2012 MERCEDES-BENZ S-CLASS SEDAN engine

pump nozzle, which could cause personal
injury.GWARNING
Hybrid vehicles: be sure to read the "HYBRID"
supplement. Otherwise, you could fail to
recognize dangers.
GWARNING
Do not fill diesel tanks with gasoline. Do not
mix diesel fuel with gasoline. Otherwise the
fuel system and engine could be damaged. In
addition, the vehicle could catch fire.
! Do not use gasoline to refuel vehicles with
a diesel engine. Do not use diesel to refuel
vehicles with a gasoline engine. Even a
small quantity of the wrong fuel will
damage the fuel system and engine.
! Do not switch on the ignition if you
accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel lines.
Notify a qualified specialist workshop and
have the fuel tank and fuel lines drained
completely.
! Overfilling the fuel tank could damage the
fuel system.
! Take care not to spill any fuel on painted
surfaces. You could otherwise damage the
paintwork.
! Use a filter when refueling from a fuel can.
Otherwise, the fuel lines and/or injection
system could be blocked by particles from
the fuel can.
Further information on fuel and on fuel grades
can be found in the "Fuel" section
( Y page 525).
Refueling
Fuel filler flap:To open the fuel filler flap;To insert the fuel filler cap=Tire pressure table?Fuel type
The fuel filler flap is unlocked or locked
automatically when you open or close the
vehicle with the SmartKey or with KEYLESS-
GO.
The position of the fuel filler cap 8 is
displayed in the instrument cluster. The arrow
next to the filling pump indicates the side of
the vehicle.
Opening
XSwitch off the engine.XRemove the SmartKey from the ignition
lock.XKEYLESS-GO: open the driver’s door.
This corresponds to SmartKey position 0:
"SmartKey removed".
The driver’s door can be closed again.XPress the fuel filler flap in the direction of
arrow :.
The fuel filler flap opens slightly.XOpen the fuel filler flap fully.XTurn the fuel filler flap counter-clockwise
and remove it.XInsert the fuel filler cap into the holder
bracket on the inside of filler flap ;.322RefuelingDriving and parking

XCompletely insert the filler neck of the fuel
pump nozzle into the tank and refuel.XOnly fill the tank until the pump nozzle
switches off.
i Do not add any more fuel after the pump
stops filling for the first time. Otherwise,
fuel may leak out.
Closing
XReplace the cap on the filler neck and turn
clockwise until it engages audibly.XClose the fuel filler flap.
i If you drive with the fuel filler cap open,
the reserve fuel warning lamp flashes. In
addition, the ; Check Engine warning
lamp may light up. A message appears in
the multifunction display ( Y page 409).
For further information on warning and
indicator lamps in the instrument cluster,
see ( Y page 429).
i Close the fuel filler flap before locking the
vehicle. Otherwise, the locking pin of the
central locking prevents the fuel filler flap
from closing.
Refueling323Driving and parkingZ

Problems with fuel and the fuel tankProblemPossible causes/consequences and M SolutionsFuel is leaking from the
vehicle.GRisk of explosion or fire
The fuel line or the fuel tank is defective.
XTurn the SmartKey to position 0 in the ignition lock immediately
and remove it ( Y page 307).XDo not restart the engine under any circumstances.XConsult a qualified specialist workshop.The engine will not
start.The fuel tank of a vehicle with a diesel engine has been run
completely dry.XRefuel the vehicle with at least 5.3 US qt (5 liters) of diesel.XTurn the ignition on for about 10 seconds( Y page 307).XStart the engine continuously for up to 10 seconds until it runs
smoothly.
or
If the engine does not start:
XTurn the ignition on again for approximately
10 seconds( Y page 307).XStart the engine again continuously for up to 10 seconds until
it runs smoothly.
orXStart the engine again via the touch-start function.
If the engine does not start after three attempts:
XConsult a qualified specialist workshop.The fuel filler flap
cannot be opened.The fuel filler flap is not unlocked.
or
The SmartKey battery is discharged.XUnlock the vehicle ( Y page 82).
or
XUnlock the vehicle using the mechanical key ( Y page 84).The fuel filler flap is unlocked, but the opening mechanism is
jammed.XConsult a qualified specialist workshop.324RefuelingDriving and parking

DEF (BlueTEC vehicles only)
Important notes on use
To function properly, BlueTEC exhaust gas
aftertreatment must be operated with the
reducing agent DEF. Adding DEF is one of the
tasks performed during maintenance. Under
normal operating conditions, a tank of DEF
lasts until the next service due date.
When the DEF level is too low, the Check
Additive See Operator's Manual
message is shown in the multifunction
display.
When the DEF supply sinks to a minimum
level, the Remaining Starts: 16 message
is shown in the multifunction display.
When the Remaining Starts: 16 message
is shown in the multifunction display, you can
start the engine 16 more times. If DEF is not
added, it will then not be possible to restart
the engine. Fill the DEF tank with about 1 gal
(3.8l) of DEF or have the DEF tank refilled at
a qualified specialist workshop.
Use the special DEF refill bottle when filling
between maintenance intervals. Contact an
authorized Mercedes-Benz Center with any
questions or, if necessary, contact Roadside
Assistance ( Y page 29).
If the outside temperature is lower than 12 ‡
( Ò 11†) , damage may occur when adding DEF.
If DEF is frozen and there is an active warning
indicator, adding may not be possible. Park
the vehicle in a warmer place, e.g. in a garage,
until DEF has become fluid again. It will then
be possible to add DEF again. Alternatively,
have the DEF tank refilled at a qualified
specialist workshop.
Further information about BlueTEC exhaust
gas aftertreatment and DEF is available at any
authorized Mercedes-Benz Center.
Adding DEFGWARNING
Make sure
R DEF does not come into contact with skin,
eyes, or clothing
R to keep DEF out of the reach of children
If you and/or others have come into contact
with DEF:
R If DEF has gotten into contact with eyes,
flush with plenty of water immediately and
seek medical help.
R Clean affected skin immediately with plenty
of water.
R If DEF was swallowed, rinse mouth
immediately with plenty of water and drink
plenty of water. Consult a physician.
GWARNING
If you open the DEF tank cap, small amounts
of ammonia vapor may be released. This
depends in particular upon the age of the DEF.
Ammonia vapors have a pungent odor and are
particularly irritating to:
R skin
R mucous membranes
R eyes
You may experience a burning sensation in
your eyes, nose and throat, as well as
coughing and watering of the eyes.
Do not inhale any ammonia vapors that may
be released. Fill the DEF tank only in well-
ventilated areas.
! Only use DEF in accordance with
ISO 22241. Do not mix any additives with
DEF, and do not dilute DEF with water. This
may destroy the BlueTEC exhaust gas
aftertreatment system.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF
Refueling325Driving and parkingZ

residues crystallize after time and
contaminate the affected surfaces.
! DEF is not a fuel additive and must not be
added to the fuel tank. If DEF is added to
the fuel tank, this can lead to engine
damage.
! Only screw on the DEF refill bottle hand-
tight. It could otherwise be damaged.
The filler neck for DEF is located under the
"Minispare" emergency spare wheel in the
trunk floor.XSwitch off the ignition.XOpen the trunk.XLift the trunk floor up ( Y page 438).XTurn the "Minispare" emergency spare
wheel fastening in the direction of the
arrow and remove it.XRemove the "Minispare" emergency spare
wheel.XTurn DEF cap : counter-clockwise and
remove it.XTurn DEF filler cap ; counter-clockwise
and open it.
Filler cap ; is secured with a plastic strap.XUnscrew the covering cap from DEF refill
bottle =.XPlace DEF refill bottle = on the filler neck
as shown and screw on clockwise hand-
tight.XPress DEF refill bottle = down.
The DEF tank is filled. This may take up to
one minute.
i To add between service intervals, fill the
DEF tank with approximately 1 gal (3.8 l) of
DEF. 1 gal (3.8 l) of DEF is equivalent to
approximately 2 DEF refill bottles. Then
have the DEF supply checked at a qualified
specialist workshop and completely refilled
if necessary.
XRelease DEF refill bottle =.
Refilling stops when the DEF refill bottle is
no longer pressed down. The DEF refill
bottle can be removed when it has been
only partially emptied.326RefuelingDriving and parking

XTurn DEF refill bottle = counter-clockwise
and remove it.XPlace DEF filler cap ; on the filler neck and
turn it clockwise.XInsert DEF cap : as shown and turn it
clockwise as far as it will go.XPlace the "Minispare" emergency spare
wheel in the emergency spare wheel well
above the DEF tank.XInsert the "Minispare" emergency spare
wheel fastening and tighten clockwise.XFold the trunk floor down.XClose the trunk lid.XDrive faster than 10 mph (16 km/h).
The Check Additive See Operator's
Manual message goes out after
approximately one minute.
i If the Check Additive See
Operator's Manual message remains
shown in the multifunction display, add an
additional bottle of DEF.
Further information on DEF ( Y page 527).
Parking
Important safety notes
GWARNING
Do not park this vehicle in areas where
combustible materials can come into contact
with the hot exhaust system. Combustible
materials, such as grass, hay or leaves could
be ignited by the hot exhaust system and
cause a vehicle fire. Do not park the vehicle
on dry grassland or harvested grain fields.
Unintended vehicle movement can cause
serious personal injury or damage to the
vehicle or the vehicle drivetrain. To reduce
such risks, always do the following before
turning off the engine and leaving the vehicle:
R keep your right foot on the brake pedal.
R engage the electric parking brake.
R shift the automatic transmission into park
position P.
R slowly release the brake pedal.
R when parked on an incline, always turn the
front wheels towards the road curb.
R turn the SmartKey in the ignition lock to
position 0 and remove the SmartKey from
the ignition lock, or press the KEYLESS-GO
Start/Stop button.
R take the SmartKey with you and lock the
vehicle when leaving.
Switching off the engine
Important safety notes
GWARNING
Do not turn off the engine before the vehicle
has come to a complete stop. With the engine
not running, there is no power assistance for
the brake and steering systems. In this case,
it is important to keep in mind that a
considerably higher degree of effort is
necessary to brake and steer the vehicle.
GWARNING
Keep in mind that turning off the engine alone
only will shift the automatic transmission into
neutral position N automatically.
Always shift the automatic transmission into
park position P before turning off the engine.
Otherwise the vehicle could roll away which
could result in an accident and/or serious
personal injury.
Parking327Driving and parkingZ

iIf you cannot turn off the engine as
described here, see "Engine emergency
stop" ( Y page 490).
Vehicles with automatic transmissionXApply the electric parking brake.XShift the transmission to position P.
Using the SmartKey
XTurn the SmartKey to position 0 in the
ignition lock and remove it.
The immobilizer is activated.
i If you turn off the engine with the
SmartKey and then remove it from the
ignition lock or open a front door, the
automatic transmission shifts to P
automatically.
Using KEYLESS-GO
XPress the Start/Stop button (Y page 307).
The engine stops and all the indicator
lamps in the instrument cluster go out.
i When the driver's door is closed, this
corresponds to SmartKey position 1. When
the driver's door is open, it corresponds to
SmartKey position 0 or "SmartKey
removed".
i If you use the Start/Stop button to switch
off the engine, the automatic transmission
shifts to N automatically. If you then open
the driver's or front-passenger door, the
automatic transmission shifts to P.
i In an emergency, the engine can be
turned off while the vehicle is in motion by
pressing and holding the Start/Stop button
for 3 seconds. This function operates
independently from the ECO start/stop
automatic engine switch-off function.
Electric parking brake
General informationGWARNING
When leaving the vehicle, always remove the
SmartKey from the starter switch, take it with
you, and lock the vehicle. Do not leave
children unattended in the vehicle, or with
access to an unlocked vehicle. Children could
release the parking brake and/or shift the
automatic transmission out of park position
P , either of which could result in an accident
and/or serious personal injury.
Applying/releasing manually
XTo apply: press handle :.
The red F (USA only) or ! (Canada
only) indicator lamp in the instrument
cluster lights up.
i The electric parking brake can also be
applied when the SmartKey is removed.
XTo release: switch on the ignition.XPull handle :.
The red F (USA only) or ! (Canada
only) indicator lamp in the instrument
cluster goes out.
i The electric parking brake cannot be
released unless the SmartKey is in position
1 in the ignition lock or if the ignition has
been switched on using the Start/Stop
button.
328ParkingDriving and parking

Engaging the electric parking brake
automatically
The electric parking brake is automatically
applied if HOLD or DISTRONIC PLUS brakes
the vehicle until it is stationary and at least
one of the following conditions is fulfilled:
R the engine is switched off.
R the driver's door is open and the seat belt
is not fastened.
R the hood is released.
R the trunk lid is opened while the automatic
transmission is in position R.
R the vehicle is stationary for a lengthy
period.
The red F (USA only) or ! (Canada
only) indicator lamp in the instrument cluster
lights up.
i In addition to the electric parking brake,
P may also be engaged automatically.
Releasing the electric parking brake
automatically
The electric parking brake is released
automatically when the following conditions
are simultaneously fulfilled:
R the engine is running.
R the automatic transmission is in position
D or R.
R the hood is closed.
R your seat belt is fastened.
R you depress the accelerator pedal.
If the automatic transmission is in position
R , the trunk lid must be closed.
If your seat belt is not fastened, the following
conditions must be fulfilled to automatically
release the electric parking brake:
R the driver's door is closed.
R you have shifted out of position P or you
have previously driven faster than 3 km/h.
R you have shifted out of position P or you
have previously driven faster than 2 mph
(3km/h).
Emergency braking
The vehicle can also be braked during an
emergency by using the electric parking
brake.
XWhile driving, push handle : of the electric
parking brake ( Y page 328).
i
The vehicle is braked as long as you keep
the handle of the electric parking brake
pressed. The longer the electric parking
brake handle is depressed, the greater the
braking force.
During braking:
R a warning tone sounds.
R the Please Release Parking Brake
message appears.
R the red F (USA only) or ! (Canada
only) indicator lamp in the instrument
cluster lights up.
When the vehicle has been braked to a
standstill, the electric parking brake is
engaged.
Parking the vehicle for a long period
If you leave the vehicle parked for longer than
four weeks, the battery may be damaged by
exhaustive discharge.
XConnect a trickle charger.
i You can obtain information about trickle
chargers from a qualified specialist
workshop.
If you leave the vehicle parked for longer than
six weeks, the vehicle may suffer damage as
a result of lack of use.
XVisit a qualified specialist workshop and
seek advice.Parking329Driving and parkingZ