2010 MERCEDES-BENZ ML350 Additive

significantly shorter or, if the vehicle is driven
cautiously, somewhat longer.
Do not continue driving in emergency mode if
R you notice knocking sounds
R the vehicle starts to shake
R smoke develops and you smell rubber
R ESP ®
is intervening continuously
R you notice tears on the tire sidewalls
After driving in emergency mode, you must
have the rims inspected by an authorized
Mercedes-Benz Center to check if they are
suitable for further use. The failed tire must
be replaced in any case.
When replacing individual or all tires on the
vehicle, make sure only tires marked with
“MOExtended” are mounted in the size
specified for your vehicle ( Y page 352).
Bleeding the fuel system (diesel
engine only)
Driving the vehicle until the fuel tank is empty
is not recommended. Otherwise, air may be
sucked into the fuel system. If this happens,
the malfunction indicator lamp = (USA
only) or ; (Canada only) comes on and the
engine may not start immediately after
refueling the vehicle.
After refueling:
XMake sure the automatic transmission is in
park position P.
The transmission position indicator in the
multifunction display should be on P.XDo not depress the accelerator.XIf necessary, remove the KEYLESS-GO
start/stop button from the starter switch.XTurn the SmartKey in the starter switch to
position 2 for at least 10 seconds.XReturn the SmartKey in the starter switch
to position 0.XTurn the SmartKey in the starter switch to
position 3 and hold it there for a maximumof 10 seconds or until the engine runs
surge-free.
If the engine does not start:
XTurn the SmartKey in the starter switch
once more to position 2 for at least
10 seconds.XReturn the SmartKey in the starter switch
to position 0.XTurn the SmartKey in the starter switch
once more to position 3 and hold it there
for a maximum of 10 seconds or until the
engine runs surge-free.XIf necessary, repeat the above steps.
If the engine still does not start after
3 attempts:
Do not make any further attempts to start the
engine. Contact an authorized Mercedes-
Benz Center or call Roadside Assistance
( Y page 201).
i When the malfunction indicator lamp
= (USA only) or ; (Canada only) in
the instrument cluster has been illuminated
for the above condition, it will remain
illuminated until the engine was cycled on
and off four times in a row.
AdBlue ®
(diesel engine only)
The BlueTEC exhaust gas aftertreatment
system requires a reducing agent (AdBlue ®
)
in order to function properly. Refilling with
AdBlue ®
is part of the regular maintenance
service work. A tankful of AdBlue ®
should
suffice until the next maintenance service
under normal driving conditions.
When the AdBlue ®
tank is low, the message
Check Additive See Operator’s
Manual appears in the multifunction display.
When the AdBlue ®
level drops to the
minimum level, the message Remaining
Starts: 20 appears in the multifunction
display.
AdBlue ®
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iWhen the message Remaining Starts:
20 appears in the multifunction display, you
can start the engine 20 more times. If you
do not add AdBlue ®
, the engine cannot be
started beyond that point. Fill the
AdBlue ®
tank with approximately 1 gal
(3.79 l) AdBlue ®
(corresponds to
approximately 2 AdBlue ®
refill containers)
or have the AdBlue ®
tank filled by an
authorized Mercedes-Benz Center.
i For refilling outside the maintenance
service intervals, refill the AdBlue ®
tank
with approximately 1 gal (3.79 l) AdBlue ®
(corresponds to approximately 2 AdBlue ®
refill containers).
Always use the particular AdBlue ®
refill
containers for refilling outside the
maintenance service interval. Contact an
authorized Mercedes-Benz Center or call
Roadside Assistance if necessary
( Y page 201).
Additional information on BlueTEC exhaust
gas aftertreatment and AdBlue ®
is available
at any authorized Mercedes-Benz Center.
Refilling with AdBlue ®

GWarning!
Make sure
R AdBlue ®
does not come into contact with
skin, eyes, or clothing
R to keep AdBlue ®
out of the reach of children
If you and/or others have come into contact
with AdBlue ®
:
R If AdBlue ®
has gotten into contact with
eyes, flush with plenty of water immediately
and seek medical help.
R Clean affected skin immediately with plenty
of water.
R If AdBlue ®
was swallowed, rinse mouth
immediately with plenty of water and drink
plenty of water. Consult a physician.GWarning!
When opening the filler cap of the AdBlue ®
tank ammonia gas vapors may escape. Refill
AdBlue ®
in a well ventilated area only.
Ammonia gas vapors have a pungent odor and
are particularly irritating for your skin,
mucous membranes, and eyes. Inhaling
ammonia gas vapors will cause burning eyes,
nose, and throat, as well as coughing and
watering eyes.
! Only use AdBlue ®
complying with
ISO 22241. Do not add additives to
AdBlue ®
and do not dilute AdBlue ®
with
water. Otherwise, the BlueTEC exhaust gas
aftertreatment system could be damaged.
Damage caused by using additives or
diluting with water are not covered by the
Mercedes-Benz Limited Warranty.
! Rinse surfaces that have come into
contact with AdBlue ®
, or remove AdBlue ®
with a moist cloth and cold water
immediately. If AdBlue ®
has crystallized
already, use cold water and a sponge.
AdBlue ®
residues will crystallize and soil
the affected surfaces.
! AdBlue ®
is not a fuel additive and must
not be added to the diesel fuel tank. If
AdBlue ®
reaches the diesel fuel tank, the
engine could be damaged which is not
covered by the Mercedes-Benz Limited
Warranty.
332AdBlue ®
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XPlace AdBlue® filler cap cover : as
illustrated and turn it clockwise to its stop.
XLower cargo compartment floor.XClose the tailgate.XDrive the vehicle at a speed of at least
10 mph (16 km/h).
The message Check Additive See
Operator’s Manual disappears after
approximately 1 minute.
iIf the message Check Additive See
Operator’s Manual still appears in the
multifunction display, refill with one more
container of AdBlue®.
iHave the AdBlue® level checked and, if
necessary, filled completely afterward at
an authorized Mercedes-Benz Center.
Battery
Safety notes
A battery should always be sufficiently
charged in order to achieve its rated service
life. Refer to Maintenance Booklet for battery
maintenance intervals.
If you use your vehicle mostly for short-
distance trips, you will need to have the
battery charge checked more frequently.
When replacing a battery, always use a
battery approved by Mercedes-Benz.
If you do not intend to operate your vehicle
for an extended period of time, contact an
authorized Mercedes-Benz Center about
steps you need to observe.
GWarning!
HYBRID vehicles: It is imperative that you read
the HYBRID Supplemental Operating
Instructions included in your vehicle literature
portfolio. You may otherwise not recognize
potential danger.
GWarning!
Observe all safety instructions and
precautions when handling automotive
batteries.
Risk of explosion.Fire, open flames and
smoking are prohibited
when handling batteries.
Avoid creating sparks.
Battery acid is caustic. Do
not allow it to come into
contact with skin, eyes or
clothing.
Wear suitable protective
clothing, especially gloves,
apron and faceguard.
Wear eye protection.
Rinse any acid spills
immediately with clear
water. Contact a physician
if necessary.
Keep children away.Follow the instructions in
this Operator’s Manual.
A battery contains materials that can harm
the environment if disposed of improperly. A
large 12 V storage battery contains lead.
Recycling of the battery is the preferred
method of disposal. Many states (USA only)
or provinces (Canada only) require sellers of
batteries to accept the old battery for
recycling.
GWarning!
Failure to follow these instructions can result
in severe injury or death.
Never lean over batteries while connecting.
You might get injured.
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Approved engine oils
Engine oils are specifically tested for their
suitability in our engines and durability for our
service intervals. Therefore, only use
approved engine oils and oil filters required
for vehicles with the Maintenance System.
For a listing of approved engine oils and oil
filters, contact an authorized Mercedes-Benz
Center or visit www.mbusa.com (USA only).
! Using engine oils and oil filters of a
specification other than those expressly
required for the Maintenance System, or
changing of oil and oil filter at change
intervals longer than those called for by the
Maintenance System will result in engine or
emission control system damage not
covered by the Mercedes-Benz Limited
Warranty.
Please follow Maintenance System
recommendations for scheduled oil
changes. Failure to do so will result in
engine or emission control system damage
not covered by the Mercedes-Benz Limited
Warranty.
Mercedes-Benz recommends MOBIL OIL.
Use the table below to determine the
MB sheet number.
ModelEngine,
type
MB sheet
number
ML 350 BlueTEC
4MATIC
642229.51ML 350 4MATIC272229.5ML 350272229.3/
229.5
ML 550 4MATIC273229.5ML 63 AMG156229.562
iMB sheet numbers are printed on the
outside of oil containers.
Viscosity grades for engine oils
Using the chart below, select oil viscosity
according to the lowest air temperature
expected before the next oil change.
Engine oil additives
! Do not blend oil additives with engine oil.
They may damage the engine. Damage or
malfunctions resulting from blending oil
additives are not covered by the Mercedes-
Benz Limited Warranty.
Air conditioning refrigerant
R134a (HFC) refrigerant and special PAG
lubricating oil are used in the air conditioning
system.
! Never use R 12 (CFC) or mineral-based
lubricating oil. Otherwise damage to the
system will occur.
Brake fluid
GWarning!
During vehicle operation, the boiling point of
the brake fluid is continuously reduced
through the absorption of moisture from the
atmosphere.
Under extremely strenuous operating
conditions, this moisture content can lead to
62Restriction: Only SAE 0W-40/SAE 5W-40 engine oils may be used.Fuels, coolants, lubricants, etc.359Technical data164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 359Z

! Do not fill the tank with gasoline. Do not
blend diesel fuel with gasoline or kerosene.
The fuel system and engine will otherwise
be damaged, which is not covered by the
Mercedes-Benz Limited Warranty.
For further information on diesel fuel pump
labeling, contact an authorized Mercedes-
Benz Center or visit www.mbusa.com (USA
only).
Biodiesel (FAME = Fatty Acid Methyl
Ester) containing fuels
Mercedes-Benz USA approves the use of B5
(standard ULSD which may contain a
maximum of 5% biodiesel) in all Common-rail
injection (CDI) and BlueTEC diesel engines.
Diesel fuels containing a higher percentage of
biodiesel, e.g. B20, as well as straight
biodiesel may cause severe damage to your
engine/fuel system and are not approved.
Please ask your service station personnel for
further information. If the B5 biodiesel blend
is not sufficiently labeled to clearly indicate
that it meets the ULSD standard, please do
not use it.
The Mercedes-Benz Limited Warranty does
not cover damages caused by the use of fuels
not meeting Mercedes-Benz approved fuel
standards.
Gasoline additives (gasoline engine)
A major concern among engine
manufacturers is carbon build-up caused by
gasoline. Mercedes-Benz recommends only
the use of quality gasoline containing
additives that prevent the build-up of carbon
deposits.
After an extended period of using fuels
without such additives carbon deposits can
build up, especially on the intake valves and
in the combustion area, leading to engine
performance problems such as:
R Warm-up hesitation
R Unstable idle
R
Knocking/pinging
R Misfire
R Power loss
In areas where carbon deposits may be
encountered due to lack of availability of
gasoline which contains these additives, the
use of Mercedes-Benz approved additives is
recommended.
Contact an authorized Mercedes-Benz Center
or visit www.mbusa.com (USA only) for a
listing of approved products. Follow
directions on the product label.
Do not blend other fuel additives with fuel.
This only results in unnecessary cost and may
be harmful to the engine operation.
! Damage or malfunction resulting from
poor fuel quality or from blending additional
fuel additives other than those tested and
approved by us for use on Mercedes-Benz
vehicles are not covered by the Mercedes-
Benz Limited Warranty or by any pre-owned
or Extended Limited Warranties.
AdBlue ®
AdBlue ®
is a non-flammable, non-toxic,
colorless and odorless, water-soluble liquid.
! Only use AdBlue ®
complying with
ISO 22241. Do not blend with additives.
! Rinse surfaces that have come into
contact with AdBlue ®
, or remove AdBlue ®
with a moist cloth and cold water
immediately. If AdBlue ®
has crystallized
already, use cold water and a sponge.
AdBlue ®
residues will crystallize and soil
the affected surfaces.
High ambient temperatures
If AdBlue ®
in the reservoir heats up to above
122‡ (50†) for a long period of time, for
example due to direct sunlight, ammonia gas
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vapors may escape when opening the
AdBlue ®
tank.GWarning!
When opening the filler cap of the AdBlue ®
tank ammonia gas vapors may escape. Refill
AdBlue ®
in a well ventilated area only.
Ammonia gas vapors have a pungent odor and
are particularly irritating for your skin,
mucous membranes, and eyes. Inhaling
ammonia gas vapors will cause burning eyes,
nose, and throat, as well as coughing and
watering eyes.
Low ambient temperatures
AdBlue ®
freezes at a temperature of
approximately 12‡ (-11†). Your vehicle is
factory equipped with an AdBlue ®
preheating
system. The vehicle can thus be operated at
temperatures below 12‡ (-11†).
Special additives
! Only use AdBlue ®
complying with
ISO 22241. Do not add additives to
AdBlue ®
and do not dilute AdBlue ®
with
water. Otherwise, the BlueTEC exhaust gas
aftertreatment system could be damaged.
Damage caused by using additives or
diluting with water are not covered by the
Mercedes-Benz Limited Warranty.
Purity
The purity of AdBlue ®
is of particular
importance for avoiding malfunctions in the
exhaust gas aftertreatment.
If AdBlue ®
is pumped out of the tank, e.g.
during repair work, the same liquid must not
be used to refill the tank as its purity is no
longer guaranteed.
! Impurities caused for example by other
service products, cleaning agents, and dust
result in increased emissions,
malfunctions, catalyst damage, or engine
damage.
Coolants
The engine coolant is a mixture of water and
anticorrosion/antifreeze, which provides:
R Corrosion protection
R Freeze protection
R Boiling protection (by increasing the boiling
point)
The cooling system was filled at the factory
with a coolant providing freeze protection to
approximately -35‡ (-37†) and corrosion
protection.
! Add premixed coolant solution only.
Adding water and MB 325.0 Anticorrosion/
Antifreeze separately from each other,
could cause engine damage not covered by
the Mercedes-Benz Limited Warranty.
If the antifreeze mixture is effective to -35‡
(-37† ), the boiling point of the coolant in the
pressurized cooling system is reached at
approximately 266‡ (130†).
The coolant solution must be used year round
to provide the necessary corrosion protection
and increase boil-over protection. Refer to
the Maintenance Booklet for replacement
interval.
Coolant system design and coolant used
determine the replacement interval. The
replacement interval published in the
Maintenance Booklet is only applicable if
MB 325.0 Anticorrosion/Antifreeze solution
or other Mercedes-Benz approved products
of equal specification are used to renew the
coolant concentration or bring it back up to
the proper level.
For information on other Mercedes-Benz
approved products of equal specification,
contact an authorized Mercedes-Benz Center
or visit www.mbusa.com (USA only).
To provide important corrosion protection,
the solution must be at least 50%
anticorrosion/antifreeze (equivalent to
freeze protection to approximately -35‡
[-37†]).362Fuels, coolants, lubricants, etc.Technical data
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