2013 MERCEDES-BENZ E-Class SEDAN Bluetec

ATTENTION ASSIST
Activating/deactivating .................237
Display message ............................ 261
Function/notes ............................. 210
Audio system
see separate operating instructions
Authorized Centers
see Qualified specialist workshop
Authorized Mercedes-Benz Center
see Qualified specialist workshop
Authorized workshops
see Qualified specialist workshop
AUTO lights
Display message ............................ 257
see Lights
Automatic engine start (ECO start/
stop function) .................................... 159
Automatic engine switch-off (ECO
start/stop function) .......................... 158
Automatic headlamp mode ..............121
Automatic transmission Automatic drive program ............... 166
Changing gear ............................... 164
DIRECT SELECT lever .....................162
Display message ............................ 271
Drive program display ....................162
Driving tips .................................... 164
Emergency running mode ..............169
Engaging drive position .................. 163
Engaging neutral ............................ 163
Engaging park position (AMG
vehicles) ........................................ 163
Engaging reverse gear ................... 163
Engaging the park position ............ 162
Kickdown ....................................... 165
Manual drive program ....................167
Overview ........................................ 161
Problem (malfunction) ...................169
Program selector button ................165
Pulling away ................................... 156
Selector lever ................................ 161
Shift ranges ................................... 166
Starting the engine ........................ 155
Steering wheel paddle shifters ...... 166
Transmission position display ........ 161
Transmission position display
(DIRECT SELECT lever) ................... 162
Transmission positions .................. 164Automatic transmission
emergency mode
...............................
169 B
Bag hook ............................................ 296
BAS (Brake Assist System) ................. 67
BAS PLUS (Brake Assist System
PLUS) .................................................... 68
Battery (SmartKey) Checking ..........................................

81
Important safety notes .................... 81
Replacing ......................................... 81
Battery (vehicle)
Charging ........................................ 350
Display message ............................ 259
Important safety notes .................. 348
Jump starting ................................. 352
Blind Spot Assist
Activating/deactivating ................. 237
Display message ............................ 264
Notes/function .............................. 214
see Active Blind Spot Assist
BlueTEC
Adding DEF .................................... 173
BlueTEC (DEF) .................................... 410
Bottle holder ...................................... 306
Box (trunk) ......................................... 299
Brake Assist see BAS (Brake Assist System)
Brake fluid
Display message ............................ 249
Notes ............................................. 412
Brake lamps
Display message ............................ 255
Brakes
ABS .................................................. 67
BAS .................................................. 67
BAS PLUS ........................................ 68
Brake fluid (notes) .........................412
Display message ............................ 247
Driving tips .................................... 180
High-performance brake system .... 181
Important safety notes .................. 180
Maintenance .................................. 181
Parking brake ................................ 176
Warning lamp ................................. 277 Index
5

Problem Possible causes/consequences and
M SolutionsThe fuel filler flap
cannot be opened. The fuel filler flap is not unlocked.
or
The SmartKey battery is discharged.
X
Unlock the vehicle using the mechanical key ( Y page 80).
X Open the trunk lid or the tailgate.
X Manually unlock the fuel filler flap using the emergency release
(Y page 171). The fuel filler flap is unlocked, but the opening mechanism is
jammed.
X
Consult a qualified specialist workshop. DEF (BlueTEC vehicles only)
Important notes on use To function properly, BlueTEC exhaust gas
aftertreatment must be operated with the
reducing
agent DEF. Adding DEF is one of the
tasks performed during maintenance. Under
normal operating conditions, a tank of DEF
lasts until the next service due date.
When the supply of DEF is almost used up,
the Check Additive See Operator's
Manual message is shown in the
multifunction display.
When the DEF supply drops to a minimum, the
Remaining Starts: 16 message is shown
in the multifunction display.
If the Remaining Starts: 16 message
appears in the multifunction display, you can
start the engine another 16 times. If DEF is
not added, it will then not be possible to
restart the engine. Fill the DEF tank with
about 1 gal (3.8l) of DEF or have the DEF tank
refilled at a qualified specialist workshop.
Use the special DEF refill bottle when filling
between maintenance intervals. Contact an
authorized Mercedes-Benz Center with any
questions or, if necessary, contact Roadside
Assistance ( Y page 23).
If the outside temperature is lower than
12 ‡ ( Ò11) †, damage may occur when adding DEF. If DEF is frozen and there is an
active warning indicator, it may not be
possible to add DEF. Park the vehicle in a
warmer place, e.g. in a garage, until DEF has
become

fluid again. It will then be possible to
add DEF again. Alternatively, have the DEF
tank refilled at a qualified specialist
workshop.
Further information about BlueTEC exhaust
gas aftertreatment and DEF is available at any
authorized Mercedes-Benz Center.
Important notes on topping up G
WARNING
Make sure
R DEF does not come into contact with skin,
eyes, or clothing
R to keep DEF out of the reach of children
If you and/or others have come into contact
with DEF:
R If DEF has gotten into contact with eyes,
flush with plenty of water immediately and
seek medical help.
R Clean

affected skin immediately with plenty
of water.
R If DEF was swallowed, rinse mouth
immediately with plenty of water and drink
plenty of water. Consult a physician. Refueling
173
Driving and parking Z

G
WARNING
If you open the DEF tank cap, small amounts
of ammonia vapor may be released. This
depends
in particular upon the age of the DEF.
Ammonia vapors have a pungent odor and are
particularly irritating to:
R skin
R mucous membranes
R eyes
You may experience a burning sensation in
your eyes, nose and throat, as well as
coughing and watering of the eyes.
Do not inhale any ammonia vapors that may
be released. Fill the DEF tank only in well-
ventilated areas.
! Only use DEF in accordance with
ISO 22241. Do not mix any additives with
DEF, and do not dilute DEF with water. This
may destroy the BlueTEC exhaust gas
aftertreatment system.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF
residues crystallize after time and
contaminate the affected surfaces.
! DEF is not a fuel additive and must not be
added to the fuel tank. If DEF is added to
the fuel tank, this can lead to engine
damage.
! Only screw on the DEF refill bottle hand-
tight. It could otherwise be damaged.
The DEF filler neck is under the trunk floor.
X Switch the ignition off.
X Open the trunk.
X Lift up the trunk floor ( Y page 301). X
Turn DEF cap : counter-clockwise and
remove it. X
Turn DEF filler cap ; counter-clockwise
and open it.
Filler

cap ; is secured with a plastic strip. X
Unscrew the protective cap from DEF refill
bottle =.
X Position DEF refill bottle = as shown on
the filler neck and screw it on hand-tight.
X Press DEF refill bottle = downwards.
The DEF tank is filled. This may take up to
one minute.
i To add between service intervals, fill the
DEF

tank with approximately 1 gal (3.8 l) of174
Refueling
Driving and parking

Winter tires
R18
7 Tires Alloy wheels
FA: 255/40 R18 99 V XL M+S
i
RA: 255/40 R18 99 V XL M+S i9 FA: 9.0 J x 18 H2
Wheel offset: 1.46 in
(37 mm)
RA: 9.5 J x 18 H2
Wheel offset: 2.05 in (52 mm) R19
Tires Alloy wheels
FA: 255/35 R19 96 V XL M+S
i
RA: 255/35
R19 96 V XL M+S i9, 10 FA: 9.0 J x 19 H2
Wheel offset: 1.46 in
(37 mm)
RA: 9.5 J x 19 H2
Wheel offset: 2.05 in (52 mm) FA: 255/35 R19 96 V XL M+S
i
RA: 285/30
R19 98 V XL M+S i8 FA: 9.0 J x 19 H2
Wheel offset: 1.46 in
(37 mm)
RA: 9.5 J x 19 H2
Wheel offset: 2.05 in (52 mm) E 350 BlueTEC
Summer tires
R18
Tires Alloy wheels
BA: 245/40 R18 97 Y XL FA: 8.5 J x 18 H2
Wheel offset: 1.89 in

(48 mm)7
Not in connection with a ceramic brake system.
9 Use of snow chains: contact an authorized Mercedes-Benz Center.
10 Maximum permissible speed for the Wagon:

137 mph (220 km/h).
8 The use of snow chains is not permitted. Observe the notes under "Snow chains".396
Wheel and tire combinations
Wheels and tires

engine and could result in the vehicle catching
fire.
! Only
use commercially available vehicular
ULTRA-LOW SULFUR DIESEL FUEL (ULSD,
15 ppm maximum sulfur content) that
meets the ASTM D975 standard. If you do
not refuel with ULSD, you may damage the
BlueTEC exhaust gas aftertreatment
system of the vehicle.
! Do not use gasoline to refuel vehicles with
a diesel engine. Do not mix diesel fuel with
gasoline, kerosene or paraffin. This may
otherwise result in damage to the fuel
system and engine.
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult a
qualified specialist workshop or on the
Internet at http://www.mbusa.com (USA
only).
Information on refueling (Y page 170).
Low outside temperatures
i Diesel fuel with improved cold flow
properties is available during the winter
months. Further information about fuel
properties can be obtained from oil
companies, e.g. at gas stations.
Flow improver
To improve the low-temperature resistance of
diesel fuel, a flow improver can be attached.
The effectiveness of a flow improver is not
guaranteed for every fuel.
Only use flow improvers tested and approved
by Mercedes-Benz. During use, please
observe the information on operation.
Correct dosage and sufficient mixing are
decisive in improving low-temperature
resistance with the flow improver.
Overdosage can potentially even decrease
low-temperature resistance and must therefore be avoided. Follow the
manufacturer's guidelines on dosage.
Mix the additive into the diesel in good time,
before the flow characteristics of the diesel
become
insufficient. Otherwise, malfunctions
can arise through heating the fuel system,
e.g. through parking in a heated garage.
More information about recommended flow
improvers can be obtained from any qualified
specialist workshop.
Flexible fuel vehicles Important safety notes
G
WARNING
E85 fuel (ethanol) and its vapours are
poisonous, highly flammable and highly
combustible. E85 fuel can cause serious
injury

if ignited, if you come into contact with
it you or if you inhale fuel vapors. Avoid
inhaling E85 fuel vapors and avoid skin
contact with E85 fuel. Extinguish any naked
flames before refueling. Keep sparks away
from E85 fuel, and do not smoke.
Flexible Fuel vehicles can be refueled with the
following fuel types:
R premium-grade unleaded gasoline
R E85 fuel
R a mixture of E85 fuel and premium-grade
unleaded gasoline
i Flexible Fuel vehicles can be recognized
by the Ethanol up to E85 sticker on the
inside of the fuel filler flap.
Fuel consumption
The energy content of E85 fuel is less than
that of the same amount of premium-grade
gasoline. The amount of fuel consumed when
operating the vehicle with E85 fuel is
therefore higher than with premium-grade
gasoline. Service products and filling capacities
409
Technical data Z

Maintenance
Inform your authorized Mercedes-Benz
Center that you are operating or have
operated the vehicle with E85 fuel.
Low outside temperatures
The
starting procedure may take much longer
when operating the vehicle with E85 fuel at
outside temperatures below 32 ‡ (0 †).
E85 fuel is not suitable for use at outside
temperatures below -4 ‡ (-20 †). DEF
General notes DEF is a non-flammable, non-toxic, colorless,
odorless and water-soluble fluid.
High outside temperatures
G
WARNING
If you open the DEF tank cap, small amounts
of ammonia vapor may be released. This
depends

in particular upon the age of the DEF.
Ammonia vapors have a pungent odor and are
particularly irritating to:
R skin
R mucous membranes
R eyes
You may experience a burning sensation in
your eyes, nose and throat, as well as
coughing and watering of the eyes.
Do not inhale any ammonia vapors that may
be released. Fill the DEF tank only in well-
ventilated areas.
Low outside temperatures DEF freezes at a temperature of
approximately

12 ‡ (-11 †). The vehicle is
equipped with a DEF preheating system when
it leaves the factory. Winter operation is
therefore also guaranteed at temperatures
below 12 ‡ (-11 †). Additives !
Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity !
Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions

in the BlueTEC exhaust gas
aftertreatment system
Assuring the purity of DEF is particularly
important with respect to avoiding
malfunctions in the BlueTEC exhaust gas
aftertreatment system.
If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
Filling capacities Model Total capacity
E 350 BlueTEC
6.5 US gal
(24.5 l)
Engine oil
General notes !
Never use engine oil or an oil filter of a
specification other than is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
intervals than those prescribed. You could
otherwise

cause engine damage or damage
to the exhaust gas aftertreatment. 410
Service products and filling capacities
Technical data

Follow the instructions in the service
interval display regarding the oil change.
Otherwise,
you may damage the engine and
the exhaust gas aftertreatment.
The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz
Center. Or visit the website
http://bevo.mercedes-benz.com.
The table shows which engine oils have been
approved for your vehicle. Model Engine
model MB
Approval
E 300 4MATIC
BlueEFFICIENCY
(Canada only)
E 350
BlueEFFICIENCY
(USA only)
E 350 4MATIC
BlueEFFICIENCY
276 229.5
E 550 4MATIC
BlueEFFICIENCY
278 229.5
E 63 AMG
157 229.5
E 350 BlueTEC
642 228.51,
229.31,
229.51
Use only SAE 0W-40 or SAE 5W-40 engine oils
for AMG vehicles.
i
MB approval is indicated on the oil
containers.
Filling capacities The following values refer to an oil change
including the oil filter. Model Capacity
E 300 4MATIC
BlueEFFICIENCY
(Canada only)
E 350
BlueEFFICIENCY
(USA only)
E 350 4MATIC
BlueEFFICIENCY
6.9 US qt (6.5 l)
E 350 BlueTEC
E 550 4MATIC
BlueEFFICIENCY
8.5 US qt (8.0 l)
E 63 AMG
With external oil
cooler:
9.0 US qt

(8.5 l) Additives
!
Do
not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity Viscosity describes the flow characteristics
of

a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE (viscosity)
classification suitable for the prevailing
outside temperatures. The table shows you
which SAE classifications are to be used. The
low-temperature characteristics of engine
oils can deteriorate significantly, e.g. as a
result of aging, soot and fuel deposits. It is Service products and filling capacities
411
Technical data Z

i
When the vehicle is first delivered, it is
filled with a coolant mixture that ensures
adequate antifreeze and corrosion
protection.
Filling capacities Missing values were not available at time of
going to print.
Model Capacity
E 300 4MATIC
BlueEFFICIENCY
(Canada only)
E 350
BlueEFFICIENCY
(USA only)
E 350 4MATIC
BlueEFFICIENCY
Approx. 10.1 US qt
(9.6 l) E 550 4MATIC
BlueEFFICIENCY
E 63 AMG
Approx. 11.5 US qt
(10.9 l) E 350 BlueTEC
Approx. 13.0 US qt
(12.3 l) i
Use MB 325.0 or MB 326.0 corrosion
inhibitor/antifreeze. Windshield/headlamp cleaning
system
Important safety notes G
WARNING
Washer solvent/antifreeze is highly
flammable. Do not spill washer solvent/
antifreeze
on hot engine parts, because it may
ignite and burn. You could be seriously
burned.
! Only use washer fluid that is suitable for
plastic lamp lenses, e.g. MB SummerFit or
MB WinterFit. Unsuitable washer fluid could damage the plastic lenses of the
headlamps.
! Do

not add distilled or de-ionized water to
the washer fluid container. Otherwise, the
level sensor may be damaged.
! Only MB SummerFit and MB WinterFit
washer fluid should be mixed together. The
spray nozzles may otherwise become
blocked.
At temperatures above freezing:
X Fill the washer fluid reservoir with a mixture
of water and windshield washer fluid, e.g.
MB SummerFit.
Add 1 part MB SummerFit to 100 parts water.
At temperatures below freezing:
X Fill the washer fluid reservoir with a mixture
of water and windshield washer fluid, e.g.
MB WinterFit.
Adapt the mixing ratio to the outside
temperature.
R Down to 14

‡ (Ò10 †): mix 1 part MB
WinterFit with 2 parts water.
R Down to Ò4 ‡ (Ò20 †): mix 1 part MB
WinterFit with 1 part water.
R Down to Ò20.2 ‡ (Ò29 †): mix 2 parts MB
WinterFit with 1 part water.
i Add windshield washer fluid, e.g. MB
SummerFit or MB WinterFit, to the washer
fluid all year round.
Filling capacities Model Capacity
All models (except
E 350 4MATIC
BlueEFFICIENCY,
Wagon)
3.7 US qt (3.5 l)
E 350 4MATIC
BlueEFFICIENCY,
Wagon
6.3 US qt (6.0 l)Service products and filling capacities
413
Technical data Z