clothing contact. Extinguish all smoking
materials.
Direct skin contact with fuels and the
inhalation of fuel vapors are damaging your
health. Tank capacity Total capacity
S 550
30
S 550 4MATIC 30
S 350 BlueTEC 4MATIC 21.9 US gal
(83.0 l) S 600
AMG vehicles
23.8 US gal
(90.0 l) Of which reserve
Approx.
2.9 US gal (11.0 l) Of which reserve fuel in
AMG vehicles
Approx.
3.7 US gal (14.0 l) Gasoline
Fuel grade
!
Do not use diesel to refuel vehicles with a
gasoline engine. Even small amounts of the
wrong fuel result in damage to the fuel
system and engine.
! You should only refuel with unleaded
premium-grade gasoline as this avoids
damaging the catalytic converter.
If engine running problems are apparent,
have the cause checked immediately and
repaired. Excess unburned fuel can
otherwise enter the catalytic converter,
leading to overheating and possibly
causing a fire.
! To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline may be used.
If there is no premium-grade unleaded
gasoline available and regular unleaded
gasoline must be used, please observe the
following precautions:
R only fill the fuel tank to half full with
regular unleaded gasoline and fill the rest
30 BlueEFFICIENCY Service products and filling capacities
531Technical data Z

intervals can be found in the Maintenance
Booklet.
Only use brake fluid approved by Mercedes-
Benz. Informatio nabout approved brake fluid
can be obtained at any qualified specialist
workshop or on the Internet at
http://bevo.mercedes-benz.com. Coolant
Important safety notes G
WARNING
Antifreeze is highly flammable. Fire, open
flames and smoking are prohibited when
handling antifreeze.
If antifreeze comes into contact with hot
engine parts, it may ignite and you could burn
yourself. Do not spill any antifreeze on hot
engine parts.
! Only add coolant that has been premixed
with the desired antifreeze protection. You
could otherwise damage the engine.
Further information on coolants can be
found in the Mercedes-Benz Specifications
for Service Products, MB Specifications for
Service Products 310.1, e.g. on the
Internet at
http://bevo.mercedes-benz.com. Or
contact a qualified specialist workshop.
! Always use a suitable coolant mixture,
even in countries where high temperatures
prevail.
Otherwise, the engine coolin gsystem is not
sufficiently protected from corrosion and
overheating.
The coolan tis a mixture of water and
antifreeze/corrosion inhibitor. It performs
the following tasks:
R corrosion protection
R antifreeze protection
R raising the boiling point If the coolant has antifreeze protection down
to -35 ‡ (-37 †), the boiling point of the
coolant under operating conditions is
approximately 266 ‡ (130 †).
The antifreeze/corrosion inhibitor
concentration in the engine cooling system
should:
R
be at least 50 %. This will protect the engine
cooling system against freezing down to
approximately -35 ‡ (-37 †).
R not exceed 55% (antifreeze protection
down to -49 ‡ [-45 †]). Otherwise, heat
will not be dissipated as effectively.
If the vehicle has lost coolant, add equal
amounts of water and antifreeze/corrosion
inhibitor. Mercedes-Benz recommends an
antifreeze/corrosion inhibitor concentrate in
accordance with MB Specifications for
Service Products 310.1.
The coolant is checked with every
maintenance interval at a qualified specialist
workshop.
i When the vehicle is first delivered, it is
filled with a coolant mixture that ensures
adequate antifreeze and corrosion
protection.
Capacity Model Capacity
S 550
35
S 550 4MATIC 35 Approx. 14.5 US qt
(13.7 l) S 600
Approx. 15.3 US qt
(14.5 l) S 63 AMG
Approx. 12.2 US qt
(11.5 l) S 65 AMG
Approx. 14.7 US qt
(13.9 l) S 350 BlueTEC
4MATIC
Approx. 12.0 US qt
(11.4 l) 35
BlueEFFICIENCY 536
Service products and filling capacitiesTechnical data