2012 MERCEDES-BENZ S-Class temperature

(100 km) as they only reach their full
performance after this distance.
R Do not use tires that are excessively worn
as the tire traction on wet road surfaces
decreases significantly when the tread
depth is less than 1
/ 8 inch (3 mm).
R Replace the tires after six years at the
latest, regardless of wear. This also applies
to the spare wheel/emergency spare
wheel.
The service life of tires depends on the
following factors amongst other things:
R driving style
R tire pressure
R mileage
MOExtended tires (tires with run-flat
properties)
MOExtended tires (tires with run-flat
properties) allow you to continue driving your
vehicle even if one or more tires are entirely
deflated.
MOExtended tires may be used only in
conjunction with the activated tire pressure
loss warning system or the activated tire
pressure monitoring system and only on
wheels specifically tested by Mercedes-Benz.
You will find notes on driving with
MOExtended tires in the "Breakdown
assistance" section ( Y page 477).
Winter operation
Please bear the following in mind
At the onset of winter, have your vehicle
winterproofed at a qualified specialist
workshop, e.g. at an authorized Mercedes-
Benz Center.
Observe the notes in the "Changing a wheel"
section ( Y page 513).
Driving with summer tires
At temperatures below 45 ‡ (+7 †), the
elasticity of summer tires and therefore also
traction and braking capability are reduced
considerably — equip your vehicle with
M+S tires. Using summer tires at very cold
temperatures could cause tears to form,
thereby damaging the tires permanently.
Mercedes-Benz cannot accept responsibility
for this type of damage.
M+S tires
At temperatures below 45 ‡(+7 †), use
winter tires or all-season tires. Both types of
tire are identified by the M+S marking.
Only winter tires bearing the i snowflake
symbol in addition to the M+S marking
provide the best possible grip in wintry road
conditions. Only these tires will allow driving
safety systems such as ABS and ESP ®
to
function optimally in winter, as these tires
have been designed specifically for driving on
snow.
Use M+S tires of the same make and tread on
all wheels to maintain safe handling
characteristics.
GWARNING
M+S tires with a tread depth of less than 1
/ 6
inch (4 mm) must be replaced immediately.
They are no longer suitable for use in winter.
Always observe the maximum permissible
speed specified for the M+S tires you have
mounted.
Once you have mounted the winter tires:
XCheck the tire pressures ( Y page 497).XRestart the tire pressure monitor
( Y page 497).GWARNING
If you use your spare wheel when M+S tires
are mounted on the other wheels, be aware
that the difference in tire characteristics
492Winter operationWheels and tires

If the tire pressures have been set to the
lower values for lighter loads and/or lower
road speeds, the pressures should be reset
to the higher values:
R if you want to drive with an increased load
and/or
R if you want to drive at higher road speeds.
i The tire pressures for increased loads
and/or higher road speeds, shown in the
tire pressure table, may have a negative
effect on driving comfort.
Option 3) The tire pressure for the
emergency/collapsible spare wheel
(depending on vehicle equipment) can be
found:
R printed in yellow on the rim of the
emergency/collapsible spare wheel
R in the "Wheel and tire combinations"
section ( Y page 514) in this manual
R on the Tire and Loading Information placard
on the B-pillar on the driver's side.
If the tire pressure is not set correctly, this
can lead to an excessive build up of heat and
a sudden loss of pressure.
For further information, consult a qualified
specialist workshop, e.g. an authorized
Mercedes-Benz Center.
Important notes on tire pressureGWARNING
Should the tire pressure drop repeatedly:
R check the tire for foreign bodies.
R check whether the wheel is losing air or the
valve is leaking.
R make sure that only a valve cap approved
by Mercedes-Benz is used on the tire valve.
Tire pressures that are too low have a
negative effect on vehicle safety, which could
lead you to cause an accident.
To test tire pressure, use a suitable tire
pressure gauge. The outer appearance of a
tire does not permit any reliable conclusion
about the tire pressure. On vehicles equipped
with the electronic tire pressure monitoring
system, the tire pressure can be checked
using the on-board computer.
The tire temperature and pressure increase
when the vehicle is in motion. This is
dependent on the driving speed and the load.
Therefore, you should only correct tire
pressures when the tires are cold.
The tires are cold:
R if the vehicle has been parked without
direct sunlight on the tires for at least three
hours and
R if the vehicle has not been driven more than
1 mile (1.6 km).
The tire temperature changes depending on
the outside temperature, the vehicle speed
and the tire load. If the tire temperature
changes by 18 ‡ (10 † ), the tire pressure
changes by approximately 10 kPa (0.1 bar/
1.5 psi). Take this into account when
checking the pressure of warm tires and only
correct the tire pressure if it is too low for the
current operating conditions. If you check the
tire pressure when the tires are warm, the
resulting value will be higher than if the tires
were cold. This is normal. Do not reduce the
tire pressure to the value specified for cold
tires. The tire pressure would otherwise be
too low.
Tire pressure495Wheels and tiresZ

iThe actual values for tires are specific to
each vehicle and may deviate from the
values in the illustration.
Maximum tire load : is the maximum
permitted weight for which the tire is
approved.
Further information on tire loads
( Y page 506).
Uniform Tire Quality Grading
Standards
Overview of Tire Quality Grading
Standards
The Uniform Tire Quality Grading is a U.S.
Government requirement. Their purpose is to
provide drivers with consistent and reliable
information regarding tire performance. Tire
manufacturers are required to grade tires
using three performance factors: tread
wear :, tire traction ;, and temperature
resistance =. Although not a Government of
Canada requirement, all tires made for sale in
North America have these grades branded on
the sidewall.
i The actual values for tires are vehicle-
specific and may deviate from the values in
the illustration.
Where applicable, the tire grading
information can be found on the tire sidewall
between the tread shoulder and maximum
tire width.
For example:Tread wearTractionTemperature200AAA
All passenger car tires must conform to the
statutory safety requirements in addition to
these grades.
Tread wear
The tread wear grade is a comparative rating
based on the wear rate of the tire when tested
under controlled conditions on a specified
U.S. government course. For example, a tire
graded 150 would wear one and one-half
times as well on the government course as a
tire graded 100.
The relative performance of tires depends
upon the actual conditions of their use,
however, and may depart significantly from
the norm, due to variations in driving habits,
service practices and differences in road
characteristics and climate conditions.
Traction
GWARNING
The traction grade assigned to this tire is
based on straight-ahead braking traction
tests, and does not include acceleration,
cornering, hydroplaning, or peak traction
characteristics.
The traction grades, from highest to lowest,
are AA, A, B, and C. Those grades represent
Uniform Tire Quality Grading Standards505Wheels and tiresZ

the tire's ability to stop on a wet surface as
measured under controlled conditions on
specified government test surfaces of asphalt
and concrete. A tire marked C may have poor
traction performance.GWARNING
If ice has formed on the road, tire traction will
be substantially reduced. Under such weather
conditions, drive, steer and brake with
extreme caution.
The safe speed on a wet, snow covered or icy
road is always lower than on dry road
surfaces.
You should pay special attention to road
conditions when temperatures are around
the freezing point.
Mercedes-Benz recommends a minimum tire
tread depth of 1
/ 6 in (4 mm) for all four winter
tires ( Y page 492) to maintain normal driving
characteristics in winter. Winter tires can
reduce the braking distance on snow covered
surfaces in comparison to summer tires.
Stopping distance, however, is still
considerably greater than when the road is
not covered with ice or snow. Take
appropriate care when driving.
! Avoid wheelspin. This can lead to damage
to the drive train.
Temperature
GWARNING
The temperature grade for this tire is
established for a tire that is properly inflated
and not overloaded. Excessive speed,
underinflation, or excessive loading, either
separately or in combination, can cause
excessive heat build-up and possible tire
failure.
The temperature grades are A (the highest),
B, and C. These represent the tire's
resistance to the generation of heat and its
ability to dissipate heat when tested under
controlled conditions on a specified indoor
laboratory test wheel. Sustained high
temperature can cause the material of the tire
to degenerate and reduce tire life, and
excessive temperature can lead to sudden
tire failure. The grade C corresponds to a level
of performance which all passenger car tires
must meet under the Federal Motor Vehicle
Safety Standard No. 109. Grades B and A
represent higher levels of performance on the
laboratory test wheel than the minimum
required by law.
Tire labeling
Tire labeling overview
The following markings are on the tire in
addition to the tire name (sales designation)
and the manufacturer's name:
:Uniform tire Quality Grading Standard
( Y page 511);DOT, Tire Identification Number
( Y page 509)=Maximum tire load ( Y page 504)?Maximum tire pressure ( Y page 496)AManufacturerBTire material ( Y page 510)506Tire labelingWheels and tires

Normal occupant weight
The number of occupants the vehicle is
designed to seat, multiplied by 68 kilograms
(150 lbs).
Uniform Tire Quality Grading
Standards
A uniform standard to grade the quality of
tires with regards to tread quality, tire traction
and temperature characteristics. Ratings are
determined by tire manufacturers using U.S.
government testing procedures. The ratings
are molded into the sidewall of the tire.
Recommended tire pressure
The recommended tire pressure applies to
the tires mounted at the factory.
The Tire and Loading Information placard
contains the recommended tire pressures for
cold tires on a fully loaded vehicle and for the
maximum permissible vehicle speed.
The tire pressure table contains the
recommended tire pressures for cold tires
under various operating conditions, i.e.
differing load and speed conditions.
Increased vehicle weight due to
optional equipment
This is the combined weight of all standard
and optional equipment available for the
vehicle, regardless of whether it is actually
installed on the vehicle or not.
Rim
This is the part of the wheel on which the tire
is mounted.
GAWR (Gross Axle Weight Rating)
The GAWR is the maximum permissible axle
weight. The actual load on an axle must never
exceed the gross axle weight rating. The
gross axle weight rating can be found on the
vehicle identification plate on the B-pillar on
the driver's side.
Speed rating
The speed rating is part of the tire
identification. It specifies the speed range for
which the tire is approved.
GVW (Gross Vehicle Weight)
The gross vehicle weight comprises the
weight of the vehicle including fuel, tools, the
spare wheel, accessories installed,
occupants, luggage and the drawbar
noseweight, if applicable. The gross vehicle
weight must not exceed the gross vehicle
weight rating GVWR as specified on the
vehicle identification plate on the B pillar on
the driver's side.
GVWR (Gross Vehicle Weight Rating)
The GVWR is the maximum permissible gross
weight of a fully loaded vehicle (the weight of
the vehicle including all accessories,
occupants, fuel, luggage and the drawbar
noseweight, if applicable). The gross vehicle
weight rating is specified on the vehicle
identification plate on the B-pillar on the
driver's side.
Maximum loaded vehicle weight
The maximum weight is the sum of the curb
weight of the vehicle, the weight of the
accessories, the total load limit and the
weight of the optional equipment installed at
the factory.
Definition of terms for tires and loading511Wheels and tiresZ

! Do not refuel with low-grade fuel and do
not use fuel additives that are not tested
and approved for Mercedes-Benz vehicles.
Damage to or malfunctions of the fuel
system may otherwise occur.
DEF
Important safety notes
i For BlueTEC vehicles only.
DEF is a non-flammable, non-toxic, colorless,
odorless and water-soluble fluid.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF
residues crystallize after time and
contaminate the affected surfaces.
High outside temperatures
If DEF heats up to over 122 ‡ (50 †) for
extended periods, e.g. as a result of direct
sunlight on the DEF reservoir, DEF can
decompose. Ammonia vapors develop as a
result.
GWARNING
When opening the filler cap of the DEF tank
ammonia gas vapors may escape. Refill DEF
in a well ventilated area only. Ammonia gas
vapors have a pungent odor and are
particularly irritating for your skin, mucous
membranes, and eyes. Inhaling ammonia gas
vapors will cause burning eyes, nose, and
throat, as well as coughing and watering eyes.
Low outside temperatures
DEF freezes at a temperature of
approximately 12 ‡ (–11 †). The vehicle is
equipped with a DEF preheating system when
it leaves the factory. Winter operation is
therefore also guaranteed at temperatures
below 12 ‡ (–11 †).
Additives
! Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity
Assuring the purity of DEF is particularly
important with respect to avoiding
malfunctions in the exhaust gas
aftertreatment system.
If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
! Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC exhaust gas
aftertreatment system
Engine oil
Please bear the following in mind
The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz Center
or go to the Internet site
http://www.mbusa.com (USA only).
! Never use engine oil or an oil filter of a
specification other than is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
Service products and capacities527Technical dataZ

intervals than those prescribed. You could
otherwise cause engine damage or damage
to the exhaust gas aftertreatment.
Follow the instructions in the service
interval display regarding the oil change.
Otherwise, you may damage the engine and
the exhaust gas aftertreatment.
The table shows which engine oils have been
approved for your vehicle.ModelEngine
modelMB
ApprovalS 550 36
S 550 4MATIC 36278229.5S 600275S 63 AMG157229.537S 65 AMG275S 350 BlueTEC
4MATIC642228.51,
229.31,
229.51
i MB approval is indicated on the oil
containers.
Additives
! Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity
Viscosity describes the flow characteristics
of a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE (viscosity)
classification suitable for the prevailing
outside temperatures. The following table
shows the correct SAE classification to be
used. The low-temperature characteristics of
engine oils can deteriorate significantly, e.g.
as a result of aging, soot and fuel deposits. It
is therefore strongly recommended that you
carry out regular oil changes using an
approved engine oil with the appropriate SAE
classification.
Refrigerant of the air-conditioning
system
The air-conditioning system is filled with
R134a refrigerant and a special PAG
lubricant.
! Never use refrigerant R 12 (CFC) or
mineral lubricants. Otherwise, you could
damage the air-conditioning system.
Brake fluid
GWARNING
Over a period of time, the brake fluid absorbs
moisture from the air; this lowers its boiling
point.
If the boiling point of the brake fluid is too low,
vapor pockets may form in the brake system
when the brakes are applied hard (e.g. when
driving downhill). This would impair braking
efficiency.
You should have the brake fluid renewed at
regular intervals. The brake fluid change
intervals can be found in the Service Booklet.
Only use brake fluid approved by Mercedes-
Benz. Information about approved brake
36 BlueEFFICIENCY
37 Restriction: only SAE 0W-40 or SAE 5W-40 engine oils may be used.528Service products and capacitiesTechnical data

fluids can be obtained from any authorized
Mercedes-Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
Coolant
Important safety notes
The coolant is a mixture of water and
antifreeze/corrosion inhibitor. It performs
the following tasks:
R corrosion protection
R antifreeze protection
R raising the boiling point
The engine cooling system is filled at the
factory with coolant that contains an
antifreeze/corrosion inhibitor that ensures
protection down to approximately -35 ‡
(-37 †).
! Only add coolant that has been premixed
with the desired antifreeze protection.
Otherwise, the engine could be damaged.
Further information on coolants and on
filling can be found in the Mercedes-Benz
Specifications for Service Products, MB
Approval 310.1, e.g. on the Internet at
http://bevo.mercedes-benz.com . You can
also consult an authorized Mercedes-Benz
Center.
! Always use a suitable coolant mixture,
even in countries where high temperatures
prevail.
Otherwise, the engine cooling system is not
sufficiently protected from corrosion and
overheating.
If the coolant has antifreeze protection down
to -35 ‡ (-37 †), the boiling point of the
coolant under operating conditions is
approximately 266 ‡ (130 †).
Your vehicle has a range of aluminum
components. Aluminum components in the
engine make it necessary to use antifreeze/
corrosion inhibitor coolant that has been
specifically formulated to protect the
aluminum parts. Using other antifreeze/
corrosion inhibitors without these
characteristics affects the service life.
The coolant must be used throughout the year
in order to maintain the necessary corrosion
protection and to provide protection from
overheating. In the Service Booklet, you can
find information on the intervals for renewal.
The renewal interval is determined by the
coolant type and the engine cooling system
design. The renewal interval in the Service
Booklet is only valid if the coolant is renewed
or filled up with Mercedes-Benz approved
products. Therefore, only use MB 325.0 or
326.0 anticorrosion/antifreeze or another
Mercedes-Benz approved product of the
same specification.
Information on other products with the same
specifications that are approved by
Mercedes-Benz can be obtained at an
authorized Mercedes-Benz Center or on the
Internet at http://bevo.mercedes-benz.com.
The coolant is checked at every maintenance
interval at an authorized Mercedes-Benz
Center.
The antifreeze/corrosion inhibitor
concentration in the engine cooling system
should:
R be at least 50%. This will protect the engine
cooling system against freezing down to
approximately -35 ‡ (-37 † ).
R not exceed 55% (antifreeze protection to
-49 ‡ [-45 † ]); otherwise, heat will not
dissipate as effectively.
If the coolant level is too low, MB 325.0 or
326.0 anticorrosion/antifreeze should be
added. Have the engine cooling system
checked for possible leaks.
Windshield/headlamp cleaning
system
GWARNING
Washer solvent/antifreeze is highly
flammable. Do not spill washer solvent/
antifreeze on hot engine parts, because it may
Service products and capacities529Technical dataZ