iWhen the message Remaining Starts:
20 appears in the multifunction display, you
can start the engine 20 more times. If you
do not add AdBlue ®
, the engine cannot be
started beyond that point. Fill the
AdBlue ®
tank with approximately 1 gal
(3.79 l) AdBlue ®
(corresponds to
approximately 2 AdBlue ®
refill containers)
or have the AdBlue ®
tank filled by an
authorized Mercedes-Benz Center.
i For refilling outside the maintenance
service intervals, refill the AdBlue ®
tank
with approximately 1 gal (3.79 l) AdBlue ®
(corresponds to approximately 2 AdBlue ®
refill containers).
Always use the particular AdBlue ®
refill
containers for refilling outside the
maintenance service interval. Contact an
authorized Mercedes-Benz Center or call
Roadside Assistance if necessary
( Y page 201).
Additional information on BlueTEC exhaust
gas aftertreatment and AdBlue ®
is available
at any authorized Mercedes-Benz Center.
Refilling with AdBlue ®
GWarning!
Make sure
R AdBlue ®
does not come into contact with
skin, eyes, or clothing
R to keep AdBlue ®
out of the reach of children
If you and/or others have come into contact
with AdBlue ®
:
R If AdBlue ®
has gotten into contact with
eyes, flush with plenty of water immediately
and seek medical help.
R Clean affected skin immediately with plenty
of water.
R If AdBlue ®
was swallowed, rinse mouth
immediately with plenty of water and drink
plenty of water. Consult a physician.GWarning!
When opening the filler cap of the AdBlue ®
tank ammonia gas vapors may escape. Refill
AdBlue ®
in a well ventilated area only.
Ammonia gas vapors have a pungent odor and
are particularly irritating for your skin,
mucous membranes, and eyes. Inhaling
ammonia gas vapors will cause burning eyes,
nose, and throat, as well as coughing and
watering eyes.
! Only use AdBlue ®
complying with
ISO 22241. Do not add additives to
AdBlue ®
and do not dilute AdBlue ®
with
water. Otherwise, the BlueTEC exhaust gas
aftertreatment system could be damaged.
Damage caused by using additives or
diluting with water are not covered by the
Mercedes-Benz Limited Warranty.
! Rinse surfaces that have come into
contact with AdBlue ®
, or remove AdBlue ®
with a moist cloth and cold water
immediately. If AdBlue ®
has crystallized
already, use cold water and a sponge.
AdBlue ®
residues will crystallize and soil
the affected surfaces.
! AdBlue ®
is not a fuel additive and must
not be added to the diesel fuel tank. If
AdBlue ®
reaches the diesel fuel tank, the
engine could be damaged which is not
covered by the Mercedes-Benz Limited
Warranty.
332AdBlue ®
(diesel engine only)Practical hints
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For more information on AdBlue®, see
(Y page 361).
The AdBlue® filler neck is located under the
cargo compartment floor.
XSwitch off the ignition.XOpen the tailgate (Y page 75).XLift the cargo compartment floor
(Y page 268).
XTurn AdBlue® filler cap cover :
counterclockwise and remove it.
XTurn AdBlue® filler cap ;
counterclockwise and open it.
Filler cap ; is tethered with a plastic strap.
XPull dust cap off of AdBlue® refill container
=.
XPlace AdBlue® refill container = on the
filler neck as illustrated and tighten it
moderately (hand-tight) by turning it
clockwise.
! Make sure to tighten the AdBlue® refill
container only moderately, i.e. hand-tight,
as you could otherwise damage it.
XPush AdBlue® refill container = down.
The AdBlue® tank is filled. This may take up
to 1 minute.
iWhen you stop pushing the AdBlue® refill
container down, the filling process is
stopped and you can remove the refill
container.
XRelease AdBlue® refill container =.XTurn AdBlue® refill container =
counterclockwise and remove it.
XPlace AdBlue® filler cap ; (Y page 332) on
filler neck and turn it clockwise.
AdBlue® (diesel engine only)333Practical hints164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 333Z
XPlace AdBlue® filler cap cover : as
illustrated and turn it clockwise to its stop.
XLower cargo compartment floor.XClose the tailgate.XDrive the vehicle at a speed of at least
10 mph (16 km/h).
The message Check Additive See
Operator’s Manual disappears after
approximately 1 minute.
iIf the message Check Additive See
Operator’s Manual still appears in the
multifunction display, refill with one more
container of AdBlue®.
iHave the AdBlue® level checked and, if
necessary, filled completely afterward at
an authorized Mercedes-Benz Center.
Battery
Safety notes
A battery should always be sufficiently
charged in order to achieve its rated service
life. Refer to Maintenance Booklet for battery
maintenance intervals.
If you use your vehicle mostly for short-
distance trips, you will need to have the
battery charge checked more frequently.
When replacing a battery, always use a
battery approved by Mercedes-Benz.
If you do not intend to operate your vehicle
for an extended period of time, contact an
authorized Mercedes-Benz Center about
steps you need to observe.
GWarning!
HYBRID vehicles: It is imperative that you read
the HYBRID Supplemental Operating
Instructions included in your vehicle literature
portfolio. You may otherwise not recognize
potential danger.
GWarning!
Observe all safety instructions and
precautions when handling automotive
batteries.
Risk of explosion.Fire, open flames and
smoking are prohibited
when handling batteries.
Avoid creating sparks.
Battery acid is caustic. Do
not allow it to come into
contact with skin, eyes or
clothing.
Wear suitable protective
clothing, especially gloves,
apron and faceguard.
Wear eye protection.
Rinse any acid spills
immediately with clear
water. Contact a physician
if necessary.
Keep children away.Follow the instructions in
this Operator’s Manual.
A battery contains materials that can harm
the environment if disposed of improperly. A
large 12 V storage battery contains lead.
Recycling of the battery is the preferred
method of disposal. Many states (USA only)
or provinces (Canada only) require sellers of
batteries to accept the old battery for
recycling.
GWarning!
Failure to follow these instructions can result
in severe injury or death.
Never lean over batteries while connecting.
You might get injured.
334BatteryPractical hints
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ModelCapacityFuels, coolants,
lubricants, etc.Brake systemAll models0.63 US qt (0.6 l)MB Brake Fluid
(DOT 4+)Cooling systemML 350 BlueTEC 4MATIC
ML 350 4MATIC
ML 350approx.
10.0 US qt (9.5 l)MB 325.0
Anticorrosion/
AntifreezeML 550 4MATICapprox.
12.7 US qt (12.0 l)ML 63 AMGapprox.
12.2 US qt (11.5 l)Fuel tankAll models25.1 US gal (95.0 l)Gasoline engine:
Premium unleaded
gasoline (Minimum
Posted Octane 91
[Avg. of
96 RON/86 MON])
Diesel engine:
ULTRA-LOW
SULFUR HIGHWAY
DIESEL FUEL
(ULSD, 15 ppm
SULFUR MAXIMUM)Fuel tank
reserveAll models,
except ML 63 AMGapprox.
3.4 US gal (13.0 l)ML 63 AMGapprox.
4.0 US gal (15.0 l)AdBlue ®
tankML 350 BlueTEC 4MATIC7.0 US gal (26.6 l)AdBlue ®
complying
with ISO 22241Air
conditioning
systemAll models—R134a refrigerant
and special
PAG lubricant oil
(never R 12)Washer system
and headlamp
cleaning
systemAll models7.6 US qt (7.2 l)MB Windshield
Washer
Concentrate 61
( Y page 364)
Washer fluid mixing
ratio ( Y page 364)61
Mixed with water or commercially available premixed washer solvent/antifreeze.358Fuels, coolants, lubricants, etc.Technical data
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! Do not fill the tank with gasoline. Do not
blend diesel fuel with gasoline or kerosene.
The fuel system and engine will otherwise
be damaged, which is not covered by the
Mercedes-Benz Limited Warranty.
For further information on diesel fuel pump
labeling, contact an authorized Mercedes-
Benz Center or visit www.mbusa.com (USA
only).
Biodiesel (FAME = Fatty Acid Methyl
Ester) containing fuels
Mercedes-Benz USA approves the use of B5
(standard ULSD which may contain a
maximum of 5% biodiesel) in all Common-rail
injection (CDI) and BlueTEC diesel engines.
Diesel fuels containing a higher percentage of
biodiesel, e.g. B20, as well as straight
biodiesel may cause severe damage to your
engine/fuel system and are not approved.
Please ask your service station personnel for
further information. If the B5 biodiesel blend
is not sufficiently labeled to clearly indicate
that it meets the ULSD standard, please do
not use it.
The Mercedes-Benz Limited Warranty does
not cover damages caused by the use of fuels
not meeting Mercedes-Benz approved fuel
standards.
Gasoline additives (gasoline engine)
A major concern among engine
manufacturers is carbon build-up caused by
gasoline. Mercedes-Benz recommends only
the use of quality gasoline containing
additives that prevent the build-up of carbon
deposits.
After an extended period of using fuels
without such additives carbon deposits can
build up, especially on the intake valves and
in the combustion area, leading to engine
performance problems such as:
R Warm-up hesitation
R Unstable idle
R
Knocking/pinging
R Misfire
R Power loss
In areas where carbon deposits may be
encountered due to lack of availability of
gasoline which contains these additives, the
use of Mercedes-Benz approved additives is
recommended.
Contact an authorized Mercedes-Benz Center
or visit www.mbusa.com (USA only) for a
listing of approved products. Follow
directions on the product label.
Do not blend other fuel additives with fuel.
This only results in unnecessary cost and may
be harmful to the engine operation.
! Damage or malfunction resulting from
poor fuel quality or from blending additional
fuel additives other than those tested and
approved by us for use on Mercedes-Benz
vehicles are not covered by the Mercedes-
Benz Limited Warranty or by any pre-owned
or Extended Limited Warranties.
AdBlue ®
AdBlue ®
is a non-flammable, non-toxic,
colorless and odorless, water-soluble liquid.
! Only use AdBlue ®
complying with
ISO 22241. Do not blend with additives.
! Rinse surfaces that have come into
contact with AdBlue ®
, or remove AdBlue ®
with a moist cloth and cold water
immediately. If AdBlue ®
has crystallized
already, use cold water and a sponge.
AdBlue ®
residues will crystallize and soil
the affected surfaces.
High ambient temperatures
If AdBlue ®
in the reservoir heats up to above
122‡ (50†) for a long period of time, for
example due to direct sunlight, ammonia gas
Fuels, coolants, lubricants, etc.361Technical data164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 361Z
vapors may escape when opening the
AdBlue ®
tank.GWarning!
When opening the filler cap of the AdBlue ®
tank ammonia gas vapors may escape. Refill
AdBlue ®
in a well ventilated area only.
Ammonia gas vapors have a pungent odor and
are particularly irritating for your skin,
mucous membranes, and eyes. Inhaling
ammonia gas vapors will cause burning eyes,
nose, and throat, as well as coughing and
watering eyes.
Low ambient temperatures
AdBlue ®
freezes at a temperature of
approximately 12‡ (-11†). Your vehicle is
factory equipped with an AdBlue ®
preheating
system. The vehicle can thus be operated at
temperatures below 12‡ (-11†).
Special additives
! Only use AdBlue ®
complying with
ISO 22241. Do not add additives to
AdBlue ®
and do not dilute AdBlue ®
with
water. Otherwise, the BlueTEC exhaust gas
aftertreatment system could be damaged.
Damage caused by using additives or
diluting with water are not covered by the
Mercedes-Benz Limited Warranty.
Purity
The purity of AdBlue ®
is of particular
importance for avoiding malfunctions in the
exhaust gas aftertreatment.
If AdBlue ®
is pumped out of the tank, e.g.
during repair work, the same liquid must not
be used to refill the tank as its purity is no
longer guaranteed.
! Impurities caused for example by other
service products, cleaning agents, and dust
result in increased emissions,
malfunctions, catalyst damage, or engine
damage.
Coolants
The engine coolant is a mixture of water and
anticorrosion/antifreeze, which provides:
R Corrosion protection
R Freeze protection
R Boiling protection (by increasing the boiling
point)
The cooling system was filled at the factory
with a coolant providing freeze protection to
approximately -35‡ (-37†) and corrosion
protection.
! Add premixed coolant solution only.
Adding water and MB 325.0 Anticorrosion/
Antifreeze separately from each other,
could cause engine damage not covered by
the Mercedes-Benz Limited Warranty.
If the antifreeze mixture is effective to -35‡
(-37† ), the boiling point of the coolant in the
pressurized cooling system is reached at
approximately 266‡ (130†).
The coolant solution must be used year round
to provide the necessary corrosion protection
and increase boil-over protection. Refer to
the Maintenance Booklet for replacement
interval.
Coolant system design and coolant used
determine the replacement interval. The
replacement interval published in the
Maintenance Booklet is only applicable if
MB 325.0 Anticorrosion/Antifreeze solution
or other Mercedes-Benz approved products
of equal specification are used to renew the
coolant concentration or bring it back up to
the proper level.
For information on other Mercedes-Benz
approved products of equal specification,
contact an authorized Mercedes-Benz Center
or visit www.mbusa.com (USA only).
To provide important corrosion protection,
the solution must be at least 50%
anticorrosion/antifreeze (equivalent to
freeze protection to approximately -35‡
[-37†]).362Fuels, coolants, lubricants, etc.Technical data
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