2006 MERCEDES-BENZ ML500 gasoline

Contents
Replacing bulbs ................................. 443
Bulbs ............................................ 443
Replacing bulbs for front lamps ... 445
Replacing bulbs for rear lamps..... 450
Adjusting headlamp aim............... 451
Replacing wiper blades ...................... 453
Removing front wiper blades........ 453
Installing front wiper blades ......... 453
Removing rear wiper blade........... 454
Installing rear wiper blade ............ 455
Flat tire .............................................. 456
Preparing the vehicle ................... 456
Mounting the spare wheel............ 457
Battery ............................................... 462
Disconnecting, removing,
reinstalling and
reconnecting the battery.............. 464
Charging the battery .................... 469
Jump starting ..................................... 470
Towing the vehicle ............................. 472
Installing towing eye bolt ............. 474
Stranded vehicle .......................... 476Fuses .................................................. 477
Aids for changing fuses................. 478
Main fuse box ............................... 478
Fuse box in
cargo compartment ...................... 479
Fuse box in
passenger compartment ............... 479
Technical data.................................. 481
Parts service....................................... 482
Warranty coverage ............................. 483
Loss of Service and Warranty
Information Booklet ...................... 483
Identification labels ............................ 484
Layout of poly-V-belt drive .................. 485
ML 350 ......................................... 485
ML 500 ......................................... 485
Engine ................................................ 486
Rims and tires .................................... 487
Rims and tires ............................... 488
Minispare wheel............................ 489Electrical system ................................ 490
Main Dimensions................................ 491
Weights .............................................. 492
Fuels, coolants, lubricants, etc. .......... 493
Capacities ..................................... 493
Engine oils .................................... 495
Engine oil additives ....................... 495
Air conditioning refrigerant ........... 495
Brake fluid .................................... 495
Premium unleaded gasoline.......... 496
Fuel requirements......................... 496
Gasoline additives......................... 497
Coolants ....................................... 497
Windshield washer and
headlamp cleaning* system ......... 500
Windshield and headlamp
washer fluid mixing ratio............... 500
Technical terms............................... 501Index................................................. 507

13 Introduction
Operator’s Manual
Change of address or ownership
If you change your address, be sure to
send in the “Change of Address Notice”
found in the Service and Warranty Informa-
tion Booklet, or simply call the
Mercedes-Benz Customer Assistance
Center (in the USA) at
1-800-FOR-MERCedes, or Customer Ser-
vice (in Canada) at 1-800-387-0100. It is in
your own interest that we can contact you
should the need arise.
If you sell your Mercedes, please leave all
literature with the vehicle to make it avail-
able to the next operator.
If you bought this vehicle used, be sure to
send in the “Notice of Purchase of Used
Truck” found in the Service and Warranty
Information Booklet, or call the
Mercedes-Benz Customer Assistance Cen-
ter (in the USA) at 1-800-FOR-MERCedes,
or Customer Service (in Canada) at
1-800-387-0100.Operating your vehicle outside the USA
or Canada
If you plan to operate your vehicle in for-
eign countries, please be aware that:

service facilities or replacement parts
may not be readily available,


unleaded gasoline for vehicles with cat-
alytic converters may not be available;
the use of leaded fuels will damage the
catalysts,


gasoline may have a considerably low-
er octane rating, and improper fuel can
cause engine damage.Certain Mercedes-Benz models are avail-
able for delivery in Europe under our Euro-
pean Delivery Program. For details, consult
an authorized Mercedes-Benz Light Truck
Center or write to:
In the USA:
Mercedes-Benz USA, LLC
European Delivery Department
One Mercedes Drive
Montvale, NJ 07645-0350
In Canada:
Mercedes-Benz Canada, Inc.
European Delivery Department
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9

58 Getting startedDriving6Symbol in multifunction display indicat-
ing that rear window wiper is activated
Switch on the ignition (
page 34).
Activating intermittent wiping

Turn switch1 to position3.
Deactivating intermittent wiping

Turn switch1 to position4.Wiping with windshield washer fluid

Turn switch1 to position2 or5.
The rear window wiper operates with
washer fluid.
Hold switch1 in position2 or5
until the rear window is clean.
For information on filling up the washer
reservoir, see “Windshield/rear window
washer system and headlamp cleaning
system*” (
page 333).
Problems while driving
The engine runs erratically and misfires

An ignition cable may be damaged.


The engine electronics may not be
operating properly.


Unburned gasoline may have entered
the catalytic converter and damaged it.

Give very little gas.

Have the problem repaired by an au-
thorized Mercedes-Benz Light Truck
Center as soon as possible.
iThe rear window wiper engages auto-
matically if the automatic transmission
is shifted to positionR with the wind-
shield wipers switched on.


320 OperationDriving instructionsControl and operation of radio transmitters
Modular COMAND System, radio and
telephone*Telephones and two-way radios
Radio transmitters, such as a portable
telephone or a citizens band unit should
only be used inside the vehicle if they are
connected to an antenna that is installed
on the outside of the vehicle.
Refer to the radio transmitter operation
instructions regarding use of an external
antenna.
Catalytic converter
Your Mercedes-Benz is equipped with
monolithic-type catalytic converters, an
important element in conjunction with the
oxygen sensors to achieve substantial con-
trol of the pollutants in the exhaust emis-
sions. Keep your vehicle in proper
operating condition by following our rec-
ommended maintenance instructions as
outlined in your Maintenance Booklet.
Warning!
G
Do not forget that your primary responsibili-
ty is to drive the vehicle. Only operate the
Modular COMAND System, radio or
telephone
1 if road, weather and traffic con-
ditions permit.
Bear in mind that at a speed of just 30 mph
(approximately 50 km/h), your vehicle is
covering a distance of 44 feet (approximate-
ly 14 m) every second.
1Observe all legal requirements.
Warning!
G
Never operate radio transmitters equipped
with a built-in or attached antenna (i.e. with-
out being connected to an external antenna)
from inside the vehicle while the engine is
running. Doing so could lead to a malfunc-
tion of the vehicle’s electronic system,
possibly resulting in an accident and/or
personal injury.
!To prevent damage to the catalytic con-
verters, use only premium unleaded
gasoline in this vehicle.
Any noticeable irregularities in engine
operation should be repaired promptly.
Otherwise, excessive unburned fuel
may reach the catalytic converter,
causing it to overheat and potentially
start a fire.

323 Operation
At the gas station
At the gas station
Refueling
The fuel filler flap is located on the
right-hand side of the vehicle towards the
rear. Locking/unlocking the vehicle with
the SmartKey or the SmartKey with
KEYLESS-GO* automatically
locks/unlocks the fuel filler flap.

Turn the engine off

by turning the SmartKey to
position0. Remove the SmartKey
from the starter switch.


by pressing the KEYLESS-GO*
start/stop button (
page 35).
Open the driver’s door (with the
driver’s door open, starter switch is
now in position0, same as
SmartKey removed from starter
switch).

Open the fuel filler flap by pushing at
the point indicated by the arrow.
The fuel filler flap springs open.

Turn the fuel cap to the left and hold on
to it until possible pressure is released.

Take off the cap.
To prevent fuel vapors from escaping
into open air, fully insert filler nozzle
unit.

Only fill your tank until the filler nozzle
unit cuts out - do not top up or over-
fill.
Warning!
G
Gasoline is highly flammable and poisonous.
It burns violently and can cause serious
injury. Whenever you are around gasoline,
avoid inhaling fumes and skin contact, extin-
guish all smoking materials. Never allow
sparks, flame or smoking materials near
gasoline!
Warning!
G
Overfilling of the fuel tank may create pres-
sure in the system which could cause a gas
discharge. This could cause the gas to spray
back out when removing the fuel pump noz-
zle, which could cause personal injury.


324 OperationAt the gas station
Replace the fuel cap by turning it
clockwise until it audibly engages.

Close the fuel filler flap.
Check regularly and before a long trip
Open the hood (
page 326).
Example ML 5001Brake fluid
2Coolant level
3Windshield washer system and
headlamp cleaning system*
Engine oil level
For more information on engine oil, see
“Engine oil” (
page 327).Brake fluid
Coolant
For normal replenishing, use water (pota-
ble water quality).
For more information, see “Coolant level”
(
page 332) and see “Fuels, coolants, lu-
bricants, etc.” (
page 493).
iOnly use premium unleaded gasoline
with a minimum Posted Octane Rating
of 91 (average of 96 RON/86 MON).
Information on gasoline quality can
normally be found on the fuel pump.
For more information on gasoline, see
the Factory Approved Service Products
pamphlet.iLeaving the engine running and the fuel
cap open can cause the yellow engine
malfunction indicator lamp
?(USA only), ±(Canada only)
to illuminate.
For more information, see “Practical
hints” (
page 385).
!If you find that the brake fluid in the
brake fluid reservoir has fallen to the
minimum mark or below, have the
brake system checked for brake pad
thickness and leaks immediately. Noti-
fy an authorized Mercedes-Benz Light
Truck Center immediately. Do not add
brake fluid as this will not solve the
problem. For more information, see
“Practical hints” (
page 381).


337 Operation
Tires and wheels
Tread depth
Do not allow your tires to wear down too
far. Adhesion properties on wet roads are
sharply reduced at tread depths under 1/8in (3 mm).
Treadwear indicators (TWI) are required by
law. These indicators are located in six
places on the tread circumference and
become visible at a tread depth of approx-
imately
1/16
in (1.6 mm), at which point
the tire is considered worn and should be
replaced.
Recommended minimum tire tread depth:


Summer tires
1/8in (3 mm)


Winter tires
1/6in (4 mm)
1TWI (T
read W
ear I
ndicator)
The treadwear indicator appears as a solid
band across the tread.Storing tires
Cleaning tires
Warning!
G
Although the applicable federal motor safety
laws consider a tire to be worn when the
treadwear indicators (TWI) become visible at
approximately
1/16in (1.6 mm), we recom-
mend that you do not allow your tires
to wear down to that level. As tread depth
approaches
1/8in (3 mm), the adhesion
properties on a wet road are sharply re-
duced.
Depending upon the weather and/or road
surface (conditions), the tire traction varies
widely.
!Keep unmounted tires in a cool, dry
place with as little exposure to light as
possible. Protect tires from contact
with oil, grease and gasoline.!Never use a round nozzle to power
wash tires. The intense jet of water can
result in damage to the tire.
Always replace a damaged tire.

486 Technical dataEngineModel
ML 350 (164.186
1)
1The quoted data apply only to the standard vehicle. See an authorized Mercedes-Benz Light Truck Center for the corresponding data of all special bodies and special
equipment.
ML 500 (164.175
1)
Engine
272
113
Mode of operation
4-stroke engine, gasoline injection
4-stroke engine, gasoline injection
No. of cylinders
6
8
Bore
3.66 in (92.90 mm)
3.81 in (97.00 mm)
Stroke
3.38 in (86.00 mm)
3.31 in (84.00 mm)
Total piston displacement
213 cu in (3498 cm
3)
303 cu in (4966 cm
3)
Compression ratio
10.7:1
10:1
Output acc. to SAE J 1349
268 hp/6000 rpm
2
(200 kW/6000 rpm)
2Premium fuel required. Performance may vary with fuel octane rating.
302 hp/5600 rpm
2
(225 kW/5600 rpm)
Maximum torque acc. to SAE J 1349
258 lb-ft/2400-5000 rpm
(350 Nm/2400-5000 rpm)
339 lb-ft/2700-4750 rpm
(460 Nm/2700-4750 rpm)
Maximum engine speed
6500 rpm
6300 rpm
Firing order
1-4-3-6-2-5
1-5-4-2-6-3-7-8
Poly-V-belt
2 404 mm
2370 mm